CN103730344B - The method forming the monox lateral wall of metallic silicon tangsten silicide grid - Google Patents

The method forming the monox lateral wall of metallic silicon tangsten silicide grid Download PDF

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Publication number
CN103730344B
CN103730344B CN201210388548.9A CN201210388548A CN103730344B CN 103730344 B CN103730344 B CN 103730344B CN 201210388548 A CN201210388548 A CN 201210388548A CN 103730344 B CN103730344 B CN 103730344B
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grid
silicon
lateral wall
metal silication
monox lateral
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CN103730344A (en
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陈瑜
马斌
陈华伦
罗啸
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Shanghai Huahong Grace Semiconductor Manufacturing Corp
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Shanghai Huahong Grace Semiconductor Manufacturing Corp
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/28008Making conductor-insulator-semiconductor electrodes
    • H01L21/28017Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
    • H01L21/28247Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon passivation or protection of the electrode, e.g. using re-oxidation
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L21/00Processes or apparatus adapted for the manufacture or treatment of semiconductor or solid state devices or of parts thereof
    • H01L21/02Manufacture or treatment of semiconductor devices or of parts thereof
    • H01L21/04Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer
    • H01L21/18Manufacture or treatment of semiconductor devices or of parts thereof the devices having potential barriers, e.g. a PN junction, depletion layer or carrier concentration layer the devices having semiconductor bodies comprising elements of Group IV of the Periodic Table or AIIIBV compounds with or without impurities, e.g. doping materials
    • H01L21/28Manufacture of electrodes on semiconductor bodies using processes or apparatus not provided for in groups H01L21/20 - H01L21/268
    • H01L21/28008Making conductor-insulator-semiconductor electrodes
    • H01L21/28017Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon
    • H01L21/28026Making conductor-insulator-semiconductor electrodes the insulator being formed after the semiconductor body, the semiconductor being silicon characterised by the conductor
    • H01L21/28123Lithography-related aspects, e.g. sub-lithography lengths; Isolation-related aspects, e.g. to solve problems arising at the crossing with the side of the device isolation; Planarisation aspects
    • H01L21/28132Lithography-related aspects, e.g. sub-lithography lengths; Isolation-related aspects, e.g. to solve problems arising at the crossing with the side of the device isolation; Planarisation aspects conducting part of electrode is difined by a sidewall spacer or a similar technique, e.g. oxidation under mask, plating
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L29/00Semiconductor devices specially adapted for rectifying, amplifying, oscillating or switching and having potential barriers; Capacitors or resistors having potential barriers, e.g. a PN-junction depletion layer or carrier concentration layer; Details of semiconductor bodies or of electrodes thereof ; Multistep manufacturing processes therefor
    • H01L29/66Types of semiconductor device ; Multistep manufacturing processes therefor
    • H01L29/66007Multistep manufacturing processes
    • H01L29/66075Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials
    • H01L29/66227Multistep manufacturing processes of devices having semiconductor bodies comprising group 14 or group 13/15 materials the devices being controllable only by the electric current supplied or the electric potential applied, to an electrode which does not carry the current to be rectified, amplified or switched, e.g. three-terminal devices
    • H01L29/66409Unipolar field-effect transistors
    • H01L29/66477Unipolar field-effect transistors with an insulated gate, i.e. MISFET
    • H01L29/66568Lateral single gate silicon transistors

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  • Engineering & Computer Science (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Computer Hardware Design (AREA)
  • Ceramic Engineering (AREA)
  • Drying Of Semiconductors (AREA)

Abstract

A kind of method that the invention discloses monox lateral wall forming metallic silicon tangsten silicide grid, including step: form the grid structure being made up of grid oxic horizon, grid polycrystalline silicon and metal silication tungsten, grid structure top is photo-etched glue protection;The RIE technique of carbon tetrafluoride carries out ashing process to photoresist to utilize process gas to include;Silicon substrate after RIE technique is carried out deionized water rinsing;Carry out RTO technique, form monox lateral wall at gate structure sidewall.The inventive method, it can be avoided that make the crystal grain of metal silication tungsten grow up and form ball bumps during growing silicon oxide side wall, is also avoided that owing to avoiding the point discharge caused by ball bumps, improves the breakdown voltage of device;The present invention can also reduce process costs.The monox lateral wall that the inventive method is formed can reduce the stress between silicon nitride layer and gate polycrystalline sidewall silicon and can repair the lattice defect of gate polycrystalline sidewall silicon.

