CN103849274A - Furniture decoration paint made of shell powder - Google Patents

Furniture decoration paint made of shell powder Download PDF

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Publication number
CN103849274A
CN103849274A CN201210509144.0A CN201210509144A CN103849274A CN 103849274 A CN103849274 A CN 103849274A CN 201210509144 A CN201210509144 A CN 201210509144A CN 103849274 A CN103849274 A CN 103849274A
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parts
coating
agent
water
add
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CN201210509144.0A
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Chinese (zh)
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刘官柱
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DALIAN FEIMA OFFICE FURNITURE Co Ltd
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DALIAN FEIMA OFFICE FURNITURE Co Ltd
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Priority to CN201210509144.0A priority Critical patent/CN103849274A/en
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Abstract

The invention discloses a furniture decoration paint made of shell powder. The preparation method comprises the following steps: subjecting the raw materials to a pretreatment, orderly adding raw materials such as shell powder, and the like according to a certain mass ratio under stirring; then adding 15 to 45 parts of antifoaming agent and 15 to 45 parts of anti-setting agent into the raw materials, stirring to dissolve the auxiliary agents so as to obtain a mixed solution; adding 55 to 75 parts of ethane-vinyl acetate copolymer emulsion adhesive, 10 to 50 parts of water-white rosin, 20 to 40 parts of polyacrylate water-retaining agent, 20 to 40 parts of polyurethane thickening agent, 20 to 40 parts of dicyclohexyl phthalate plasticizer, and 40 to 70 parts color paste; slowly and evenly spraying the materials mentioned above into a blending container, continuously stirring so as to obtain the paint; painting a substrate surface with the paint; and drying and balancing the water content so as to obtain the finished product. The paint prepared by the preparation method mentioned above is green, environment-friendly, and pollution-free, has a very good adhesive force on basic surface, has a very good flexibility and heat resistant property, which are better than that of conventional paints, and also has a very wide application range.

