CN103830121B - Liquid make-up - Google Patents
Liquid make-up Download PDFInfo
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- CN103830121B CN103830121B CN201310624841.5A CN201310624841A CN103830121B CN 103830121 B CN103830121 B CN 103830121B CN 201310624841 A CN201310624841 A CN 201310624841A CN 103830121 B CN103830121 B CN 103830121B
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Abstract
The present invention provides a kind of liquid make-up, it is by being compounded ascorbic acid glucoside, 4 methoxysalicylic acids have an excellent whitening effect, and smoothly there is satiety when being applied to skin, and skin absorbs soon, salubrious not sticky sense of touch is formed after absorption, can obtain in the past no unique use feeling.A kind of liquid make-up, it is characterised in that contain：(A) ascorbic acid glucoside of 1.0~5.0 mass % and/or 4 methoxysalicylic acids or its salt, the polyacrylic acid of (B) 0.001~0.1 mass % or xanthans of its metal salt and (C) 0.01~1.0 mass %, the L values of the liquid make-up are more than 50, are transparent or semitransparent.
Description
Technical field
The present invention relates to the liquid make-up with whitening effect.Further specifically, Vitamin C is contained even if being related to
Sour glucoside and/or 4- methoxysalicylic acid will not stick it is greasy or astringent, have satiety and skin absorb it is fast, absorb after formed
The liquid make-up with unique use feeling of salubrious sense of touch.
Background technology
The alkoxy salicylic acid such as ascorbic acid glucoside and 4- methoxysalicylic acids is the known makeup as whitening agent
, there are the cosmetics of the various forms compounded with the whitening agent in product component.But it is also known that, according to needed for performance whitening effect
The amount of full, be compounded ascorbic acid glucoside and 4- methoxyl group water relative to amount of the cosmetics generally more than 1.0 mass %
Poplar acid can produce glutinous greasy, astringent when salt form chemicals.
Recorded in patent document 1, by the amino modified the macromolecule organic silicon for being compounded the degree of polymerization with particular range
Or ammonium modified high-molecular organosilicon, it can suppress glutinous greasy as caused by the whitening agents such as ascorbic acid glucoside, ursin, can obtain
The salubrious use feeling used suitable for spring and summer.
Recorded in patent document 2, it is a small amount of by being compounded in the liquid make-up containing alkoxy salicyclic acid derivatives
The oil component of (0.01~3 mass %), can suppress glutinous greasy, astringent.In addition, recorded in patent document 3, in compounding 4- methoxies
In the cosmetics of base salicylic acid or its salt, especially liquid make-up combination compounded with a certain amount of 4- methoxysalicylic acids or its
When salt, hyaluronic acid and xanthans, it is glutinous it is greasy be suppressed, can obtain use feeling and the excellent liquid make-up of whitening effect.
However, although the cosmetics described in above patent document 1~3 can suppress by ascorbic acid glucoside, 4- first
It is glutinous greasy caused by epoxide salicylic acid, but still have insufficient part for the use sense of touch as cosmetics.
Prior art literature
Patent document
Patent document 1：Japanese Unexamined Patent Publication 2002-60331 publications
Patent document 2：Japanese Unexamined Patent Publication 2009-242326 publications
Patent document 3：Japanese Unexamined Patent Publication 2011-136936 publications
The content of the invention
Problems to be solved by the invention
For applied to liquid make-ups such as the cosmetics of skin, especially toners, it is important using sense of touch
One of characteristic.It is an object of the invention to provide a kind of cosmetics, it is by being compounded ascorbic acid glucoside, 4- methoxyl group water
Poplar is sour and has excellent whitening effect, and smoothly has satiety when applied to skin, and skin absorbs fast, suction
Formed after receipts clearly without sticky sense of touch, can obtain in the past no unique use feeling.
