CN103787278A - Ozone generating system based on bipolar pulse power supply - Google Patents
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- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 title claims abstract description 93
- 238000006243 chemical reaction Methods 0.000 claims abstract description 20
- 238000001816 cooling Methods 0.000 claims abstract description 7
- 230000004888 barrier function Effects 0.000 claims description 7
- 238000004519 manufacturing process Methods 0.000 abstract description 5
- 230000005684 electric field Effects 0.000 abstract description 3
- 238000002347 injection Methods 0.000 abstract description 3
- 239000007924 injection Substances 0.000 abstract description 3
- 230000010355 oscillation Effects 0.000 abstract description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 8
- 239000007789 gas Substances 0.000 description 8
- 239000001301 oxygen Substances 0.000 description 8
- 229910052760 oxygen Inorganic materials 0.000 description 8
- 238000010586 diagram Methods 0.000 description 6
- 230000003647 oxidation Effects 0.000 description 5
- 238000007254 oxidation reaction Methods 0.000 description 5
- 238000001914 filtration Methods 0.000 description 4
- 210000002381 plasma Anatomy 0.000 description 4
- 238000005265 energy consumption Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000003990 capacitor Substances 0.000 description 2
- 239000000498 cooling water Substances 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 230000001590 oxidative effect Effects 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 238000009920 food preservation Methods 0.000 description 1
- 239000003574 free electron Substances 0.000 description 1
- 230000020169 heat generation Effects 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 125000004430 oxygen atom Chemical group O* 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
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- 238000007639 printing Methods 0.000 description 1
- 238000012827 research and development Methods 0.000 description 1
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- 238000003786 synthesis reaction Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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Abstract
本发明公开了一种基于双极性脉冲电源的臭氧发生系统,包括气源、臭氧发生器和冷却装置,还包括向臭氧发生器供电的双极性脉冲电源,双极性脉冲电源包括主电路和控制电路;主电路包括:三相整流滤波电路,用于将三相交流电压转换为稳定的直流电压;IGBT变换电路,用于将直流电压转化为脉冲电压;升压电路,输出端接有所述的臭氧发生器,并用于对所述的脉冲电压升压;控制电路接入IGBT变换电路,并用于调节整流后的直流电压和IGBT变换电路的输出电压以及脉冲频率。本发明采用双极性脉冲电源为供电电源,可以有效避免传统电源大部分能量的振荡损耗,提高反应器能量注入,可快速建立强电场,减少臭氧发生器放电管的发热量,提高臭氧产量和臭氧生成能效。
The invention discloses an ozone generating system based on a bipolar pulse power supply, which includes a gas source, an ozone generator and a cooling device, and also includes a bipolar pulse power supply for supplying power to the ozone generator. The bipolar pulse power supply includes a main circuit and control circuit; the main circuit includes: three-phase rectification filter circuit, used to convert three-phase AC voltage into stable DC voltage; IGBT conversion circuit, used to convert DC voltage into pulse voltage; booster circuit, the output terminal is connected with The ozone generator is used to boost the pulse voltage; the control circuit is connected to the IGBT conversion circuit and used to adjust the rectified DC voltage, the output voltage of the IGBT conversion circuit and the pulse frequency. The present invention uses a bipolar pulse power supply as the power supply, which can effectively avoid the oscillation loss of most of the energy of the traditional power supply, improve the energy injection of the reactor, quickly establish a strong electric field, reduce the calorific value of the discharge tube of the ozone generator, and increase the ozone production and Ozone generation energy efficiency.
Description
技术领域technical field
本发明属于臭氧应用技术领域,具体涉及一种采用双极性脉冲电源供电,采用空气源或者氧气源发生臭氧的臭氧发生系统。The invention belongs to the technical field of ozone application, and in particular relates to an ozone generating system which adopts a bipolar pulse power supply to generate ozone and uses an air source or an oxygen source to generate ozone.
