CN103788842A - Environment-friendly anti-aging glass-reinforced plastic composite coating material and preparation method of coating material - Google Patents
Environment-friendly anti-aging glass-reinforced plastic composite coating material and preparation method of coating material Download PDFInfo
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- CN103788842A CN103788842A CN201410016864.2A CN201410016864A CN103788842A CN 103788842 A CN103788842 A CN 103788842A CN 201410016864 A CN201410016864 A CN 201410016864A CN 103788842 A CN103788842 A CN 103788842A
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Abstract
An environment-friendly anti-aging glass-reinforced plastic composite coating material is characterized by comprising the following raw materials in parts by weight: 33-35 parts of an unsaturated polyester resin, 6-10 parts of phenolic resin, 2-3 parts of aluminium hydroxide, 1-2 parts of magnesium oxide, 26-28 parts of alkali free glass fiber, 1-2 parts of ammonium borate, 3-4 parts of cumarone, 2-3 parts of a crosslinking agent TAC, 4-6 parts of dibutyl phthalate, 5-7 parts of methyl ethyl ketone peroxide, 2-3 parts of dibutyltin oxide, 3-4 parts of 4-methoxyphenol, 3-5 parts of n-propyl methacrylate, 1-2 parts of a ceramic powder, and 1-2 parts of an additive. The additive is added, so that the material has good physical property and mechanical performance, so as to exert the effect of reinforcement. The preparation method is simple and reasonable, and the products formed by the preparation method have the characteristics of excellent corrosion resistance, high strength, light quality, equal mechanical performance to part metal materials, low cost, energy source saving, environment protection, and low carbon.
Description
Technical field
The present invention relates to a kind of composite coating material and preparation method thereof, particularly a kind of environment-friendly anti-aging glass reinforced plastic composite coating material and preparation method thereof.
Background technology
Glass-reinforced plastic material is to embed by glass fibre reinforcement the material that is wrapped to form composite structure in curing thermosetting resin or by it, has good corrosion resistance nature and weather resistance, so be widely used in the outdoor and severe place of environment.The glass-reinforced plastic material of production and application adopts resin infiltration woven fiber glass material to carry out moulding more in the market.The method effect of impregnation is good, and prepared content of glass fiber is high.But owing to being subject to the restriction of woven fiber glass volume and shape, make it be not suitable with especially the product that is difficult for uniform-compression for such as tube stub, tee pipe fitting, bend pipe tools etc.In addition, its impact resistance of glass-reinforced plastic material prepared by the method is poor, and layering easily occurs laminated face.In order to address the above problem, there is investigator that glass fibre is cut into glass fiber powder, then glass fiber powder is put in the mixed solution being formed by epoxy resin, softening agent etc., in ball mill, stir again and add filler, solidifying agent, be prepared into thus a kind of glass-reinforced plastic material that does not contain woven fiber glass laying.Although the glass-reinforced plastic material that the method provides has overcome the defect that woven fiber glass itself causes, because glass fibre is cut into powdery, thereby the peculiar physical property of its fiber itself is also weakened greatly.
Summary of the invention
The object of this invention is to provide a kind of environment-friendly anti-aging glass reinforced plastic composite coating material and preparation method thereof.
In order to realize object of the present invention, the present invention passes through following scheme implementation:
A kind of environment-friendly anti-aging glass reinforced plastic composite coating material, is made up of the raw material of following weight part: unsaturated polyester resin 33-35, resol 6-10, aluminium hydroxide 2-3, magnesium oxide 1-2, alkali-free glass fiber 26-28, ammonium borate 1-2, coumarone 3-4, linking agent TAC2-3, dibutyl phthalate 4-6, methylethyl ketone peroxide 5-7, dibutyltin oxide 2-3, MEHQ 3-4, n propyl methacrylate 3-5, ceramics powder 1-2, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: nano aluminium oxide 12-14, zircon 4-6, mica powder 3-4, aluminum nitride powder 2-3, feldspar 3-5, zinc borate 2-4, zinc oxide 5-7, bicarbonate of ammonia 3-4, dibutyltin oxide 2-3, vinylbenzene 3-5, the just own ester 3-4 of methacrylic acid, Syzygium aromaticum stem oil 2-3; Nano aluminium oxide, zircon, aluminum nitride powder, feldspar are put into calcining furnace by preparation method, at 550-570 ℃, calcine 4-5 hour, take out, mix with mica powder, zinc borate, zinc oxide, bicarbonate of ammonia, grinding obtains 300-400 order powder, then, add again the just own ester of vinylbenzene, methacrylic acid, Syzygium aromaticum stem oil to mix, continue to grind 40-50 minute, to fully disperseing, then add other remaining component, continue to grind after 30-45 minute, under 1400-1600 rev/min, stir 15-30 minute, obtain auxiliary agent.