Description

A kind of oyster shell whiting furniture decoration coating
Technical field
The present invention relates to a kind of coating and preparation method thereof, particularly a kind of oyster shell whiting furniture decoration coating.
Background technology
Along with the quickening of China's modernization construction, the raising of living standards of the people and improvement, the indoor environment building cause of China has had considerable progress, people pollute consciousness to living environment and are improving constantly, but, aggregate level still allows of no optimist, and room air pollution remains one of main killer who is detrimental to health, and strengthens administering very urgent.It is introduced, the primary pollution source of current Chinese indoor environment is from building, decoration and furniture, and formaldehyde, benzene, ammonia pollute to exceed standard and had a strong impact on the healthy of people.House ornamentation is inevitably, paint, and wood furniture, ubiquitous.Existing coating products in the market, can not adsorb obnoxious flavour, and the obnoxious flavour of the high density having in cannot adsorption chamber, can not meet the requirement of people to quality of life.
Modern science analytical proof, oyster shell whiting is rich in multiple element, and Shellfish is the food that people extremely like, but left a large amount of shell becomes the rubbish that is difficult to disaggregating treatment.Shell is rich in calcium carbonate, the traditional chemical thimerosal of " shell solution " alternative hospital life-time service, and not only sterilisation effect is good, and can not produce any chemical pollution to environment.This " shell solution ", although alkalescence is very strong, can not play corrosive nature as other basic solutions, and even the skin of harm people.This is because because shellfish lives in seawater, and seawater is dissolved with the mineral composition of multiple prevention corrosion, therefore " shell solution " is also a kind of safe home disinfecting agent, is specially adapted to kitchen, bathroom and toilet disinfection.
House fitting and furniture all use formaldehyde as tamanori while making in a large number, but formaldehyde is a kind of volatile chemical, and after sucking, nature can have a negative impact to human body, even may bring out cancer.And the paint for wall of oyster shell whiting can make concentration of formaldehyde in room be reduced to original 1/5th at short notice, in addition can also absorb other objectionable constituent that all chemical coatings come out, ensure to make the harmful chemical component in room air be controlled at lower level.Electron microscope demonstration, shell powder contains many duck eyes, once volatile matter formaldehyde enters duck eye, the distinctive calcium carbonate of shell will be decomposed into the harmless element such as hydrogen and carbonic acid gas.
No matter the method for the invention is choosing or the flow process of manufacture craft of raw material, all abandoned completely in original coating production process, add a large amount of industrial chemicals drawback, avoid the secondary pollution of indoor wall finishing, environmental protection low-carbon (LC), more remarkable more by force to the ability of obnoxious flavour adsorption-decomposition function.
Summary of the invention
The object of this invention is to provide a kind of strong adhesion, difficult drop-off, be applicable to the furniture decoration coating of multiple body surface, can adopt on the plate face of sheet material and apply professional tackiness agent, local or entirety applies the decorative paint of following explained hereafter, thereby prepare sturdy and durable, texture good, pattern is changeable, price is moderate, the household decorations that cost performance is good or furniture.Coating of the present invention is achieved through the following technical solutions:
2. the oyster shell whiting that utilizes of the present invention is prepared furniture decoration coating, and it is made up of in mass ratio following component:
Figure BDA00002494920500021
Preparation method for coating mentioned above is as follows, and preparation process is:
(1) prepare oyster shell whiting: powder of natural shell is raw material, after cleaning, carry out again sterilising treatment, be crushed to 100 ~ 300 orders, after being dried, obtain oyster shell whiting;
(2) in pill tank, add 800 ~ 1000 parts of water, in the situation that opening whipping appts, 60 ~ 90 parts of sodium polyacrylates, 70 ~ 90 parts of tripoly phosphate sodium STPPs and 70 ~ 90 parts of Sodium hexametaphosphate 99s are slowly spread equably in pill tank and do not stop to stir, under agitation condition, slowly add 200 part of 100 order oyster shell whiting, then add 15 ~ 45 parts of defoamers, 15 ~ 45 portions of anti-settling agents, stir it are fully dissolved, and obtain mixed solution;
(3) by 55 ~ 75 parts of ethene-vinyl acetate copolymer emulsion sizing agents under agitation condition, slowly add equably in the mixed solution of step (2) gained, successively add subsequently 10 ~ 50 parts of water-white rosin, 20 ~ 40 parts of polyacrylic ester water-holding agents, 20 ~ 40 parts of polyurethane thickeners, 20 ~ 40 parts of dicyclohexyl phthalate softening agent and 40 ~ 70 parts of mill bases; Under agitation condition, obtain coating;
(4) step (3) gained coating adopts manual print roll coating mode coated substrate surface; Dry 20 ~ 50min under 40 ~ 100 DEG C of conditions, after equilibrium water content, finished product.
For technical scheme mentioned above, wherein preferably condition is as follows: the described sterilising method of step (1) is: adopt moist heat sterilization at 121 DEG C, sterilizing 20-30min.
For technical scheme mentioned above, wherein preferably condition is as follows: the condition of step (1) ~ (3) described stirring for to stir 10 ~ 20min under 1000 ~ 2000r/min.
For technical scheme mentioned above, wherein preferably condition is as follows: base material is plank or house ornamentation paper, and conventional sheet material has core-board, glued board, solid wood board, shaving board, decoration panel, density board etc.; This coating has good sticking power, thermotolerance, stability, suitability; Be better than existing coating.
In technical scheme mentioned above, except raw material oyster shell whiting, remaining auxiliary agent, comprises anti-settling agent, thickening material, wetting agent, flow agent, defoamer, stablizer, tinting materials etc. can carry out equivalent replacement according to those skilled in the art's the general knowledge of knowing altogether, and the replacement that why not departs from modification, increase and decrease or the equivalent manners done in the situation of technical solution of the present invention in office, within all should being included in scope of the present invention.
