CN103865329A - Environment-friendly hydrophilic engraved intaglio plate ink and preparation method thereof - Google Patents
Environment-friendly hydrophilic engraved intaglio plate ink and preparation method thereof Download PDFInfo
- Publication number
- CN103865329A CN103865329A CN201410103459.4A CN201410103459A CN103865329A CN 103865329 A CN103865329 A CN 103865329A CN 201410103459 A CN201410103459 A CN 201410103459A CN 103865329 A CN103865329 A CN 103865329A
- Authority
- CN
- China
- Prior art keywords
- ink
- environment
- low
- parts
- melting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses environment-friendly hydrophilic engraved intaglio plate ink and a preparation method thereof. The environment-friendly hydrophilic engraved intaglio plate ink comprises the following components in parts by weight: 10 to 40 parts of alkyd resin linking material, 5 to 30 parts of phenolic resin linking material, 5 to 35 parts of high-viscosity phenolic resin linking material, 5 to 30 parts of pigment, 2 to 15 parts of wax, 0 to 8 parts of drying agent, 10 to 80 parts of filler and 0 to 15 parts of solvent. The ink is applicable to an engraved intaglio plate printer at a high speed (8,000 to 10,000 large pieces of paper per hour), shows high printing adaptation, meets a water wiping plate system, and also reaches international general standards of paper money in terms of materialization resistance and machine washing resistance.
Description
Technical field
The present invention relates to a kind of carving intaglio printing ink.
Background technology
In recent years, along with the development of industrial technology, be applied to the challenge that the intaglio ink technology in false proof field is subject to aspect environment protection more and more higher.How further reducing organic volatilizable thing (VOC) in engraving intaglio printing ink becomes Ge great ink supplier's research topic.Meanwhile, in printing process, need to use contain the alkaloids such as sodium hydroxide and romote antiquity oily substance wiping version liquid wipes edition and aftertreatment, produced a large amount of need industrial organic waste water to be processed, larger to the harm of environment.Therefore the content that, how to reduce organic volatilizable thing becomes the trend of environmental protection ink development.
Organic volatilizable thing comes from the production building-up process of low-melting ink vehicle on the one hand, and it is used for the synthetic of solvent method low-melting ink vehicle as azeotropic solvent, can also add in low-melting ink vehicle as the component that regulates low-melting ink vehicle rheological property; On the other hand, it,, also as a component in ink formulations, becomes an organic component of ink, in the production process and application process of ink, also needs to use solvent to regulate to promote its performance.Therefore, how effectively to reduce in low-melting ink vehicle and ink formulations the content of the organic volatilizable thing of required use in production process extremely, do not affect again the printability of ink on printing press, become a direction of ink applied research simultaneously.
Summary of the invention
The object of this invention is to provide a kind of environment-friendly type wetting ability plate engraving ink and preparation method thereof, the defect existing to overcome prior art.
Environment-friendly type wetting ability plate engraving ink of the present invention, comprises the component of following parts by weight:
Preferably, described environment-friendly type wetting ability plate engraving ink, comprises the component of following parts by weight:
Described Synolac class low-melting ink vehicle is the polyurethane-modified hydrophilic polyol acid resin that is applicable to pure water wiping environment-friendly type intaglio ink, and preferably adopting ZhongChao printing ink Co., Ltd's trade mark is the product of AA-1;
Described resol low-melting ink vehicle is the high acid value rosin modified phenolic resin class low-melting ink vehicle that is applicable to intaglio ink, and the resol class low-melting ink vehicle of high viscosity; The product that preferably employing is AA-2 as ZhongChao printing ink Co., Ltd's trade mark;
The product that it is AA-3 that described high viscosity resol low-melting ink vehicle preferably adopts as ZhongChao printing ink Co., Ltd's trade mark;
Described pigment comprises various high patience pigment, as azo pigment, pyrazoline ketone pigment, sulfonaphthol class, phthalocyanine pigment etc.;
Described filler comprises various natural and synthetic calcium carbonate, kaolin, talcum powder etc.;
Described wax class is various natural and synthetic waxs etc., as carnauba wax, Ka Naba wax, oxidized polyethlene wax;
Described siccative class is that effective constituent is the organic salts such as cobalt metal, manganese, zirconium, iron, cerium, calcium, as manganese iso-octoate, manganese iso-octoate, zirconium iso-octoate;
Described solvent is humatite solvent and plant oil solvent, and the boiling range of humatite oils solvent is between 200 to 230 ℃.
The preparation method of described environment-friendly type wetting ability plate engraving ink, comprises the following steps:
By the solvent of Synolac low-melting ink vehicle, resol low-melting ink vehicle, pigment, filler, wax class and gross weight 30～40%, stir, then transfer on three roller ink grinding mills and be rolled, add remaining solvent and siccative can obtain product.
The ink preparing is adapted at a high speed the engraving plate printer of (8000 to 10000 large per hour), and printability is good, meets water and wipes version system, and materialization patience, resistance to machine washing performance meet banknote general international standard.
