CN103860396A - Oil-in-water type emulsion solid cosmetic material - Google Patents
Oil-in-water type emulsion solid cosmetic material Download PDFInfo
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- CN103860396A CN103860396A CN201310682654.2A CN201310682654A CN103860396A CN 103860396 A CN103860396 A CN 103860396A CN 201310682654 A CN201310682654 A CN 201310682654A CN 103860396 A CN103860396 A CN 103860396A
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- type emulsion
- water type
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/04—Dispersions; Emulsions
- A61K8/06—Emulsions
- A61K8/062—Oil-in-water emulsions
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
- A61K8/0216—Solid or semisolid forms
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/42—Amides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q19/00—Preparations for care of the skin
Abstract
The invention relates to an oil-in-water type emulsion solid cosmetic material. Specifically, the invention provides an oil-in-water type emulsion solid cosmetic material which has the characteristics of an oil-in-water type emulsion cosmetic material which are moist, cool and refreshing in use and excellent in skin adhesion, also has good access of a cosmetic applicator and a smooth feeling in use, and is high in form maintenance and excellent in portability in continuous use. The oil-in-water type emulsion solid cosmetic material in the invention contains 1.0 mass% to 3.5 mass% of (a) agar and 0.05 mass% to 1.0 mass% of (b) acrylamide water-soluble thickener agent.
Description
Technical field
The present invention relates to solid-state oil-in-water emulsion type cosmetic preparation, usability, the skin that water moistens refrigerant sense that has of the characteristic that described solid-state oil-in-water emulsion type cosmetic preparation is so-called oil-in-water emulsion type cosmetic preparation attaches property excellence, simultaneously good for the access of makeup application body, there is level and smooth use sense, and shape keeping property while using is continuously high, Portability is excellent.
Background technology
In the past, the aqueous cosmetic of oil-in-water emulsion type cosmetic preparation etc. was widely used and came as the State of cosmetics of naturality excellence of usability, decoration with so-called water profit, frank refrigerant sense.
Generally there are emulsion form or liquid, white shape etc. as the form of oil-in-water emulsion type cosmetic preparation in the past.And its container form is mostly ampuliform form or the tubulose form with sealing of lid, consider it is inconvenient from the viewpoint of usability or Portability.In recent years, except these cosmetics forms, also developed and provide the water soluble solid agent that uses agar or gelatin and the technology (reference example is as patent documentation 1) of making solid-state oil-in-water emulsion type cosmetic preparation.
Solid-state oil-in-water emulsion type cosmetic preparation is like this usability excellence that has water and moisten refrigerant sense, and the good cosmetics of Portability.But, when with identical solid-state water-in-oil emulsified cosmetic relatively time, in the time taking cosmetics with the applicator of so-called finger or coating tool, there is applicator and slip over the poor shortcoming of access of the surperficial cosmetics of cosmetics.Therefore, for the access that makes oil-in-water type emulsion solid, cosmetic well need to be taken a lot of time.For example, as patent documentation 2, disclose the oil-in-water cosmetic being packed in container, before solidifying, water-retaining property flaky material is attached to cosmetics surface, after cooling curing, water-retaining property flaky material is peeled off and removed surperficial one deck, make thus the good technology of access of cosmetics.
[prior art document]
[patent documentation]
[patent documentation 1] Japanese kokai publication hei 5-178723
[patent documentation 2] Japanese kokai publication hei 7-17828
Summary of the invention
[problem that invention will solve]
But, use the technology of the water-retaining property flaky material of peeling off the attaching of cosmetics surface of patent documentation 2, although can how much improve the easiness of taking of bringing into use the new product cosmetics initial stage, but for peel off after water-retaining property flaky material Reusability cosmetics time take easiness, it is sufficient that not talkative its improves effect.In addition, because the access of cosmetics is insufficient, if more cosmetics are taken on finger or coating tool, need to apply strong strength, in the time of Reusability cosmetics, have that solid-state cosmetics split, the problem of destruction etc., can not meet so-called contrary characteristic of taking the usability of easiness and the hardness of tolerance Reusability or Portability simultaneously.