Environment-friendly anti-aging glass reinforced plastic composite coating material of the present invention, made by following concrete steps:
(1) unsaturated polyester resin, resol, coumarone, linking agent TAC, dibutyl phthalate, n propyl methacrylate are put into reactor and be heated to while stirring molten state, obtain A material;
(2) alkali-free glass fiber is put into ball mill and grind, mix with aluminium hydroxide, magnesium oxide, ammonium borate, ceramics powder, dibutyltin oxide, MEHQ, stir 15-20 minute, obtain B material;
(3) A material is mixed with B material, add auxiliary agent and all the other remaining components, under the speed of 450-600 rev/min, stir 22-25 minute, cast, curing.
Advantage of the present invention is: the present invention adds auxiliary agent, makes material have good physicals and mechanical property, plays the effect of reinforcement; Production technique of the present invention is simple, reasonable, and the product of formation has superior corrosion resistance nature, also has stronger strength characteristics, product weight is light, and its mechanical property can compare favourably with part metals material, and cost is low, save energy, environmental protection low-carbon (LC), is applicable to promoting the use of.
Embodiment
Below by specific examples, the present invention is described in detail.
A kind of environment-friendly anti-aging glass reinforced plastic composite coating material, by following weight part (kilogram) raw material make: unsaturated polyester resin 33, resol 6, aluminium hydroxide 2, magnesium oxide 1, alkali-free glass fiber 26, ammonium borate 1, coumarone 3, linking agent TAC2, dibutyl phthalate 4, methylethyl ketone peroxide 5, dibutyltin oxide 2, MEHQ 3, n propyl methacrylate 3, ceramics powder 1, auxiliary agent 1;
Described auxiliary agent by following weight part (kilogram) raw material make: nano aluminium oxide 12, zircon 4, mica powder 3, aluminum nitride powder 2, feldspar 3, zinc borate 2, zinc oxide 5, bicarbonate of ammonia 3, dibutyltin oxide 2, vinylbenzene 3, the just own ester 3 of methacrylic acid, Syzygium aromaticum stem oil 2; Nano aluminium oxide, zircon, aluminum nitride powder, feldspar are put into calcining furnace by preparation method, at 550-570 ℃, calcine 4-5 hour, take out, mix with mica powder, zinc borate, zinc oxide, bicarbonate of ammonia, grinding obtains 300-400 order powder, then, add again the just own ester of vinylbenzene, methacrylic acid, Syzygium aromaticum stem oil to mix, continue to grind 40-50 minute, to fully disperseing, then add other remaining component, continue to grind after 30-45 minute, under 1400-1600 rev/min, stir 15-30 minute, obtain auxiliary agent.
Environment-friendly anti-aging glass reinforced plastic composite coating material of the present invention, made by following concrete steps:
(1) unsaturated polyester resin, resol, coumarone, linking agent TAC, dibutyl phthalate, n propyl methacrylate are put into reactor and be heated to while stirring molten state, obtain A material;
(2) alkali-free glass fiber is put into ball mill and grind, mix with aluminium hydroxide, magnesium oxide, ammonium borate, ceramics powder, dibutyltin oxide, MEHQ, stir 15-20 minute, obtain B material;
(3) A material is mixed with B material, add auxiliary agent and all the other remaining components, under the speed of 450-600 rev/min, stir 22-25 minute, cast, curing.
The tensile strength of the glass-reinforced plastic material of the embodiment of the present invention is 251 Mpa.
