CN103830121A - Liquid cosmetic material - Google Patents
Liquid cosmetic material Download PDFInfo
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- CN103830121A CN103830121A CN201310624841.5A CN201310624841A CN103830121A CN 103830121 A CN103830121 A CN 103830121A CN 201310624841 A CN201310624841 A CN 201310624841A CN 103830121 A CN103830121 A CN 103830121A
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Abstract
The invention provides a liquid cosmetic material. With the mixture of ascorbyl glucoside and 4-methoxysalicylic acid, the liquid cosmetic material has an excellent skin whitening effect and is smooth and full when being applied to the skin; and moreover, the liquid cosmetic material can be absorbed by the skin rapidly and generate a refreshing and non-sticky sense of touch, thereby providing an unprecedented unique usage feel. The liquid cosmetic material is characterized by comprising (A) 1.0-5.0 mass% of ascorbyl glucoside and/or 4-methoxysalicylic acid or salt thereof; (B) 0.001-0.1 mass% of polyacrylic acid or metal salt thereof; and (C) 0.01-1.0 mass% of xanthan gum. The L value of the liquid cosmetic material is higher than 50, and the liquid cosmetic material is transparent or semi-transparent.
Description
Technical field
The present invention relates to have the liquid make-up of whitening effect.Further specifically, though relate to contain ascorbic acid glucoside and/or 4-methoxyl group salicylic acid can not stick yet greasy or astringent, have satiety and skin absorb fast, form the unique liquid make-up that uses impression of having of salubrious sense of touch after absorbing.
Background technology
The alkoxyl salicylic acid such as ascorbic acid glucoside and 4-methoxyl group salicylic acid are as whitening agent and known cosmetic composition exists compounding to have the cosmetics of the various forms of this whitening agent.But also known, according to the required sufficient amount of performance whitening effect, be more than 1.0 quality % amount while carrying out the salt type chemicals such as compounding ascorbic acid glucoside and 4-methoxyl group salicylic acid with respect to cosmetics entirety, can produce glutinous greasy, astringent.
In patent documentation 1, record, there is amino modified the macromolecule organic silicon or the ammonium modified high-molecular organosilicon of the degree of polymerization of particular range by compounding, that can suppress to be caused by the whitening agent such as ascorbic acid glucoside, arbutin is glutinous greasy, can obtain being suitable for the salubrious use impression that spring and summer uses.
In patent documentation 2, record, by the oil component of compounding in the liquid make-up that contains alkoxyl salicyclic acid derivatives a small amount of (0.01～3 quality %), can suppress glutinous greasy, astringent.In addition, in patent documentation 3, record, in cosmetics, the especially liquid make-up of compounding 4-methoxyl group salicylic acid or its salt, combine compounding while having a certain amount of 4-methoxyl group salicylic acid or its salt, hyaluronic acid and xanthan gum, stick greasy being suppressed, can obtain using the liquid make-up of impression and whitening effect excellence.
But, although that the cosmetics of recording in above-mentioned patent documentation 1～3 can suppress to be caused by ascorbic acid glucoside, 4-methoxyl group salicylic acid is glutinous greasy, for the use sense of touch as cosmetics, still there is insufficient part.
Prior art document
Patent documentation
Patent documentation 1: TOHKEMY 2002-60331 communique
Patent documentation 2: TOHKEMY 2009-242326 communique
Patent documentation 3: TOHKEMY 2011-136936 communique
Summary of the invention
the problem that invention will solve
For being applied to the liquid make-ups such as the cosmetics of skin, especially astringent, it uses sense of touch is one of important characteristic.The object of the present invention is to provide a kind of cosmetics, it has excellent whitening effect by compounding ascorbic acid glucoside, 4-methoxyl group salicylic acid, and in the time being applied to skin, smoothly there is satiety, and skin absorbs fast, after absorbing, form clearly and not sticky sense of touch, the uniqueness can in the past not had is used impression.
for the scheme of dealing with problems
The inventor etc. conduct in-depth research in order to address the above problem, found that, by have the polyacrylic acid and the xanthan gum that combine compounding ormal weight in the ascorbic acid glucoside of the required abundant amount of performance whitening effect and/or the salicylic transparent or semitransparent liquid make-up of 4-methoxyl group in compounding, can reach the use impression of aforementioned uniqueness, thereby complete the present invention.