The solution used to solve the problem
The inventors of the present invention have made intensive studies to solve the above-mentioned problems, it turns out that, by compounded with performance
The transparent or semitransparent fluidization of an adequate amount of ascorbic acid glucoside and/or 4- methoxysalicylic acid needed for whitening effect
The polyacrylic acid and xanthans of combination compounding ormal weight, can reach foregoing unique use feeling in cosmetic, so as to complete
The present invention.
That is, the present invention is a kind of liquid make-up, it is characterised in that is contained：(A) ascorbic acid of 1.0~5.0 mass %
Glucoside and/or 4- methoxysalicylic acids or its salt, the polyacrylic acid or its metal salt and (C) of (B) 0.001~0.1 mass %
The xanthans of 0.01~1.0 mass %, the L values of the liquid make-up are more than 50, are transparent or semitransparent.
The effect of invention
According to the present invention, by the way that the polyacrylic acid and xanthans of ormal weight is applied in combination, even if being compounded by high concentration anti-
The salt form whitening agent of bad hematic acid glucoside, 4- methoxysalicylic acids etc and there is excellent whitening effect, can also obtain as
Under unique use feeling：Will not stick it is greasy, it is smooth when applied to skin and there is satiety (dense and plump sense of touch), and
And skin absorbs soon, and salubrious sense of touch is formed after absorption.
Embodiment
(A) ascorbic acid glucoside and/or 4- methoxysalicylic acids
As long as ascorbic acid glucoside is used as the glucosides of the ascorbic acid of whitening agent in cosmetics etc., without spy
Do not limit, for example, L-AA glucosides such as L-AA -2- glucosides etc. can be included.
4- methoxysalicylic acids can be used as selecting in the 4- methoxysalicylic acids or its salt of whitening agent from cosmetics etc.
Select.As the salt of 4- methoxysalicylic acids, it is not particularly limited, such as can includes as sodium salt, sylvite, calcium salt, magnesium salts
Alkali metal salt or alkali salt；And the salt such as ammonium salt, amino-acid salt.
The compounding amount phase of ascorbic acid glucoside and/or 4- methoxysalicylic acids (component A) in the cosmetics of the present invention
It is 1.0~5.0 mass % for liquid make-up total amount, is preferably 1.0~3.0 mass %.During less than 1.0 mass %, it is difficult to obtain
Sufficient whitening effect, in addition, the glutinous greasy problem of the problem as the present invention will not be produced.On the other hand, it is compounded more than 5.0
During quality %, greasy inhibition is sticked sometimes and is not given full play to.Especially, the lower limit as component A, can also use 1.0 matter
%, 1.5 mass %, the value of 2.0 mass % are measured, as upper limit value, 5.0 mass %, 4.0 mass %, 3.0 mass % can also be used
Value.
(B) polyacrylic acid
The polyacrylic acid (component B) used in the present invention is that water-soluble thickener can be used as in cosmetics, quasi drug etc.
The polyacrylic acid of compounding or its metal salt, are preferably sodium salt.As long as the weight average molecular weight of polyacrylic acid is with thickening power
In the range of be just not particularly limited, preferably using the polyacrylic acid of the molecular weight with 1,000,000~6,000,000 or so.
The polyacrylic acid used in the present invention can also be commercially available product, for example, as complete neutralization thing (sodium salt), can enumerate
Go out ARONVIS SX (molecular weight 4,000,000~5,000,000), ARONVIS MX (molecular weight 2,000,000~3,000,000) etc., as in part
And thing, ARONVIS AHX etc. (being Toagosei Co., Ltd's manufacture) can be included.
The compounding amount of polyacrylic acid in the cosmetics of the present invention is 0.001~0.1 matter relative to liquid make-up total amount
Measure %, be preferably 0.001~0.01 mass %.During less than 0.001 mass %, the present invention can not obtain the use feeling of uniqueness, compounding
During more than 0.1 mass %, exist produce glutinous greasy tendency on the contrary.Especially, the lower limit as component B, can also use 0.001
Quality %, 0.002 mass %, the value of 0.005 mass %, as upper limit value, can also use 0.1 mass %, 0.05 mass %, 0.01
The value of quality %.