背景技术Background technique
臭氧是一种具有极强氧化能力与杀菌性能的无毒强氧化剂,它的氧化能力仅次于氟,除了不能与铂、金、铱和氟发生反应外,几乎可与元素周期表中的任何一种元素发生作用。臭氧不仅能迅速和彻底地杀灭空气中、水中和物体表面的有害细菌和微生物,而且还能实现脱色、除臭和保鲜等功能。另外,臭氧可用作选择氧化和定量氧化剂,它的氧化温度低,能于常温常压下发生强氧化,且氧化后的残存臭氧可在极短时间内自行分解还原为氧气或氧原子,而不产生二次污染,属于一种无公害、无污染、无残留的氧化与消毒剂。因此,臭氧被大量应用于有机合成、无机化工、冶金、造纸、印染、食品保鲜、医疗器具及餐具消毒等领域,涉及到人们生活的各个方面。Ozone is a non-toxic and strong oxidizing agent with extremely strong oxidizing ability and bactericidal performance. An element acts. Ozone can not only quickly and thoroughly kill harmful bacteria and microorganisms in the air, in water and on the surface of objects, but also realize the functions of decolorization, deodorization and freshness preservation. In addition, ozone can be used as a selective oxidation and quantitative oxidant. Its oxidation temperature is low, and it can undergo strong oxidation at normal temperature and pressure, and the residual ozone after oxidation can be decomposed and reduced to oxygen or oxygen atoms in a very short time. It does not produce secondary pollution, and is a pollution-free, pollution-free, and residue-free oxidation and disinfectant. Therefore, ozone is widely used in organic synthesis, inorganic chemical industry, metallurgy, papermaking, printing and dyeing, food preservation, medical equipment and tableware disinfection, etc., involving all aspects of people's lives.
供电电源和臭氧发生器是臭氧发生系统的核心与关键,几十年来一直是臭氧技术研究与发展的重点,也是大功率臭氧发生的难点。采用双极性脉冲电源发生臭氧可以有效避免传统电源大部分能量在系统中的振荡损耗,从而可以有效提高向反应器能量注入,另外用脉冲放电技术,可在反应器内快速建立强电场,臭氧发生器放电管放电时发热量会大大减少,从而可以提高臭氧产量和臭氧生成能效。The power supply and ozone generator are the core and key of the ozone generation system. They have been the focus of ozone technology research and development for decades, and are also the difficulty of high-power ozone generation. The use of bipolar pulse power supply to generate ozone can effectively avoid the oscillation loss of most of the energy in the traditional power supply in the system, so as to effectively improve the energy injection into the reactor. In addition, the pulse discharge technology can quickly establish a strong electric field in the reactor, and the ozone When the generator discharge tube is discharged, the heat generation will be greatly reduced, so that the ozone production and the energy efficiency of ozone generation can be improved.
发明内容Contents of the invention
为了克服现有的臭氧发生系统臭氧能耗高的问题,本发明采用一种基于双极性脉冲电源的臭氧发生系统,该系统可以有效的提高臭氧产量,降低能耗。In order to overcome the problem of high ozone energy consumption in the existing ozone generating system, the present invention adopts an ozone generating system based on a bipolar pulse power supply, which can effectively increase ozone production and reduce energy consumption.
一种基于双极性脉冲电源的臭氧发生系统,包括气源、臭氧发生器和冷却装置,还包括向臭氧发生器供电的双极性脉冲电源,所述的双极性脉冲电源包括主电路和控制电路;A kind of ozone generating system based on bipolar pulse power supply, including gas source, ozone generator and cooling device, also includes the bipolar pulse power supply that supplies power to the ozone generator, described bipolar pulse power supply includes main circuit and Control circuit;
所述的主电路包括:The main circuit includes:
三相整流滤波电路,用于将三相交流电压转换为稳定的直流电压;Three-phase rectification filter circuit, used to convert three-phase AC voltage into stable DC voltage;
IGBT变换电路,用于将直流电压转化为脉冲电压;IGBT conversion circuit for converting DC voltage into pulse voltage;
升压电路,输出端接有所述的臭氧发生器,并用于对所述的脉冲电压升压;A boost circuit, the output terminal is connected with the ozone generator, and is used to boost the pulse voltage;
所述的控制电路接入IGBT变换电路,并用于调节整流后的直流电压和IGBT变换电路的输出电压以及脉冲频率。The control circuit is connected to the IGBT conversion circuit, and is used to adjust the rectified DC voltage, the output voltage and the pulse frequency of the IGBT conversion circuit.
