CN100369984C - Environmental protection antistatic anti-cracking putty powder - Google Patents

Environmental protection antistatic anti-cracking putty powder Download PDF

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Publication number
CN100369984C
CN100369984C CNB031456383A CN03145638A CN100369984C CN 100369984 C CN100369984 C CN 100369984C CN B031456383 A CNB031456383 A CN B031456383A CN 03145638 A CN03145638 A CN 03145638A CN 100369984 C CN100369984 C CN 100369984C
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China
Prior art keywords
powder
environment
friendly type
cracking
antistatic anti
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Expired - Fee Related
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CNB031456383A
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CN1566230A (en
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王刚伟
何唯平
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Shenzhen Oceanpower Industrial Co Ltd
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Shenzhen Oceanpower Industrial Co Ltd
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Priority to CNB031456383A priority Critical patent/CN100369984C/en
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Abstract

The present invention relates to environmental protection type antistatic and anti-cracking putty powder which is composed of 2 to 5% of polymer powder, 15 to 35% of conductive materials, 20 to 30% of white cement, 3 to 8% of gypsum powder, 5 to 15% of bentonitic clay, 15 to 35% of quartz powder, 5 to 15% of talcum powder, 0.3 to 0.5% of water keeping agents, 0 to 1.5% of anti-cracking agents, 0.1 to 0.5% of dispersing agents, 0.1 to 1.0% of defoaming agent and 0.3 to 0.8% of reinforcement fiber. Due to the fact that the conductive materials having an antistatic function, impervious fillers and the reinforcement fiber having an anti-cracking function are added; meanwhile, high quality additives are also matched, the basic performance of the produced putty is ensured; meanwhile, the present invention has the antistatic functional characteristics of electromagnetic interference shielding, adsorption dust prevention, etc., and also has the advantages of environmental protection, no pollution, innocuity, no stimulation, good quality, quick drying, water resistance, crack resistance, easy grinding, strong adhesion force, etc.