(C) xanthans
The xanthans (component C) used in the present invention is as long as to be used for the xanthans of cosmetics, quasi drug etc. all the time
.As xanthans, commercially available product can also be used.
The present invention cosmetics in xanthans compounding amount relative to liquid make-up total amount for 0.01~1.0 mass %,
Preferably 0.05~0.3 mass %.During less than 0.01 mass %, reduction is astringent, glutinous greasy effect is insufficient, more than 1.0 mass %
When, become glutinous greasy the reason for waiting on the contrary.Especially, the lower limit as component C, can also use 0.01 mass %, 0.02 mass %,
The value of 0.05 mass %, as upper limit value, can also use 1.0 mass %, 0.7 mass %, the value of 0.3 mass %.
The cosmetics of the present invention, can also be without prejudice to this hair in addition to containing above-mentioned required component (component A, B and C)
The other any conditions for being mixed in the liquid make-ups such as toner can be matched somebody with somebody by containing in the range of bright effect.
Wherein, by being further compounded hydrophilic surfactant active's (components D), use feeling can further improve, so
It is preferred that.
The hydrophilic surfactant active used in the present invention is not particularly limited, such as polyoxyethylene polyoxy can be included
The polyoxyalkylene alkyls such as propylene decyl myristyl ether；The polyoxyalkylene hydrogenated castor oil such as Crodaret；It is poly-
The polyoxyalkylene phytosterols such as ethylene oxide phytosterol, polyoxyethylene polyoxypropylene phytosterol；Polyoxyethylene polybutylene two
Two polyalcohol ether of polyoxyalkylene dialkyl group such as two polyalcohol ether of methyl；Polyoxyethylene sorbitan monostearate, polyoxyethylene
The polyoxyalkylene sorbitan alcohol fatty acid ester such as dehydrated sorbitol mono-fatty acid ester；The sucrose-fatties such as sucrose stearate
Ester；The fatty acid polyglycol oxyalkylene glyceride such as isostearic acid polyoxyethylene glyceride；The acyl group alkane such as stearyl N-methyltaurine sodium
Base taurate；Organic silicon modified by polyether such as polyoxyethylene dimethyl siloxane etc..To contained in hydrophilic surfactant active
The quantity of polyalkylene oxide groups is not particularly limited, and is preferably 10~100, such as from 10,20,30,40,50,60 or 100 or so
Radical amount in select.
Particularly preferred hydrophilic surfactant active is selected from polyoxyethylene polyoxypropylene decyl myristyl ether, polyoxy second
One or both of alkene rilanit special, polyoxyethylene phytosterol, two polyalcohol ether of polyoxyethylene polybutylene dimethyl with
On, they are excellent for without glutinous improvement greasy, without the use feeling such as astringent.
The compounding amount of hydrophilic surfactant active is usually 0.01~3.0 mass %, preferably relative to liquid make-up total amount
For 0.05~1.0 mass %.Especially, the lower limit as components D, can also use 0.01 mass %, 0.02 mass %, 0.05 matter
The value of % is measured, as upper limit value, 3.0 mass %, 2.0 mass %, the value of 1.0 mass % can also be used.
By being further compounded hydrophilic surfactant active, skin, which absorbs, becomes more preferable, furthermore it is also possible to increase oil component
Molten, emulsification.
In addition, when being further compounded oil component (component E), especially wettability, without it is astringent, without it is glutinous it is greasy improved, so
It is preferred that.
As the oil component that can be compounded in the present invention, it is not particularly limited, such as liquid fat, solid oil can be included
Fat, wax oil, hydrocarbon ils, higher fatty acids, higher alcohol, ester oil, silicone oil.It is particularly preferred squalene, atoleine, Nexbase 2004, different
Dodecane, isohexadecane, isostearic acid, isooctadecanol, three isooctyl acid glyceride (triethylhexanoin), pentaerythrite four
(thylhexoic acid) ester, thylhexoic acid cetyl, dimethyl polysiloxane, methyl phenyl silicone, decamethylcyclopentaandoxane
Deng liquid oil element.
