CN1037355C - Staticelectric conducting powder paint - Google Patents
Staticelectric conducting powder paint Download PDFInfo
- Publication number
- CN1037355C CN1037355C CN94105369A CN94105369A CN1037355C CN 1037355 C CN1037355 C CN 1037355C CN 94105369 A CN94105369 A CN 94105369A CN 94105369 A CN94105369 A CN 94105369A CN 1037355 C CN1037355 C CN 1037355C
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- paint
- powder coating
- electrically conductive
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- static
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Abstract
The present invention relates to static conductive powder paint which is compounded from 55 to 65 wt% of polyester resin, epoxy resin or polyurethane resin, 27 to 40 wt% of filler, 4 to 5 wt% of levelling agent and 3 to 4 wt% of solidifying agent. The present invention is characterized in that the paint also contains 0.15 to 20 wt% of conductive particulate medium, and the medium can be prepared from one kind or the mixture of two kinds of graphite, acetylene black and zinc oxide. The paint can make a film forming layer have antistatic performance on the basis of the guarantee of wear resistance and corrosion resistance. The paint is especially suitable for electrostatic resistance and corrosion resistance for surfaces in the petroleum industry, the chemical industry and the electronic industry.
Description
The present invention relates to a kind of body surface electrostatic that can prevent and lead the static powder coating.
Common static powder coating generally adopts vibrin, Resins, epoxy urethane resin as the film forming matrix, is being equipped with wear-and corrosion-resistant filler, tinting material, flow agent, solidifying agent, matting agent, toughner etc.By electrostatic power unit, utilize it to radiate 25～65KV static voltage, charged powder particle is coated on workpiece surface, form the corrosion-resistant protective layer of insulation.But consider that from the industrial safety aspect abrasion-proof corrosion-proof layer that above-mentioned static powder coating forms does not have electrostatic conductive performance,, can cause fearful blast because of the poly-attached a large amount of static charge of film formation surface in some inflammable and explosive occasions.Therefore,, spray the occasion of above-mentioned static powder, need carry out antistatic treatment, the film forming matrix is had on the good abrasion-proof corrosion-proof performance basis, possess eliminating layer surface electrostatic function powder for needs from security standpoint.
CN88106888.8 has introduced a kind of plastic static coating conductive agent, this conductive agent mainly is applicable in the electrostatic coating with low polar high crystalline plastics as primary coat, to form one deck conducting film, improve electrostatic coating usefulness such as surface of plastic products.Its goal of the invention and the present invention have essential distinction.
As the conducting paint composite that CN89100775.X introduces, said composition is suitable for being applied on non-conducting material and the semiconductor material, makes the antistatic film that is used for electronics and electrotechnics aspect.
Above-mentioned two kinds of conductive agents all are to be used to be coated in the non-conductive medium surface to form conductive coating, be not to be coated on metal material surface as antistatic layer, and above-mentioned conductive agent abrasion-proof corrosion-proof performance also can not show a candle to existing common static powder, therefore, its material composition and purposes aspect and the present invention are also inequality.
The object of the present invention is to provide a kind of wear resistant corrosion resistant to lead the static powder coating, this powder coating is to form on the basis at existing common static powder coating, with addition of some conducting medium particle, makes the film forming matrix of its formation can eliminate the static that the surface forms.
A kind of static powder coating of leading, comprise that the urethane resin vibrin or the Resins, epoxy that account for gross weight about 55～65% makes the film forming base-material, be equipped with 27～40% wear resistant corrosion resistant filler again, 4～5% solid flow agent, 3～4% solidifying agent material deliverings also contain the electrically conductive particles medium that accounts for gross weight 0.15～20% in the above-mentioned powder coating component.This conducting medium can adopt graphite, acetylene black, zinc oxide etc., and each conducting medium can Individual existence, also can adopt two or more conducting medium combination collocation to use.Filler of the present invention can adopt titanium dioxide, barium sulfate, zinc sulfide white, talcum powder etc.
Above-mentioned conductivity of leading the static powder coating is adjustable, its base-material and one timing of material delivering component content, and the quantity that the electrically conductive particles medium adds is many more, and the conductivity of coating is good more; Vice versa.Can add gross weight 1～5% tinting material for making coating have color.
