CN103740303A - Water-based blister oil and preparation method thereof - Google Patents

Water-based blister oil and preparation method thereof Download PDF

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CN103740303A
CN103740303A CN201310659868.8A CN201310659868A CN103740303A CN 103740303 A CN103740303 A CN 103740303A CN 201310659868 A CN201310659868 A CN 201310659868A CN 103740303 A CN103740303 A CN 103740303A
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agent
absorbing oil
acrylic emulsion
water
company
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汪博士
梁文波
汪博火
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BANGGU CHEMICAL Co Ltd
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BANGGU CHEMICAL Co Ltd
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Abstract

The invention relates to water-based blister oil and a preparation method thereof. The water-based blister oil is characterized by comprising the following components: by weight, 35-40% of acrylic emulsion C, 10-20% of acrylic emulsion D, 15-25% of an aqueous solvent, 10-30% of a blister agent, 2-10% of wax emulsion, 0.1-0.5% of a leveling agent, 0.1-0.5% of a wetting agent, 0.05-0.2% of a penetrating agent and 0.05-0.2% of a defoaming agent, wherein the acrylic emulsion C is acrylic emulsion C-51 of Guangzhou chao xiang yue company, and the acrylic liquid D is acrylic emulsion D-52 of the Guangzhou chao xiang yue company. The water-based blister oil prepared by the invention has the advantages of security, non-toxicity and environmental friendliness, and eliminates the damage of the organic solvent synthesized blister oil on the human body, and the market prospect is broad.