其中,气源为氧气源或者干燥洁净空气源;Wherein, the gas source is an oxygen source or a dry and clean air source;
优选的,所述的三相整流滤波电路包括三相桥式全控整流电路和滤波电路。Preferably, the three-phase rectification and filtering circuit includes a three-phase bridge fully-controlled rectification circuit and a filtering circuit.
优选的,所述的IGBT变换电路包括逆变电路和LC串联谐振电路。Preferably, the IGBT conversion circuit includes an inverter circuit and an LC series resonant circuit.
优选的,所述的三相交流电压经滤波器进入所述的三相整流滤波电路。Preferably, the three-phase AC voltage enters the three-phase rectification and filtering circuit through a filter.
优选的,所述的升压电路为变压器。Preferably, the boost circuit is a transformer.
优选的,所述的控制电路包括单片机控制电路、控制电源和IGBT控制电路:Preferably, the control circuit includes a single-chip microcomputer control circuit, a control power supply and an IGBT control circuit:
单片机控制电路用于为控制电源和IGBT控制电路提供电信号;The single-chip microcomputer control circuit is used to provide electrical signals for the control power supply and the IGBT control circuit;
控制电源用于把单片机控制电路信号放大,调节整流后的直流电压;The control power supply is used to amplify the signal of the single-chip microcomputer control circuit and adjust the rectified DC voltage;
IGBT控制电路把单片机控制电路信号放大,调节IGBT变换电路的输出电压以及脉冲频率。The IGBT control circuit amplifies the signal of the microcontroller control circuit, and adjusts the output voltage and pulse frequency of the IGBT conversion circuit.
优选的,还设有接入所述臭氧发生器的臭氧分析仪。Preferably, an ozone analyzer connected to the ozone generator is also provided.
优选的,所述的臭氧发生器包括壳体和位于壳体内的放电管,放电管和壳体组成阻挡放电反应器。Preferably, the ozone generator includes a housing and a discharge tube located in the housing, and the discharge tube and the housing form a barrier discharge reactor.
优选的,所述的放电管包括高压极、介质层、高压极线和保险丝,所述介质层覆盖在高压极表面,高压极线两端分别连接高压极与双极性脉冲电源,保险丝位于所述的高压极线与高压极之间。Preferably, the discharge tube includes a high-voltage pole, a dielectric layer, a high-voltage pole line and a fuse. The medium layer covers the surface of the high-voltage pole, and the two ends of the high-voltage pole line are respectively connected to the high-voltage pole and the bipolar pulse power supply. Between the high-voltage pole line and the high-voltage pole mentioned above.
臭氧发生器以介质阻挡放电的方式发生臭氧,高压极和壳体间发生介质阻挡放电,高压极与接地极中间通过介质层隔开,高压极通过高压极线与双极性脉冲电源相连接,高压极与高压极线之间为保险丝。The ozone generator generates ozone in the form of dielectric barrier discharge. Dielectric barrier discharge occurs between the high-voltage electrode and the shell. The high-voltage electrode and the ground electrode are separated by a dielectric layer. The high-voltage electrode is connected to the bipolar pulse power supply through the high-voltage pole line. Between the high voltage pole and the high voltage pole line is a fuse.
优选的,所述双极性脉冲电源的脉宽为10-200μs,脉冲频率为50-20000Hz,双极性脉冲电源的脉冲宽度为微秒级,功率输出为0-10kW。Preferably, the pulse width of the bipolar pulse power supply is 10-200 μs, the pulse frequency is 50-20000 Hz, the pulse width of the bipolar pulse power supply is on the order of microseconds, and the power output is 0-10 kW.
