CN103858552A - Method for constructing soil of plough layer on coarse sand earth surface by heavy metal polluted sediment - Google Patents
Method for constructing soil of plough layer on coarse sand earth surface by heavy metal polluted sediment Download PDFInfo
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Abstract
The invention discloses a method for constructing soil of a plough layer on a coarse sand earth surface by heavy metal polluted sediment. The method comprises the following steps of step 1), loosening the coarse sand surface to be regulated, and levelling the ground; step 2), laying the heavy metal polluted sediment on the coarse sand surface; step 3), sprinkling stabilizers on the heavy metal polluted sediment; step 4), performing rotary tillage for the first time; step 5), performing dry-wet alternating treatment for 15 days, and exposing to the sun for 7 days, and then performing rotary tillage for the second time, wherein the rotary tillage direction is opposite to that of the second time; after rotary tillage, the water mass fraction of a mixture of the sediment, the coarse sand and the stabilizers is naturally reduced to be 25-30%, performing alternating treatment and rotary tillage for the third time, wherein the rotary tillage direction is vertical to that of the second time; step 6), after performing rotary tillage for the third time, planting leguminous green manure for one crop, performing rotary tillage for the fourth time and returning the green manure to the field, and after two months, obtaining the soil of the plough layer. The heavy metal stabilization effect of the soil of the plough layer obtained by the method is obvious, and the heavy metal content of the planted vegetable crops conforms to the national standard.
Description
Technical field
The invention belongs to land control engineering field, particularly a kind of method that builds topsoil with heavy metal polluted bed mud in coarse sand earth's surface.
Background technology
Land control is to poor efficiency utilization, irrational utilization, does not utilize and the soil of production and construction activity and natural calamity damage is renovated, and improves the activity of land utilization efficiency; Also be the important means that intensive land used, in good time replenished cultivated land and lifting soil production capacity are saved in efficiently using the available land, strengthening.High especially to the requirement of topsoil in wherein land control engineering, improve at least one grade by renovating rear farmland quality than the front farmland quality of regulation.It is that more than 15～20cm nutrient is complete that specific targets are renovated soil thickness exactly, and organic abundant, granular structure is good, and soil environment is good, the suitable long-term cultivation that carries out.In the land control engineering of present stage, the source of topsoil mainly contains following pattern: the backfill of (1) unsoil layer; (2) development & construction project backfilling new soil; (3) in existing topsoil, apply three kinds of main topsoils such as fertilizer improvement and carry out source module, but above-mentioned pattern is all based on the more rich area of soil resource in training works and can realizes, and partial mode is subject to the reason of soil haul distance to cause economic technology cost compared with high and can not realize.
Coarse sand soil is for a long time under artificial unreasonable plantation operation and natural precipitation Scouring Condition, and soil structure medium silt and glutinous grain are run off gradually, and the land deterioration of sand appears in soil.Finally cause the topsoil in such soil to destroy, soil water-retaining water conservation is poor, and soil fertility is barren, cannot carry out normal agricultural planting activity in production, and the most serious occurred land resources completely loses.The problem that solves topsoil in coarse sand district land control engineering is very important, and lacking soil is also the Main Economic technical factor that restriction coarse sand district land control engineering advances fast.
Bed mud is the important component part of water body, is mainly made up of clay mineral, organic matter, reactive metal oxides, and this natural particle has huge specific surface area, in water environment, plays an important role, and it is the Yuan Hehui of various pollutants in water.Sediment Dredging is the effective measures of improving lake water quality, disposes dredging bed mud and need to reach safe, reasonable, economic requirement simultaneously.The recycling of bed mud more carrys out the more to obtain people's concern, gently, in the dredging bed mud recycling approach of intermediate pollution, soil utilization has that consumption is large, the good advantage of the simple and economical property of technology, the agricultural resources utilization of dredging bed mud, not only can turn waste into wealth, and reduce environmental pollution.