Description

A kind of water plastics-absorbing oil and preparation method thereof
Technical field
The present invention relates to blister plastic packaging field, relate in particular to a kind of water plastics-absorbing oil and preparation method thereof.
Background technology
Blister plastic packaging is a kind of novel packaged form, generally by irregularly shaped object, as toy, stationery, instrument, daily necessities etc., by using PVC or PET cell-shell to its sealing protection in addition, again cell-shell and paper card are bonded together, form the transparent packaged form of complete rule.The advantage of this packaged form is: one,, by using cell-shell to wrap up to irregular product, can make the profile of irregularity align mutually, accumulating is convenient; Two, the cell-shell of blister plastic packaging adopts transparent material, the most conventional with PVC, PET, at Product Terminal, generally paper card is hung and is placed, and the proterties of product is very clear, and therefore the product of this packing is easy to be placed in the awake destination locations in market, is convenient to sell; Three, blister plastic packaging can guarantee that product in plastic uptake cell-shell is not by extraneous dust pollution, and steam is had to certain iris action, has guaranteed that the quality of product is unaffected.
Blister plastic packaging technique is relatively ripe at present, and correlation technique has realized industrial applications.In this kind of technology of the package, be mainly concerned with because have: cell-shell, paper card, plasltic-absorbing oil.Cell-shell plays object is sealed to fixing effect; Paper card plays a supportive role to object, and printing figure message information, describes product simultaneously; Plasltic-absorbing oil, under the condition of heating, is bonded together cell-shell and paper card securely, and that during assurance accumulating, packs is complete.The plastic uptake heat seal packaging process of blister plastic packaging is: cell-shell and the paper card pressing that scribbles plasltic-absorbing oil, use electrically heated or high frequency mode simultaneously, by cell-shell and paper card heating, plasltic-absorbing oil after cell-shell after softening and fusing carries out firmly bonding, after cooling, cell-shell, plasltic-absorbing oil, paper card form one, complete blister packaging process.When carrying out plastic uptake heat seal encapsulation, plasltic-absorbing oil produces adhesive effect under heating, by paper card and cell-shell good bond.
Normal temperature state, plasltic-absorbing oil possesses the feature of general gloss oil coating as a kind of extraordinary gloss oil coating, have certain glossiness and wear resistance.The plasltic-absorbing oil using at present still be take solvent-borne type plasltic-absorbing oil as main, and the solvent of use mostly is benzene class, and in drying process, organic solvent all evaporate in atmosphere, has caused the pollution of environment, to workman is healthy, causes potential danger.Therefore, research water-based gloss oil forms the development trend of the industry.
Summary of the invention
The object of the invention is, for the deficiencies in the prior art, provides a kind of water plastics-absorbing oil and preparation method thereof, and the water plastics-absorbing oil that makes to prepare had both met the requirement of blister plastic packaging, met again environmental requirement and industry development trend.
In order to solve the problems of the technologies described above, the object of the invention is to be achieved through the following technical solutions:
A water plastics-absorbing oil, is characterized in that, consists of: ACRYLIC EMULSION C35-40% the component of following weight percent, ACRYLIC EMULSION D10-20%, aqueous solvent 15-25%, plastic uptake agent 10-30%, wax emulsion 2-10%, flow agent 0.1-0.5%, wetting agent 0.1-0.5%, permeate agent 0.05-0.2%, defoamer 0.05-0.2%, wherein ACRYLIC EMULSION C is the ACRYLIC EMULSION C-51 of Guangzhou Chao Xiangyue company, and ACRYLIC EMULSION D is the ACRYLIC EMULSION D-52 of Guangzhou Chao Xiangyue company.
Further, described aqueous solvent comprises ethanol or methyl alcohol or Virahol 5-15%, and water 10-15%.
Further, described plastic uptake agent is the plastic uptake agent 872 that Guangzhou Chao Xiangyue company produces.
The MD-2000 of the WE6Huo Weng Kaier company of BASF AG further, 91240 of described wax emulsion Shi Gongyao International Trading Company Ltd.
Further, described flow agent is 5211 of Dow Corning Corporation.
Further, described wetting agent is OT-75.
Further, described permeate agent is fast T, JFC-1, JFC-2 or the AEP of Hangzhou Jiu Ling company.
Further again, described defoamer is the loyal DF568 of company in Shanghai or the DC65 of Dow Corning Corporation.
The preparation method of described water plastics-absorbing oil, it is characterized in that comprising the following steps: ACRYLIC EMULSION C and ACRYLIC EMULSION D are mixed, then add plastic uptake agent, then add successively aqueous solvent, wax emulsion, flow agent, wetting agent, permeate agent and defoamer, mix.
Compared with prior art, water plastics-absorbing oil of the present invention and preparation method thereof has following beneficial effect:
Water plastics-absorbing oil suitability of the present invention is good, and viscosity is about 17-25 second (50-200mpas), and solid content is 35-38%, and glossiness is high, wear resistance is good; Can meet the growth requirement of blister plastic packaging industry to plasltic-absorbing oil, take water as solvent, not containing organic solvent, safe, nontoxic, environmental protection, eliminated the injury of the synthetic plasltic-absorbing oil of organic solvent to human body, and market outlook are wide.
