CN103797035B - 镧系氧杂氮化络合物、包括该氧杂氮化络合物的催化体系和用于共轭二烯类的(共)聚合的方法 - Google Patents

镧系氧杂氮化络合物、包括该氧杂氮化络合物的催化体系和用于共轭二烯类的(共)聚合的方法 Download PDF

Info

Publication number
CN103797035B
CN103797035B CN201280044048.1A CN201280044048A CN103797035B CN 103797035 B CN103797035 B CN 103797035B CN 201280044048 A CN201280044048 A CN 201280044048A CN 103797035 B CN103797035 B CN 103797035B
Authority
CN
China
Prior art keywords
group
polymerization
branched
straight
represent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
CN201280044048.1A
Other languages
English (en)
Chinese (zh)
Other versions
CN103797035A (zh
Inventor
乔瓦尼·里奇
安娜·索玛斯
朱塞佩·利昂
奥尔多·博格利亚
弗朗切斯科·迈斯
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Versalis SpA
Original Assignee
Versalis SpA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Versalis SpA filed Critical Versalis SpA
Publication of CN103797035A publication Critical patent/CN103797035A/zh
Application granted granted Critical
Publication of CN103797035B publication Critical patent/CN103797035B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07FACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F5/00Compounds containing elements of Groups 3 or 13 of the Periodic Table
    • C07F5/003Compounds containing elements of Groups 3 or 13 of the Periodic Table without C-Metal linkages
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/06Butadiene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F136/00Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F136/02Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F136/04Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • C08F136/08Isoprene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F36/00Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
    • C08F36/02Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
    • C08F36/04Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00Polymerisation catalysts
    • C08F4/42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/54Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof
    • C08F4/545Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with other compounds thereof rare earths being present, e.g. triethylaluminium + neodymium octanoate
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
CN201280044048.1A 2011-09-14 2012-09-13 镧系氧杂氮化络合物、包括该氧杂氮化络合物的催化体系和用于共轭二烯类的(共)聚合的方法 Active CN103797035B (zh)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
IT001652A ITMI20111652A1 (it) 2011-09-14 2011-09-14 Complesso oss-azotato di lantanidi, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati
ITMI2011A001652 2011-09-14
PCT/EP2012/067990 WO2013037911A1 (en) 2011-09-14 2012-09-13 Oxo-nitrogenated complex of lanthanides, catalytic system comprising said oxo-nitrogenated complex and process for the (co)polymerization of conjugated dienes

Publications (2)

Publication Number Publication Date
CN103797035A CN103797035A (zh) 2014-05-14
CN103797035B true CN103797035B (zh) 2017-07-28

Family

ID=44907950

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201280044048.1A Active CN103797035B (zh) 2011-09-14 2012-09-13 镧系氧杂氮化络合物、包括该氧杂氮化络合物的催化体系和用于共轭二烯类的(共)聚合的方法

Country Status (18)

Country Link
US (1) US9200101B2 (enExample)
EP (1) EP2756009B1 (enExample)
KR (1) KR101944141B1 (enExample)
CN (1) CN103797035B (enExample)
BR (1) BR112014005460B1 (enExample)
CA (1) CA2845871C (enExample)
ES (1) ES2735538T3 (enExample)
HU (1) HUE045643T2 (enExample)
IN (1) IN2014DN01828A (enExample)
IT (1) ITMI20111652A1 (enExample)
MY (1) MY185082A (enExample)
PL (1) PL2756009T3 (enExample)
PT (1) PT2756009T (enExample)
RU (1) RU2615780C2 (enExample)
TR (1) TR201911225T4 (enExample)
TW (1) TWI577686B (enExample)
WO (1) WO2013037911A1 (enExample)
ZA (1) ZA201400268B (enExample)

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITUB20159429A1 (it) * 2015-12-24 2017-06-24 Versalis Spa Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-imminico di vanadio.
IT201700006307A1 (it) * 2017-01-20 2018-07-20 Versalis Spa Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997025740A1 (en) * 1996-01-11 1997-07-17 Fsi International Improved process for metals removal using beta-diketone or beta-ketoimine ligand forming compounds