Therefore, in the urgent need to solid-state oil-in-water emulsion type cosmetic preparation, described solid-state oil-in-water emulsion type cosmetic preparation has usability, the skin attaching property excellence that water moistens refrigerant sense that have for the characteristic of oil-in-water emulsion type cosmetic preparation, simultaneously good for the access of makeup application body, there is level and smooth use sense, and shape keeping property while using is continuously high, Portability is excellent.
[method of dealing with problems]
Use for reference described practical situation, the inventor carries out the result of wholwe-hearted research repeatedly, the present invention finds, using the oil-in-water type emulsion solid, cosmetic obtaining as the agar of water soluble solid agent and the combination of acrylic amide water-soluble thickener, have the usability that water moistens refrigerant sense, good for the access of makeup application body, it is high and have a level and smooth usability that skin attaches property, and the shape keeping property while use is continuously high, Portability is also excellent.
Further; find as the acrylic amide water-soluble thickener using in the present invention; preferably contain the material of the copolymer using acryloyldimethyl taurate as construction unit; more preferably contain one or more that select from using acryloyldimethyl taurate and 2-(Acryloyloxy)ethanol and/or acrylates as the copolymer of construction unit; shape keeping property can significantly improve thus for the taking easiness and use continuously of makeup application body time, until completed the present invention.
That is, the present invention is a kind of oil-in-water type emulsion solid, cosmetic, it is characterized in that, contains following (a)～composition (c):
(a) agar of 1.0 quality %～3.5 quality %,
(b) acrylic amide water-soluble thickener of 0.05 quality %～1.0 quality %,
(c) oil preparation.
Further; above-mentioned oil-in-water type emulsion solid, cosmetic; it is characterized in that; as (b) acrylic amide water-soluble thickener; preferably contain the copolymer of acryloyldimethyl taurate as construction unit; more preferably, from selecting one or more using acryloyldimethyl taurate and 2-(Acryloyloxy)ethanol and/or acrylates as the copolymer of construction unit.
[invention effect]
Oil-in-water type emulsion solid, cosmetic according to the present invention can provide, there is the usability that water moistens refrigerant sense, access for makeup application body is good, it is high and have a level and smooth use sense that skin attaches property, and the shape keeping property while use is continuously high, the solid-state oil-in-water emulsion type cosmetic preparation of Portability excellence.
Detailed description of the invention
Describe the preferred embodiment of oil-in-water type emulsion solid, cosmetic of the present invention below, in detail.
The present invention is a kind of solid-state oil-in-water emulsion type cosmetic preparation, it is characterized in that, (b) acrylic amide water-soluble thickener of (a) agar that contains 1.0 quality %～3.5 quality % and 0.05 quality %～1.0 quality % and (c) oil preparation, it has water and moistens the usability of refrigerant sense, access for makeup application body is good, it is high and have level and smooth use sense that skin attaches property, and shape keeping property while using is continuously high, Portability excellence.
In the present invention, in order to solidify oil-in-water emulsion type cosmetic preparation, give the hardness of tolerance usability and Portability and use water soluble solid agent.As water soluble solid agent, from using sense of touch to consider, particularly preferably (a) agar.(a) agar can be enumerated, for example, and as ウ Le ト ラ agar AX-200(Ina Food Industry Co., Ltd. system of commercially available product) etc.
The content of (a) agar using in oil-in-water type emulsion solid, cosmetic of the present invention, is preferably 1.0 quality %～3.5 quality % in oil-in-water type emulsion solid, cosmetic total amount.When less than 1.0 quality %, the shape keeping property during from continuous use and the viewpoint of crushing strength are considered and not preferred.And, while exceeding 3.5 quality %, from so-calledly taking easiness, attach sense, without the use sense of touch of tight sense (Star ッ パ リ sense) (level and smooth usability), the viewpoint consideration of the shape keeping property while use continuously and not preferred.