But α-gel for higher alcohol etc. is composed with hydrophilic surfactant active, by higher fatty acids with
For the higher fatty acids soap that metal salt combination forms, oil component is applied in combination and there is skin absorption of growth encourage liquid make-up etc.
The tendency that use feeling deteriorates, it is not preferable.
In addition, the compounding amount of the oil component in the cosmetics of the present invention is set to 5.0 mass % relative to liquid make-up total amount
Below, the scope for being preferably set to 0.4~3.0 mass % is preferable.When being compounded the oil component more than 5.0 mass %, on the contrary sometimes
Produce glutinous greasy.Especially, the lower limit as component E, can also use 0.4 mass %, 1.0 mass %, the value of 1.5 mass %, as
Upper limit value, can also use 5.0 mass %, 4.0 mass %, the value of 3.0 mass %.
As other any conditions, the component being usually compounded in cosmetics, such as ultra-violet absorber, surface can be included
Activating agent (in addition to components D), moisturizer, thickener (in addition to polyacrylic acid and xanthans), alcohols, powdered ingredients, coloring
Material, pH adjusting agent, stabilizer, preservative, spices, various skin-nourishing agent etc..
Especially, from the viewpoint of moistening effect, preferably it is compounded the moisturizer such as glycerine and butanediol.
The cosmetics of the present invention are skin-lightening cosmetic, and the transparent or semitransparent liquid make-up such as toner especially is being made
When preferably play the present invention effect.It is usually below 1000mPas, particularly preferred as long as just not limiting viscosity for liquid
For below 500mPas, this is preferable for skin absorption.
In the present invention, " transparent or semitransparent " refers to, in the Lab colorimetric systems (Hunter Lab system) of cosmetics
L values be more than 50.L values are that the expression when transparency of purified water being set to 100, completely opaque situation being set to 0 is saturating
The value of lightness.That is, for L values closer to 100, transparency is higher.L values can for example use colour difference meter (Spectro color meter
SE2000 (Japanese electricity Shi Co., Ltd. manufacture) or COLOR-EYE7000A (GretagMacbeth, LLC. are manufactured)) etc. surveyed
It is fixed.The liquid make-up of the present invention is that transparency (L values) is more than 50, transparent or semitransparent cosmetics.
Can be solvable system's liquid make-up (toner, essence in addition, the formulation of liquid make-up is not particularly limited
Magnificent liquid etc.), two series of strata liquid make-ups (Essence etc.), oil-in-water liq cosmetics (toner, lotion, Essence etc.).
Embodiment
Hereinafter, by embodiment, the present invention will be described in detail, but the present invention is not limited to these examples.Compounding in embodiment
Amount is represented with quality % in case of no particular description.
Prepare the cosmetics (Essence) with the composition described in table 1 below~5 and be used as sample.Pass through the expert of 10 people
" quality that skin absorbs ", " wettability ", " without glutinous greasy when dry ", " without astringent when dry " when group membership is coated each sample and
The evaluation of " satiety ".For each pilot project, each panel member is evaluated according to following evaluation score benchmark, according to
Metewand is set as 4 grades by the summation of the evaluation score.Result is shown in each table in the lump.
<Evaluation score benchmark>
5 points：It is very excellent
4 points：It is excellent
3 points：Commonly
2 points：Difference
1 point：It is excessively poor
<Metewand>
◎：Total score is more than 40 points
○：Total score is 30~39 points
△：Total score is 20~29 points
×：Total score is less than 19 points
[table 1]
[table 2]
It is according to table 1 as a result, the sample in the ascorbic acid glucoside compounded with ormal weight is (transparent or semitransparent
Toner) in when being compounded with the polyacrylic acid and xanthans of the amount of particular range in the application, in all characteristics of evaluation
Obtain gratifying result.However, as shown in table 2, when not being compounded one or both of polyacrylic acid and xanthans, use
Property is poor, and satiety is not also obtained even if polyacrylic acid is replaced with hyaluronic acid.In addition, the compounding of polyacrylic acid or xanthans
Amount more than the application particular range when, skin absorption difference is glutinous greasy to become obvious.