Ink detects according to the method for " mensuration of content of volatile organic compound in < HJ/T370-2007 environmental labelling product technical requirements > appendix A product ", and content of volatile organic compound is 8%.
The present invention starts with from the main low-melting ink vehicle of ink, from the wetting ability of Synolac and resol oil two aspects raising low-melting ink vehicles, meets the requirement of environmental protection Chemicals respectively.Synolac is introduced the material such as polyoxyethylene glycol, TriMethylolPropane(TMP) that can strengthen the finished product hydrophilicity from starting material in building-up process, react with linolic acid, the tung oil acid that can promote dryness, finally use the modifications such as tolylene diisocyanate, promote and wiped the cleaning performance of version liquid to ink, can also reduce the content of organic volatilizable thing in ink simultaneously.Take these two kinds of low-melting ink vehicles as main body, add auxiliary low-melting ink vehicle, pigment, filler, additive of other types etc., through rolling processing, the ink that production obtains, the content of its organic volatilizable thing reduces, and does not affect printability on the machine of ink simultaneously, can meet the printing demand of existing seal paper money equipment, product svelteness, gravure printed hand feel is good.Under high speed printing, to wipe alkaloids usage quantity in version liquid and can be reduced to 0.2%, romote antiquity, oily substance usage quantity can be reduced to 0.1%, did not occur set-off phenomenon, had reduced difficulty, the intensity of banknote printing ink wastewater treatment.Physical chemistry patience, the resistance to machine washing performance of printing meet banknote general international standard.
Embodiment
In embodiment, if no special instructions, component is weight part.
In embodiment, raw material sources:
Synolac: the product that company of the ZhongChao printing ink Co., Ltd trade mark is AA-1;
Plant oil modified high acid value resol low-melting ink vehicle: the product that ZhongChao printing ink Co., Ltd's trade mark is AA-2;
High viscosity resol low-melting ink vehicle: the product that ZhongChao printing ink Co., Ltd's trade mark is AA-3;
Embodiment 1
Formula:
Press gravure ink manufacturing process rolling three times, obtain a kind of plate engraving ink.Detected result: viscosity is 12.0Pa.s/40 ℃, the set time is 14h, and resistance to rubbing is 5 grades, and alkaline-resisting is 5 grades, and acidproof is 5 grades, resistance to ethanol is 5 grades.This ink can directly use pure water to wipe version being applied in intaglio ink, not set-off is received class tensio-active agent without sulforicinoleic acid; Do not contain alkaloids.
Embodiment 2
20 parts of Synolac
13 parts of plant oil modified high acid value resol low-melting ink vehicles
17 parts of high viscosity resol low-melting ink vehicles
24 parts of permanent yellow pigment
20 parts, calcium carbonate
3 parts of carnauba waxs
1.5 parts of % of manganese iso-octoate
Petroleum solvent (boiling range: 170 ℃～210 ℃) 1.5%
Press gravure ink manufacturing process rolling three times, obtain a kind of plate engraving ink.Detected result: viscosity is 11.0Pa.s/40 ℃, the set time is 15h, and resistance to rubbing is 5 grades, and alkaline-resisting is 5 grades, and acidproof is 5 grades, resistance to ethanol is 5 grades.This ink can directly use pure water to wipe version being applied in intaglio ink, not set-off is received class tensio-active agent without sulforicinoleic acid; Do not contain alkaloids.
Claims (6)
1. environment-friendly type wetting ability plate engraving ink, is characterized in that, comprises the component of following parts by weight:
2. environment-friendly type wetting ability plate engraving ink according to claim 1, is characterized in that, comprises the component of following parts by weight:
3. environment-friendly type wetting ability plate engraving ink according to claim 1 and 2, is characterized in that, described Synolac class low-melting ink vehicle is the polyurethane-modified hydrophilic polyol acid resin that is applicable to pure water wiping environment-friendly type intaglio ink;
Described resol low-melting ink vehicle is the high acid value rosin modified phenolic resin class low-melting ink vehicle that is applicable to intaglio ink, and the resol class low-melting ink vehicle of high viscosity.
4. environment-friendly type wetting ability plate engraving ink according to claim 3, is characterized in that, described Synolac class low-melting ink vehicle is that ZhongChao printing ink Co., Ltd's trade mark is the product of AA-1;
Described resol low-melting ink vehicle is that ZhongChao printing ink Co., Ltd's trade mark is the product of AA-2;
The product that it is AA-3 that described high viscosity resol low-melting ink vehicle preferably adopts as ZhongChao printing ink Co., Ltd's trade mark.
5. environment-friendly type wetting ability plate engraving ink according to claim 1 and 2, is characterized in that, described pigment is azo pigment, pyrazoline ketone pigment, sulfonaphthol class or phthalocyanine pigment;
Described filler is calcium carbonate, kaolin or talcum powder;
Described wax class is carnauba wax, Ka Naba wax or oxidized polyethlene wax;
Described siccative is that effective constituent is the organic salt of cobalt metal, manganese, zirconium, iron, cerium or calcium;
Described solvent is humatite solvent or plant oil solvent, and the boiling range of humatite oils solvent is between 200 to 230 ℃.
