CN103794673A - Platinum-silicon nanowire infrared detector and manufacturing method thereof - Google Patents

Platinum-silicon nanowire infrared detector and manufacturing method thereof Download PDF

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CN103794673A
CN103794673A CN201410081602.4A CN201410081602A CN103794673A CN 103794673 A CN103794673 A CN 103794673A CN 201410081602 A CN201410081602 A CN 201410081602A CN 103794673 A CN103794673 A CN 103794673A
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CN103794673B (en
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李华高
熊平
钟四成
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Cetc Chip Technology Group Co ltd
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CETC 44 Research Institute
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    • HELECTRICITY
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    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
    • H10F77/00Constructional details of devices covered by this subclass
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    • H10F77/14Shape of semiconductor bodies; Shapes, relative sizes or dispositions of semiconductor regions within semiconductor bodies
    • H10F77/143Shape of semiconductor bodies; Shapes, relative sizes or dispositions of semiconductor regions within semiconductor bodies comprising quantum structures
    • H10F77/1437Quantum wires or nanorods
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10FINORGANIC SEMICONDUCTOR DEVICES SENSITIVE TO INFRARED RADIATION, LIGHT, ELECTROMAGNETIC RADIATION OF SHORTER WAVELENGTH OR CORPUSCULAR RADIATION
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Abstract

一种铂硅纳米线红外探测器,所述铂硅纳米线红外探测器包括P型外延硅衬底层、铂硅薄膜光敏层、P型多晶硅盖帽层、减反射膜层,P型外延硅衬底层、铂硅薄膜光敏层、P型多晶硅盖帽层、减反射膜层依次层叠在一起;所述铂硅薄膜光敏层即为铂硅纳米线;所述铂硅纳米线红外探测器的工作模式采用正照方式。本发明的有益技术效果是:利用铂硅纳米线可增加吸收率,同时,铂硅纳米线顶端存在极大的边缘场,产生雪崩倍增效应,大幅度提高铂硅红外探测器的量子效率;增加P型多晶硅盖帽层,可使光生热空穴的逃逸机率增加一倍,并且阻止了减反射膜层内的可动电荷与光生自由电子交换,降低铂硅红外探测器的噪声及暗电流;探测器采用正照方式,大幅简化了封装工艺,提高了器件的可靠性。

A platinum-silicon nanowire infrared detector, the platinum-silicon nanowire infrared detector comprising a P-type epitaxial silicon substrate layer, a platinum-silicon film photosensitive layer, a P-type polysilicon capping layer, an antireflection film layer, and a P-type epitaxial silicon substrate layer , platinum-silicon thin-film photosensitive layer, P-type polysilicon capping layer, and anti-reflection film layers are stacked together in sequence; the platinum-silicon thin-film photosensitive layer is platinum-silicon nanowire; the working mode of the platinum-silicon nanowire infrared detector adopts positive illumination Way. The beneficial technical effects of the present invention are: the utilization of platinum-silicon nanowires can increase the absorption rate, and at the same time, there is a huge fringe field at the top of the platinum-silicon nanowires, which produces an avalanche multiplication effect and greatly improves the quantum efficiency of platinum-silicon infrared detectors; The P-type polysilicon cap layer can double the escape probability of photogenerated heat holes, and prevent the exchange of mobile charges and photogenerated free electrons in the anti-reflection film layer, reducing the noise and dark current of platinum silicon infrared detectors; detection The device adopts the positive illumination method, which greatly simplifies the packaging process and improves the reliability of the device.