Owing to containing the nutritive elements such as abundant organic matter, nitrogen, phosphorus in bottom mud in lake, its recycling oneself through becoming the focus of current research, but heavy metal element wherein exceeds standard, oneself becomes the key factor that its agricultural resources of restriction utilizes.Many scholars have launched research widely for how reducing and reduce heavy metal toxicity in dredging bed mud, but systematicness, economy and practicality also do not reach requirement.Therefore the research of, how bottom mud in lake being carried out reasonable resource utilization and avoiding heavy metal to pollute soil one botanical system just seems that tool is of great significance.In addition, because bed mud CLAY MINERALS AND THEIR SIGNIFICANCE content is higher, cause the bed mud after dehydration easily to harden into lump, its physical arrangement is unsuitable for plant growth.Therefore solving the physico chemical property that also need to regulate, improve it and build soil in heavy metal pollution.
The research of utilization of river bottom mud, not only can solve bed mud problem of outlet, can produce again certain economic benefit.Bed mud resource technology mainly contains: brickmaking, potting grain, adsorbent, soil utilization etc.Much research shows, after bottom mud in lake soil utilizes, total granular structure and water-stable granular structure increase; Also soil moisture content, field capacity and soil porosity and capillary porosity have been improved simultaneously.Content of organic matter bed mud high and that rotten amount of cure is higher can make the bulk density of soil reduce after using, and volume of soil soild phase reduces gradually, and liquid and gas volume increases gradually; But the higher and low bed mud becoming thoroughly decomposed of clay mineral content may increase the bulk density of soil and cause and harden.Therefore, bed mud use the various physicochemical characters that can obviously improve soil, thereby improve the ability of soil water-retaining, fertilizer conservation and water supply, fertilizer.Bed mud and the sediment particles fertilizer being mixed with thereof contain a certain amount of nutrient, higher than pig manure nutrient content, have certain fertilizer efficiency effect.After illustrating that thus bed mud soil utilizes, all can improve soil nutrient content level.The utilization of bed mud soil can not only be brought a large amount of organic matters and mineral nutrient into, and for the microorganism in soil provides nutrient, and bed mud itself contains abundant microorganism, improved the quantity of edaphon.Meanwhile, use municipal sludge and can change the population structure of edaphon, improve the ratio of soil nitrification bacterium, increase enzymic activity, improve the basic fertility of soil and the content of soil humus.In bed mud, contain a large amount of nitrogen and phosphorus, also contain the trace elements such as potassium, calcium, iron, sulphur, magnesium, zinc, copper, manganese, boron, molybdenum, can slowly supply with the required nutrient of plant strain growth.
The risk that the utilization of bed mud soil exists is simultaneously mainly heavy metal pollution, and in bed mud, heavy metal is of a great variety, mainly contains Cu, Pb, Zn, Ni, Cr, Hg, Cd etc., is to limit the key factor that its extensive soil utilizes.At present more to the Pollution Study of heavy metal-polluted soil, mainly concentrate on soil plough horizon heavy metal after the utilization of bed mud soil the each position of variation, crop Heavy Metal Accumulation amount, there is form and impact etc. thereof.The rationally agricultural heavy metal pollution that can not cause soil and agricultural product of bed mud, but chronic administration can increase the content of heavy metal in soil.Therefore, chronic administration bottom mud in lake and fertilizer thereof need carry out necessary monitoring.In bed mud, contain Some Organic Pollutants, can reach in vivo higher level by bioconcentration, thereby produce stronger toxic action, also may jeopardize the mankind's health by food chain.
In addition, the very consolidation of bed mud quality after natural-dehydration, unit weight is up to 1.89g/cm
3, porosity only has 23.8%.The soil porosity scope that is applicable to the good growth of plant is generally 55%～65%.Very consolidation is hard for the low soil of porosity, affects growth and the breathing of root system of plant.Therefore, if dredging bed mud is not carried out to quality adjusting, just can not become the medium of plant growth, affect it in a large number for soil.