Description

The antistatic anti-cracking putty powder of a kind of environment-friendly type
Technical field the present invention relates to a kind of functional putty powder that is used for construction wall, and particularly being used in has on the particular requirement place static, with the special-purpose antistatic anti-cracking putty powder of the matching used body of wall bottoming of antistatic coating.
The harm in some cases of background technology static is known by people already, every year is hundreds of millions of because of the loss that static caused, for this reason, at some static there is particular requirement, in places such as electronics, communication, computer, precision instrument, weaving, powder processing and flammable explosive gas, antistatic be safety in production and the necessary condition that ensures quality product always.
In general, the film coated surface resistance value is 10 12Below can eliminate the static charge that is accumulated in film coated surface, the standard A STM F150-98 of American Society Testing and Materials with resistance value 2.5 * 10 4~1.0 * 10 6The sheet material of ohm is called conductive sheet metal, and is 1.0 * 10 with resistance value 6-9The sheet material of ohm is called electrostatically dissipative sheet material, and these sheet materials can prevent the accumulation of static charge.Therefore, people adopt the place of conductive flooring usually at needs, adopt the method for pasting anti-electrostatic sheet material to reduce the loss that static comes.But this method but is not clearly for those to the antistatic extra high place antistatic effect that requires, and sheet material is not easy to clean, also easy-maintaining not, and the life-time service antistatic effect also can reduce gradually.
In recent years, along with the progress of antistatic technology and the development of coating technology, people generally adopt antistatic coating application concrete or cement basal plane, to obtain antistatic effect, facts have proved that this method is compared the anti-electrostatic effect that is produced with traditional pasting board mode, not only effect is obvious, and it is lasting to hold time.
Say that in a sense building coating is a kind of work in-process, have only through the construction film forming to be only final finished attached to the coating on the basal plane.In this process, though putty is the supplementary material in the building coating coating process, form a connecting link but it plays in metope basic unit and between filming, the vital role of bonding transition is also being born important functions such as preventing metope cracking, the peeling of filming, specific functionality simultaneously.
Along with the appearance of country to building materials hazardous and noxious substances limit standard, the environmental issue of putty, also be subjected to human consumer's extensive concern, how to develop and a kind ofly require environmental protection, energy-conservation, pollution-free, high hiding rare, life-span long, the putty that easy construction can satisfy the specific function needs has again become the development trend of putty from now on, at present, being seen antistatic putty product mostly is oil product both at home and abroad, and the aqueous antistatic putty of environment-friendly type yet there are no relevant report.
Summary of the invention is in conjunction with the development of modern antistatic technology and coating technology, the invention discloses the antistatic anti-cracking putty powder of a kind of environment-friendly type, adopt its prepared putty not only to have shield electromagnetic interference, prevent to adsorb anti-static function characteristic such as dust, also have advantages such as environment friendly and pollution-free, nontoxic, non-stimulated, thick matter, fast dried, water-fast, freedom from cracking, easy polishing, strong adhesion.
The antistatic anti-cracking putty powder of this environment-friendly type of the present invention comprises following component: the talcum powder of the wilkinite of the white cement of the polymer powder of the 2-5% of counting by weight percentage, the electro-conductive material of 15-35%, 20-30%, the terra alba of 3-8%, 5-15%, the silica powder of 15-35%, 5-15%, the water-holding agent of 0.3-0.5%, the antichecking agent of 0-1.5%, the dispersion agent of 0.1-0.5%, the defoamer of 0.1-1.0% and the fortifying fibre of 0.3-0.8%, and all component per-cent sums are 100%.
Wherein, polymer powder is esters of acrylic acid, vinyl acetate class elasticity or non-resilient copolymer emulsion dry powder, as elasticity such as pure third, phenylpropyl alcohol and vinegar third, vinegar uncle or non-resilient emulsion dry powder base-material etc.; Also can adopt polyvinyl alcohol resin dry powder.
Electro-conductive material is 100-800 purpose composite conducting mica powder, conductive zinc oxide, conductive carbon black, graphite etc.
Filler is the 425# white cement, 250-500 order terra alba, the wilkinite of 300-800 order smectites sodium base, 120-400 order silica powder, 250-400 order talcum powder etc.
Auxiliary agent is antichecking agent, dispersion agent and defoamer, is produced by German Kening Co.,Ltd (Cognis).
Water-holding agent can be the methylcellulose gum series products of molecular weight about 15000-40000.
Fortifying fibre is that length is polyacrylonitrile fibre or the carbon fiber of 1.0-3.0mm.
Proportionally, above each component of weighing fully stirred 15-30 minute with mediating stirrer after the oven dry successively, mixed powdery components, was packaged as finished product with the weather-proof dressing bag.
Compared with prior art, invention is filled a prescription in the selected starting material, added the fortifying fibre of the electro-conductive material with antistatic property, impervious filler and anti-be full of cracks effect, also mated high quality additive simultaneously, these just make the putty of producing guarantee that fundamental property simultaneously, have water-fast preferably and anti-cracking, can guarantee that enough once criticizing scrape thickness, effectively antistatic effect.
Compare with traditional wall putty, use this putty of being produced of prescription to have shield electromagnetic interference, prevent to adsorb anti-static function characteristic such as dust, but also have advantages such as environment friendly and pollution-free, nontoxic, non-stimulated, thick matter, fast dried, water-fast, freedom from cracking, easy polishing, strong adhesion, supporting with it antistatic coating, because of putty layer thickness is generally 1.5mm-5.0mm, conductive section increases, and can more strengthen its conductivity; Supporting with it conduction emulsion paint can reduce the conducting powder consumption, reduces cost, and shows that it is good ornamental, and it is big because of the conducting powder consumption that adds to have improved original conduction emulsion paint, the defective that can't show beautiful color; In addition, conduct electricity putty relatively with now general oiliness, because it adopts the water-based base material fully, organic solvent-free and harmful organic substance, compliance with environmental protection requirements, and be the single component powder morphology, packed and transported is convenient.
Embodiment
Embodiment:
Prepare expanded polystyrene veneer heat-insulation and heat-preservation fire prevention putty powder of the present invention according to described preparation method, its component concentration (by weight) is as follows:
425# white cement 25%
Polymer powder 24-88P (Ke Laien) 4%
500 order conductive mica powders (monarch river science and technology) 24%
400 order terra albas 5%
500 order sodium bentonites 10%
120 order silica powders 23%
400 order talcum powder 7%
Antichecking agent Loxanol P (Cognis) 0.8%
Dispersion agent Hydropalat 760 (Cognis) 0.3%
Defoamer Dehydran1922 (Cognis) 0.2%
Methyl cellulose ether (Bayer) 0.4%
2mm fortifying fibre (road prestige 2000) 0.5%
During site operation, in above component putty powder, mix 40% water,, adjust to suitable viscosity and can criticize and scraped with machine or artificial mixing and stirring with weight ratio.Use the scraper blade coating on the asbestos model putty for preparing, test comparison is not added the putty sample of electro-conductive material and fortifying fibre simultaneously, find the model moderate drying speed of blade coating putty of the present invention, very outstanding electrostatic-proof function is arranged, according to ASTMF150-98 resistance instrument experiment test, sheet resistance value is less than 10 8Ohm electroconductibility is preferably arranged, and grinability is good, and sticking power is good, and is water-fast impervious, and long-term physical environment is deposited without any cracking phenomena, and conductivity continues permanent.

Claims (10)