Embodiment
Below the preferred embodiments of the present invention are described, should be appreciated that preferred embodiment described herein, only for description and interpretation the present invention, is not intended to limit the present invention.
Raw material:
ACRYLIC EMULSION C: the ACRYLIC EMULSION C-51 of Guangzhou Chao Xiangyue company; ACRYLIC EMULSION D: the ACRYLIC EMULSION D-52 of Guangzhou Chao Xiangyue company; Aqueous solvent is selected from ethanol or methyl alcohol or Virahol, and water; The plastic uptake agent 872 that plastic uptake agent can select Guangzhou Chao Xiangyue company to produce; Wax emulsion can select Gong Yao International Trading Company Ltd 91240, the MD-2000 of the WE6Huo Weng Kaier company of BASF AG; Flow agent can be selected 5211 of Dow Corning Corporation; Wetting agent can be selected OT75; Permeate agent can be fast T, JFC-1, JFC-2 or the AEP of Hangzhou Jiu Ling company; Defoamer can be the loyal DF568 of company in Shanghai or the DC65 of Dow Corning Corporation.
Embodiment 1
A water plastics-absorbing oil, is comprised of the component of following weight percent: ACRYLIC EMULSION C35%, ACRYLIC EMULSION D20%, ethanol 10%, water 10%, plastic uptake agent 21.6%, wax emulsion 2%, flow agent 0.5%, wetting agent 0.5%, permeate agent 0.2%, defoamer 0.2%.
The preparation method of above-mentioned water plastics-absorbing oil is: ACRYLIC EMULSION C and ACRYLIC EMULSION D are mixed, then add plastic uptake agent, then add successively aqueous solvent, wax emulsion, flow agent, wetting agent, permeate agent and defoamer, mix.
Embodiment 2
A water plastics-absorbing oil, is comprised of the component of following weight percent: ACRYLIC EMULSION C40%, ACRYLIC EMULSION D14.7%, methyl alcohol 15%, water 10%, plastic uptake agent 10%, wax emulsion 10%, flow agent 0.1%, wetting agent 0.1%, permeate agent 0.05%, defoamer 0.05%.
The preparation method of above-mentioned water plastics-absorbing oil is: ACRYLIC EMULSION C and ACRYLIC EMULSION D are mixed, then add plastic uptake agent, then add successively aqueous solvent, wax emulsion, flow agent, wetting agent, permeate agent and defoamer, mix.
Embodiment 3
A water plastics-absorbing oil, is comprised of the component of following weight percent: ACRYLIC EMULSION C37%, ACRYLIC EMULSION D10%, Virahol 5%, water 15%, plastic uptake agent 30%, wax emulsion 2%, flow agent 0.3%, wetting agent 0.3%, permeate agent 0.2%, defoamer 0.2%.
The preparation method of above-mentioned water plastics-absorbing oil is: ACRYLIC EMULSION C and ACRYLIC EMULSION D are mixed, then add plastic uptake agent, then add successively aqueous solvent, wax emulsion, flow agent, wetting agent, permeate agent and defoamer, mix.
Embodiment 4
A water plastics-absorbing oil, is comprised of the component of following weight percent: ACRYLIC EMULSION C40%, ACRYLIC EMULSION D20%, ethanol 5%, water 10%, plastic uptake agent 17.8%, wax emulsion 6%, flow agent 0.5%, wetting agent 0.5%, permeate agent 0.1%, defoamer 0.1%.
The preparation method of above-mentioned water plastics-absorbing oil is: ACRYLIC EMULSION C and ACRYLIC EMULSION D are mixed, then add plastic uptake agent, then add successively aqueous solvent, wax emulsion, flow agent, wetting agent, permeate agent and defoamer, mix.
Embodiment 5
The water plastics-absorbing oil that above-described embodiment 1~4 is prepared characterizes and performance measurement
(1) viscosity: according to GB/T11175-2002, adopt NDJ-1 type rotational viscosimeter, select suitable rotor and suitable tachometry water plastics-absorbing oil viscosity.Meanwhile, with being coated with-4 glasss, measure viscosity.
(2) solid content: get 1.0-2.0g product, dry to constant weight in microwave oven, the quality of front and back product dried in record, calculates solid content.
Solid content=sample dry weight/sample weight in wet base * 100%
(3) glossiness: glossiness has reflected the aesthetic measure of package printing material after plasltic-absorbing oil drying and forming-film, is used mirror luster degree meter coating to be carried out to the detection of glossiness.
(4) wear resistance: wear resistance reflected after plasltic-absorbing oil film forming, paper card wrapping material in handling, storage and transport process, the tolerance degree to external force wearing and tearing.Actual detection method is for using friction testing machine to carry out friction test to the paper card of coating plasltic-absorbing oil, with coating, is worn and ink layer has just occurred that friction number of times when show-through characterizes the wear resistance of plasltic-absorbing oil.
Result shows:
(1) embodiment 1~4 gained water plastics-absorbing oil viscosity is at 17-25 second (50-200mpas), and solid content 35-38%, under this condition, is easy to use every square metre of 6-10 gram of oil mass in seasoning machine adjustment, and guarantees normal dry;
(2), after water plastics-absorbing oil drying and forming-film, as the supercoat to ink printing layer, except possessing the character such as waterproof, protection against the tide, anti-pickup, also need to meet the requirement to glossiness and wear resistance.Find that gained water plastics-absorbing oil can meet glossiness more than 65, wear-resisting 400 the above requirements of 20N pressure.
Finally it should be noted that: these are only the preferred embodiments of the present invention; be not limited to the present invention; for a person skilled in the art; all any modifications of doing within the spirit and principles in the present invention, be equal to replacement, improvement etc., within protection scope of the present invention all should be included in.