Summary of the invention
Utilize the deficiency of technology for the technical deficiency of existing coarse sand district's land forming, bed mud agricultural resources, the object of the present invention is to provide a kind of method that builds topsoil with heavy metal polluted bed mud in coarse sand earth's surface.
A kind of method that builds topsoil with heavy metal polluted bed mud in coarse sand earth's surface provided by the invention, comprises the steps:
1) loosened in coarse sand to be renovated earth's surface, ground grading;
2) heavy metal polluted bed mud is laid on the coarse sand earth's surface described in step 1);
3) stabilizing agent is spread on to step 2) on described heavy metal polluted bed mud;
4) at completing steps 3) ground on carry out rotary tillage for the first time;
5) alternation of wetting and drying is processed 15 days, is exposed to the sun 7 days, carries out rotary tillage for the second time, rotary tillage direction and contrary for the second time; After rotary tillage, the mixture quality moisture content natural-dehydration of bed mud, coarse sand, stabilizing agent is reduced to 25～30%, carries out rotary tillage for the third time, and rotary tillage direction is with vertical for the second time;
6) after rotary tillage for the third time, plant 1 batch of leguminous green manure, when green manure plant height reaches 30-35cm, carry out the 4th rotary tillage by also field of green manure, after 2 months, obtain topsoil.
Wherein, described in step 1), the standard of ground grading is the ratio of slope≤3:1000.
Wherein, step 2) described heavy metal polluted bed mud is heavy metal pollution river bottom mud and/or heavy metal pollution bottom mud in lake.
Wherein, step 2) thickness of described heavy metal polluted bed mud tiling is 24cm.
Wherein, the stabilizing agent described in step 3) is that heavy metal is processed stabilizing agent, is preferably the stabilizing agent that comprises following weight portion composition: 5 parts, fused calcium magnesium phosphate, 5 parts, calcium oxide, 1～3 part of light dolomite.
Wherein, the usage amount of the stabilizing agent described in step 3) is: every 100 weight portion bed muds stabilizing agent 0.8～1.2 weight portion, preferably every 100 weight portion bed muds stabilizing agent 1 weight portion.
Wherein, alternation of wetting and drying is processed 15 days described in step 5), for water spray once makes the moistening rear airing of bed mud 5 days, repeatedly carries out totally 15 days 3 times.
Wherein, the degree of depth of described rotary tillage is for the first time 24cm; The degree of depth of rotary tillage is for the second time 27cm; The degree of depth of rotary tillage is for the third time 30cm; The degree of depth of the 4th rotary tillage is 30cm; The rotary tillage mode of 4 times is the rotary tillage of advancing in the shape of a spiral.
Wherein, described leguminous green manure, preferably one or more in khuskhus, French beans, sesbania.
The present invention also provide with heavy metal polluted bed mud in coarse sand earth's surface build topsoil method Heavy Metal Pollution in Sediments administer on application.
The present invention also provides the application of the topsoil obtaining in coarse sand earth's surface structure topsoil method with heavy metal polluted bed mud in proportion of crop planting.
Compared with prior art, the present invention has the following advantages and effect:
The present invention is take heavy-metal composite pollution river bottom mud as handling object, adopting fused calcium magnesium phosphate, calcium oxide, light dolomite is heavy metal stabilizer, take coarse sand, also field green manure is as physicochemical property modifying agent, the bed mud heavy metal stablizing effect of processing is good, can leach composition reduces, be difficult to Crop, physicochemical property improved effect is obvious simultaneously, has good effect of increasing production.For the disposal of resources of contaminated river bottom mud provides outlet, for the structure of topsoil in coarse sand soil training works has proposed new method, become in China's bed mud disposal of resources, land control engineering, topsoil builds complement each other and organically combine simultaneously.