Family Cites Families (19)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NL111783C (enExample) 1955-10-17
US4206132A (en) * 1971-09-24 1980-06-03 The United States Of America As Represented By The Secretary Of The Air Force Lanthanide chelate of a fluorinated ligand
DE2830080A1 (de) 1978-07-08 1980-01-17 Bayer Ag Katalysator, dessen herstellung und verwendung zur loesungspolymerisation von butadien
IT1140452B (it) 1981-09-25 1986-09-24 Anic Spa Procedimento per la polimerizzazione di diolefine coniugate e mezzi adatti allo scopo
IT1197465B (it) 1986-08-25 1988-11-30 Consiglio Nazionale Ricerche Catalizzatori migliorati a base di neodimio per la polimerizzazione di diolefine coniugate
US4950790A (en) * 1988-11-14 1990-08-21 Air Products And Chemicals, Inc. Volatile fluorinated β-ketoimines and associated metal complexes
IT1228442B (it) 1989-02-21 1991-06-19 Consiglio Nazionale Ricerche Nuovi catalizzatori a base di neodimio per la polimerizzazione di diolefine coniugate.
IT1313599B1 (it) 1999-08-05 2002-09-09 Enichem Spa Complessi metallici utilizzabili nella catalisi per la (co)polimerizzazione delle alfa-olefine
US6544919B1 (en) * 1999-10-06 2003-04-08 Sri International Multinuclear transition metal catalysts for preparation of multimodal polymer compositions
AU2002217006A1 (en) * 2000-11-09 2002-05-21 Michelin Recherche Et Technique S.A. Catalytic system and method for preparing elastomers using same
US6943224B2 (en) * 2001-04-30 2005-09-13 W. R. Grace & Co.-Conn. Process for preparing supported transition metal catalyst systems and catalyst systems prepared thereby
US6919467B2 (en) * 2001-12-18 2005-07-19 Univation Technologies, Llc Imino-amide catalyst compositions for the polymerization of olefins
EP1367069A1 (en) * 2002-05-28 2003-12-03 Dow Global Technologies Inc. Process for homo-or copolymerization of conjugated diens
US7091150B2 (en) * 2003-12-19 2006-08-15 The Goodyear Tire & Rubber Company Synthetic polyisoprene rubber
EP1840130B1 (en) * 2005-01-21 2012-12-26 Riken Metal complex containing tridentate ligand, and polymerization catalyst comprising the same
CN1931839A (zh) * 2006-09-27 2007-03-21 温州大学 一种n-取代吡咯的合成方法
WO2009132514A1 (zh) * 2008-04-29 2009-11-05 中国科学院长春应用化学研究所 异戊二烯或丁二烯顺1,4-聚合双组分催化体系及聚合方法
CN101260164B (zh) * 2008-04-29 2010-12-22 中国科学院长春应用化学研究所 异戊二烯或丁二烯顺1,4-选择性聚合的催化体系及制法和用法
WO2011061151A1 (en) 2009-11-17 2011-05-26 Basell Polyolefine Gmbh Ethylene copolymers

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1997025740A1 (en) * 1996-01-11 1997-07-17 Fsi International Improved process for metals removal using beta-diketone or beta-ketoimine ligand forming compounds

Also Published As

Publication number Publication date
RU2014113637A (ru) 2015-10-20
KR20140069086A (ko) 2014-06-09
BR112014005460A2 (pt) 2017-03-21
EP2756009B1 (en) 2019-05-15
TW201323431A (zh) 2013-06-16
EP2756009A1 (en) 2014-07-23
PT2756009T (pt) 2019-07-09
MY185082A (en) 2021-04-30
CN103797035A (zh) 2014-05-14
BR112014005460B1 (pt) 2020-10-27
PL2756009T3 (pl) 2019-10-31
WO2013037911A1 (en) 2013-03-21
US20140221592A1 (en) 2014-08-07
HUE045643T2 (hu) 2020-01-28
TR201911225T4 (tr) 2019-08-21
IN2014DN01828A (enExample) 2015-05-15
ES2735538T3 (es) 2019-12-19
ITMI20111652A1 (it) 2013-03-15
RU2615780C2 (ru) 2017-04-11
KR101944141B1 (ko) 2019-04-17
TWI577686B (zh) 2017-04-11
US9200101B2 (en) 2015-12-01
CA2845871C (en) 2019-08-06
CA2845871A1 (en) 2013-03-21
ZA201400268B (en) 2014-10-29

Similar Documents

Publication Publication Date Title
CN104837876B (zh) 用于在包含钴的双亚胺络合物的催化体系存在下制备共轭二烯的(共)聚合物的工艺
CN103842393B (zh) 镧系双亚胺络合物、包括该双亚胺络合物的催化体系和用于共轭二烯类的(共)聚合的方法
US10766979B2 (en) Bis-imine pyridine complex of lanthanides catalytic system comprising said bis-imine pyridine complex and process for the (co)polymerization of conjugated dienes
EP2935206A1 (en) Oxo-nitrogenated complex of cobalt, catalytic system comprising said oxo-nitrogenated complex and process for the (co) polymerization of conjugated dienes
CN103797035B (zh) 镧系氧杂氮化络合物、包括该氧杂氮化络合物的催化体系和用于共轭二烯类的(共)聚合的方法

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant