CN103820739A - 铁素体耐热铸钢及其制备方法和应用 - Google Patents
铁素体耐热铸钢及其制备方法和应用 Download PDFInfo
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- CN103820739A CN103820739A CN201410071850.0A CN201410071850A CN103820739A CN 103820739 A CN103820739 A CN 103820739A CN 201410071850 A CN201410071850 A CN 201410071850A CN 103820739 A CN103820739 A CN 103820739A
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- steel
- heat resisting
- resisting cast
- ferrite heat
- cast steel
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- 229910001208 Crucible steel Inorganic materials 0.000 title claims abstract description 87
- 229910000859 α-Fe Inorganic materials 0.000 title claims abstract description 82
- 238000002360 preparation method Methods 0.000 title claims abstract description 18
- 229910000831 Steel Inorganic materials 0.000 claims abstract description 91
- 239000010959 steel Substances 0.000 claims abstract description 91
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 38
- 229910045601 alloy Inorganic materials 0.000 claims abstract description 37
- 239000000956 alloy Substances 0.000 claims abstract description 37
- 238000005266 casting Methods 0.000 claims abstract description 27
- 229910052742 iron Inorganic materials 0.000 claims abstract description 19
- 238000004519 manufacturing process Methods 0.000 claims abstract description 13
- 239000012535 impurity Substances 0.000 claims abstract description 11
- 238000002844 melting Methods 0.000 claims abstract description 8
- 230000008018 melting Effects 0.000 claims abstract description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 44
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 37
- 150000002910 rare earth metals Chemical class 0.000 claims description 33
- 239000004411 aluminium Substances 0.000 claims description 32
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 32
- 239000000203 mixture Substances 0.000 claims description 26
- PXHVJJICTQNCMI-UHFFFAOYSA-N nickel Substances [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 25
- 229910000519 Ferrosilicon Inorganic materials 0.000 claims description 23
- 239000007788 liquid Substances 0.000 claims description 23
- 229910052804 chromium Inorganic materials 0.000 claims description 21
- 239000010955 niobium Substances 0.000 claims description 18
- 229910052759 nickel Inorganic materials 0.000 claims description 17
- 229910052791 calcium Inorganic materials 0.000 claims description 16
- 239000011575 calcium Substances 0.000 claims description 16
- 229910052710 silicon Inorganic materials 0.000 claims description 16
- 239000002893 slag Substances 0.000 claims description 16
- 229910052758 niobium Inorganic materials 0.000 claims description 14
- 229910052757 nitrogen Inorganic materials 0.000 claims description 13
- 238000001816 cooling Methods 0.000 claims description 12
- 229910052748 manganese Inorganic materials 0.000 claims description 12
- 238000009413 insulation Methods 0.000 claims description 10
- 229910052698 phosphorus Inorganic materials 0.000 claims description 10
- 229910052788 barium Inorganic materials 0.000 claims description 9
- 229910052702 rhenium Inorganic materials 0.000 claims description 9
- 229910052717 sulfur Inorganic materials 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 7
- 238000007669 thermal treatment Methods 0.000 claims description 6
- 229910000616 Ferromanganese Inorganic materials 0.000 claims description 5
- 229910000592 Ferroniobium Inorganic materials 0.000 claims description 5