Coating of the present invention, has good sticking power, snappiness and wear-resisting weather-proof, is applicable to the surface of various objects, as plastics basal plane, wooden primary surface, paper substrate surface and body of wall basal plane, is applicable to upholstery.Be different from present general commercial coating product, according to different purposes, adopt different proportionings, best effect is provided.
Embodiment
Following non-limiting example can make the present invention of those of ordinary skill in the art's comprehend, but does not limit the present invention in any way.Test method described in following embodiment, if no special instructions, is ordinary method; Described raw material all can obtain from commercial channels.
Embodiment 1. is for paper substrate topcoating
(1) prepare oyster shell whiting: powder of natural shell is raw material, after cleaning, carry out again sterilising treatment, be crushed to 100 orders, after being dried, obtain oyster shell whiting; Described sterilising method is: adopt moist heat sterilization at 121 DEG C, sterilizing 25min.
(2) in pill tank, add 800 parts of water, in the situation that opening whipping appts, 60 parts of sodium polyacrylates, 85 parts of tripoly phosphate sodium STPPs and 85 parts of Sodium hexametaphosphate 99s are slowly spread equably in pill tank and do not stop to stir, under 1500r/min condition, stir 20min, under agitation condition, slowly add 200 part of 100 order oyster shell whiting, then add 25 parts of defoamers, 25 portions of anti-settling agents, stir 20min it is fully dissolved, obtain mixed solution;
(3) by 75 parts of ethene-vinyl acetate copolymer emulsion sizing agents under 1000r/min condition, slowly add equably in the mixed solution of step (2) gained, stir 15min, successively add subsequently 20 parts of water-white rosin, 30 parts of polyacrylic ester water-holding agents, 40 parts of polyurethane thickeners, 40 parts of dicyclohexyl phthalate softening agent and 50 parts of mill bases; Stirring velocity is controlled under 1000r/min condition, stirs 10min, obtains coating;
(4) step (3) gained coating adopts manual print roll coating mode coated substrate surface; Dry 50min under 60 DEG C of conditions, after equilibrium water content, finished product.
(5) will be coated onto on paper substrate surface with the coating that above-mentioned preparation method prepares, in the time that paper substrate is bending, coming off does not appear in film, and film is flawless.To sum up, coating of the present invention, has good snappiness, and good sticking power and thermotolerance are better than existing coating, are applicable to paper substrate surface, have wide range of applications.
Embodiment 2. is for the coating of wooden primary surface
(1) prepare oyster shell whiting: prepare oyster shell whiting: powder of natural shell is raw material, after cleaning, carry out again sterilising treatment, be crushed to 100 ~ 300 orders, after being dried, obtain oyster shell whiting; Described sterilising method is: adopt moist heat sterilization at 121 DEG C, sterilizing 25min.
(2) in pill tank, add 800 parts of water, in the situation that opening whipping appts, 65 parts of sodium polyacrylates, 90 parts of tripoly phosphate sodium STPPs and 90 parts of Sodium hexametaphosphate 99s are slowly spread equably in pill tank and do not stop to stir, under 2000r/min condition, stir 10 ~ 20min, under agitation condition, slowly add 200 part of 100 order oyster shell whiting, then add 25 parts of defoamers, 25 portions of anti-settling agents, stir 20min it is fully dissolved, obtain mixed solution;
(3) by 75 parts of ethene-vinyl acetate copolymer emulsion sizing agents under 2000r/min condition, slowly add equably in the mixed solution of step (2) gained, stir 20min, successively add subsequently 20 parts of water-white rosin, 30 parts of polyacrylic ester water-holding agents, 40 parts of polyurethane thickeners, 40 parts of dicyclohexyl phthalate softening agent and 60 parts of mill bases; Stirring velocity is controlled under 2000r/min condition, stirs 20min, obtains coating;
(4) step (3) gained coating adopts manual print roll coating mode coated substrate surface; Dry 40min under 70 DEG C of conditions, after equilibrium water content, finished product.
(5) will be coated onto on face veneer with the coating that above-mentioned preparation method prepares, in the time that glued board is bending, coming off does not appear in film, and film is flawless.To sum up, coating of the present invention, has good snappiness, and good sticking power and thermotolerance are better than existing coating, are applicable to wooden primary surface, have wide range of applications.
Embodiment 3. is for the coating of body of wall basal plane
(1) prepare oyster shell whiting: powder of natural shell is raw material, after cleaning, carry out again sterilising treatment, be crushed to 100 ~ 300 orders, after being dried, obtain oyster shell whiting; Described sterilising method is: adopt moist heat sterilization at 121 DEG C, sterilizing 25min.
(2) in pill tank, add 800 parts of water, in the situation that opening whipping appts, 60 parts of sodium polyacrylates, 80 parts of tripoly phosphate sodium STPPs and 80 parts of Sodium hexametaphosphate 99s are slowly spread equably in pill tank and do not stop to stir, under 2000r/min condition, stir 10 ~ 20min, under agitation condition, slowly add 200 part of 100 order oyster shell whiting, then add 35 parts of defoamers, 35 portions of anti-settling agents, stir 20min it is fully dissolved, obtain mixed solution;
(3) by 65 parts of ethene-vinyl acetate copolymer emulsion sizing agents under 2000r/min condition, slowly add equably in the mixed solution of step (2) gained, stir 20min, successively add subsequently 20 parts of water-white rosin, 30 parts of polyacrylic ester water-holding agents, 40 parts of polyurethane thickeners, 40 parts of dicyclohexyl phthalate softening agent and 50 parts of mill bases; Stirring velocity is controlled under 2000r/min condition, stirs 20min, obtains coating;
(4) step (3) gained coating adopts manual print roll coating mode coated substrate surface; Dry 20min under 100 DEG C of conditions, after equilibrium water content, finished product.
(5) by being coated onto on body of wall basal plane with the coating that above-mentioned preparation method prepares, there is equally good sticking power, be better than existing coating.