As (b) acrylic amide water-soluble thickener using in oil-in-water type emulsion solid, cosmetic of the present invention; can enumerate; for example, (2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate) copolymer, (sodium acrylate/sodium acryloyldimethyl taurate) copolymer, (ammonium acryloyldime-thyltaurate/VP) copolymer, (ammonium acryloyldime-thyltaurate methacrylic acid behenyl alcohol polyethers-25) cross linked polymer etc.Wherein, particularly preferably; (2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate) copolymer, (sodium acrylate/sodium acryloyldimethyl taurate) copolymer can be selected one or more uses from aforesaid propylene amide-type water-soluble thickener.
(b) acrylic amide water-soluble thickener can use commercially available product.For example, as the commercially available product of (2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate) copolymer, can enumerate, SEPINOV EMT10, SIMULGEL NS(are SEPPIC society system above) etc.In addition, as the commercially available product of (sodium acrylate/sodium acryloyldimethyl taurate) copolymer, can enumerate SIMULGEL EG(SEPPIC society system) etc.As the commercially available product of (ammonium acryloyldime-thyltaurate/VP) copolymer; can enumerate Aristoflex AVC(Clariant society system) etc.; as the commercially available product of (ammonium acryloyldime-thyltaurate methacrylic acid behenyl alcohol polyethers-25) cross linked polymer, can enumerate Aristoflex HMB(Clariant society system) etc.
In the present invention, the content of above-mentioned (b) acrylic amide water-soluble thickener, preferably 0.05 quality %～1.0 quality % in oil-in-water type emulsion solid, cosmetic total amount.When less than 0.05 quality %, the viewpoint of the shape keeping property when taking easiness and use is continuously considered not preferred.And while exceeding 1.0 quality %, from the so-called use sense of touch without tight sense (level and smooth usability), the viewpoint of crushing strength is considered and not preferred.
(c) oil preparation using in oil-in-water type emulsion solid, cosmetic of the present invention is for so-called skin moistening sense (エ モ リ エ Application ト sense), attaches the material that the object of the use sense of touch regulator etc. of sense is used, have no particular limits, can use the fluid oil, solid oil, the semisolid oil that in ordinary cosmetics, use.
As the fluid oil of compounding in the present invention, as long as the material using in the ordinary cosmetics for liquid oil content at normal temperatures, have no particular limits, specifically can enumerate, liquid paraffin, the hydrocarbon-type oil of squalane etc., malic acid two iso stearyl esters, isopropyl myristate, 2 ethyl hexanoic acid cetyl ester, isopropyl palmitate, palm acid ethyl hexyl ester, three Miglyol 812s (ト リ カ プ リ Le カ プ リ Application acid グ リ セ リ Le), the esters oil of three-2 ethyl hexanoic acid glyceride etc., olive oil, Oleum Ricini, macadimia nut oil, the vegetable oil of jojoba wet goods, oleyl alcohol, octyl group Lauryl Alcohol, the higher alcohol of i-octadecanol etc., isostearic acid, the higher fatty acids of oleic acid etc., dimethyl polysiloxane, methyl phenyl silicone, the silicone oil of decamethyl Pentamethylene. siloxanes etc. etc.Can use one or more of these fluid oil compositions.
As the solid oil of compounding in the present invention, semisolid oil, as long as the material using in ordinary cosmetics, have no particular limits, specifically can enumerate, vaseline, hard paraffin, microwax, the hydro carbons of polyethylene etc., castor oil hydrogenated, hydrogenation Jojoba oil, Brazil wax, the oils and fats of the plant origin of rice bran wax etc., three Glyceryl Behenates, the esters of cholesterol fatty acid ester etc., stearic acid, the higher fatty acids class of behenic acid etc., stearyl alcohol, the higher alcohols of behenyl alcohol etc., alkyl-modified silicone, the silicone of acrylic compounds modified silicone etc. etc.Can use one or more of these solid oils, semisolid oil composition.