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 claims description 5
- 238000004458 analytical method Methods 0.000 claims description 5
- 239000010425 asbestos Substances 0.000 claims description 5
- 238000006392 deoxygenation reaction Methods 0.000 claims description 5
- DALUDRGQOYMVLD-UHFFFAOYSA-N iron manganese Chemical compound [Mn].[Fe] DALUDRGQOYMVLD-UHFFFAOYSA-N 0.000 claims description 5
- ZFGFKQDDQUAJQP-UHFFFAOYSA-N iron niobium Chemical compound [Fe].[Fe].[Nb] ZFGFKQDDQUAJQP-UHFFFAOYSA-N 0.000 claims description 5
- 229910052746 lanthanum Inorganic materials 0.000 claims description 5
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 claims description 5
- 229910052895 riebeckite Inorganic materials 0.000 claims description 5
- 230000000630 rising effect Effects 0.000 claims description 5
- 230000003595 spectral effect Effects 0.000 claims description 5
- 229910000604 Ferrochrome Inorganic materials 0.000 claims description 4
- 230000006698 induction Effects 0.000 claims description 2
- 230000003647 oxidation Effects 0.000 abstract description 15
- 238000007254 oxidation reaction Methods 0.000 abstract description 15
- 238000007599 discharging Methods 0.000 abstract 1
- 238000010079 rubber tapping Methods 0.000 abstract 1
- 230000000052 comparative effect Effects 0.000 description 28
- 239000011651 chromium Substances 0.000 description 22
- 238000000034 method Methods 0.000 description 18
- 239000000463 material Substances 0.000 description 17
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 13
- 239000011572 manganese Substances 0.000 description 13
- 239000000126 substance Substances 0.000 description 9
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 8
- 206010016256 fatigue Diseases 0.000 description 8
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 6
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 5
- 229910001566 austenite Inorganic materials 0.000 description 5
- 239000010935 stainless steel Substances 0.000 description 5
- 229910001220 stainless steel Inorganic materials 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 3
- 239000002131 composite material Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000013078 crystal Substances 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 238000009661 fatigue test Methods 0.000 description 3
- 238000013021 overheating Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910001018 Cast iron Inorganic materials 0.000 description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 208000020442 loss of weight Diseases 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 239000010703 silicon Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 1
- 201000001376 Familial Combined Hyperlipidemia Diseases 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 208000037656 Respiratory Sounds Diseases 0.000 description 1
- 238000005275 alloying Methods 0.000 description 1
- 230000002929 anti-fatigue Effects 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000011089 carbon dioxide Nutrition 0.000 description 1
- 230000004087 circulation Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- UNASZPQZIFZUSI-UHFFFAOYSA-N methylidyneniobium Chemical compound [Nb]#C UNASZPQZIFZUSI-UHFFFAOYSA-N 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000008092 positive effect Effects 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Images
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Treatment Of Steel In Its Molten State (AREA)
Abstract