; the present invention is a kind of liquid make-up; it is characterized in that; contain: (A) polyacrylic acid of the ascorbic acid glucoside of 1.0～5.0 quality % and/or 4-methoxyl group salicylic acid or its salt, (B) 0.001～0.1 quality % or its slaine and (C) xanthan gum of 0.01～1.0 quality %; the L-value of described liquid make-up is more than 50, for transparent or semitransparent.
the effect of invention
According to the present invention, by being used in combination polyacrylic acid and the xanthan gum of ormal weight, even if the salt type whitening agent by high concentration compounding ascorbic acid glucoside, 4-methoxyl group salicylic acid and so on has excellent whitening effect, also can obtain following uniqueness and use impression: can not stick greasy, level and smooth and there is satiety (dense and plump sense of touch) in the time being applied to skin, and skin absorption is fast, after absorbing, form salubrious sense of touch.
Detailed description of the invention
(A) ascorbic acid glucoside and/or 4-methoxyl group salicylic acid
Ascorbic acid glucoside, as long as be used as the glucosides of the ascorbic acid of whitening agent in cosmetics etc., is not particularly limited, and for example, can list the L-AA glucosides such as L-AA-2-glucoside etc.
4-methoxyl group salicylic acid can be selected from be used as the 4-methoxyl group salicylic acid of whitening agent or its salt cosmetics etc.As the salicylic salt of 4-methoxyl group, be not particularly limited, for example can list alkali metal salt or alkali salt as sodium salt, potassium salt, calcium salt, magnesium salt; And the salt such as ammonium salt, amino acid salts.
The compounding amount of the ascorbic acid glucoside in cosmetics of the present invention and/or 4-methoxyl group salicylic acid (composition A) is 1.0～5.0 quality %, is preferably 1.0～3.0 quality % with respect to liquid make-up total amount.When less than 1.0 quality %, be difficult to obtain sufficient whitening effect, in addition, also can not produce the glutinous greasy problem as problem of the present invention.On the other hand, when compounding exceedes 5.0 quality %, glutinous greasy inhibition is not given full play to sometimes.Especially, as the lower limit of composition A, also can adopt the value of 1.0 quality %, 1.5 quality %, 2.0 quality %, as higher limit, also can adopt the value of 5.0 quality %, 4.0 quality %, 3.0 quality %.
(B) polyacrylic acid
The polyacrylic acid (composition B) using in the present invention is for can, as polyacrylic acid or its slaine of water-soluble thickener compounding in cosmetics, quasi drug etc., being preferably sodium salt.Polyacrylic weight average molecular weight, as long as be just not particularly limited in the scope with thickening power, is preferably used the polyacrylic acid of the molecular weight with 1,000,000～6,000,000 left and right.
The polyacrylic acid using in the present invention can be also commercially available product, for example, as complete corrective (sodium salt), can list ARONVIS SX (molecular weight 4,000,000～5,000,000), ARONVIS MX (molecular weight 2,000,000～3,000,000) etc., as part corrective, can list (being Toagosei Co., Ltd manufacture) such as ARONVIS AHX.
Polyacrylic compounding amount in cosmetics of the present invention is 0.001～0.1 quality %, is preferably 0.001～0.01 quality % with respect to liquid make-up total amount.When less than 0.001 quality %, the present invention cannot obtain unique use impression, when compounding exceedes 0.1 quality %, exists on the contrary and produces glutinous greasy tendency.Especially, as the lower limit of composition B, also can adopt the value of 0.001 quality %, 0.002 quality %, 0.005 quality %, as higher limit, also can adopt the value of 0.1 quality %, 0.05 quality %, 0.01 quality %.