In oil-in-water type emulsion solid, cosmetic of the present invention, can also be as required, not damaging in the scope of effect of the present invention, other composition suitably using in the ordinary cosmetics of compounding except the essential constituent of above-mentioned (a)～(c), for example, powder composition, wetting agent, surfactant, UV absorbent, film former, antiseptic, vitamins, beauty treatment composition, antioxidant, spice etc.
As the powder composition of compounding in the present invention, as long as the material using in ordinary cosmetics, there is no particular limitation, specifically can enumerate, Muscovitum, Kaolin, synthetic mica, silicon dioxide, calcium carbonate, magnesium carbonate, aluminium oxide, iron sesquioxide, yellow iron oxide, iron oxide black, cobalt oxide, ultramarine, Prussian blue, titanium oxide, zinc oxide, pearl pigment (mica titanium, fish scale pool, bismuth oxychloride etc.), boron nitride, organic pigment (red No. 228, red No. 226, blue No. 404 etc.), polyethylene powders, polymethyl methacrylate, organopolysiloxane elastomer etc.Also can use two or more the compound material in these powder, in addition, also can use, adopt known method, the material obtaining with enforcement surface treatments such as silicone compounds, metal soap, amino-acid compound, fluorine compounds.In order to have obtained diversified use sense of touch, and when as cosmetic cosmetic, for the tone that obtains wishing, can use one kind or two or more in these powder.
As the wetting agent of compounding in the present invention, as long as the material using in ordinary cosmetics, there is no particular limitation, specifically can enumerate glycerol, propylene glycol, 1,3 butylene glycol, dipropylene glycol, Polyethylene Glycol etc.
As the purposes of oil-in-water type emulsion solid, cosmetic of the present invention, there is no particular limitation, and for example, the cosmetics that can be used as skin protection use, cosmetic, Hair grooming etc. use.Preferably be suitable for foundation cream, eye shadow, rouge, eyebrow pencil, eyeliner, mascara, lipstick, adornment foremilk etc.
[embodiment]
Below, enumerate embodiment and illustrate the present invention, but it does not limit the present invention with any degree.In the explanation of embodiment, first the effect test method using in the present invention is described.
The evaluation methodology > of < oil-in-water type emulsion solid, cosmetic
[usability test]
Please 10 cosmetics specialty pass judgment on the oil-in-water type emulsion solid, cosmetics of librarian use embodiment and comparative example, for each assessment item of " taking easiness (for taking of the cosmetics of applicator) ", " attaching sense (being attached at skin) ", " without tight sense (level and smooth usability) ", respectively according to following evaluation criterion, give the scoring of 5 grades, further, by the each member's who obtains scoring equalization, judge respectively each project based on this average mark and following criterion with 4 grades.
[evaluation criterion]
Scoring;
5 points: very good
4 points: good
3 points: neither better nor worse
2 points: slightly poor
1 point: poor
[criterion]
◎: average mark is more than 4.5 points
Zero: average mark is more than 3.5 points and 4.5 points of less thaies
△: average mark is more than 1.5 points and 3.5 points of less thaies
×: 1.5 points of average mark less thaies
[shape keeping property while use continuously]
Please 10 the continuous oil-in-water type emulsion solid, cosmetics that use embodiment and comparative example for 50 times of cosmetics professional evaluator, whether cosmetics keep thing piece form to give respectively the scoring of 5 grades according to following evaluation criterion, further, by the each member's who obtains scoring equalization, judge with 4 grades based on this average mark and following criterion.