In order to keep above-mentioned coating to possess the favorable mechanical performance, chemical property and optical property should guarantee to reduce the add-on of electrically conductive particles medium as far as possible under the electrostatic conductive performance prerequisite, usually more satisfactory add-on should be controlled at 0.15～4%, preferably is controlled in 0.15～0.5% scope.
The present invention relatively not only has identical anticorrosion and decorate properties with domestic and international existing common static coating, and main is that the present invention has increased a kind of antistatic property, and the resistivity of leading electrostatic coating can be adjusted according to customer requirements.Electrically conductive particles medium such as graphite, zinc oxide etc. are added in the common static powder in proportion, utilize electrostatic power unit that powder particle is sprayed on workpiece surface.Then; the workpiece that will be coated with is sent in the process furnace again; when intensification is heated to 60 ℃ of left and right sides; resin begins fusing; in fusion process gradually; electrically conductive particles begins to the coatingsurface drift, and forms the conductive network that electrically conductive particles density is concentrated relatively on the coating top layer, and the electrically conductive particles in the top layer is in contact with one another substantially.Although electrically conductive particles changes with temperature and time in heat-processed, constantly float to the top layer, when temperature reached design requirements, the surface of above-mentioned conductive network can form the transparent corrosion prevention film of one deck high-quality again, and this thicknesses of layers is less than below 10 microns.
This product mainly is applicable to oil, chemical industry, electron trade, can avoid or remove static damage, eliminates because of producing the various unsafe factors that static is hidden.The technology of the present invention performance index:
1. powder fineness: the 160-180 order is by 99.5%.
2. paint film appearance: from unglazed to light is arranged, from smooth to wrinkle, mallear stria, class's line, little to big tangerine line etc., have multiple color, texture to analyse clearly.
3. condition of cure: 120 ℃-200 ℃, 3-35 minute.
4. coating thickness: 30-500 micron.
5. gloss: 2%-80%,
6. sticking power: 1-2 level.
7. shock strength: 45-50KY.
8. snappiness: 1-2 millimeter.
9. water tolerance: it is intact to soak 1000 hours paint films.
10. resistance to salt water: 500 hours no changes of 5% sodium chloride solution room temperature.
11. oil-proofness: 20
#It is intact that machine oil soaks 400 hours paint films.
12. acid resistance: it is intact that 5% sulphuric acid soln soaks 240 hours paint films.
13. alkali resistance: it is intact that 5% sodium hydroxide solution soaks 300 hours paint films.
14. resistance value: 10-10
8Ohm.
Claims (3)
1. lead the static powder coating for one kind, comprise that the urethane resin, vibrin or the Resins, epoxy that account for gross weight 55～65% are as the film forming base-material, be equipped with 27～40% filler, 4～5% flow agent, 3～4% solidifying agent again, also contain at least a of the graphite that accounts for gross weight 0.15～20%, acetylene black, zinc oxide electrically conductive particles medium in the above-mentioned powder coating component.
2. powder coating according to claim 1, the content that it is characterized in that said electrically conductive particles medium is 0.15～4%.