Description

The method forming the monox lateral wall of metallic silicon tangsten silicide grid
Technical field
The present invention relates to a kind of semiconductor integrated circuit method of manufacturing technology, particularly relate to a kind of formation metal silication tungsten The method of the monox lateral wall of grid.
Background technology
In the MOS technique of metallic silicon tangsten silicide grid (Tungsten Polycide), after gate patterns has etched, Need to form a layer thickness in the sidewall surfaces of grid structure to be about Monox lateral wall protect Layer.As it is shown in figure 1, be the structural representation of the monox lateral wall of the metallic silicon tangsten silicide grid that existing method is formed;Existing Having method generally to use the method sidewall growth monox lateral wall at grid structure of boiler tube, wherein grid structure includes depending on Secondary it is formed at the grid oxic horizon 102 on silicon substrate 101 surface, grid polycrystalline silicon 103 and metal silication tungsten 104, The surface of metal silication tungsten 104 is also formed with silicon nitride protective layer 105, by high-temperature oxydation in boiler tube, described The sidewall surfaces of grid structure forms monox lateral wall 106.The monox lateral wall 106 that existing method is formed can reduce The follow-up silicon nitride layer grown for self-registered technology (Self-Alignment Contact) and grid polycrystalline silicon 103 Stress between sidewall, can play the effect of cushion;Monox lateral wall 106 is the high-temperature oxydation shape by boiler tube Becoming, so also being able to play high temperature repair, the lattice that during minimizing pattern etching, polysilicon sidewall produces lacks Fall into;Meanwhile, monox lateral wall 106 can also effectively act as insulation effect, it is to avoid point discharge, decreases electric charge Assembling in the silicon nitride layer, so sidewall breakdown voltage for raising metal-oxide-semiconductor plays a good role.
Though the monox lateral wall 106 of boiler tube method growth, film quality compact structure, furnace tube operation temperature is higher, Easily cause metal silication tungsten to aoxidize recrystallization, cause crystallite dimension (Grain Size) to grow up and form spherical (pilling) Protruding (pilling) 107, ball bumps 107 has large effect to the pattern of grid, easily makes when situation is serious Become point discharge to puncture grid curb wall, reduce the side wall breakdown voltage of metal-oxide-semiconductor.
Summary of the invention
The technical problem to be solved is to provide the side of a kind of monox lateral wall forming metallic silicon tangsten silicide grid Method, is avoided that the sidewall at metal silication tungsten forms ball bumps and avoids the point discharge caused by ball bumps, Improve the breakdown voltage of device, it is possible to reducing the process costs forming monox lateral wall, the monox lateral wall of formation can be very The stress reduced between silicon nitride layer and gate polycrystalline sidewall silicon got well and the lattice that gate polycrystalline sidewall silicon can be repaired Defect.
For solving above-mentioned technical problem, the method bag of the monox lateral wall forming metallic silicon tangsten silicide grid that the present invention provides Include following steps:
Step one, sequentially form grid oxic horizon, grid polycrystalline silicon and metal silication tungsten in surface of silicon;Use light Carving technology defines grid structure graphics field with photoresist, uses etching technics successively to described with photoresist for mask Metal silication tungsten, described grid polycrystalline silicon and described grid oxic horizon perform etching formation grid structure figure.
Step 2, carry out reactive ion etching process, utilize reactive ion etching process that described photoresist is ashed Process and described photoresist is removed;The process gas of reactive ion etching process includes carbon tetrafluoride (CF4), instead Bombard the sidewall surfaces of described metal silication tungsten by the fluorion produced and utilize fluorine during answering ion etch process Ion and the chemical reaction of tungsten silicide make the sidewall surfaces of described metal silication tungsten roughening, thus improve described metallic silicon Change the oxidized speed of sidewall surfaces of tungsten.
Step 3, the described silicon substrate after reactive ion etching process is carried out deionized water rinsing.
Step 4, the described silicon substrate after deionized water rinsing is carried out rapid thermal oxidation annealing;Described Rapid Thermal It is 100 angstroms~150 that oxidizing annealing makes described metal silication tungsten, the sidewall surfaces of described grid polycrystalline silicon form a thickness Angstrom monox lateral wall.
