CN103740303A - Water-based blister oil and preparation method thereof - Google Patents
Water-based blister oil and preparation method thereof Download PDFInfo
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- CN103740303A CN103740303A CN201310659868.8A CN201310659868A CN103740303A CN 103740303 A CN103740303 A CN 103740303A CN 201310659868 A CN201310659868 A CN 201310659868A CN 103740303 A CN103740303 A CN 103740303A
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- absorbing oil
- acrylic emulsion
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- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 43
- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- 239000000839 emulsion Substances 0.000 claims abstract description 54
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 51
- 239000000080 wetting agent Substances 0.000 claims abstract description 15
- 239000003125 aqueous solvent Substances 0.000 claims abstract description 11
- 239000004033 plastic Substances 0.000 claims description 28
- 239000013530 defoamer Substances 0.000 claims description 14
- 239000012466 permeate Substances 0.000 claims description 14
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 12
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 6
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 4
- 239000003960 organic solvent Substances 0.000 abstract description 4
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 230000008901 benefit Effects 0.000 abstract description 2
- 230000006378 damage Effects 0.000 abstract description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract 6
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 230000000149 penetrating effect Effects 0.000 abstract 1
- 239000000047 product Substances 0.000 description 9
- 238000004806 packaging method and process Methods 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000007787 solid Substances 0.000 description 5
- 238000001035 drying Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 238000007639 printing Methods 0.000 description 3
- 238000001514 detection method Methods 0.000 description 2
- 238000011161 development Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000012858 packaging process Methods 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 230000001070 adhesive effect Effects 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005538 encapsulation Methods 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000003319 supportive effect Effects 0.000 description 1
- 239000012780 transparent material Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to water-based blister oil and a preparation method thereof. The water-based blister oil is characterized by comprising the following components: by weight, 35-40% of acrylic emulsion C, 10-20% of acrylic emulsion D, 15-25% of an aqueous solvent, 10-30% of a blister agent, 2-10% of wax emulsion, 0.1-0.5% of a leveling agent, 0.1-0.5% of a wetting agent, 0.05-0.2% of a penetrating agent and 0.05-0.2% of a defoaming agent, wherein the acrylic emulsion C is acrylic emulsion C-51 of Guangzhou chao xiang yue company, and the acrylic liquid D is acrylic emulsion D-52 of the Guangzhou chao xiang yue company. The water-based blister oil prepared by the invention has the advantages of security, non-toxicity and environmental friendliness, and eliminates the damage of the organic solvent synthesized blister oil on the human body, and the market prospect is broad.
Description
Technical field
The present invention relates to blister plastic packaging field, relate in particular to a kind of water plastics-absorbing oil and preparation method thereof.
Background technology
Blister plastic packaging is a kind of novel packaged form, generally by irregularly shaped object, as toy, stationery, instrument, daily necessities etc., by using PVC or PET cell-shell to its sealing protection in addition, again cell-shell and paper card are bonded together, form the transparent packaged form of complete rule.The advantage of this packaged form is: one,, by using cell-shell to wrap up to irregular product, can make the profile of irregularity align mutually, accumulating is convenient; Two, the cell-shell of blister plastic packaging adopts transparent material, the most conventional with PVC, PET, at Product Terminal, generally paper card is hung and is placed, and the proterties of product is very clear, and therefore the product of this packing is easy to be placed in the awake destination locations in market, is convenient to sell; Three, blister plastic packaging can guarantee that product in plastic uptake cell-shell is not by extraneous dust pollution, and steam is had to certain iris action, has guaranteed that the quality of product is unaffected.
Blister plastic packaging technique is relatively ripe at present, and correlation technique has realized industrial applications.In this kind of technology of the package, be mainly concerned with because have: cell-shell, paper card, plasltic-absorbing oil.Cell-shell plays object is sealed to fixing effect; Paper card plays a supportive role to object, and printing figure message information, describes product simultaneously; Plasltic-absorbing oil, under the condition of heating, is bonded together cell-shell and paper card securely, and that during assurance accumulating, packs is complete.The plastic uptake heat seal packaging process of blister plastic packaging is: cell-shell and the paper card pressing that scribbles plasltic-absorbing oil, use electrically heated or high frequency mode simultaneously, by cell-shell and paper card heating, plasltic-absorbing oil after cell-shell after softening and fusing carries out firmly bonding, after cooling, cell-shell, plasltic-absorbing oil, paper card form one, complete blister packaging process.When carrying out plastic uptake heat seal encapsulation, plasltic-absorbing oil produces adhesive effect under heating, by paper card and cell-shell good bond.
