CN103865314A - Novel detergent for printing ink and preparation method of detergent - Google Patents

Novel detergent for printing ink and preparation method of detergent Download PDF

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Publication number
CN103865314A
CN103865314A CN201410067417.XA CN201410067417A CN103865314A CN 103865314 A CN103865314 A CN 103865314A CN 201410067417 A CN201410067417 A CN 201410067417A CN 103865314 A CN103865314 A CN 103865314A
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China
Prior art keywords
parts
detergent
acid
diethylene glycol
mixing kettle
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CN201410067417.XA
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Chinese (zh)
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CN103865314B (en
Inventor
刘全新
姚利刚
姚静
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Yingmei Polytron Technologies Inc, Anhui
Original Assignee
ANHUI YINGMEI COLOR PRINTING & PACKAGING Co Ltd
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Publication of CN103865314A publication Critical patent/CN103865314A/en
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Abstract

The invention discloses a novel detergent for printing ink. The novel detergent is characterized by being prepared from the raw materials in parts by weight: 3-4 parts of disodium ethylenediamine tetraacetate, 3-4 parts of OP-10, 20-24 parts of kerosene, 3-4 parts of potassium pyrophosphate, 10-12 parts of butyl carbitol, 3-4 parts of citric acid, 4-5 parts of malic acid, 4-5 parts of diethylene glycol dibutyl ether, 2-3 parts of butyl titanate, 4-5 parts of assistants and 100-110 parts of water. According to the novel detergent and the preparation method disclosed by the invention, the assistants are added, so that the processing property of the detergent is improved, and toxic and side effects and the pollution to the environment are reduced. The novel detergent disclosed by the invention has a good cleaning effect, is high in speed, free of heating during deinking, low in volatility, extremely low in toxicity, free of injury to the human body and low in environmental pollution; in addition, the novel detergent has little damage to printing equipment and is convenient to use.

Description

A kind of novel printing detergent for ink and preparation method thereof
Technical field
The present invention relates to print cleaning technique field, particularly a kind of novel printing detergent for ink and preparation method thereof.
Background technology
In printing industry, often use now to have the element purge of ink for printing machinery forme, rubber roll, blanket etc. be to clean with organic solvents such as gasoline, kerosene, acetone, alcohol; Such clean-out system exists inflammable, explosive, contaminate environment, harm bedding sack health, and to cleaning part, as: glue rod, blanket surface burn into swelling action, to parts damages, shorten work-ing life widely, simultaneously to using workman's skin of hand burn into injury of solvent, this solvent cleaning weak effect, gasoline, coal are the products of petroleum refining, and ballooning oil prices, can cause the waste of Nonrenewable resources petroleum-based energy so now.At present, the widely used clean-out system in market, is not that to be acidity be exactly to be alkalescence, is acid clean-out system and can has a strong impact on original true qualities and smooth finish, is alkaline clean-out system and can permeates cleaning objects, causes object corrosion, even comes off.
Chinese patent 200510122330.9 discloses a kind of natural plant type detergent, it is characterized in that by 60~80 parts of limonene, 10~20 parts, turps, 10~15 parts of propylene glycol phenylates, 5~10 parts of Terpineol 350s, 1~3 part of citral, natural plant solvent and emulsifying agent that evenly mixed preparing forms mix composition.But this clean-out system is not invented for cleaning printing-ink, so its effect of cleaning printing-ink is also short of to some extent.
Summary of the invention
The object of this invention is to provide a kind of novel printing detergent for ink and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of novel printing detergent for ink, is made up of the raw material of following weight part: disodium ethylene diamine tetraacetate 3-4, OP-10 3-4, kerosene 20-24, potassium pyrophosphate 3-4, diethylene glycol monobutyl ether 10-12, citric acid 3-4, oxysuccinic acid 4-5, diethylene glycol dibutyl ether 4-5, butyl (tetra) titanate 2-3, auxiliary agent 4-5, water 100-110;
Described auxiliary agent is made up of the raw material of following weight part: Silane coupling reagent KH-570 2-3, ricinolic acid 2-3, tea-polyphenol 2-3, glyceryl monostearate 4-5, neopentyl glycol 2-3, p-tert-butyl benzoic acid 3-4, oxidation inhibitor 1035 1-2, ethanol 15-18; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 DEG C, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 DEG C, stirs 30-40 minutes, to obtain final product.
Novel printing detergent for ink of the present invention, made by following concrete steps:
(1) at room temperature kerosene, potassium pyrophosphate, diethylene glycol monobutyl ether, citric acid, oxysuccinic acid are added in mixing kettle, add in mixing kettle after the water of half amount is heated to 65-75 DEG C, be stirred to completely and dissolve;
(2) disodium ethylene diamine tetraacetate, OP-10, diethylene glycol dibutyl ether 4-5, butyl (tetra) titanate are added in mixing kettle, add the water that is heated to 80-90 DEG C of surplus, stir 4-6 minute with the speed of 1300-1400 rev/min;
(3) finally auxiliary agent and all the other remaining components are added in mixing kettle, stir, naturally cooling.
Excellent effect of the present invention is: the present invention adds auxiliary agent, has improved the processing performance of clean-out system, reduces its toxic side effect and the pollution to environment; Cleaning performance of the present invention is good, and speed is fast, does not need heating when deinking, and volatility is little, and toxicity is extremely low, and to human body, without injury, environmental pollution is little, and little to printing equipment damaging action, easy to use.
Embodiment
Below by specific examples, the present invention is described in detail.
A kind of novel printing detergent for ink, by following weight part (kilogram) raw material make: disodium ethylene diamine tetraacetate 3, OP-10 3, kerosene 20, potassium pyrophosphate 3, diethylene glycol monobutyl ether 10, citric acid 3, oxysuccinic acid 4, diethylene glycol dibutyl ether 4, butyl (tetra) titanate 2, auxiliary agent 4, water 100;
Described auxiliary agent by following weight part (kilogram) raw material make: Silane coupling reagent KH-570 3, ricinolic acid 2, tea-polyphenol 2, glyceryl monostearate 4, neopentyl glycol 2, p-tert-butyl benzoic acid 4, oxidation inhibitor 1,035 1, ethanol 15; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 DEG C, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 DEG C, stirs 30-40 minutes, to obtain final product.
Novel printing detergent for ink of the present invention, made by following concrete steps:
(1) at room temperature kerosene, potassium pyrophosphate, diethylene glycol monobutyl ether, citric acid, oxysuccinic acid are added in mixing kettle, add in mixing kettle after the water of half amount is heated to 65-75 DEG C, be stirred to completely and dissolve;
(2) disodium ethylene diamine tetraacetate, OP-10, diethylene glycol dibutyl ether 4-5, butyl (tetra) titanate are added in mixing kettle, add the water that is heated to 80-90 DEG C of surplus, stir 4-6 minute with the speed of 1300-1400 rev/min;
(3) finally auxiliary agent and all the other remaining components are added in mixing kettle, stir, naturally cooling.
Ink is applied on the stainless steel metal thin slice of certain mass, under state of nature, dries, steel disc is placed in to the beaker that fills clean-out system, at 25 DEG C, soak after 5 minutes, more at the uniform velocity vibrate 5 minutes, obtaining cleaning soil removal efficiency is 93.4%, and cleansing power is good.With this clean-out system, with compared with gasoline, kerosene, rubber cloth increases the service life 2 years, and ink roller can increase the service life 3 years.