Claims (2)
1. an environment-friendly anti-aging glass reinforced plastic composite coating material, it is characterized in that, made by the raw material of following weight part: unsaturated polyester resin 33-35, resol 6-10, aluminium hydroxide 2-3, magnesium oxide 1-2, alkali-free glass fiber 26-28, ammonium borate 1-2, coumarone 3-4, linking agent TAC2-3, dibutyl phthalate 4-6, methylethyl ketone peroxide 5-7, dibutyltin oxide 2-3, MEHQ 3-4, n propyl methacrylate 3-5, ceramics powder 1-2, auxiliary agent 1-2;
Described auxiliary agent is made up of the raw material of following weight part: nano aluminium oxide 12-14, zircon 4-6, mica powder 3-4, aluminum nitride powder 2-3, feldspar 3-5, zinc borate 2-4, zinc oxide 5-7, bicarbonate of ammonia 3-4, dibutyltin oxide 2-3, vinylbenzene 3-5, the just own ester 3-4 of methacrylic acid, Syzygium aromaticum stem oil 2-3; Nano aluminium oxide, zircon, aluminum nitride powder, feldspar are put into calcining furnace by preparation method, at 550-570 ℃, calcine 4-5 hour, take out, mix with mica powder, zinc borate, zinc oxide, bicarbonate of ammonia, grinding obtains 300-400 order powder, then, add again the just own ester of vinylbenzene, methacrylic acid, Syzygium aromaticum stem oil to mix, continue to grind 40-50 minute, to fully disperseing, then add other remaining component, continue to grind after 30-45 minute, under 1400-1600 rev/min, stir 15-30 minute, obtain auxiliary agent.
2. environment-friendly anti-aging glass reinforced plastic composite coating material according to claim 1, is characterized in that, is made up of following concrete steps:
(1) unsaturated polyester resin, resol, coumarone, linking agent TAC, dibutyl phthalate, n propyl methacrylate are put into reactor and be heated to while stirring molten state, obtain A material;
(2) alkali-free glass fiber is put into ball mill and grind, mix with aluminium hydroxide, magnesium oxide, ammonium borate, ceramics powder, dibutyltin oxide, MEHQ, stir 15-20 minute, obtain B material;
(3) A material is mixed with B material, add auxiliary agent and all the other remaining components, under the speed of 450-600 rev/min, stir 22-25 minute, cast, curing.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201410016864.2A CN103788842A (en) | 2014-01-15 | 2014-01-15 | Environment-friendly anti-aging glass-reinforced plastic composite coating material and preparation method of coating material |
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| CN201410016864.2A CN103788842A (en) | 2014-01-15 | 2014-01-15 | Environment-friendly anti-aging glass-reinforced plastic composite coating material and preparation method of coating material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109161312A (en) * | 2018-04-09 | 2019-01-08 | 南通德瑞森复合材料有限公司 | A kind of fiberglass paint preparation method |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101704342A (en) * | 2009-09-16 | 2010-05-12 | 桂林市恒达玻璃钢有限公司 | Automobile glass steel plastic instrument platform and manufacturing technology thereof |
| CN103286963A (en) * | 2012-03-02 | 2013-09-11 | 深圳光启创新技术有限公司 | Preparation method of glass-reinforced plastic, and glass-reinforced plastic antenna housing and preparation method thereof |
| CN103302872A (en) * | 2012-03-14 | 2013-09-18 | 杨亚升 | Glass fiber reinforced plastic section for solar cell module frame and production method thereof |
| CN103319868A (en) * | 2013-07-09 | 2013-09-25 | 上海神冠光电科技有限公司 | Colored translucent fiberglass |
-
2014
- 2014-01-15 CN CN201410016864.2A patent/CN103788842A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101704342A (en) * | 2009-09-16 | 2010-05-12 | 桂林市恒达玻璃钢有限公司 | Automobile glass steel plastic instrument platform and manufacturing technology thereof |
| CN103286963A (en) * | 2012-03-02 | 2013-09-11 | 深圳光启创新技术有限公司 | Preparation method of glass-reinforced plastic, and glass-reinforced plastic antenna housing and preparation method thereof |
| CN103302872A (en) * | 2012-03-14 | 2013-09-18 | 杨亚升 | Glass fiber reinforced plastic section for solar cell module frame and production method thereof |
| CN103319868A (en) * | 2013-07-09 | 2013-09-25 | 上海神冠光电科技有限公司 | Colored translucent fiberglass |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109161312A (en) * | 2018-04-09 | 2019-01-08 | 南通德瑞森复合材料有限公司 | A kind of fiberglass paint preparation method |
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Application publication date: 20140514 |
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