Normal temperature state, plasltic-absorbing oil possesses the feature of general gloss oil coating as a kind of extraordinary gloss oil coating, have certain glossiness and wear resistance.The plasltic-absorbing oil using at present still be take solvent-borne type plasltic-absorbing oil as main, and the solvent of use mostly is benzene class, and in drying process, organic solvent all evaporate in atmosphere, has caused the pollution of environment, to workman is healthy, causes potential danger.Therefore, research water-based gloss oil forms the development trend of the industry.
Summary of the invention
The object of the invention is, for the deficiencies in the prior art, provides a kind of water plastics-absorbing oil and preparation method thereof, and the water plastics-absorbing oil that makes to prepare had both met the requirement of blister plastic packaging, met again environmental requirement and industry development trend.
In order to solve the problems of the technologies described above, the object of the invention is to be achieved through the following technical solutions:
A water plastics-absorbing oil, is characterized in that, consists of: ACRYLIC EMULSION C35-40% the component of following weight percent, ACRYLIC EMULSION D10-20%, aqueous solvent 15-25%, plastic uptake agent 10-30%, wax emulsion 2-10%, flow agent 0.1-0.5%, wetting agent 0.1-0.5%, permeate agent 0.05-0.2%, defoamer 0.05-0.2%, wherein ACRYLIC EMULSION C is the ACRYLIC EMULSION C-51 of Guangzhou Chao Xiangyue company, and ACRYLIC EMULSION D is the ACRYLIC EMULSION D-52 of Guangzhou Chao Xiangyue company.
Further, described aqueous solvent comprises ethanol or methyl alcohol or Virahol 5-15%, and water 10-15%.
Further, described plastic uptake agent is the plastic uptake agent 872 that Guangzhou Chao Xiangyue company produces.
The MD-2000 of the WE6Huo Weng Kaier company of BASF AG further, 91240 of described wax emulsion Shi Gongyao International Trading Company Ltd.
Further, described flow agent is 5211 of Dow Corning Corporation.
Further, described wetting agent is OT-75.
Further, described permeate agent is fast T, JFC-1, JFC-2 or the AEP of Hangzhou Jiu Ling company.
Further again, described defoamer is the loyal DF568 of company in Shanghai or the DC65 of Dow Corning Corporation.
The preparation method of described water plastics-absorbing oil, it is characterized in that comprising the following steps: ACRYLIC EMULSION C and ACRYLIC EMULSION D are mixed, then add plastic uptake agent, then add successively aqueous solvent, wax emulsion, flow agent, wetting agent, permeate agent and defoamer, mix.
Compared with prior art, water plastics-absorbing oil of the present invention and preparation method thereof has following beneficial effect:
Water plastics-absorbing oil suitability of the present invention is good, and viscosity is about 17-25 second (50-200mpas), and solid content is 35-38%, and glossiness is high, wear resistance is good; Can meet the growth requirement of blister plastic packaging industry to plasltic-absorbing oil, take water as solvent, not containing organic solvent, safe, nontoxic, environmental protection, eliminated the injury of the synthetic plasltic-absorbing oil of organic solvent to human body, and market outlook are wide.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein, only for description and interpretation the present invention, is not intended to limit the present invention.
Raw material:
ACRYLIC EMULSION C: the ACRYLIC EMULSION C-51 of Guangzhou Chao Xiangyue company; ACRYLIC EMULSION D: the ACRYLIC EMULSION D-52 of Guangzhou Chao Xiangyue company; Aqueous solvent is selected from ethanol or methyl alcohol or Virahol, and water; The plastic uptake agent 872 that plastic uptake agent can select Guangzhou Chao Xiangyue company to produce; Wax emulsion can select Gong Yao International Trading Company Ltd 91240, the MD-2000 of the WE6Huo Weng Kaier company of BASF AG; Flow agent can be selected 5211 of Dow Corning Corporation; Wetting agent can be selected OT75; Permeate agent can be fast T, JFC-1, JFC-2 or the AEP of Hangzhou Jiu Ling company; Defoamer can be the loyal DF568 of company in Shanghai or the DC65 of Dow Corning Corporation.
Embodiment 1
A water plastics-absorbing oil, is comprised of the component of following weight percent: ACRYLIC EMULSION C35%, ACRYLIC EMULSION D20%, ethanol 10%, water 10%, plastic uptake agent 21.6%, wax emulsion 2%, flow agent 0.5%, wetting agent 0.5%, permeate agent 0.2%, defoamer 0.2%.
The preparation method of above-mentioned water plastics-absorbing oil is: ACRYLIC EMULSION C and ACRYLIC EMULSION D are mixed, then add plastic uptake agent, then add successively aqueous solvent, wax emulsion, flow agent, wetting agent, permeate agent and defoamer, mix.