1. antistatic anti-cracking putty powder of environment-friendly type, its component concentration is: the talcum powder of the wilkinite of the white cement of the polymer powder of the 2-5% of counting by weight percentage, the electro-conductive material of 15-35%, 20-30%, the terra alba of 3-8%, 5-15%, the silica powder of 15-35%, 5-15%, the water-holding agent of 0.3-0.5%, the antichecking agent of 0-1.5%, the dispersion agent of 0.1-0.5%, the defoamer of 0.1-1.0% and the fortifying fibre of 0.3-0.8%, all per-cent sums are 100%.
2. the antistatic anti-cracking putty powder of environment-friendly type according to claim 1 is characterized in that: polymer powder is the elasticity or the non-resilient copolymer emulsion dry powder of esters of acrylic acid, vinyl acetate class, also can adopt polyvinyl alcohol resin dry powder.
3. the antistatic anti-cracking putty powder of environment-friendly type according to claim 1 and 2 is characterized in that, these polymer powders can be elasticity or non-resilient emulsion dry powder base-materials such as pure third, phenylpropyl alcohol and vinegar third, vinegar uncle.
4. the antistatic anti-cracking putty powder of environment-friendly type according to claim 1 is characterized in that, described electro-conductive material is 100-800 purpose composite conducting mica powder, conductive zinc oxide, conductive carbon black or graphite.
5. the antistatic anti-cracking putty powder of environment-friendly type according to claim 1, it is characterized in that, described filler is the white cement of 425#, 250-400 purpose terra alba, the wilkinite of 300-800 purpose smectites sodium base, 120-400 purpose silica powder and the formed mixture of 250-400 purpose talcum powder.
6. the antistatic anti-cracking putty powder of environment-friendly type according to claim 1 is characterized in that, water-holding agent is the methylcellulose gum series products of molecular weight about 15000-40000.
7. the antistatic anti-cracking putty powder of environment-friendly type according to claim 1 is characterized in that, described fortifying fibre is that length is polyacrylonitrile fibre or the carbon fiber of 1.0-3.0mm.
8. the antistatic anti-cracking putty powder of environment-friendly type according to claim 1 is characterized in that the antichecking agent that is added is the Loxanol P of Cognis company.
9. the antistatic anti-cracking putty powder of environment-friendly type according to claim 1 is characterized in that the dispersion agent that is added is the Hydropalat 760 of Cognis company.
10. the antistatic anti-cracking putty powder of environment-friendly type according to claim 1 is characterized in that the defoamer that is added is the Dehydran 1922 of Cognis company.
CNB031456383A 2003-07-02 2003-07-02 Environmental protection antistatic anti-cracking putty powder Expired - Fee Related CN100369984C (en)

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CN100369984C true CN100369984C (en) 2008-02-20

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Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101914318B (en) * 2010-08-04 2012-08-08 童捷 Formula of putty for inner wall of building
EP2712853A1 (en) * 2012-10-01 2014-04-02 Dantonit A/S A powder composition and slurry for preparing heat conducting materials
CN104263051A (en) * 2014-10-24 2015-01-07 常熟市奇越新型建材贸易有限公司 Environment-friendly putty powder
CN104893393A (en) * 2015-05-29 2015-09-09 柳州普亚贸易有限公司 Preparation method of radiation-resistant putty powder
CN104877426A (en) * 2015-05-29 2015-09-02 柳州普亚贸易有限公司 Radiation-preventive putty powder
CN109401412A (en) * 2018-10-23 2019-03-01 西安航天三沃化学有限公司特种涂料分公司 A kind of aqueous static conductive putty and preparation method thereof
CN110305515A (en) * 2019-06-21 2019-10-08 万红梅 A kind of long-acting anti-crack mastic powder
CN112979233A (en) * 2019-12-02 2021-06-18 佛山科导宏图新型材料有限公司 Anti-static tile joint mixture and preparation method thereof

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1099779A (en) * 1994-05-20 1995-03-08 于延泉 Staticelectric conducting powder paint
CN1193639A (en) * 1998-04-29 1998-09-23 王国真 Anti-electrostatic powder coating material and spraying method
CN1345901A (en) * 2000-09-26 2002-04-24 上海中铝化工有限公司 Powdered indoor water-resistant putty
CN1402766A (en) * 1999-12-04 2003-03-12 纳幕尔杜邦公司 Antistatic powder coating compositions and their use

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1099779A (en) * 1994-05-20 1995-03-08 于延泉 Staticelectric conducting powder paint
CN1193639A (en) * 1998-04-29 1998-09-23 王国真 Anti-electrostatic powder coating material and spraying method
CN1402766A (en) * 1999-12-04 2003-03-12 纳幕尔杜邦公司 Antistatic powder coating compositions and their use
CN1345901A (en) * 2000-09-26 2002-04-24 上海中铝化工有限公司 Powdered indoor water-resistant putty

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GR01 Patent grant
EE01 Entry into force of recordation of patent licensing contract

Assignee: Shenzhen Oceanpower Chemical Technology Co., Ltd.

Assignor: Haichuan Industry Co., Ltd., Shenzhen

Contract fulfillment period: 2008.8.9 to 2015.1.17 contract change

Contract record no.: 2008440000274

Denomination of invention: Environmental protection antistatic anti-cracking putty powder

Granted publication date: 20080220

License type: Exclusive license

Record date: 20081014

LIC Patent licence contract for exploitation submitted for record

Free format text: EXCLUSIVE LICENSE; TIME LIMIT OF IMPLEMENTING CONTACT: 2008.8.9 TO 2015.1.17; CHANGE OF CONTRACT

Name of requester: SHENZHEN HAICHUAN CHEMICAL TECHNOLOGY CO., LTD.

Effective date: 20081014

C19 Lapse of patent right due to non-payment of the annual fee
CF01 Termination of patent right due to non-payment of annual fee