3. powder coating according to claim 1, the content that it is characterized in that said electrically conductive particles medium is 0.15～0.5%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94105369A CN1037355C (en) | 1994-05-20 | 1994-05-20 | Staticelectric conducting powder paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94105369A CN1037355C (en) | 1994-05-20 | 1994-05-20 | Staticelectric conducting powder paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1099779A CN1099779A (en) | 1995-03-08 |
| CN1037355C true CN1037355C (en) | 1998-02-11 |
Family
ID=5032036
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94105369A Expired - Fee Related CN1037355C (en) | 1994-05-20 | 1994-05-20 | Staticelectric conducting powder paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1037355C (en) |
Families Citing this family (21)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE19958485A1 (en) | 1999-12-04 | 2001-06-21 | Dupont Performance Coatings | Antistatic powder coating compositions and their use |
| CN1328169C (en) * | 2002-12-25 | 2007-07-25 | 中粉高科技株式会社 | Electroconductive zinc oxide powder and method for production thereof, and electroconductive composition |
| JP4393460B2 (en) | 2002-12-25 | 2010-01-06 | ハクスイテック株式会社 | Conductive zinc oxide powder, process for producing the same, and conductive composition |
| CN100369984C (en) * | 2003-07-02 | 2008-02-20 | 深圳市海川实业股份有限公司 | Environmental protection antistatic anti-cracking putty powder |
| CN100374518C (en) * | 2005-12-13 | 2008-03-12 | 山东电力研究院 | Flue gas purified anticorrosive conductive coating |
| CN102233701B (en) * | 2010-04-20 | 2013-07-17 | 宝山钢铁股份有限公司 | Color-coating steel plate and coating process |
| CN102311699B (en) * | 2010-06-30 | 2013-06-19 | 贝科工业涂料(上海)有限公司 | Antistatic polyester coating used for roll material and manufacturing method thereof |
| CN103254487A (en) * | 2013-05-08 | 2013-08-21 | 山西安德鲁科技有限公司 | Electric-conducting flame-retarding thermoplastic powder, preparation method and applications thereof |
| CN103409042A (en) * | 2013-05-30 | 2013-11-27 | 常熟市方塔涂料化工有限公司 | Solvent-free epoxy floor paint and preparation method thereof |
| CN104745044A (en) * | 2015-03-31 | 2015-07-01 | 信和新材料股份有限公司 | Zinc-rich primer using activation technique |
| CN105219219A (en) * | 2015-10-19 | 2016-01-06 | 国网浙江省电力公司湖州供电公司 | A kind of novel wear resistant, protection against corrosion, Antistatic Paint and preparation method thereof |
| CN105385321B (en) * | 2015-12-25 | 2018-03-06 | 德清县金秋塑粉有限公司 | A kind of conductive powder paint |
| CN105694666A (en) * | 2016-02-01 | 2016-06-22 | 芜湖市四捍粉末涂料有限公司 | Thermosetting antistatic flame-retardant powder paint |
| CN105936790A (en) * | 2016-05-26 | 2016-09-14 | 广西梧州龙鱼漆业有限公司 | Hammer paint |
| CN108753133A (en) * | 2018-05-08 | 2018-11-06 | 广东合邦新型粉末涂料科技股份有限公司 | A kind of solvent resistant wiping powdery paints and preparation method thereof |
| CN108587402A (en) * | 2018-05-16 | 2018-09-28 | 厦门新沪厦五金工贸有限公司 | A kind of tapping screw |
| CN108912855A (en) * | 2018-06-25 | 2018-11-30 | 合肥艾飞新材料有限公司 | A kind of preparation method of antistatic powder coating |
| CN109135514A (en) * | 2018-08-09 | 2019-01-04 | 安徽省华欣能源装备科技有限公司 | A kind of protective powder coating and preparation method thereof for oil tank |
| CN109096878A (en) * | 2018-08-09 | 2018-12-28 | 安徽省华欣能源装备科技有限公司 | A kind of wear-resisting antistatic powdery paints and preparation method thereof |
| CN112094576A (en) * | 2020-09-30 | 2020-12-18 | 中山市创渝中涂料科技有限公司 | Production and processing technology of antistatic powder coating |
| CN112226147A (en) * | 2020-10-14 | 2021-01-15 | 洛阳乐卡粉末有限公司 | Antistatic thermosetting powder coating for military storage cabinet and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55157666A (en) * | 1979-05-29 | 1980-12-08 | Toagosei Chem Ind Co Ltd | Preparation of electrically conductive powder coating |
| JPS55157665A (en) * | 1979-05-29 | 1980-12-08 | Toagosei Chem Ind Co Ltd | Electrically conductive powder coating |
-
1994
- 1994-05-20 CN CN94105369A patent/CN1037355C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS55157666A (en) * | 1979-05-29 | 1980-12-08 | Toagosei Chem Ind Co Ltd | Preparation of electrically conductive powder coating |
| JPS55157665A (en) * | 1979-05-29 | 1980-12-08 | Toagosei Chem Ind Co Ltd | Electrically conductive powder coating |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1099779A (en) | 1995-03-08 |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 19980211 |