Description

Platinum silicon nanowires Infrared Detectors and preparation method thereof
Technical field
The present invention relates to a kind of Infrared Detectors, relate in particular to a kind of platinum silicon nanowires Infrared Detectors and preparation method thereof.
Background technology
The PtSi infrared focal plane array device that adopts PtSi/P-Si Schottky barrier detector to make has the features such as pixel integrated level is high, photoresponse good uniformity, chip good stability, range of application is very extensive, but with InSb, the comparison of HgTeCd Infrared Detectors, platinum infrared silicon detector quantum efficiency is low 1 more than the order of magnitude; For many years, technical staff is devoted to improve the research of platinum infrared silicon detector quantum efficiency always.
Summary of the invention
For the problem in background technology, the present invention proposes a kind of platinum silicon nanowires Infrared Detectors, its structure is: described platinum silicon nanowires Infrared Detectors comprises P type epitaxial silicon substrate layer, platinum silicon thin film photosensitive layer, P type polysilicon block layer, antireflection film layer, and P type epitaxial silicon substrate layer, platinum silicon thin film photosensitive layer, P type polysilicon block layer, antireflection film layer stack gradually together; Described platinum silicon thin film photosensitive layer is platinum silicon nanowires; The mode of operation of described platinum silicon nanowires Infrared Detectors adopts just according to mode.
The operation principle of aforementioned platinum silicon nanowires Infrared Detectors is: infrared radiation is from positive incident, after antireflection film layer transmission, the infrared light that photon energy is less than Si energy gap arrives platinum silicon thin film photosensitive layer through P type polysilicon block layer, and inspire electron-hole pair in platinum silicon thin film photosensitive layer, energy exceedes the hot hole of barrier height and crosses PtSi/P-Si potential barrier, enter P type epitaxial silicon substrate layer and P type polysilicon block layer, this just makes to have in platinum silicon thin film photosensitive layer the accumulation of electronics, and cuniculate accumulation in P type epitaxial silicon substrate layer and P type polysilicon block layer, P type epitaxial silicon substrate layer and all ground connection of P type polysilicon block layer, in platinum silicon thin film photosensitive layer, the electronics of accumulation is collected by diode, complete the detection to infrared radiation, due to multiple reflections between the platinum silicon nanowires of Infrared in platinum silicon thin film photosensitive layer, increase the absorptivity of platinum silicon thin film to infrared radiation, the platinum silicon thin film photosensitive layer of nanostructure and P type epitaxial silicon substrate layer form Schottky Barrier Contact, there is larger fringing field effect, produce larger fringe field, light induced electron generation avalanche multiplication effect, the quantum efficiency of increase detector, on platinum silicon sodium rice, increase one deck P type polysilicon block layer, can make the escape probability of photoproduction hot hole double, and stoped movable charge and the exchange of photoproduction free electron in antireflective coating, reduce noise and the dark current of platinum infrared silicon detector, meanwhile, detector of the present invention adopts just according to mode, can realize ultraviolet, visible ray, medium-wave infrared multispectral sensing, compared with carrying on the back the mode of photograph, except existing aforementioned advantages, has also significantly simplified packaging technology, has improved the reliability of device.
Based on the conventional structure on existing Infrared Detectors, on platinum silicon nanowires Infrared Detectors of the present invention, be also provided with output diode, the resistance of P+ ditch, contact conductor, P+ diffusely with N guard ring.
In order further to improve the absorptivity of platinum silicon thin film photosensitive layer to infrared radiation, described P type epitaxial silicon substrate layer surface is also laminated with aluminium reflector layer; The infrared ray not absorbed by platinum silicon thin film photosensitive layer transmiting through P type epitaxial silicon substrate layer, after the reflection of aluminium reflector layer, can again arrive platinum silicon nanowires photosensitive layer and be absorbed.
Preferably, described antireflection film layer adopts hafnia film.
Based on aforementioned device, the invention allows for a kind of platinum silicon nanowires Infrared Detectors manufacture method, its processing step is:
1) provide P type epitaxial silicon substrate layer;
2) at the upper surface growth grid oxygen medium layer of P type epitaxial silicon substrate layer, at grid oxygen medium layer surface deposition silicon nitride medium layer;
3) adopt boron diffusion technology on P type epitaxial silicon substrate layer, to form the resistance of P+ ditch and P+ diffusely;
4) adopt phosphonium ion injection technology to form respectively output diode and N guard ring on P type epitaxial silicon substrate layer;
5) adopt plasma etching industrial that the silicon nitride medium layer within the scope of photosensitive area is etched away; Adopt wet corrosion technique that the grid oxygen medium layer within the scope of photosensitive area is eroded; Exposed P type epitaxial silicon substrate layer region is out photosensitive area window;
6) adopt ultra high vacuum sputtering technology in photosensitive area range of deposited platinum film in-situ annealing; Adopt platinum assisted etch process wet etching photosensitive area window, form silicon nanowires, corrode and remove platinum film with chloroazotic acid;
7) erode the natural oxidizing layer on silicon nanowires, adopt ultra high vacuum sputtering technology in photosensitive area deposit platinum film in-situ annealing, generate platinum silicon thin film on silicon nanowires, form platinum silicon nanowires, platinum silicon nanowires is platinum silicon thin film photosensitive layer; Corrode and remove unreacted platinum film with chloroazotic acid;