(C) xanthan gum
The xanthan gum (composition C) using in the present invention is as long as for all the time for the xanthan gum of cosmetics, quasi drug etc.As xanthan gum, also can use commercially available product.
The compounding amount of the xanthan gum in cosmetics of the present invention is 0.01～1.0 quality %, is preferably 0.05～0.3 quality % with respect to liquid make-up total amount.When less than 0.01 quality %, reduce astringent, glutinous greasy effect insufficient, while exceeding 1.0 quality %, become on the contrary the reason of glutinous greasy grade.Especially, as the lower limit of composition C, also can adopt the value of 0.01 quality %, 0.02 quality %, 0.05 quality %, as higher limit, also can adopt the value of 1.0 quality %, 0.7 quality %, 0.3 quality %.
Cosmetics of the present invention except containing above-mentioned essential composition (composition A, B and C), can also the scope that does not hinder effect of the present invention contain can compounding in other any composition of the liquid make-ups such as astringent.
Wherein, by further compounding hydrophilic surfactant active (components D), use impression further to improve, so preferably.
The hydrophilic surfactant active who uses in the present invention is not particularly limited, for example, can lists the polyoxyalkylene alkyl such as polyoxyethylene polyoxypropylene decyl myristyl ether; The polyoxyalkylene castor oil hydrogenated such as polyoxyethylene hydrogenated Oleum Ricini; The polyoxyalkylene plant sterols such as polyoxyethylene plant sterol, polyoxyethylene polyoxypropylene plant sterol; Polyoxyalkylene dialkyl group two polyalcohol ethers such as polyoxyethylene polyoxy butylene dimethyl two polyalcohol ethers; The polyoxyalkylene sorbitan fatty acid esters such as polyoxyethylene sorbitan monostearate, Polysorbate 80; The sucrose fatty acid ester such as sucrose stearate; The fatty acid polyglycol oxyalkylene glyceride such as isostearic acid polyoxyethylene glyceride; The acyl group alkyltaurates such as stearyl N-methyltaurine sodium; The organic silicon modified by polyether such as polyoxyethylene dimethyl siloxane etc.Quantity to polyalkylene oxide groups contained in hydrophilic surfactant active is not particularly limited, and is preferably 10～100, for example, from the group quantity of 10,20,30,40,50,60 or 100 left and right, select.
Particularly preferred hydrophilic surfactant active is selected from one or more in polyoxyethylene polyoxypropylene decyl myristyl ether, polyoxyethylene hydrogenated Oleum Ricini, polyoxyethylene plant sterol, polyoxyethylene polyoxy butylene dimethyl two polyalcohol ethers, and they for being excellent for improvement glutinous greasy, that experience without the use such as astringent.
Hydrophilic surfactant active's compounding amount is generally 0.01～3.0 quality %, is preferably 0.05～1.0 quality % with respect to liquid make-up total amount.Especially, as the lower limit of components D, also can adopt the value of 0.01 quality %, 0.02 quality %, 0.05 quality %, as higher limit, also can adopt the value of 3.0 quality %, 2.0 quality %, 1.0 quality %.
By further compounding hydrophilic surfactant active, skin absorbs and becomes better, in addition, can also make oil component solubilising, emulsifying.
In addition, further when compounding oil component (composition E), especially wettability, without astringent, without glutinous greasy improving, so preferred.
As oil component that can compounding in the present invention, be not particularly limited, for example can list liquid fat, solid grease, wax oil, hydrocarbon ils, higher fatty acids, higher alcohol, ester oil, silicone oil.The particularly preferably liquid oil composition such as zamene, liquid paraffin, hydrogenated polydecene, Fancol ID, 2-Methylpentadecane, isostearic acid, isooctadecanol, three isooctyl acid glyceride (triethylhexanoin), tetramethylolmethane four (thylhexoic acid) ester, thylhexoic acid cetyl, dimethyl polysiloxane, methyl phenyl silicone, decamethylcyclopentaandoxane.
