CN103756078B - Natural product and TR (Thermoplastic Rubber) synthetic shoe sole as well as formula and preparation process thereof - Google Patents
Natural product and TR (Thermoplastic Rubber) synthetic shoe sole as well as formula and preparation process thereof Download PDFInfo
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- CN103756078B CN103756078B CN201410026808.7A CN201410026808A CN103756078B CN 103756078 B CN103756078 B CN 103756078B CN 201410026808 A CN201410026808 A CN 201410026808A CN 103756078 B CN103756078 B CN 103756078B
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- rubber
- shoe sole
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- 229920002725 thermoplastic elastomer Polymers 0.000 title claims abstract description 30
- 229930014626 natural product Natural products 0.000 title abstract 5
- 238000002360 preparation method Methods 0.000 title abstract 2
- 238000009472 formulation Methods 0.000 title 1
- 229920001971 elastomer Polymers 0.000 claims abstract description 16
- 239000005060 rubber Substances 0.000 claims abstract description 16
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000012766 organic filler Substances 0.000 claims abstract description 13
- 229920002472 Starch Polymers 0.000 claims abstract description 9
- 239000004698 Polyethylene Substances 0.000 claims abstract description 7
- -1 polyethylene Polymers 0.000 claims abstract description 7
- 229920000573 polyethylene Polymers 0.000 claims abstract description 7
- 235000019890 Amylum Nutrition 0.000 claims description 7
- 235000011187 glycerol Nutrition 0.000 claims description 6
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical group C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 4
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical group C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 claims description 4
- 239000004902 Softening Agent Substances 0.000 claims description 4
- 229920001577 copolymer Polymers 0.000 claims description 4
- 239000003999 initiator Substances 0.000 claims description 4
- 241000196324 Embryophyta Species 0.000 claims 3
- 244000017020 Ipomoea batatas Species 0.000 claims 1
- 235000002678 Ipomoea batatas Nutrition 0.000 claims 1
- 229920001592 potato starch Polymers 0.000 claims 1
- 229940100445 wheat starch Drugs 0.000 claims 1
- 239000002245 particle Substances 0.000 abstract 2
- 238000005299 abrasion Methods 0.000 abstract 1
- 239000008107 starch Substances 0.000 abstract 1
- 235000019698 starch Nutrition 0.000 abstract 1
- 239000000463 material Substances 0.000 description 22
- 238000004519 manufacturing process Methods 0.000 description 7
- 230000015572 biosynthetic process Effects 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 4
- 238000003786 synthesis reaction Methods 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 229920003193 cis-1,4-polybutadiene polymer Polymers 0.000 description 2
- 229920003048 styrene butadiene rubber Polymers 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000013536 elastomeric material Substances 0.000 description 1
- 239000003209 petroleum derivative Substances 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 238000005987 sulfurization reaction Methods 0.000 description 1
- 238000004073 vulcanization Methods 0.000 description 1
Landscapes
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to a natural product and TR (Thermoplastic Rubber) synthetic shoe sole as well as a formula and a preparation process of the synthetic shoe sole. The natural product and TR synthetic shoe sole has the following parameters: the hardness is 60-63 degrees, the density is greater than 0.95g/cm<3>, the volume abrasion degree is 160-175mm<3>, the tension strength is 8.0-9.5Mpa, the elongation at break is 1120-1200%, the tear strength is 32.0-33.0KN/m, and the hard fold times is greater than 50 thousand at normal temperature. The formula of the natural product and TR synthetic shoe sole comprises the following components in parts by weight: 0.5-1.5 parts of natural particles and 1.5-2.5 parts of thermoplastic rubber, wherein the natural particles comprise plant starch, glycerol, polyethylene and organic filler; each 100 parts of the thermoplastic rubber comprises 35-45 parts of thermoplastic elastomers and 55-65 parts of rubber. The natural product and TR synthetic shoe sole is environment-friendly on the basis of advantages of the conventional rubber shoe soles.
Description
Technical field
The present invention relates to a kind of natural goods, TR synthesis sole and formula thereof and manufacture craft.
Background technology
Traditional rubber soles generally adopts styrene-butadiene rubber(SBR), the elastomeric materials such as cis-1,4-polybutadiene rubber and vulcanizing agent, treated oil, after the raw materials such as silicon-dioxide are mixing, form through vulcanization, although the material tool that elastomeric material obtains after sulfuration has good wearability, but this material no longer has thermoplasticity feature, can not recycle, and it is well-known, TR material recoverable, belong to a kind of ep-type material, for this reason, TR material can be utilized replace the styrene-butadiene rubber(SBR) that tradition uses, the elastomeric materials such as cis-1,4-polybutadiene rubber, add natural particulates replaces petroleum derivative material as industrial rubber etc. simultaneously, make natural goods, TR synthesizes sole, make this natural goods, TR synthesizes sole on the basis of the former rubber soles advantage of continuity, environmental protection more.In addition, the patent that the formula that this natural goods, TR synthesize sole is applied on January 9th, 2014 relative to applicant, number of patent application is 2014100102221, the formula of disclosed natural goods, rubber synthesis sole, the simpler more environmental protection of the starting material that the formula that this natural goods, TR synthesize sole uses.