[evaluation criterion]
Scoring;
5 points: very good
4 points: slight splitting occurs thing piece
3 points: thing piece splits, thing piece becomes fritter to come off
2 points: thing piece entirety produces be full of cracks, and thing piece in bulk comes off
1 point: thing piece entirety produces be full of cracks, and thing piece entirety comes off from container
[criterion]
◎: average mark is more than 4.5 points
Zero: average mark is more than 3.5 points and 4.5 points of less thaies
△: average mark is more than 1.5 points and 3.5 points of less thaies
×: 1.5 points of average mark less thaies
[crushing strength]
Based on following evaluation criterion, the oil-in-water type emulsion solid, cosmetic that makes embodiment and comparative example with 4 grades of evaluations falls back to the thing piece shape keeping property after 5 times the plywood of thickness 15mm from the height of 50cm.
[evaluation criterion]
◎: the destruction that there is no thing piece completely
Zero: thing piece surface slight damage
△: thing piece partial destruction
×: thing piece entirety is destroyed
[ageing stability]
The oil-in-water type emulsion solid, cosmetic of embodiment and comparative example is left standstill in the temperature chamber of 40 DEG C, observe the apparent condition after 3 months, evaluate based on following evaluation criterion.
[evaluation criterion]
Zero: without abnormal (water or oil separating, ooze out the globule, powder coagulation etc.)
×: there is abnormal (water or oil separating, ooze out the globule, powder coagulation etc.)
(embodiment 1～10 and comparative example 1～11)
With the formula shown in following table 1 and table 2, modulation oil-in-water type emulsion solid, cosmetic (rouge).For the compositions obtaining (assess sample), based on above-mentioned evaluation methodology, implement the evaluation of each project.Its result is merged and is shown in table 1 and table 2.
In addition, for each raw material of (note 1) in table 1, table 2～(note 5), this does not use following commercially available product.And the compounding numerical quantity in table 1 and table 2 is expressed as quality %.
(note 1) SEPINOV EMT10; SEPPIC society system
(note 2) SIMULGEL EG; SEPPIC society system
(note 3) Aristoflex AVC; Clariant society system
(note 4) Aristoflex HMB; Clariant society system
(note 5) ウ Le ト ラ agar AX-200; Ina Food Industry Co., Ltd.'s system.
[table 1]
(modulation method) modulates the compositions of embodiment 1～5 and comparative example 1～5 with following methods.After each raw material of compounding 1～16, heating, dissolves 15 and 16 and makes aqueous portion.The oil phase part that each raw material of compounding 17～29 is obtained and above-mentioned aqueous portion compounding, emulsifying.Then, the thing piece of generation is packed in container, makes it cooling, curing, obtain oil-in-water type emulsion solid, cosmetic.
[table 2]
(modulation method) modulates the compositions of embodiment 6～10 and comparative example 6～11 with following methods.After each raw material of compounding 1～9, heating, dissolves 7～9 and makes aqueous portion.The oil phase part that each raw material of compounding 10～22 is obtained and above-mentioned aqueous portion compounding, emulsifying.Then, the thing piece of generation is packed in container, makes it cooling, curing, obtain oil-in-water type emulsion solid, cosmetic.
As indicated in table 1 and table 2, as the embodiment 1～10 of the embodiment of the present invention, taking easiness, attach sense, in whole assessment items of shape keeping property without tight sense, while using continuously, crushing strength, ageing stability, there is good result.On the other hand, the comparative example 1～11 of discontented foot composition of the present invention can not meet whole assessment items.
Particularly, comparative example 1～6 and 11 lacks any one of composition of (a) as essential component of the present invention～(c).In comparative example 1, due to the acrylic amide water-soluble thickener lacking as (b) composition, the shape keeping property existing problems when therefore taking easiness and using continuously.Use in the comparative example 2～5 of the thickening agent beyond acrylic amide water-soluble thickener, taking easiness, attach sense, in shape keeping property while using continuously, ageing stability, compare with embodiment 1～10, the result of being on duty mutually.All good result that improve, that meet contrary characteristic of the shape keeping property particularly, can not obtain taking easiness and using continuously time.
In addition,, in the comparative example 6 of the water soluble solid agent beyond being used as the agar of (a) composition, take easiness, attaching property, shape keeping property, ageing stability existing problems while using continuously.In comparative example 11, due to the oil preparation lacking as (c) composition, therefore attach sense, have problems without tight sense.