8) utilize pecvd process in photosensitive area and photosensitive area peripheral deposit low-temperature silicon dioxide film;
9) adopt photoetching process that the low-temperature silicon dioxide thin film corrosive within the scope of photosensitive area is fallen;
10) adopt ultra high vacuum sputtering technology in photosensitive area and photosensitive area peripheral deposit P type polysilicon membrane, in-situ annealing, forms P type polysilicon block layer.
11) adopt and corrode the method for peeling off, remove low-temperature silicon dioxide and the P type polysilicon membrane of periphery, photosensitive area;
12) adopt magnetron sputtering technique deposit hafnium oxide antireflection film layer on P conformal polysilicon block layer;
13) adopt photoetching process to form fairlead;
14) utilize magnetron sputtering technique at the positive deposit aluminium of detector film, photoetching forms contact conductor;
15) polished backside, utilizes magnetron sputtering technique at detector back side deposit aluminium film, forms aluminium reflector layer.
Useful technique effect of the present invention is: utilize platinum silicon nanowires can increase absorptivity, meanwhile, platinum silicon nanowires top exists great fringing field, produces avalanche multiplication effect, increases substantially the quantum efficiency of platinum infrared silicon detector; Increase P type polysilicon block layer, can make the escape probability of photoproduction hot hole double, and stoped movable charge and the exchange of photoproduction free electron in antireflection film layer, reduce noise and the dark current of platinum infrared silicon detector; Detector adopts just according to mode, has significantly simplified packaging technology, has improved the reliability of device.
Accompanying drawing explanation
Fig. 1, structural representation of the present invention;
In figure, the corresponding title of each mark is respectively: aluminium reflector layer 1, P type epitaxial silicon substrate layer 2, platinum silicon thin film photosensitive layer 3, P type polysilicon block layer 4, antireflection film layer 5, output diode 6, P+ ditch resistance 7, contact conductor 8, P+ diffusely 9, N guard ring 10, grid oxygen medium layer 11, silicon nitride medium layer 12.
Embodiment
A kind of platinum silicon nanowires Infrared Detectors, its structure is: described platinum silicon nanowires Infrared Detectors comprises P type epitaxial silicon substrate layer 2, platinum silicon thin film photosensitive layer 3, P type polysilicon block layer 4, antireflection film layer 5, and P type epitaxial silicon substrate layer 2, platinum silicon thin film photosensitive layer 3, P type polysilicon block layer 4, antireflection film layer 5 stack gradually together; Described platinum silicon thin film photosensitive layer 3 is platinum silicon nanowires; The mode of operation of described platinum silicon nanowires Infrared Detectors adopts just according to mode.
Further, on described platinum silicon nanowires Infrared Detectors, be also provided with output diode 6, P+ ditch resistance 7, contact conductor 8, P+ diffusely 9 and N guard ring 10.
Further, described P type epitaxial silicon substrate layer 2 back sides are also laminated with aluminium reflector layer 1.
Further, described antireflection film layer 5 adopts hafnia film.
A kind of platinum silicon nanowires Infrared Detectors manufacture method, the steps include:
1) provide P type epitaxial silicon substrate layer 2;
2) at the upper surface growth grid oxygen medium layer 11 of P type epitaxial silicon substrate layer 2, at grid oxygen medium layer 11 surface deposition silicon nitride medium layer 12;
3) adopt boron diffusion technology on P type epitaxial silicon substrate layer 2, to form the resistance 7 of P+ ditch and P+ diffusely 9;
4) adopt phosphonium ion injection technology to form respectively output diode 6 and N guard ring 10 on P type epitaxial silicon substrate layer 2;
5) adopt plasma etching industrial that the silicon nitride medium layer 12 within the scope of photosensitive area is etched away; Adopt wet corrosion technique that the grid oxygen medium layer 11 within the scope of photosensitive area is eroded; Exposed P type epitaxial silicon substrate layer 2 regions are out photosensitive area window;
6) adopt ultra high vacuum sputtering technology in photosensitive area range of deposited platinum film in-situ annealing; Adopt platinum assisted etch process wet etching photosensitive area window, form silicon nanowires, corrode and remove platinum film with chloroazotic acid;
7) erode the natural oxidizing layer on silicon nanowires, adopt ultra high vacuum sputtering technology in photosensitive area deposit platinum film in-situ annealing, generate platinum silicon thin film on silicon nanowires, form platinum silicon nanowires, platinum silicon nanowires is platinum silicon thin film photosensitive layer 3; Corrode and remove unreacted platinum film with chloroazotic acid;
8) utilize pecvd process in photosensitive area and photosensitive area peripheral deposit low-temperature silicon dioxide film;
9) adopt photoetching process that the low-temperature silicon dioxide thin film corrosive within the scope of photosensitive area is fallen;
10) adopt ultra high vacuum sputtering technology in photosensitive area and photosensitive area peripheral deposit P type polysilicon membrane, in-situ annealing, forms P type polysilicon block layer 4.
11) adopt and corrode the method for peeling off, remove low-temperature silicon dioxide and the P type polysilicon membrane of periphery, photosensitive area;
12) adopt magnetron sputtering technique deposit hafnium oxide antireflection film layer 5 on P conformal polysilicon block layer 4;
13) adopt photoetching process to form fairlead;
14) utilize magnetron sputtering technique at the positive deposit aluminium of detector film, photoetching forms contact conductor 8;
15) polished backside, utilizes magnetron sputtering technique at detector back side deposit aluminium film, forms aluminium reflector layer 1.