Summary of the invention
The object of the invention is to existing rubber soles not recoverable shortcoming not environmentally, provide a kind of natural goods of environmental protection, TR to synthesize sole and formula thereof and manufacture craft.
It is as follows that the present invention is achieved in that natural goods, TR synthesize sole design parameter: hardness: 60-63 degree; Density >0.95g/cm
3; Volume worn degree 160mm
3-175mm
3; Tensile strength 8.0Mpa-9.5Mpa; Elongation at break 1120%-1200%; Tear strength 32.0KN/m-33.0KN/m; Folding number: normal temperature >5 ten thousand times.
Natural goods, TR synthesize a formula for sole, calculate: natural particulates 0.5 part ~ 1.5 parts, thermoplastic rubber 1.5 parts ~ 2.5 parts with weight ratio; Wherein in every hundred parts of natural particulates, containing plant amylum 40 parts ~ 45 parts, glycerine 5 ~ 10 parts, polyethylene 30 ~ 35 parts, organic filler 15 parts-20 parts; Wherein in every hundred parts of thermoplastic rubbers, containing thermoplastic elastomer 35 parts ~ 45 parts, rubber 55 parts ~ 65 parts; In every hundred parts of organic fillers, containing compatilizer 40 parts ~ 55 parts, 35 parts ~ 45 parts, softening agent, initiator 10 parts ~ 15 parts.
A kind of natural goods, TR synthesize the manufacture craft of sole:
Step 1: natural particulates, thermoplastic rubber are put into Banbury mixer banburying, the banburying time is 5 minutes-6 minutes, and temperature controls within the scope of 150 DEG C ~ 170 DEG C;
Step 2: material complete for banburying is put into roller, adds look mother, and temperature controls within the scope of 150 DEG C ~ 170 DEG C, 5 minutes-6 minutes time;
Step 3: be directly mapped on mould by material, high-temperature pressurizing, temperature controls within the scope of 160 DEG C-170 DEG C, pressure-controlling is within the scope of 150Pa-170Pa, and the time is 3 minutes-5 minutes;
Step 4: after material cooled, opens mould, can obtain complete sole.
The present invention has the following advantages: utilize the advantages such as the sole of TR materials synthesis has outward appearance flower diversity, good hand touch, beautiful in colour, smooth finish is good, and TR material can be recycled, this natural goods, TR is made to synthesize sole on the basis of the former rubber soles advantage of continuity, environmental protection more.
Embodiment
Below in conjunction with embodiment, the invention will be further described.
Embodiment one
The manufacture craft that a kind of natural goods, TR synthesize sole comprises the following steps:
Step 1: prepare natural particulates 0.5 part, thermoplastic rubber 2.5 parts;
Wherein in every hundred parts of natural particulates, containing plant amylum 40 parts, glycerine 10 parts, polyethylene 30 parts, organic filler 20 parts; Wherein in every hundred parts of thermoplastic rubbers, containing thermoplastic elastomer 35 parts, rubber 65 parts; In every hundred parts of organic fillers, containing ethylene-propylene copolymer 40 parts, sorbyl alcohol 45 parts, dicumyl peroxide 15 parts; Said components is poured into banburying in Banbury mixer, the banburying time is 5 minutes, and temperature controls at 170 DEG C.
Step 2: material complete for banburying is put into roller, adds look mother, and temperature controls at 150 DEG C, and the time is 6 minutes;
Step 3: be directly mapped on mould by material, high-temperature pressurizing, temperature controls at 160 DEG C, pressure-controlling is at 150Pa, and the time is 5 minutes;
Step 4: after material cooled, opens mould, can obtain complete sole.
Embodiment two
The manufacture craft that a kind of natural goods, TR synthesize sole comprises the following steps:
Step 1: prepare natural particulates 1 part, thermoplastic rubber 2 parts;
Wherein in every hundred parts of natural particulates, containing plant amylum 43 parts, glycerine 8 parts, polyethylene 32 parts, organic filler 17 parts; Wherein in every hundred parts of thermoplastic rubbers, containing thermoplastic elastomer 40 parts, rubber 60 parts; In every hundred parts of organic fillers, containing ethylene-propylene copolymer 45 parts, sorbyl alcohol 43 parts, dicumyl peroxide 12 parts; Said components is poured into banburying in Banbury mixer, the banburying time is 5.5 minutes, and temperature controls at 160 DEG C.
Step 2: material complete for banburying is put into roller, adds look mother, and temperature controls at 160 DEG C, and the time is 5.5 minutes;
Step 3: be directly mapped on mould by material, high-temperature pressurizing, temperature controls at 165 DEG C, pressure-controlling is at 160Pa, and the time is 4 minutes;
Step 4: after material cooled, opens mould, can obtain complete sole.