Illustrate that embodiment 11～13 is as other Formulation Example of the present invention below.
[embodiment 11: foundation cream]
(compounding composition) (quality %)
(1) butanediol 15.0
(2) glycerol 6.0
(3) antiseptic is appropriate
(4) water surplus
(5) hyaluronate sodium (1 quality % aqueous solution) 2.0
(6) (2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate) copolymer (note 1) 0.3
(7) xanthan gum 0.05
(8) agar (note 5) 1.5
(9) gellan gum 0.15
(10) PEG-60 castor oil hydrogenated 1.2
(11) squalane 1.0
(12) vaseline 1.0
(13) Brazil wax 0.2
(14) isostearic acid sorbitan ester 0.1
(15) cyclopentasiloxane 1.0
(16) trimethylsiloxy silicic acid 1.0
(17) ethylhexyl methoxy cinnamate 4.0
(18) octocrylene 2.0
(19) the own ester 1.0 of diethylamino hydroxy benzoyl benzoic acid
(20) natural Vitamin E 0.02
(21) titanium oxide 7.0 of silicone-treated
(22) yellow iron oxide 2.4 of silicone-treated
(23) iron oxide red 0.36 of silicone-treated
(24) iron oxide black 0.18 of silicone-treated
(25) Muscovitum 1.0 of silicone-treated
(26) silicon dioxide 2.0
(27) hydrolecithin 1.9.
(method for making), behind compounding blending constituent (1)～(9), heating, dissolves (8) and (9) and makes aqueous portion.The oil phase part that compounding (10)～(27) are obtained and above-mentioned aqueous portion compounding, emulsifying.Then the thing piece of generation is packed in container, makes it cooling, curing, obtain foundation cream.
The foundation cream of above-described embodiment 11 is to have usability, skin that water moistens refrigerant sense to attach property excellence,, shape keeping property high foundation cream when having level and smooth use sense and continuously using good for the access of makeup application body.
[embodiment 12: eye shadow]
(compounding composition) (quality %)
(1) butanediol 6.0
(2) glycerol 3.0
(3) antiseptic is appropriate
(4) water surplus
(5) (2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate) copolymer (note 1) 0.2
(6) xanthan gum 0.1
(7) agar (note 5) 2.1
(8) gellan gum 0.1
(9) PEG-60 castor oil hydrogenated 1.2
(10) thylhexoic acid cetyl ester 5.0
(11) polydimethylsiloxane 0.5
(12) natural Vitamin E 0.02
(13) isostearic acid sorbitan ester 0.2
(14) yellow iron oxide 0.15 of silicone-treated
(15) iron oxide red 0.12 of silicone-treated
(16) red No. 226 0.12
(17) Muscovitum 1.5 of silicone-treated
(18) glass powder 12.0 of titanium-oxide-coated
(19) Muscovitum 3.0 of titanium-oxide-coated
(20) hydrolecithin 0.5.
(method for making), behind compounding blending constituent (1)～(8), heating, dissolves (7) and (8) and makes aqueous portion.The oil phase part that compounding (9)～(20) are obtained and above-mentioned aqueous portion compounding, emulsifying.Then the thing piece of generation is packed in container, makes it cooling, curing, obtain eye shadow.
The eye shadow of above-described embodiment 12 is, has usability, skin that water moistens refrigerant sense and attaches property excellence,, shape keeping property high eye shadow when having level and smooth use sense and continuously using good for the access of makeup application body.