[table 3]
[table 4]
It is according to table 3 as a result, even if changing the species of be compounded hydrophilic surfactant active's (components D), as long as
Required component A~C meets the condition of the present invention, it becomes possible to reaches excellent usability.In addition, as shown in Table 4,
By being compounded oil component (component E), wettability further improves, but lacks and must cannot get excellent use feeling during component A~C
By (comparative example 8~10), oil component compounding amount more than 5 mass % when, on the contrary produce stick greasy (comparative example 11).
[table 5]
Shown in table 5, even in being compounded 4- methoxysalicylic acids or 4- methoxysalicylics as whitening agent (component A)
When both acid and ascorbic acid glucoside, as long as component A~C meets that the condition of the present invention can just reach excellent usability.
Other embodiments of the invention (example of liquid make-up) described below.In evaluation similar to the above
To gratifying result.
20 liquid make-up of embodiment (toner)
Claims (3)
1. a kind of liquid make-up, it is characterised in that contain：
(A) ascorbic acid glucoside of 1.0~5.0 mass % and/or 4- methoxysalicylic acids or its salt,
(B) polyacrylic acid of 0.001~0.1 mass % or its metal salt,
(C) xanthans of 0.01~1.0 mass % and
(D) hydrophilic surfactant active of 0.01~3.0 mass %,
The L values of the liquid make-up are more than 50, are transparent or semitransparent.
2. liquid make-up according to claim 1, it is characterised in that (D) hydrophilic surfactant active be selected from
By polyoxyalkylene alkyl, polyoxyalkylene hydrogenated castor oil, polyoxyalkylene phytosterol, two polyalcohol ether group of polyoxyalkylene dialkyl group
Into one or both of group more than.
3. liquid make-up according to claim 1 or 2, it is characterised in that also contain (E) oil component, the oil component
Content is below 5.0 mass % relative to liquid make-up total amount.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012-258991 | 2012-11-27 | ||
| JP2012258991 | 2012-11-27 | ||
| JP2013-199420 | 2013-09-26 | ||
| JP2013199420A JP6273117B2 (en) | 2012-11-27 | 2013-09-26 | Liquid cosmetics |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103830121A CN103830121A (en) | 2014-06-04 |
| CN103830121B true CN103830121B (en) | 2018-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310624841.5A Active CN103830121B (en) | 2012-11-27 | 2013-11-26 | Liquid make-up |
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| Country | Link |
|---|---|
| CN (1) | CN103830121B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101612103A (en) * | 2008-06-24 | 2009-12-30 | 莱雅公司 | Partially applied whitening agent, the method that is used for the skin penetration enhancer of water-soluble whitening active component and is used for skin whitening |
| CN102046142A (en) * | 2008-05-30 | 2011-05-04 | 株式会社资生堂 | Oil-in-water type topical agent for skin |
| CN102470086A (en) * | 2009-12-21 | 2012-05-23 | 株式会社资生堂 | Sheet-like cosmetic |
-
2013
- 2013-11-26 CN CN201310624841.5A patent/CN103830121B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102046142A (en) * | 2008-05-30 | 2011-05-04 | 株式会社资生堂 | Oil-in-water type topical agent for skin |
| CN101612103A (en) * | 2008-06-24 | 2009-12-30 | 莱雅公司 | Partially applied whitening agent, the method that is used for the skin penetration enhancer of water-soluble whitening active component and is used for skin whitening |
| CN102470086A (en) * | 2009-12-21 | 2012-05-23 | 株式会社资生堂 | Sheet-like cosmetic |
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| CN103830121A (en) | 2014-06-04 |
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