Claims (2)

1. a novel printing detergent for ink, it is characterized in that, made by the raw material of following weight part: disodium ethylene diamine tetraacetate 3-4, OP-10 3-4, kerosene 20-24, potassium pyrophosphate 3-4, diethylene glycol monobutyl ether 10-12, citric acid 3-4, oxysuccinic acid 4-5, diethylene glycol dibutyl ether 4-5, butyl (tetra) titanate 2-3, auxiliary agent 4-5, water 100-110;
Described auxiliary agent is made up of the raw material of following weight part: Silane coupling reagent KH-570 2-3, ricinolic acid 2-3, tea-polyphenol 2-3, glyceryl monostearate 4-5, neopentyl glycol 2-3, p-tert-butyl benzoic acid 3-4, oxidation inhibitor 1035 1-2, ethanol 15-18; Preparation method mixes Silane coupling reagent KH-570, ricinolic acid, ethanol, is heated to 60-70 DEG C, stirs after 20-30 minute, then adds other remaining component, is warming up to 80-85 DEG C, stirs 30-40 minutes, to obtain final product.
2. novel printing detergent for ink according to claim 1, is characterized in that, is made up of following concrete steps:
(1) at room temperature kerosene, potassium pyrophosphate, diethylene glycol monobutyl ether, citric acid, oxysuccinic acid are added in mixing kettle, add in mixing kettle after the water of half amount is heated to 65-75 DEG C, be stirred to completely and dissolve;
(2) disodium ethylene diamine tetraacetate, OP-10, diethylene glycol dibutyl ether 4-5, butyl (tetra) titanate are added in mixing kettle, add the water that is heated to 80-90 DEG C of surplus, stir 4-6 minute with the speed of 1300-1400 rev/min;
(3) finally auxiliary agent and all the other remaining components are added in mixing kettle, stir, naturally cooling.
CN201410067417.XA 2014-02-27 2014-02-27 A kind of printing ink washing agent and preparation method thereof Active CN103865314B (en)

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CN103865314B CN103865314B (en) 2016-04-27

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104830141A (en) * 2015-04-30 2015-08-12 南京信息工程大学 Microemulsion printing ink cleaner and preparation method thereof

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1088952A (en) * 1992-12-26 1994-07-06 化工部北京化工研究院 Emulsion type high-efficiency non-toxic ink remover
CN103525161A (en) * 2013-10-23 2014-01-22 合肥环照高分子材料厂 High-efficiency printing ink cleaning agent and preparation method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1088952A (en) * 1992-12-26 1994-07-06 化工部北京化工研究院 Emulsion type high-efficiency non-toxic ink remover
CN103525161A (en) * 2013-10-23 2014-01-22 合肥环照高分子材料厂 High-efficiency printing ink cleaning agent and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104830141A (en) * 2015-04-30 2015-08-12 南京信息工程大学 Microemulsion printing ink cleaner and preparation method thereof

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Address after: Seven road 236112 Anhui city in Fuyang Province Economic Development Zone No. 99 Ying Ying

Patentee after: Yingmei Polytron Technologies Inc, Anhui

Address before: Seven road 236112 Anhui city in Fuyang Province Economic Development Zone No. 99 Ying Ying

Patentee before: ANHUI YINGMEI COLOR PRINTING & PACKAGING CO., LTD.