[embodiment 13: eye cream]
(compounding composition) (quality %)
(1) butanediol 4.0
(2) glycerol 6.0
(3) dipropylene glycol 3.0
(4) hyaluronate sodium (aqueous solution of 1 quality %) 2.0
(5) antiseptic is appropriate
(6) water surplus
(7) (2-(Acryloyloxy)ethanol/sodium acryloyldimethyl taurate) copolymer (note 1) 0.6
(8) agar (note 5) 3.0
(9) gellan gum 0.3
(10) PEG-60 castor oil hydrogenated 1.0
(11) thylhexoic acid cetyl ester 2.0
(12) Jojoba oil 1.0
(13) squalane 3.0
(14) cetostearyl alcohol 0.5
(15) natural Vitamin E 0.01.
(method for making), behind compounding blending constituent (1)～(9), heating, dissolves (8) and (9) and makes aqueous portion.The oil phase part that compounding (10)～(15) are obtained and above-mentioned aqueous portion compounding, emulsifying.Then the thing piece of generation is packed in container, makes it cooling, curing, obtain eye cream.
The eye cream of above-described embodiment 13 is, have usability, skin that water moistens refrigerant sense attaches property excellence,, shape keeping property high eye cream when having level and smooth use sense and continuously using good for the access of makeup application body.
Claims (3)
1. an oil-in-water type emulsion solid, cosmetic, is characterized in that, contains following (a)～composition (c):
(a) agar of 1.0 quality %～3.5 quality %,
(b) acrylic amide water-soluble thickener of 0.05 quality %～1.0 quality %,
(c) oil preparation.
2. oil-in-water type emulsion solid, cosmetic according to claim 1, is characterized in that, described composition (b) is for containing the copolymer of acryloyldimethyl taurate as construction unit.
3. oil-in-water type emulsion solid, cosmetic according to claim 1; it is characterized in that, described composition (b) is one or more from selecting as the copolymer of construction unit taking acryloyldimethyl taurate and 2-(Acryloyloxy)ethanol and/or acrylates.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012274591A JP6082981B2 (en) | 2012-12-17 | 2012-12-17 | Oil-in-water emulsified solid cosmetic |
| JP2012-274591 | 2012-12-17 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103860396A true CN103860396A (en) | 2014-06-18 |
| CN103860396B CN103860396B (en) | 2018-04-17 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310682654.2A Active CN103860396B (en) | 2012-12-17 | 2013-12-12 | Oil-in-water type emulsion solid, cosmetic |
Country Status (3)
| Country | Link |
|---|---|
| JP (1) | JP6082981B2 (en) |
| KR (1) | KR101967901B1 (en) |
| CN (1) | CN103860396B (en) |
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| CN111263630A (en) * | 2017-10-31 | 2020-06-09 | 株式会社资生堂 | Oil-in-water type emulsified solid cosmetic |
| CN111419739A (en) * | 2020-04-09 | 2020-07-17 | 丽鑫生技化妆品（上海）有限公司 | Cool air cushion foundation and preparation method thereof |
| CN113274300B (en) * | 2020-02-19 | 2024-04-30 | 株式会社常盘 | Oil-in-water type solid cosmetic and cosmetic |
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| JP6009373B2 (en) * | 2013-02-28 | 2016-10-19 | 日本メナード化粧品株式会社 | Oil-in-water powder cosmetic |
| CN111050739A (en) * | 2018-03-30 | 2020-04-21 | 株式会社漫丹 | Gel-like cosmetic |
| JP7313860B2 (en) * | 2019-03-29 | 2023-07-25 | 花王株式会社 | Oil-in-water emulsified cosmetic |
| KR102294392B1 (en) * | 2019-08-29 | 2021-08-27 | 주식회사 코리아나화장품 | All-in-one Cosmetic Composition With Balm Type for Cooling Skin Temperature |