Claims (5)

1. a platinum silicon nanowires Infrared Detectors, it is characterized in that: described platinum silicon nanowires Infrared Detectors comprises P type epitaxial silicon substrate layer (2), platinum silicon thin film photosensitive layer (3), P type polysilicon block layer (4), antireflection film layer (5), and P type epitaxial silicon substrate layer (2), platinum silicon thin film photosensitive layer (3), P type polysilicon block layer (4), antireflection film layer (5) stack gradually together; Described platinum silicon thin film photosensitive layer (3) is platinum silicon nanowires; The mode of operation of described platinum silicon nanowires Infrared Detectors adopts just according to mode.
2. platinum silicon nanowires Infrared Detectors according to claim 1, is characterized in that: on described platinum silicon nanowires Infrared Detectors, be also provided with output diode (6), the resistance of P+ ditch (7), contact conductor (8), P+ (9) and N guard ring (10) diffusely.
3. platinum silicon nanowires Infrared Detectors according to claim 1, is characterized in that: described P type epitaxial silicon substrate layer (2) back side is also laminated with aluminium reflector layer (1).
4. platinum silicon nanowires Infrared Detectors according to claim 1, is characterized in that: described antireflection film layer (5) adopts hafnia film.
5. a platinum silicon nanowires Infrared Detectors manufacture method, is characterized in that: following steps for manufacturing platinum silicon nanowires Infrared Detectors:
1) provide P type epitaxial silicon substrate layer (2);
2) at the upper surface growth grid oxygen medium layers (11) of P type epitaxial silicon substrate layer (2), at grid oxygen medium layer (11) surface deposition silicon nitride medium layer (12);
3) adopt boron diffusion technology in the upper P+ of formation of P type epitaxial silicon substrate layer (2) ditch resistance (7) and P+ (9) diffusely;
4) adopt phosphonium ion injection technology on P type epitaxial silicon substrate layer (2), to form respectively output diode (6) and N guard ring (10);
5) adopt plasma etching industrial that the silicon nitride medium layer (12) within the scope of photosensitive area is etched away; Adopt wet corrosion technique that the grid oxygen medium layer (11) within the scope of photosensitive area is eroded; Exposed P type epitaxial silicon substrate layer (2) region is out photosensitive area window;
6) adopt ultra high vacuum sputtering technology in photosensitive area range of deposited platinum film in-situ annealing; Adopt platinum assisted etch process wet etching photosensitive area window, form silicon nanowires, corrode and remove platinum film with chloroazotic acid;
7) erode the natural oxidizing layer on silicon nanowires, adopt ultra high vacuum sputtering technology in photosensitive area deposit platinum film in-situ annealing, generate platinum silicon thin film on silicon nanowires, form platinum silicon nanowires, platinum silicon nanowires is platinum silicon thin film photosensitive layer (3); Corrode and remove unreacted platinum film with chloroazotic acid;
8) utilize pecvd process in photosensitive area and photosensitive area peripheral deposit low-temperature silicon dioxide film;
9) adopt photoetching process that the low-temperature silicon dioxide thin film corrosive within the scope of photosensitive area is fallen;
10) adopt ultra high vacuum sputtering technology in photosensitive area and photosensitive area peripheral deposit P type polysilicon membrane, in-situ annealing, forms P type polysilicon block layer (4);
11) adopt and corrode the method for peeling off, remove low-temperature silicon dioxide and the P type polysilicon membrane of periphery, photosensitive area;
12) adopt magnetron sputtering technique at the upper deposit hafnium oxide antireflection film layer (5) of P conformal polysilicon block layer (4);
13) adopt photoetching process to form fairlead;
14) utilize magnetron sputtering technique at the positive deposit aluminium of detector film, photoetching forms contact conductor (8);
15) polished backside, utilizes magnetron sputtering technique at detector back side deposit aluminium film, forms aluminium reflector layer (1).
CN201410081602.4A 2014-03-07 2014-03-07 Platinum silicon nanowires Infrared Detectors and preparation method thereof Active CN103794673B (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104143581A (en) * 2014-08-12 2014-11-12 中国电子科技集团公司第四十四研究所 Palladium silicon nanowire room temperature infrared detector and its manufacturing method
CN105841823A (en) * 2016-04-14 2016-08-10 董友强 Manganese-silicon nanowire infrared detector and manufacturing method thereof
CN107394000A (en) * 2017-08-08 2017-11-24 中国电子科技集团公司第四十四研究所 Silicon substrate platinum nano-tube detector and preparation method thereof
CN107895743A (en) * 2016-10-04 2018-04-10 豪威科技股份有限公司 The apparatus and method of single-photon avalanche photodiode detector
CN108847427A (en) * 2018-05-08 2018-11-20 广东工业大学 A kind of two-dimensional material photodetector of embedded reflecting mirror and its preparation method and application
CN112582495A (en) * 2020-12-03 2021-03-30 无锡中微晶园电子有限公司 Infrared enhanced silicon-based photoelectric detector