Description
C | Si | Mn | P | S | Cr | Ni | Nb | Re | N | Al | |
实施例1 | 0.25 | 0.91 | 0.43 | 0.023 | 0.078 | 14.55 | 1.15 | 0.20 | 0.02 | 0.027 | 0.01 |
实施例2 | 0.20 | 1.20 | 0.45 | 0.022 | 0.10 | 15.00 | 1.10 | 0.17 | 0.02 | 0.034 | 0.07 |
实施例3 | 0.16 | 1.16 | 0.42 | 0.016 | 0.11 | 15.79 | 0.97 | 0.30 | 0.05 | 0.046 | 0.09 |
实施例4 | 0.21 | 1.07 | 0.50 | 0.018 | 0.096 | 15.22 | 1.05 | 0.75 | 0.058 | 0.049 | 0.11 |
实施例5 | 0.18 | 0.95 | 0.48 | 0.020 | 0.089 | 16.14 | 1.16 | 0.92 | 0.051 | 0.041 | 0.14 |
对比例1 | 0.21 | 1.59 | 0.59 | 0.015 | 0.075 | 21.47 | 1.03 | 1.00 | 0.01 | 0.055 | 0.17 |
对比例2 | 0.21 | 1.46 | 0.44 | 0.024 | 0.084 | 20.12 | 1.05 | 2.96 | 0.03 | 0.048 | 0.08 |
抗拉强度Rm(RPa) | 塑性强度Rp0.2(RPa) | 伸长率A(%) | |
实施例1 | 886 | 599 | 4.5 |
实施例2 | 698 | 432 | 16.5 |
实施例3 | 634 | 430 | 20.0 |
实施例4 | 735 | 528 | 5.0 |
实施例5 | 750 | 499 | 11 |
对比例1 | 414 | / | 0.5 |
对比例2 | 511 | 326 | 4.5 |
Claims (14)
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106987759A (zh) * | 2017-03-29 | 2017-07-28 | 海城市欣锐铸件有限公司 | 一种含稀土元素的耐腐蚀螺纹钢冶炼方法 |
CN107321920A (zh) * | 2017-07-05 | 2017-11-07 | 天长市兴宇铸造有限公司 | 一种用于精铸件铸造的浇注方法 |
TWI697569B (zh) * | 2017-05-24 | 2020-07-01 | 日商東華隆股份有限公司 | 熔融金屬電鍍浴用構件 |
CN116334499A (zh) * | 2023-03-05 | 2023-06-27 | 襄阳金耐特机械股份有限公司 | 一种铁素体耐热铸钢及其用途 |
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CN1032680A (zh) * | 1987-10-31 | 1989-05-03 | 冶金工业部钢铁研究总院 | 稀土、高铬铁素体耐热铸钢 |
JPH08225898A (ja) * | 1995-02-17 | 1996-09-03 | Daido Steel Co Ltd | 耐熱鋳鋼 |
JP2000355738A (ja) * | 1999-06-15 | 2000-12-26 | Kubota Corp | 耐熱疲労性・耐腐食疲労性およびドリル加工性等に優れたフェライト−オーステナイト二相ステンレス鋼および製紙用サクションロール胴部材 |
CN100999800A (zh) * | 2006-12-31 | 2007-07-18 | 宁波万冠熔模铸造有限公司 | 含稀土元素的铸钢及其生产方法 |
JP2007254885A (ja) * | 2006-02-23 | 2007-10-04 | Daido Steel Co Ltd | 薄肉鋳物部品及びその製造方法 |
CN102301029A (zh) * | 2009-04-27 | 2011-12-28 | 爱信高丘株式会社 | 铁素体耐热铸钢及排气系统部件 |
CN102304671A (zh) * | 2011-08-29 | 2012-01-04 | 遵化市新宏宇冶金机械有限公司 | 一种多元低合金耐磨铸钢斗齿及其制备方法 |
CN102822370A (zh) * | 2010-03-31 | 2012-12-12 | 日立金属株式会社 | 常温韧性优异的铁素体系耐热铸钢和由其构成的排气系统零件 |
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2014
- 2014-02-28 CN CN201410071850.0A patent/CN103820739B/zh active Active
Patent Citations (8)
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CN1032680A (zh) * | 1987-10-31 | 1989-05-03 | 冶金工业部钢铁研究总院 | 稀土、高铬铁素体耐热铸钢 |
JPH08225898A (ja) * | 1995-02-17 | 1996-09-03 | Daido Steel Co Ltd | 耐熱鋳鋼 |
JP2000355738A (ja) * | 1999-06-15 | 2000-12-26 | Kubota Corp | 耐熱疲労性・耐腐食疲労性およびドリル加工性等に優れたフェライト−オーステナイト二相ステンレス鋼および製紙用サクションロール胴部材 |
JP2007254885A (ja) * | 2006-02-23 | 2007-10-04 | Daido Steel Co Ltd | 薄肉鋳物部品及びその製造方法 |
CN100999800A (zh) * | 2006-12-31 | 2007-07-18 | 宁波万冠熔模铸造有限公司 | 含稀土元素的铸钢及其生产方法 |
CN102301029A (zh) * | 2009-04-27 | 2011-12-28 | 爱信高丘株式会社 | 铁素体耐热铸钢及排气系统部件 |
CN102822370A (zh) * | 2010-03-31 | 2012-12-12 | 日立金属株式会社 | 常温韧性优异的铁素体系耐热铸钢和由其构成的排气系统零件 |
CN102304671A (zh) * | 2011-08-29 | 2012-01-04 | 遵化市新宏宇冶金机械有限公司 | 一种多元低合金耐磨铸钢斗齿及其制备方法 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106987759A (zh) * | 2017-03-29 | 2017-07-28 | 海城市欣锐铸件有限公司 | 一种含稀土元素的耐腐蚀螺纹钢冶炼方法 |
CN106987759B (zh) * | 2017-03-29 | 2019-01-08 | 海城市欣锐铸件有限公司 | 一种含稀土元素的耐腐蚀螺纹钢冶炼方法 |
TWI697569B (zh) * | 2017-05-24 | 2020-07-01 | 日商東華隆股份有限公司 | 熔融金屬電鍍浴用構件 |
CN107321920A (zh) * | 2017-07-05 | 2017-11-07 | 天长市兴宇铸造有限公司 | 一种用于精铸件铸造的浇注方法 |
CN116334499A (zh) * | 2023-03-05 | 2023-06-27 | 襄阳金耐特机械股份有限公司 | 一种铁素体耐热铸钢及其用途 |
CN116334499B (zh) * | 2023-03-05 | 2024-02-02 | 襄阳金耐特机械股份有限公司 | 一种铁素体耐热铸钢及其用途 |
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