Embodiment 2
A water plastics-absorbing oil, is comprised of the component of following weight percent: ACRYLIC EMULSION C40%, ACRYLIC EMULSION D14.7%, methyl alcohol 15%, water 10%, plastic uptake agent 10%, wax emulsion 10%, flow agent 0.1%, wetting agent 0.1%, permeate agent 0.05%, defoamer 0.05%.
The preparation method of above-mentioned water plastics-absorbing oil is: ACRYLIC EMULSION C and ACRYLIC EMULSION D are mixed, then add plastic uptake agent, then add successively aqueous solvent, wax emulsion, flow agent, wetting agent, permeate agent and defoamer, mix.
Embodiment 3
A water plastics-absorbing oil, is comprised of the component of following weight percent: ACRYLIC EMULSION C37%, ACRYLIC EMULSION D10%, Virahol 5%, water 15%, plastic uptake agent 30%, wax emulsion 2%, flow agent 0.3%, wetting agent 0.3%, permeate agent 0.2%, defoamer 0.2%.
The preparation method of above-mentioned water plastics-absorbing oil is: ACRYLIC EMULSION C and ACRYLIC EMULSION D are mixed, then add plastic uptake agent, then add successively aqueous solvent, wax emulsion, flow agent, wetting agent, permeate agent and defoamer, mix.
Embodiment 4
A water plastics-absorbing oil, is comprised of the component of following weight percent: ACRYLIC EMULSION C40%, ACRYLIC EMULSION D20%, ethanol 5%, water 10%, plastic uptake agent 17.8%, wax emulsion 6%, flow agent 0.5%, wetting agent 0.5%, permeate agent 0.1%, defoamer 0.1%.
The preparation method of above-mentioned water plastics-absorbing oil is: ACRYLIC EMULSION C and ACRYLIC EMULSION D are mixed, then add plastic uptake agent, then add successively aqueous solvent, wax emulsion, flow agent, wetting agent, permeate agent and defoamer, mix.
Embodiment 5
The water plastics-absorbing oil that above-described embodiment 1～4 is prepared characterizes and performance measurement
(1) viscosity: according to GB/T11175-2002, adopt NDJ-1 type rotational viscosimeter, select suitable rotor and suitable tachometry water plastics-absorbing oil viscosity.Meanwhile, with being coated with-4 glasss, measure viscosity.
(2) solid content: get 1.0-2.0g product, dry to constant weight in microwave oven, the quality of front and back product dried in record, calculates solid content.
Solid content=sample dry weight/sample weight in wet base * 100%
(3) glossiness: glossiness has reflected the aesthetic measure of package printing material after plasltic-absorbing oil drying and forming-film, is used mirror luster degree meter coating to be carried out to the detection of glossiness.
(4) wear resistance: wear resistance reflected after plasltic-absorbing oil film forming, paper card wrapping material in handling, storage and transport process, the tolerance degree to external force wearing and tearing.Actual detection method is for using friction testing machine to carry out friction test to the paper card of coating plasltic-absorbing oil, with coating, is worn and ink layer has just occurred that friction number of times when show-through characterizes the wear resistance of plasltic-absorbing oil.
Result shows:
(1) embodiment 1～4 gained water plastics-absorbing oil viscosity is at 17-25 second (50-200mpas), and solid content 35-38%, under this condition, is easy to use every square metre of 6-10 gram of oil mass in seasoning machine adjustment, and guarantees normal dry;
(2), after water plastics-absorbing oil drying and forming-film, as the supercoat to ink printing layer, except possessing the character such as waterproof, protection against the tide, anti-pickup, also need to meet the requirement to glossiness and wear resistance.Find that gained water plastics-absorbing oil can meet glossiness more than 65, wear-resisting 400 the above requirements of 20N pressure.
Finally it should be noted that: these are only the preferred embodiments of the present invention; be not limited to the present invention; for a person skilled in the art; all any modifications of doing within the spirit and principles in the present invention, be equal to replacement, improvement etc., within protection scope of the present invention all should be included in.
Claims (9)
1. a water plastics-absorbing oil, is characterized in that, the component of following weight percent, consists of:
Wherein ACRYLIC EMULSION C is the ACRYLIC EMULSION C-51 of Guangzhou Chao Xiangyue company, and ACRYLIC EMULSION D is the ACRYLIC EMULSION D-52 of Guangzhou Chao Xiangyue company.
2. water plastics-absorbing oil according to claim 1, is characterized in that, described aqueous solvent comprises ethanol or methyl alcohol or Virahol 5-15%, and water 10-15%.
3. water plastics-absorbing oil according to claim 1, is characterized in that, described plastic uptake agent is the plastic uptake agent 872 that Guangzhou Chao Xiangyue company produces.