Claims (6)

1. an oyster shell whiting furniture decoration coating, is characterized in that, is made up of in mass ratio following component:
Figure FDA00002494920400011
2. a kind of coating according to claim 1, is characterized in that, its preparation method comprises:
(1) prepare oyster shell whiting: powder of natural shell is raw material, after cleaning, carry out again sterilising treatment, be crushed to 100 ~ 300 orders, after being dried, obtain oyster shell whiting;
(2) in pill tank, add 800 ~ 1000 parts of water, in the situation that opening whipping appts, 60 ~ 90 parts of sodium polyacrylates, 70 ~ 90 parts of tripoly phosphate sodium STPPs and 70 ~ 90 parts of Sodium hexametaphosphate 99s are slowly spread equably in pill tank and do not stop to stir, under agitation condition, slowly add 200 part of 100 order oyster shell whiting, then add 15 ~ 45 parts of defoamers, 15 ~ 45 portions of anti-settling agents, stir it are fully dissolved, and obtain mixed solution;
(3) by 55 ~ 75 parts of ethene-vinyl acetate copolymer emulsion sizing agents under agitation condition, slowly add equably in the mixed solution of step (2) gained, successively add subsequently 10 ~ 50 parts of water-white rosin, 20 ~ 40 parts of polyacrylic ester water-holding agents, 20 ~ 40 parts of polyurethane thickeners, 20 ~ 40 parts of dicyclohexyl phthalate softening agent and 40 ~ 70 parts of mill bases; Under agitation condition, obtain coating;
(4) step (3) gained coating adopts manual print roll coating mode coated substrate surface; Dry 20 ~ 50min under 40 ~ 100 DEG C of conditions, after equilibrium water content, finished product.
3. coating according to claim 1, is characterized in that, the described sterilising method of step (1) is: adopt moist heat sterilization at 121 DEG C, sterilizing 20-30min.
4. coating according to claim 1, is characterized in that, the condition of step (1) ~ (3) described stirring for to stir 10 ~ 20min under 1000 ~ 2000r/min.
5. coating according to claim 1, is characterized in that, described wooden base has core-board, glued board, solid wood board, shaving board, decoration panel, the one in density board.
6. coating according to claim 1, is characterized in that, described auxiliary agent comprises anti-settling agent, thickening material, wetting agent, flow agent, defoamer, stablizer, the one in tinting material.
CN201210509144.0A 2012-11-29 2012-11-29 Furniture decoration paint made of shell powder Pending CN103849274A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104119798A (en) * 2014-06-23 2014-10-29 青岛万源生物科技有限公司 Device and method for producing marine organism shell powder coating and marine organism shell powder coating
CN105062331A (en) * 2015-08-06 2015-11-18 天长市巨龙车船涂料有限公司 Absorption odor-less emulsion paint added with lime and crab shell powder and preparation method thereof

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104119798A (en) * 2014-06-23 2014-10-29 青岛万源生物科技有限公司 Device and method for producing marine organism shell powder coating and marine organism shell powder coating
CN105062331A (en) * 2015-08-06 2015-11-18 天长市巨龙车船涂料有限公司 Absorption odor-less emulsion paint added with lime and crab shell powder and preparation method thereof

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Application publication date: 20140611