The degree of depth of the present invention's rotary tillage is for the first time 24cm, guarantees the preliminary mixing of bed mud and stabilizing agent and contacts; Alternation of wetting and drying is processed 15 days, rotary tillage for the second time after being exposed to the sun 7 days, and the degree of depth is 27cm, rotary tillage direction, with reverse for the first time, guarantees that bed mud, stabilizing agent and part coarse sand fully mix; The mixture quality moisture content of bed mud, coarse sand, stabilizing agent carries out rotary tillage for the third time while being reduced to 25～30%, rotary tillage direction is vertical with rotary tillage for the second time, the degree of depth is 30cm, guarantee that bed mud and coarse sand mix by design proportion (volume 4:1), make constructed topsoil thickness meet the requirement of land control.The present invention is consumption and bed mud and the coarse sand mixed proportion that realizes bed mud and coarse sand by the laying depth of on-the-spot bed mud and the rotary tillage degree of depth, has actual productive value and meaning.After first three rotary tillage soil body settlement stability, this topsoil thickness >=26cm.
Topsoil sediment particles diameter≤3cm that method of the present invention obtains after processing, bed mud and coarse sand mix.
Inventor is from the angle of heavy metal occurrence patterns and crops absorption, by leaching test, the growing vegetables field experiment of heavy metal, the aspects such as rain fed crop field experiment have proved that the heavy metal of processing in rear bed mud has good stablizing effect, has prevented secondary pollution problem and the food-safety problem of bed mud in agricultural resources utilizes.The acid-base value of inventor's soil from bed mud builds topsoil regulates test, soil fertility improvement and volume increase test, soil mechanical composition to regulate the aspects such as test to prove that bed mud builds topsoil and can entirety improve soil quality effect, for the further utilization of bed mud in agricultural resources laid a good foundation.
Test through reality, the method of the invention bed mud after treatment, the stabilization effect of heavy metal Cr, Cu, Zn and Cd is obvious, content of beary metal in water spinach and the green soy bean of plantation all lower than regulation in " the GB2762-2012 national food safety standard-pollutants in food limitation " of up-to-date issue relevant limit value, and lower than regulation in " GB18406.1-2001 agricultural product security quality pollution-free vegetable safety requirements " relevant limit value.
Embodiment
Following examples are used for illustrating the present invention, but are not used for limiting the scope of the invention.
Embodiment 1 builds the method for topsoil in coarse sand earth's surface with heavy metal polluted bed mud
In November, 2012, in Xia Si village, Xin Po town, Longhua District, Haikou City, Hainan Province, by loose, smooth earth's surface, coarse sand to be renovated ground, the standard of ground grading is the ratio of slope≤3:1000.
Bed mud in the Haikou City Xin Po town river embankment of dredging out is carried out to natural-dehydration and pave after nature dries dehydration and be evenly laid in above coarse sand, bed mud laying depth is 24cm.
Evenly apply stabilizing agent to above-mentioned heavy metal polluted bed mud, described stabilizing agent comprises fused calcium magnesium phosphate, calcium oxide, light dolomite, and mass ratio corresponding to three is 5:5:2, every stabilizing agent 1 weight portion for 100 weight portion bed muds.
On the ground of having spread stabilizing agent, carry out rotary tillage for the first time with rotovator (rotary tillage service machine is below identical for Dongfanghong 1GQN-125 rotovator, China Yituo Group Co.,Ltd); Alternation of wetting and drying is processed 15 days, is exposed to the sun 7 days, carries out rotary tillage for the second time, rotary tillage direction and contrary for the second time; After rotary tillage, the mixture quality moisture content of bed mud, coarse sand, stabilizing agent is reduced to 25～30% naturally, carries out rotary tillage for the third time, and rotary tillage direction is with vertical for the second time; After rotary tillage, plant for the third time 1 batch of leguminous green manure, green manuring is khuskhus, carries out the 4th rotary tillage by also field of green manure after growing to plant height 30cm, after 2 months, obtains topsoil.Described alternation of wetting and drying is processed 15 days, for water spray once makes the moistening rear airing of bed mud 5 days, repeatedly carries out totally 15 days 3 times.The degree of depth of described rotary tillage is for the first time 24cm; The degree of depth of rotary tillage is for the second time 27cm; The degree of depth of rotary tillage is for the third time 30cm; The degree of depth of the 4th rotary tillage is 30cm; The rotary tillage mode of 4 times is the rotary tillage of advancing in the shape of a spiral.