| JP2021138621A (en) * | 2020-03-02 | 2021-09-16 | 花王株式会社 | Oil-in-water-type emulsified cosmetic material |
| FR3117016A1 (en) * | 2020-12-07 | 2022-06-10 | ABC Texture | Cosmetic composition for sun protection in the form of a solid emulsion. |
| WO2024014279A1 (en) * | 2022-07-11 | 2024-01-18 | 株式会社資生堂 | Oil-in-water emulsion composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0615744A2 (en) * | 1993-03-10 | 1994-09-21 | Kose Corporation | Solid oil in water type cosmetic composition |
| CN101057815A (en) * | 2006-04-18 | 2007-10-24 | 株式会社资生堂 | Cosmetic product for skin |
| JP2011046670A (en) * | 2009-08-28 | 2011-03-10 | Kao Corp | O/w type sunscreen cosmetic |
Family Cites Families (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP3242137B2 (en) * | 1991-12-27 | 2001-12-25 | 株式会社コーセー | Oil-in-water solid cosmetics |
| JP3442108B2 (en) * | 1993-06-29 | 2003-09-02 | 株式会社コーセー | Oil-in-water solid cosmetics |
| JPH10236919A (en) * | 1997-02-26 | 1998-09-08 | Shiseido Co Ltd | Oil-in-water type solid cosmetic |
| JP3531735B2 (en) * | 2000-01-11 | 2004-05-31 | 株式会社資生堂 | Method for producing thickener and cosmetic |
| JP2003300856A (en) * | 2002-04-05 | 2003-10-21 | Fancl Corp | Cosmetic composition |
| JP4401875B2 (en) * | 2004-06-24 | 2010-01-20 | 株式会社資生堂 | Oil-in-water emulsion composition |
| JP2006312610A (en) * | 2005-05-09 | 2006-11-16 | Naris Cosmetics Co Ltd | Solid pasty cosmetic |
| JP4341983B2 (en) * | 2007-12-07 | 2009-10-14 | 株式会社資生堂 | Topical skin preparation |
| JP2009298752A (en) * | 2008-06-17 | 2009-12-24 | Shiseido Co Ltd | Skin care preparation composition for external use |
| JP5851722B2 (en) * | 2011-05-24 | 2016-02-03 | 花王株式会社 | Makeup cosmetics |
-
2012
- 2012-12-17 JP JP2012274591A patent/JP6082981B2/en active Active
-
2013
- 2013-12-12 CN CN201310682654.2A patent/CN103860396B/en active Active
- 2013-12-17 KR KR1020130157430A patent/KR101967901B1/en active IP Right Grant
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0615744A2 (en) * | 1993-03-10 | 1994-09-21 | Kose Corporation | Solid oil in water type cosmetic composition |
| CN101057815A (en) * | 2006-04-18 | 2007-10-24 | 株式会社资生堂 | Cosmetic product for skin |
| JP2011046670A (en) * | 2009-08-28 | 2011-03-10 | Kao Corp | O/w type sunscreen cosmetic |
Non-Patent Citations (1)
| Title |
|---|
| 潮鑫日用化学: "Sepinov EMT 10丙烯酸羟乙酯/丙烯酰二甲基牛磺酸钠共聚物", 《HTTP://BLOG.SOHU.COM/S/NTIXNJI1OTG/221120314.HTML》 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110996881A (en) * | 2017-07-14 | 2020-04-10 | 科丝美诗株式会社 | Method for forming solid cosmetic containing gelling agent |
| CN111263630A (en) * | 2017-10-31 | 2020-06-09 | 株式会社资生堂 | Oil-in-water type emulsified solid cosmetic |
| CN111263630B (en) * | 2017-10-31 | 2023-12-08 | 株式会社资生堂 | Oil-in-water type emulsified solid cosmetic |
| CN113274300B (en) * | 2020-02-19 | 2024-04-30 | 株式会社常盘 | Oil-in-water type solid cosmetic and cosmetic |
| CN111419739A (en) * | 2020-04-09 | 2020-07-17 | 丽鑫生技化妆品（上海）有限公司 | Cool air cushion foundation and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| KR101967901B1 (en) | 2019-04-10 |
| KR20140078572A (en) | 2014-06-25 |
| JP2014118386A (en) | 2014-06-30 |
| JP6082981B2 (en) | 2017-02-22 |
| CN103860396B (en) | 2018-04-17 |
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