But, for the higher fatty acids soap combining for α-gel that higher alcohol etc. and hydrophilic surfactant active are combined, by higher fatty acids and slaine, be used in combination the tendency that oil component exists the skin absorption etc. that encourages liquid make-up to use impression to worsen, therefore not preferred.
In addition, to be made as 5.0 quality % scope following, that be preferably made as 0.4～3.0 quality % with respect to liquid make-up total amount be preferred to the compounding amount of the oil component in cosmetics of the present invention.When compounding exceedes the oil component of 5.0 quality %, sometimes produce on the contrary glutinous greasy.Especially, as the lower limit of composition E, also can adopt the value of 0.4 quality %, 1.0 quality %, 1.5 quality %, as higher limit, also can adopt the value of 5.0 quality %, 4.0 quality %, 3.0 quality %.
As other any composition, can list the composition of common compounding in cosmetics, such as UV absorbent, surfactant (except components D), wetting agent, thickening agent (except polyacrylic acid and xanthan gum), alcohols, powder composition, coloured material, pH adjusting agent, stabilizing agent, antiseptic, spice, various skin-nourishing agent etc.
Especially, from the viewpoint of moistening effect, the wetting agents such as preferred compounding glycerol and butanediol.
Cosmetics of the present invention are skin-lightening cosmetic, especially in the time making the transparent or semitransparent liquid make-up such as astringent, preferably bring into play effect of the present invention.As long as for liquid does not just limit viscosity, be generally below 1000mPas, be particularly preferably below 500mPas, this absorbs skin is preferred.
In the present invention, " transparent or semitransparent " refers to, the L-value in the Lab colorimetric system (Hunter Lab system) of cosmetics is more than 50.L-value is that the transparency of purified water is made as to 100, complete lighttight situation is made as to the value of the expression transparency of 0 o'clock.That is, L-value more approaches 100, and transparency is higher.L-value for example can use colour difference meter (Spectro color meter SE2000 (Japanese electricity Shi Co., Ltd. manufacture) or COLOR-EYE7000A (GretagMacbeth, LLC. manufactures)) etc. to measure.Liquid make-up of the present invention is that transparency (L-value) is more than 50, transparent or semitransparent cosmetics.
In addition, dosage form to liquid make-up is not particularly limited, can be solvable be liquid make-up (astringent, essence etc.), two series of strata liquid make-ups (essence etc.), oil-in-water liq cosmetics (astringent, emulsion, essence etc.).
Embodiment
Below, describe the present invention in detail by embodiment, but the present invention is not limited to these examples.Compounding amount in embodiment represents with quality % in case of no particular description.
Preparation has the cosmetics (essence) of the composition of recording in following table 1～5 as sample.The evaluation of " skin absorb quality ", " wettability " while being coated with each sample by 10 people's the member of expert group, when dry " without glutinous greasy ", when dry " without astringent " and " satiety ".For each pilot project, each member of expert group evaluates according to following evaluation score benchmark, according to the summation of this evaluation score, metewand is set as to 4 grades.To the results are shown in each table.
< evaluation score benchmark >
5 points: very excellent
4 points: excellence
3 points: common
2 points: poor
1 point: non-constant
< metewand >
◎: total score is more than 40 points
Zero: total score is 30～39 points
△: total score is 20～29 points
×: total score is below 19 points
[table 1]
[table 2]
According to the result shown in table 1, in the time of compounding had compounding in the sample (transparent or semitransparent astringent) of the ascorbic acid glucoside of the ormal weight polyacrylic acid of the amount of particular range and xanthan gum in the application, in all characteristics of evaluating, all obtain gratifying result.But as shown in table 2, when the one or both in compounding polyacrylic acid and xanthan gum, usability is not poor, does not obtain satiety even polyacrylic acid is replaced with to hyaluronic acid yet.In addition, the compounding amount of polyacrylic acid or xanthan gum is during more than the application's particular range, and skin absorption difference glutinous greasyly becomes obvious.