After the 4th rotary tillage 2 months, use the Method-1311 Toxicity Characteristic Leaching Procedure(TCLP of EPA) measure, 0.3% lime+0.3% fused calcium magnesium phosphate is set simultaneously and does stabilizing agent (100 weight portion bed muds add 0.3 weight portion lime and 0.3 weight portion fused calcium magnesium phosphate) as a comparison.Described method bed mud after treatment, TCLP leaching concentration obviously reduces.Wherein, the leaching concentration of Cr element has reduced 46.91% than not stablizing group, has reduced 32.56% with respect to lime fused calcium magnesium phosphate processed group; The leaching concentration of Cu element has reduced 72.22% than not stablizing group, has reduced 45.07% with respect to lime fused calcium magnesium phosphate processed group; The leaching concentration of Zn element has reduced 26.14% than not stablizing group, has reduced 24.07% with respect to lime fused calcium magnesium phosphate processed group; The leaching concentration of Cd element has reduced 40.55% than not stablizing group, has reduced 30.41% with respect to lime fused calcium magnesium phosphate processed group; In leachate, the concentration of Pb, As, Hg element is all lower than detection limit.
Result is specifically in table 1, and Leaching of Heavy Metals reduces, and stablizing effect is obvious.
Heavy metal concentration (unit: μ g/L) in bed mud TCLP leachate before and after table 1 is stable
| Process title | Cr | Cu | Zn | Cd | Pb | As | Hg |
| Unstable | 4.37 | 11.23 | 146.68 | 5.08 | ＜1.00 | ＜0.15 | ＜0.15 |
| Lime+fused calcium magnesium phosphate | 3.44 | 5.68 | 142.69 | 4.34 | ＜1.00 | ＜0.15 | ＜0.15 |
| Stabilizing agent of the present invention | 2.32 | 3.12 | 108.34 | 3.02 | ＜1.00 | ＜0.15 | ＜0.15 |
The application of the topsoil that embodiment 2 the present invention obtain on proportion of crop planting
On the topsoil that bed mud obtains by method of the present invention in embodiment 1, plant according to a conventional method water spinach (originating from respectively Thailand up to seed Co., Ltd and gold soil, Beijing agrotechnique research institute), Dry crop green soy bean.Simultaneously do the stable test topsoil of stabilizing agent so that 0.3% lime+0.3% fused calcium magnesium phosphate to be set, be covered with do not stablize bed mud topsoil as a comparison.In process of crop growth, record physical signs and growth indexes, when results, record output, and vegetables and green soy bean are carried out to content of beary metal detection.
Result is, the physical signs of the rear bed mud planting vegetable of processing and growth indexes are all better than 0.3% lime+0.3% fused calcium magnesium phosphate and do the vegetables of planting on stabilizing agent and untreated bed mud, and output is also done soil and the untreated bed mud soil of stabilizing agent apparently higher than 0.3% lime+0.3% fused calcium magnesium phosphate.Process the content of beary metal of planting vegetable on the bed mud of front and back in table 2.
Content of beary metal (unit: mg/kg) before and after table 2 is stable in bed mud planting vegetable
After stabilization processes, the content of beary metal in water spinach all obviously reduces.Cr constituent content has reduced 43.96% than not stablizing group, has reduced 22.65% with respect to lime fused calcium magnesium phosphate processed group; Cu constituent content has reduced 39.14% than not stablizing group, has reduced 23.03% with respect to lime fused calcium magnesium phosphate processed group; Cd constituent content has reduced 82.59% than not stablizing group, has reduced 34.52% with respect to lime fused calcium magnesium phosphate processed group; The unstable group of Pb constituent content represents to detect a bit, but stabilizer treatment of the present invention and lime fused calcium magnesium phosphate are processed content lower than method detection limit; As constituent content is all lower than method detection limit.