Claims (9)

1. a water plastics-absorbing oil, is characterized in that, the component of following weight percent, consists of:
Figure FDA0000432895620000011
Wherein ACRYLIC EMULSION C is the ACRYLIC EMULSION C-51 of Guangzhou Chao Xiangyue company, and ACRYLIC EMULSION D is the ACRYLIC EMULSION D-52 of Guangzhou Chao Xiangyue company.
2. water plastics-absorbing oil according to claim 1, is characterized in that, described aqueous solvent comprises ethanol or methyl alcohol or Virahol 5-15%, and water 10-15%.
3. water plastics-absorbing oil according to claim 1, is characterized in that, described plastic uptake agent is the plastic uptake agent 872 that Guangzhou Chao Xiangyue company produces.
4. water plastics-absorbing oil according to claim 1, is characterized in that, described wax emulsion Shi Gongyao International Trading Company Ltd 91240, the MD-2000 of the WE6Huo Weng Kaier company of BASF AG.
5. water plastics-absorbing oil according to claim 1, is characterized in that, described flow agent is 5211 of Dow Corning Corporation.
6. water plastics-absorbing oil according to claim 1, is characterized in that, described wetting agent is OT-75.
7. water plastics-absorbing oil according to claim 1, is characterized in that, described permeate agent is fast T, JFC-1, JFC-2 or the AEP of Hangzhou Jiu Ling company.
8. water plastics-absorbing oil according to claim 1, is characterized in that, described defoamer is the loyal DF568 of company in Shanghai or the DC65 of Dow Corning Corporation.
9. according to the preparation method of the arbitrary described water plastics-absorbing oil of claim 1~8, it is characterized in that comprising the following steps: ACRYLIC EMULSION C and ACRYLIC EMULSION D are mixed, then add plastic uptake agent, add successively again aqueous solvent, wax emulsion, flow agent, wetting agent, permeate agent and defoamer, mix.
CN201310659868.8A 2013-12-09 2013-12-09 Water-based blister oil and preparation method thereof Pending CN103740303A (en)

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Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104530893A (en) * 2014-12-09 2015-04-22 东莞市蓝铂化工科技有限公司 Aqueous plastic suction oil and preparation method thereof
CN106916552A (en) * 2017-04-24 2017-07-04 施玉芳 A kind of plastic uptake adhesive
CN108728024A (en) * 2018-06-28 2018-11-02 杭州海维特化工科技有限公司 A kind of collapsible PVC furniture film water vacuum plastic-absorption and preparation method thereof
CN108822653A (en) * 2018-07-20 2018-11-16 中山火炬职业技术学院 A kind of aqueous line plastics-absorbing oil and preparation method thereof
CN109777337A (en) * 2018-12-27 2019-05-21 万华化学(宁波)有限公司 A kind of high gloss water plastics-absorbing oil and preparation method thereof
CN110079175A (en) * 2019-05-30 2019-08-02 江苏美乔科技有限公司 A kind of environment-friendly water-based plastics-absorbing oil and preparation method thereof
CN111945477A (en) * 2020-08-14 2020-11-17 上海紫华薄膜科技有限公司 Release heat-sealing packaging paper and manufacturing method thereof

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CN1412211A (en) * 2001-10-11 2003-04-23 机械工业部广州电器科学研究所 Preparation method of water plastics-absorbing oil
CN102154941A (en) * 2011-03-18 2011-08-17 上海理工大学 Preparation method of waterproof printing polishing oil for paper presswork
CN102605674A (en) * 2012-03-30 2012-07-25 无锡德冠生物科技有限公司 Water-based gross oil and preparation method of water-based gross oil

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CN102154941A (en) * 2011-03-18 2011-08-17 上海理工大学 Preparation method of waterproof printing polishing oil for paper presswork
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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104530893A (en) * 2014-12-09 2015-04-22 东莞市蓝铂化工科技有限公司 Aqueous plastic suction oil and preparation method thereof
CN106916552A (en) * 2017-04-24 2017-07-04 施玉芳 A kind of plastic uptake adhesive
CN108728024A (en) * 2018-06-28 2018-11-02 杭州海维特化工科技有限公司 A kind of collapsible PVC furniture film water vacuum plastic-absorption and preparation method thereof
CN108728024B (en) * 2018-06-28 2020-08-14 杭州海维特化工科技有限公司 Reelable PVC furniture film water-based vacuum absorption plastic and preparation method thereof
CN108822653A (en) * 2018-07-20 2018-11-16 中山火炬职业技术学院 A kind of aqueous line plastics-absorbing oil and preparation method thereof
CN109777337A (en) * 2018-12-27 2019-05-21 万华化学(宁波)有限公司 A kind of high gloss water plastics-absorbing oil and preparation method thereof
CN109777337B (en) * 2018-12-27 2021-07-23 万华化学(宁波)有限公司 High-glossiness water-based blister oil and preparation method thereof
CN110079175A (en) * 2019-05-30 2019-08-02 江苏美乔科技有限公司 A kind of environment-friendly water-based plastics-absorbing oil and preparation method thereof
CN111945477A (en) * 2020-08-14 2020-11-17 上海紫华薄膜科技有限公司 Release heat-sealing packaging paper and manufacturing method thereof
CN111945477B (en) * 2020-08-14 2022-07-05 上海紫华薄膜科技有限公司 Release heat-sealing packaging paper and manufacturing method thereof

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