与现有技术比,本发明的有益效果是:采用双极性脉冲电源为臭氧发生系统的供电电源,双极性脉冲电源发生臭氧可以有效避免传统电源大部分能量在系统中的振荡损耗,从而可以有效提高向反应器能量注入,另外采用脉冲放电技术,可在反应器内快速建立强电场,臭氧发生器放电管放电时发热量会大大减少,从而可以提高臭氧产量和臭氧生成能效。Compared with the prior art, the beneficial effect of the present invention is: the bipolar pulse power supply is used as the power supply of the ozone generating system, and the generation of ozone by the bipolar pulse power supply can effectively avoid the oscillation loss of most of the energy of the traditional power supply in the system, thereby It can effectively increase the energy injection into the reactor. In addition, the pulse discharge technology can quickly establish a strong electric field in the reactor, and the heat generated by the discharge tube of the ozone generator will be greatly reduced, thereby improving the ozone production and ozone generation energy efficiency.
附图说明Description of drawings
图1为臭氧发生系统图;Fig. 1 is the ozone generating system diagram;
图2为双极性脉冲电源的电路框图;Fig. 2 is the circuit block diagram of bipolar pulse power supply;
图3为主电路电路图;Fig. 3 main circuit circuit diagram;
图4为臭氧发生器壳体图;Fig. 4 is the housing figure of ozone generator;
图5为臭氧发生器放电管图。Figure 5 is a diagram of the discharge tube of the ozone generator.
具体实施方式Detailed ways
如图1所示,一种基于双极性脉冲电源的臭氧发生系统,包括双极性脉冲电源11、气源12、臭氧发生器13、冷却装置14和臭氧分析仪15,臭氧发生器13分别与双极性脉冲电源11、气源12、冷却装置14和臭氧分析仪15相连接。As shown in Figure 1, a kind of ozone generation system based on bipolar pulse power supply comprises bipolar
如图2所示,双极性脉冲电源包括主电路9和控制电路10,控制电路10包括IGBT控制电路5、控制电源6、单片机控制电路7和操作界面8。As shown in FIG. 2 , the bipolar pulse power supply includes a main circuit 9 and a control circuit 10 , and the control circuit 10 includes an IGBT control circuit 5 , a control power supply 6 , a single-chip microcomputer control circuit 7 and an operation interface 8 .
如图3所示,主电路9包括三相整流滤波电路1、IGBT变换电路2、升压电路3,升压电路的输出端接入臭氧发生器4。As shown in FIG. 3 , the main circuit 9 includes a three-phase rectification and filtering circuit 1 , an
三相整流滤波电路1由晶闸管D1-D6、电容C1-C2和电感L2组成,IGBT变换电路2由绝缘栅双极型晶体管V1-V4、电感L3、和电容C3组成,升压电路3为变压器。The three-phase rectification filter circuit 1 is composed of thyristors D1-D6, capacitors C1-C2 and inductor L2, the
三相交流电压经开关K1、滤波器L1送到三相整流滤波电路1转换成稳定的直流电压,该直流电压经IGBT变换电路2转换成脉冲电压,该脉冲电压经升压电路3升压后对臭氧发生器充电。The three-phase AC voltage is sent to the three-phase rectification filter circuit 1 through the switch K1 and the filter L1 to be converted into a stable DC voltage, and the DC voltage is converted into a pulse voltage by the
控制电路接入IGBT变换电路,并用于调节整流后的直流电压和IGBT变换电路的输出电压以及脉冲频率。控制电路包括单片机控制电路、控制电源和IGBT控制电路:单片机控制电路用于为控制电源和IGBT控制电路提供电信号;控制电源用于把单片机控制电路信号放大,调节整流后的直流电压;IGBT控制电路把单片机控制电路信号放大,调节IGBT变换电路的输出电压以及脉冲频率。The control circuit is connected to the IGBT conversion circuit, and is used to adjust the rectified DC voltage, the output voltage and the pulse frequency of the IGBT conversion circuit. The control circuit includes a single-chip microcomputer control circuit, control power supply and IGBT control circuit: the single-chip microcomputer control circuit is used to provide electrical signals for the control power supply and IGBT control circuit; the control power supply is used to amplify the single-chip control circuit signal and adjust the rectified DC voltage; IGBT control The circuit amplifies the signal of the single-chip microcomputer control circuit, and adjusts the output voltage and pulse frequency of the IGBT conversion circuit.