After stabilization processes, the heavy metal of green soy bean (edible part), each processes Pb, As element lower than method detection limit; Cr constituent content has reduced 44.27% than not stablizing group, has reduced 17.04% with respect to lime fused calcium magnesium phosphate processed group; Cu constituent content has reduced 50.14% than not stablizing group, has reduced 20.21% with respect to lime fused calcium magnesium phosphate processed group; Cd constituent content has reduced 63.22% than not stablizing group, has increased by 48.39% with respect to lime fused calcium magnesium phosphate processed group.
The topsoil acid-base value that embodiment 3 the present invention build regulates application
In embodiment 1, bed mud, by the present invention through stablizing constructed topsoil, is planted water spinach (originating from Thailand up to seed Co., Ltd) according to a conventional method.Simultaneously so that being set, 0.3% lime+0.3% fused calcium magnesium phosphate does the stable topsoil of stabilizing agent (but this processes not green manuring processing), with locality nature agricultural land soil as a comparison.Soil mechanical composition regulating effect (table 3) and soil fertility condition effect (table 4) after monitoring different disposal soil planting crop.
The different stable topsoil mechanical composition regulating effects (unit: %) of processing of table 3
Regulate data to find out from the soil mechanical composition of table 3 field experiment, applying this invention technology can make the mechanical composition of constructed topsoil have larger regulating effect, constructed soil particle structure is had and very significantly improve effect, improved soil water-retaining, reported fertile effect.Take natural farmland soil as contrast, this technology can make clay content promote nearly 4%, silt content also contrasts and can improve, sand grain content reduces, this has larger impact for soil structure, especially by the biological modification measure of green manure, can make constructed soil not be prone to situation about hardening.
The different stable topsoil fertility regulating effects (unit: %) of processing of table 4
From table 4 field soil Fertility Monitoring test data, the soil of the more natural farmland of the present invention's soil organic matter after treatment and other processing has larger increase, and the amplitude of increase is more than 28%; It is very obvious that total nitrogen content is processed increase effect, and this processing has increased respectively 4.66 times, 1.04 times than nature farmland and the processing of lime fused calcium magnesium phosphate group, and this invention technology is remarkable to fertility regulating effect, is presented as that good production application is worth.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, do not departing under the prerequisite of the technology of the present invention principle; can also make some improvements and modifications, these improvements and modifications also should be considered as protection scope of the present invention.
Claims (10)
1. a method that builds topsoil with heavy metal polluted bed mud in coarse sand earth's surface, comprises the steps:
1) loosened in coarse sand to be renovated earth's surface, ground grading;
2) heavy metal polluted bed mud is laid on the coarse sand earth's surface described in step 1);
3) stabilizing agent is spread on to step 2) on described heavy metal polluted bed mud;
4) at completing steps 3) ground on carry out rotary tillage for the first time;
5) alternation of wetting and drying is processed 15 days, is exposed to the sun 7 days, carries out rotary tillage for the second time, rotary tillage direction and contrary for the second time; After rotary tillage, the mixture quality moisture content natural-dehydration of bed mud, coarse sand, stabilizing agent is reduced to 25～30%, carries out rotary tillage for the third time, and rotary tillage direction is with vertical for the second time;
6) after rotary tillage for the third time, plant 1 batch of leguminous green manure, when green manure plant height reaches 30-35cm, carry out the 4th rotary tillage by also field of green manure, after 2 months, obtain topsoil.