Embodiment three
The manufacture craft of a kind of natural goods, thermoplastic rubber synthesis sole comprises the following steps:
Step 1: prepare natural particulates 1.5 parts, thermoplastic rubber 1.5 parts;
Wherein in every hundred parts of natural particulates, containing plant amylum 45 parts, glycerine 5 parts, polyethylene 35 parts, organic filler 15 parts; Wherein in every hundred parts of thermoplastic rubbers, containing thermoplastic elastomer 45 parts, rubber 55 parts; In every hundred parts of organic fillers, containing ethylene-propylene copolymer 55 parts, sorbyl alcohol 35 parts, dicumyl peroxide 10 parts; Said components is poured into banburying in Banbury mixer, the banburying time is 6 minutes, and temperature controls at 150 DEG C.
Step 2: material complete for banburying is put into roller, adds look mother, and temperature controls at 170 DEG C, and the time is 5 minutes;
Step 3: be directly mapped on mould by material, high-temperature pressurizing, temperature controls at 170 DEG C, pressure-controlling is at 170Pa, and the time is 3 minutes;
Step 4: after material cooled, opens mould, can obtain complete sole.
It is as follows that the natural goods that these three kinds of embodiments obtain, TR synthesize sole design parameter:
Hardness: 60-63 degree; Density >0.95g/cm
3; Volume worn degree 160mm
3-175mm
3; Tensile strength 8.0Mpa-9.5Mpa; Elongation at break 1120%-1200%; Tear strength 32.0KN/m-33.0KN/m; Folding number: normal temperature >5 ten thousand times.
Claims (3)
1. natural goods, TR synthesize a sole, it is characterized in that: its formula is, calculate, natural particulates 0.5 part ~ 1.5 parts, thermoplastic rubber 1.5 parts ~ 2.5 parts with weight ratio; Wherein in every hundred parts of natural particulates, containing plant amylum 40 parts ~ 45 parts, glycerine 5 ~ 10 parts, polyethylene 30 ~ 35 parts, organic filler 15 parts-20 parts; Wherein in every hundred parts of thermoplastic rubbers, containing thermoplastic elastomer 35 parts ~ 45 parts, rubber 55 parts ~ 65 parts; In every hundred parts of organic fillers, containing compatilizer 40 parts ~ 55 parts, 35 parts ~ 45 parts, softening agent, initiator 10 parts ~ 15 parts.
2. natural goods according to claim 1, TR synthesize sole, it is characterized in that: its formula is, calculate, natural particulates 1 part, thermoplastic rubber 2 parts with weight ratio; Wherein in every hundred parts of natural particulates, containing plant amylum 43 parts, glycerine 8 parts, polyethylene 32 parts, organic filler 17 parts; Wherein in every hundred parts of thermoplastic rubbers, containing thermoplastic elastomer 40 parts, rubber 60 parts; In every hundred parts of organic fillers, containing compatilizer 45 parts, 43 parts, softening agent, initiator 12 parts.
3. natural goods according to claim 1 and 2, TR synthesize sole, it is characterized in that, described plant amylum is W-Gum, sweet potato starch, wheat starch; Described compatilizer is ethylene-propylene copolymer, and described softening agent is sorbyl alcohol, and described initiator is dicumyl peroxide.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410026808.7A CN103756078B (en) | 2014-01-20 | 2014-01-20 | Natural product and TR (Thermoplastic Rubber) synthetic shoe sole as well as formula and preparation process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410026808.7A CN103756078B (en) | 2014-01-20 | 2014-01-20 | Natural product and TR (Thermoplastic Rubber) synthetic shoe sole as well as formula and preparation process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103756078A CN103756078A (en) | 2014-04-30 |
| CN103756078B true CN103756078B (en) | 2015-05-27 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410026808.7A Active CN103756078B (en) | 2014-01-20 | 2014-01-20 | Natural product and TR (Thermoplastic Rubber) synthetic shoe sole as well as formula and preparation process thereof |
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| CN (1) | CN103756078B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105778211A (en) * | 2016-03-21 | 2016-07-20 | 苏州越湖海绵复合厂 | Antiskid and anti-aging shoe material and production method thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1718127A (en) * | 2004-07-09 | 2006-01-11 | 刘志强 | Integral shoe sole using leather, manufacturing method thereof, and shoes using the same |
| CN102336944A (en) * | 2011-06-24 | 2012-02-01 | 吴江市信许塑料鞋用配套有限公司 | Environmental protection sole material and its preparation method |
| CN102850773A (en) * | 2012-09-24 | 2013-01-02 | 吴江市信许塑料鞋用配套有限公司 | Wear-resistant puncture-resistant sole material |
-
2014
- 2014-01-20 CN CN201410026808.7A patent/CN103756078B/en active Active
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| Publication number | Publication date |
|---|---|
| CN103756078A (en) | 2014-04-30 |
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