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US4536658A (en) * 1983-01-05 1985-08-20 The United States Of America As Represented By The Secretary Of The Air Force Hybrid Schottky infrared focal plane array
US4544939A (en) * 1981-08-25 1985-10-01 Rca Corporation Schottky-barrier diode radiant energy detector with extended longer wavelength response
US4875082A (en) * 1986-06-20 1989-10-17 Ford Aerospace Corporation Schottky barrier photodiode structure
CN102030309A (en) * 2010-11-10 2011-04-27 中国科学院理化技术研究所 Preparation method of Mn27Si47-Si heterostructure nanowire array or Mn27Si47 nanowire array

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US4544939A (en) * 1981-08-25 1985-10-01 Rca Corporation Schottky-barrier diode radiant energy detector with extended longer wavelength response
US4536658A (en) * 1983-01-05 1985-08-20 The United States Of America As Represented By The Secretary Of The Air Force Hybrid Schottky infrared focal plane array
US4875082A (en) * 1986-06-20 1989-10-17 Ford Aerospace Corporation Schottky barrier photodiode structure
CN102030309A (en) * 2010-11-10 2011-04-27 中国科学院理化技术研究所 Preparation method of Mn27Si47-Si heterostructure nanowire array or Mn27Si47 nanowire array

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104143581A (en) * 2014-08-12 2014-11-12 中国电子科技集团公司第四十四研究所 Palladium silicon nanowire room temperature infrared detector and its manufacturing method
CN105841823A (en) * 2016-04-14 2016-08-10 董友强 Manganese-silicon nanowire infrared detector and manufacturing method thereof
CN107895743A (en) * 2016-10-04 2018-04-10 豪威科技股份有限公司 The apparatus and method of single-photon avalanche photodiode detector
CN107895743B (en) * 2016-10-04 2020-07-10 豪威科技股份有限公司 Apparatus and method for single-photon avalanche photodiode detectors
CN107394000A (en) * 2017-08-08 2017-11-24 中国电子科技集团公司第四十四研究所 Silicon substrate platinum nano-tube detector and preparation method thereof
CN108847427A (en) * 2018-05-08 2018-11-20 广东工业大学 A kind of two-dimensional material photodetector of embedded reflecting mirror and its preparation method and application
CN112582495A (en) * 2020-12-03 2021-03-30 无锡中微晶园电子有限公司 Infrared enhanced silicon-based photoelectric detector
CN112582495B (en) * 2020-12-03 2024-04-09 无锡中微晶园电子有限公司 Infrared reinforced silicon-based photoelectric detector

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