2. the method for topsoil of building in coarse sand earth's surface with heavy metal polluted bed mud according to claim 1, is characterized in that, the standard of ground grading is the ratio of slope≤3:1000 described in step 1).
3. the method for topsoil of building in coarse sand earth's surface with heavy metal polluted bed mud according to claim 1, is characterized in that step 2) described heavy metal polluted bed mud is heavy metal pollution river bottom mud and/or heavy metal pollution bottom mud in lake; The thickness of heavy metal polluted bed mud tiling is 24cm.
4. the method for topsoil of building in coarse sand earth's surface with heavy metal polluted bed mud according to claim 1, is characterized in that, the stabilizing agent described in step 3) is that heavy metal is processed stabilizing agent.
5. the method for topsoil of building in coarse sand earth's surface with heavy metal polluted bed mud according to claim 4, is characterized in that, the stabilizing agent described in step 3) comprises following weight portion composition: 5 parts, fused calcium magnesium phosphate, 5 parts, calcium oxide, 1～3 part of light dolomite.
6. the method for topsoil of building in coarse sand earth's surface with heavy metal polluted bed mud according to claim 5, is characterized in that, the usage amount of the stabilizing agent described in step 3) is: every 100 weight portion bed muds stabilizing agent 1 weight portions.
7. the method for topsoil of building in coarse sand earth's surface with heavy metal polluted bed mud according to claim 1, is characterized in that, alternation of wetting and drying is processed 15 days described in step 5), for water spray once makes the moistening rear airing of bed mud 5 days, repeatedly carries out totally 15 days 3 times.
8. the method that builds topsoil with heavy metal polluted bed mud in coarse sand earth's surface according to claim 1, is characterized in that, the degree of depth of described rotary tillage is for the first time 24cm; The degree of depth of rotary tillage is for the second time 27cm; The degree of depth of rotary tillage is for the third time 30cm; The degree of depth of the 4th rotary tillage is 30cm.
Claim 1-8 any one with heavy metal polluted bed mud in coarse sand earth's surface build topsoil method Heavy Metal Pollution in Sediments administer on application.
10. the application of the topsoil that claim 1-8 any one obtains in coarse sand earth's surface structure topsoil method with heavy metal polluted bed mud in proportion of crop planting.
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| CN105254401A (en) * | 2015-09-23 | 2016-01-20 | 北京世纪阿姆斯生物工程有限公司 | Soil improvement agent, and preparation method thereof |
| CN106811201A (en) * | 2017-01-24 | 2017-06-09 | 东南大学 | A kind of magnesium oxide-based curing agent and its application process |
| CN108834460A (en) * | 2018-05-16 | 2018-11-20 | 美丽国土（北京）生态环境工程技术研究院有限公司 | Mud utilizes methods and applications |
| CN110216139A (en) * | 2019-05-24 | 2019-09-10 | 广州市华南自然资源科学技术研究院 | A kind of water transfer heavy metals in farmland of improving the soil removes the construction method of system |
| CN114568061A (en) * | 2022-01-26 | 2022-06-03 | 广西壮族自治区农业科学院 | Rapid reconstruction method of plough layer |
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| CN105254401A (en) * | 2015-09-23 | 2016-01-20 | 北京世纪阿姆斯生物工程有限公司 | Soil improvement agent, and preparation method thereof |
| CN106811201A (en) * | 2017-01-24 | 2017-06-09 | 东南大学 | A kind of magnesium oxide-based curing agent and its application process |
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| CN110216139A (en) * | 2019-05-24 | 2019-09-10 | 广州市华南自然资源科学技术研究院 | A kind of water transfer heavy metals in farmland of improving the soil removes the construction method of system |
| CN114568061A (en) * | 2022-01-26 | 2022-06-03 | 广西壮族自治区农业科学院 | Rapid reconstruction method of plough layer |
| CN114568061B (en) * | 2022-01-26 | 2023-10-31 | 广西壮族自治区农业科学院 | Rapid reconstruction method of plough layer |
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