[table 3]
[table 4]
According to the result shown in table 3, even if change hydrophilic surfactant active's's (components D) of institute's compounding kind, as long as must meet condition of the present invention by composition A～C, just can reach excellent usability.In addition, as shown in Table 4, by compounding oil component (composition E), wettability is further improved, but lack when can not get excellent use must composition A～C time and experiencing the compounding amount of (comparative example 8～10), oil component and exceed 5 quality %, produce on the contrary glutinous greasy (comparative example 11).
[table 5]
Shown in table 5, even as whitening agent (composition A) and when compounding 4-methoxyl group salicylic acid or 4-methoxyl group salicylic acid and ascorbic acid glucoside, as long as composition A～C meets condition of the present invention and just can reach excellent usability.
Other embodiments of the invention (example of liquid make-up) are below shown.All in evaluation similar to the above, obtain gratifying result.
Embodiment 20 liquid make-ups (astringent)
Claims (4)
1. a liquid make-up, is characterized in that, contains:
(A) ascorbic acid glucoside of 1.0～5.0 quality % and/or 4-methoxyl group salicylic acid or its salt,
(B) polyacrylic acid of 0.001～0.1 quality % or its slaine and
(C) xanthan gum of 0.01～1.0 quality %,
The L-value of described liquid make-up is more than 50, for transparent or semitransparent.
2. liquid make-up according to claim 1, is characterized in that, also contains (D) hydrophilic surfactant active.
3. liquid make-up according to claim 1 and 2, it is characterized in that, described (D) hydrophilic surfactant active selects one or more in the group of free polyoxyalkylene alkyl, polyoxyalkylene castor oil hydrogenated, polyoxyalkylene plant sterol, polyoxyalkylene dialkyl group two polyalcohol ethers compositions.
4. according to the liquid make-up described in any one in claim 1～3, it is characterized in that, also contain (E) oil component, the content of this oil component is below 5.0 quality % with respect to liquid make-up total amount.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2012258991 | 2012-11-27 | ||
| JP2012-258991 | 2012-11-27 | ||
| JP2013199420A JP6273117B2 (en) | 2012-11-27 | 2013-09-26 | Liquid cosmetics |
| JP2013-199420 | 2013-09-26 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103830121A true CN103830121A (en) | 2014-06-04 |
| CN103830121B CN103830121B (en) | 2018-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310624841.5A Active CN103830121B (en) | 2012-11-27 | 2013-11-26 | Liquid make-up |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101612103A (en) * | 2008-06-24 | 2009-12-30 | 莱雅公司 | Partially applied whitening agent, the method that is used for the skin penetration enhancer of water-soluble whitening active component and is used for skin whitening |
| CN102046142A (en) * | 2008-05-30 | 2011-05-04 | 株式会社资生堂 | Oil-in-water type topical agent for skin |
| CN102470086A (en) * | 2009-12-21 | 2012-05-23 | 株式会社资生堂 | Sheet-like cosmetic |
-
2013
- 2013-11-26 CN CN201310624841.5A patent/CN103830121B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102046142A (en) * | 2008-05-30 | 2011-05-04 | 株式会社资生堂 | Oil-in-water type topical agent for skin |
| CN101612103A (en) * | 2008-06-24 | 2009-12-30 | 莱雅公司 | Partially applied whitening agent, the method that is used for the skin penetration enhancer of water-soluble whitening active component and is used for skin whitening |
| CN102470086A (en) * | 2009-12-21 | 2012-05-23 | 株式会社资生堂 | Sheet-like cosmetic |
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| CN103830121B (en) | 2018-04-20 |
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