6. according to the preparation method of the environment-friendly type wetting ability plate engraving ink described in claim 1～5 any one, it is characterized in that, comprise the following steps: by the solvent of Synolac low-melting ink vehicle, resol low-melting ink vehicle, pigment, filler, wax class and gross weight 30～40%, stir, then transfer on three roller ink grinding mills and be rolled, add remaining solvent and siccative can obtain product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410103459.4A CN103865329A (en) | 2014-03-19 | 2014-03-19 | Environment-friendly hydrophilic engraved intaglio plate ink and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410103459.4A CN103865329A (en) | 2014-03-19 | 2014-03-19 | Environment-friendly hydrophilic engraved intaglio plate ink and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103865329A true CN103865329A (en) | 2014-06-18 |
Family
ID=50904367
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410103459.4A Pending CN103865329A (en) | 2014-03-19 | 2014-03-19 | Environment-friendly hydrophilic engraved intaglio plate ink and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103865329A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107183171A (en) * | 2017-06-23 | 2017-09-22 | 深圳市裕同包装科技股份有限公司 | A kind of fruit active fresh-keeping ink and its preparation technology |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475765A (en) * | 2009-01-13 | 2009-07-08 | 中国印钞造币总公司 | Upconversion printing ink for intaglio printing |
| CN102558955A (en) * | 2012-01-09 | 2012-07-11 | 西安印钞有限公司 | Carving gravure printing ink applicable to non-absorbent printed material and connecting materials of carving gravure printing ink |
| CN103204984A (en) * | 2013-04-17 | 2013-07-17 | 中钞油墨有限公司 | Polyurethane-modified hydrophilic alkyd resin binder for water erasing of intaglio printing ink |
-
2014
- 2014-03-19 CN CN201410103459.4A patent/CN103865329A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101475765A (en) * | 2009-01-13 | 2009-07-08 | 中国印钞造币总公司 | Upconversion printing ink for intaglio printing |
| CN102558955A (en) * | 2012-01-09 | 2012-07-11 | 西安印钞有限公司 | Carving gravure printing ink applicable to non-absorbent printed material and connecting materials of carving gravure printing ink |
| CN103204984A (en) * | 2013-04-17 | 2013-07-17 | 中钞油墨有限公司 | Polyurethane-modified hydrophilic alkyd resin binder for water erasing of intaglio printing ink |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107183171A (en) * | 2017-06-23 | 2017-09-22 | 深圳市裕同包装科技股份有限公司 | A kind of fruit active fresh-keeping ink and its preparation technology |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN1955234B (en) | Photogravure ink equal to cut ink and its application | |
| CN101275043B (en) | Environment-friendly water-soluble plate engraving ink | |
| CN103408994B (en) | Water-based gloss oil and preparation method thereof | |
| CN101974267B (en) | Aqueous ultraviolet light curing pearlescent silk screen ink and preparation method thereof | |
| CN101979446B (en) | Gravure ink capable of generating special surface effects and preparation method | |
| CN101531845B (en) | Flexographic ink with high degradation rate | |
| CN102241913B (en) | Gravure water-based frosted ink and preparation method thereof | |
| CN101688080A (en) | vanadium-drier intaglio ink | |
| CN102719140B (en) | Varnish for water-borne anti-counterfeiting ink and water-borne anti-counterfeiting ink prepared by varnish | |
| CN101624490B (en) | Electroconductive polymer printing ink and preparation method thereof | |
| CN103786461B (en) | A kind of business round fountain solution and preparation method thereof | |
| CN104943434A (en) | Non-ionic surfactant fountain solution | |
| JPH09100431A (en) | Intaglio printing ink based on soybean oil and method for preparing the same | |
| CN101250352B (en) | Soybean oil based intaglio printing ink and bonding material thereof | |
| CN101613545A (en) | A kind of water color ink and making method that is used for intaglio printing | |
| CN103087597A (en) | Offset printing online water-based varnish applicable to UV (ultraviolet) code spraying and preparation method thereof | |
| CN101240133B (en) | Water-based conductive color paste | |
| EP3317356B1 (en) | Environmentally friendly ink and fountain solution for wet offset printing process and wet offset printing process | |
| CN103865329A (en) | Environment-friendly hydrophilic engraved intaglio plate ink and preparation method thereof | |
| CN103666088A (en) | Special aqueous gold ink for tipping paper, preparation method and application thereof | |
| CN105315780A (en) | Volatilization drying water-based rotary screen pearly-luster printing ink and preparation method thereof | |
| CN104327589B (en) | A kind of black Environmental-protection water-based ink and preparation method thereof | |
| CN101812255A (en) | Preprinted ink for high-temperature resistant carton | |
| CN104164133A (en) | Soybean oil base offset ink | |
| CN101624491B (en) | Water-based driography electrically conductive ink and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140618 |
|
| RJ01 | Rejection of invention patent application after publication |