4. water plastics-absorbing oil according to claim 1, is characterized in that, described wax emulsion Shi Gongyao International Trading Company Ltd 91240, the MD-2000 of the WE6Huo Weng Kaier company of BASF AG.
5. water plastics-absorbing oil according to claim 1, is characterized in that, described flow agent is 5211 of Dow Corning Corporation.
6. water plastics-absorbing oil according to claim 1, is characterized in that, described wetting agent is OT-75.
7. water plastics-absorbing oil according to claim 1, is characterized in that, described permeate agent is fast T, JFC-1, JFC-2 or the AEP of Hangzhou Jiu Ling company.
8. water plastics-absorbing oil according to claim 1, is characterized in that, described defoamer is the loyal DF568 of company in Shanghai or the DC65 of Dow Corning Corporation.
9. according to the preparation method of the arbitrary described water plastics-absorbing oil of claim 1～8, it is characterized in that comprising the following steps: ACRYLIC EMULSION C and ACRYLIC EMULSION D are mixed, then add plastic uptake agent, add successively again aqueous solvent, wax emulsion, flow agent, wetting agent, permeate agent and defoamer, mix.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310659868.8A CN103740303A (en) | 2013-12-09 | 2013-12-09 | Water-based blister oil and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310659868.8A CN103740303A (en) | 2013-12-09 | 2013-12-09 | Water-based blister oil and preparation method thereof |
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| CN103740303A true CN103740303A (en) | 2014-04-23 |
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| CN201310659868.8A Pending CN103740303A (en) | 2013-12-09 | 2013-12-09 | Water-based blister oil and preparation method thereof |
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Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530893A (en) * | 2014-12-09 | 2015-04-22 | 东莞市蓝铂化工科技有限公司 | A kind of water-based plastic-absorbing oil and preparation method thereof |
| CN106916552A (en) * | 2017-04-24 | 2017-07-04 | 施玉芳 | A kind of plastic uptake adhesive |
| CN108728024A (en) * | 2018-06-28 | 2018-11-02 | 杭州海维特化工科技有限公司 | A kind of collapsible PVC furniture film water vacuum plastic-absorption and preparation method thereof |
| CN108822653A (en) * | 2018-07-20 | 2018-11-16 | 中山火炬职业技术学院 | A kind of aqueous line plastics-absorbing oil and preparation method thereof |
| CN109777337A (en) * | 2018-12-27 | 2019-05-21 | 万华化学（宁波）有限公司 | A kind of high gloss water plastics-absorbing oil and preparation method thereof |
| CN110079175A (en) * | 2019-05-30 | 2019-08-02 | 江苏美乔科技有限公司 | A kind of environment-friendly water-based plastics-absorbing oil and preparation method thereof |
| CN111945477A (en) * | 2020-08-14 | 2020-11-17 | 上海紫华薄膜科技有限公司 | Release heat-sealing packaging paper and manufacturing method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104530893A (en) * | 2014-12-09 | 2015-04-22 | 东莞市蓝铂化工科技有限公司 | A kind of water-based plastic-absorbing oil and preparation method thereof |
| CN106916552A (en) * | 2017-04-24 | 2017-07-04 | 施玉芳 | A kind of plastic uptake adhesive |
| CN108728024A (en) * | 2018-06-28 | 2018-11-02 | 杭州海维特化工科技有限公司 | A kind of collapsible PVC furniture film water vacuum plastic-absorption and preparation method thereof |
| CN108728024B (en) * | 2018-06-28 | 2020-08-14 | 杭州海维特化工科技有限公司 | Reelable PVC furniture film water-based vacuum absorption plastic and preparation method thereof |
| CN108822653A (en) * | 2018-07-20 | 2018-11-16 | 中山火炬职业技术学院 | A kind of aqueous line plastics-absorbing oil and preparation method thereof |
| CN109777337A (en) * | 2018-12-27 | 2019-05-21 | 万华化学（宁波）有限公司 | A kind of high gloss water plastics-absorbing oil and preparation method thereof |
| CN109777337B (en) * | 2018-12-27 | 2021-07-23 | 万华化学（宁波）有限公司 | High-glossiness water-based blister oil and preparation method thereof |
| CN110079175A (en) * | 2019-05-30 | 2019-08-02 | 江苏美乔科技有限公司 | A kind of environment-friendly water-based plastics-absorbing oil and preparation method thereof |
| CN111945477A (en) * | 2020-08-14 | 2020-11-17 | 上海紫华薄膜科技有限公司 | Release heat-sealing packaging paper and manufacturing method thereof |
| CN111945477B (en) * | 2020-08-14 | 2022-07-05 | 上海紫华薄膜科技有限公司 | Release heat-sealing packaging paper and manufacturing method thereof |
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Application publication date: 20140423 |
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