空气或氧气从气源12进入臭氧发生器13,臭氧发生器13在双极性脉冲电源11的作用下发生介质阻挡放电,放电产生的低温等离子体与空气或者氧气反应生成臭氧,冷却装置14提供循环冷却水冷却臭氧发生器13,从臭氧发生器13出来的含臭氧尾气进入臭氧分析仪15检测臭氧浓度。Air or oxygen enters the
如图4所示,为本发明臭氧发生器壳体图,臭氧发生器的壳体16内布置放电通道,每个放电通道内可以放置一个放电管17,也可以几个放电管17串联放置,不同放电通道内的放电管17为并联布置。As shown in Figure 4, it is the housing diagram of the ozone generator of the present invention, discharge channels are arranged in the
如图5所示,为本发明臭氧发生器放电管图,包括高压极18、介质层19、高压极线20和保险丝21,介质层19覆盖在高压极18表面,保险丝21位于放电管17和高压极线20之间,放电管17和壳体16组成介质阻挡放电反应器,壳体16作为接地极与高压极18放电,介质层19与壳体16的间隙为放电通道,在放电通道内产生大量的等离子体,包括自由电子、自由基、活性粒子等,这些等离子体与干燥洁净的空气或者氧气反应生成臭氧。As shown in Figure 5, it is a diagram of the discharge tube of the ozone generator of the present invention, including a
以下是采用本发明的基于双极性脉冲电源的臭氧发生系统发生臭氧的一个具体实例。气源采用氧气源,流量为5L/min,双极性脉冲电源的峰值电压为5kV,峰值电流为0.9A,脉冲宽度为50μs,频率为2000Hz,冷却装置提供循环冷却水冷却臭氧发生器,臭氧发生器放电管与壳体间发生介质阻挡放电,放电产生的等离子体与氧气相互作用产生含臭氧的尾气,含臭氧尾气进入臭氧检测仪,检测的臭氧浓度为145mg/L,计算得到臭氧能效为134g/kWh。采用基于双极性脉冲电源的臭氧发生系统臭氧浓度和能效都较高,可以提高臭氧产量,减小臭氧发生能耗。The following is a specific example of ozone generation using the ozone generating system based on bipolar pulse power supply of the present invention. The gas source is an oxygen source, the flow rate is 5L/min, the peak voltage of the bipolar pulse power supply is 5kV, the peak current is 0.9A, the pulse width is 50μs, and the frequency is 2000Hz. The cooling device provides circulating cooling water to cool the ozone generator, and the ozone A dielectric barrier discharge occurs between the discharge tube of the generator and the shell, and the plasma generated by the discharge interacts with oxygen to produce an ozone-containing tail gas, which enters the ozone detector, and the detected ozone concentration is 145 mg/L. The calculated ozone energy efficiency is 134g/kWh. The ozone generation system based on the bipolar pulse power supply has high ozone concentration and energy efficiency, which can increase the ozone production and reduce the energy consumption of ozone generation.
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
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CN108622859A (en) * | 2018-07-11 | 2018-10-09 | 湖北汽车工业学院 | Underwater ozone generating means |
CN110002405A (en) * | 2019-04-22 | 2019-07-12 | 金仪得科技(深圳)有限公司 | A kind of hand-hold ozone generator |
CN113443605A (en) * | 2021-05-19 | 2021-09-28 | 宜兴鹏鹞浩冉环保科技有限公司 | Ozone generation system based on bipolar pulse power supply |
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CN108622859A (en) * | 2018-07-11 | 2018-10-09 | 湖北汽车工业学院 | Underwater ozone generating means |
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CN110002405B (en) * | 2019-04-22 | 2023-06-02 | 金毅电子(深圳)有限公司 | Handheld ozone generator |
CN113443605A (en) * | 2021-05-19 | 2021-09-28 | 宜兴鹏鹞浩冉环保科技有限公司 | Ozone generation system based on bipolar pulse power supply |
CN113443605B (en) * | 2021-05-19 | 2024-04-12 | 江苏达格水务有限公司 | Ozone generation system based on bipolar pulse power supply |
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