Further improving is that in step one, the surface at described metal silication tungsten is also formed with silicon nitride protective layer, uses In described metal silication tungsten is protected.
Further improving is also to include fluoroform in the process gas of reactive ion etching process described in step 2 (CHF3) and oxygen (O2)。
Further improve and be, the technological temperature of the described rapid thermal oxidation annealing in step 4 is 975 DEG C, technique time Between be 20 seconds~30 seconds, process gas is made up of oxygen and nitrogen, and nitrogen flow is 20 centimetres3/ minute~50 lis Rice3/ minute, the content of oxygen is the 1%~2% of the total amount of process gas.
The inventive method is by being passed through CF when removing the photoresist above grid structure by RIE technique4, oxygen and CHF3, it is possible to pass through CF4And CHF3The fluorion that gas ionization the produces side to grid structure particularly metal silication tungsten Wall surface carries out bombarding and making the sidewall surfaces of metal silication tungsten roughening;The sidewall surfaces of metal silication tungsten roughening it After, it is possible to increase the oxidized speed of sidewall surfaces of described metal silication tungsten, make the sidewall surfaces of described metal silication tungsten It is easier to oxidized, it is not necessary to use high and time length the furnace process of temperature to form monox lateral wall, and only need to adopt Just can form monox lateral wall in the sidewall surfaces of grid structure by RTO technique, use the time of RTO technique to be smaller than The high temperature heating time of furnace process, institute is in the process of the present invention it can be avoided that make metal due to long high-temperature oxydation The crystal grain of tungsten silicide is grown up and is formed ball bumps, is also avoided that owing to avoiding the point discharge caused by ball bumps, Improve the breakdown voltage of device.The present invention uses RTO technique to form monox lateral wall simultaneously, and the cost of this technique is lower. The monox lateral wall that the inventive method is formed can also well reduce answering between silicon nitride layer and gate polycrystalline sidewall silicon Power and the lattice defect of gate polycrystalline sidewall silicon can be repaired.
Accompanying drawing explanation
The present invention is further detailed explanation with detailed description of the invention below in conjunction with the accompanying drawings:
Fig. 1 is the structural representation of the oxide layer sidewall of the metallic silicon tangsten silicide grid that existing method is formed;
Fig. 2 is embodiment of the present invention method flow diagram;
Fig. 3 A-Fig. 3 C is the device architecture schematic diagram in each step of embodiment of the present invention method.
Detailed description of the invention
As in figure 2 it is shown, be embodiment of the present invention method flow diagram;As shown in Fig. 3 A to Fig. 3 C, it is that the present invention implements Device architecture schematic diagram in each step of example method.The embodiment of the present invention forms the monox lateral wall of metallic silicon tangsten silicide grid Method comprise the steps:
Step one, as shown in Figure 3A, sequentially form on silicon substrate 1 surface grid oxic horizon 2, grid polycrystalline silicon 3, Metal silication tungsten 4, and silicon nitride protective layer 5 is formed on the surface of described metal silication tungsten 4;Use photoetching process 6 define grid structure graphics field with photoresist, use etching technics successively to described nitrogen with photoresist 6 for mask SiClx protective layer 5, described metal silication tungsten 4, described grid polycrystalline silicon 3 and described grid oxic horizon 2 perform etching And form the grid structure being made up of described grid oxic horizon 2, described grid polycrystalline silicon 3 and described metal silication tungsten 4 Figure, is that the described silicon nitride protective layer 5 of grid structure graphics field is photo-etched glue 6 and protects during etching.
Step 2, as shown in Figure 3 B, carries out reactive ion etching process, utilizes reactive ion etching process to described Photoresist 6 carries out ashing process and is removed by described photoresist 6;The process gas of reactive ion etching process includes Carbon tetrafluoride, fluoroform and oxygen, during reactive ion etching process, process gas knows from experience ionization and by producing Fluorion bombard the sidewall surfaces of described metal silication tungsten 4 and to utilize the chemical reaction of fluorion and tungsten silicide to make described The sidewall surfaces of metal silication tungsten is roughening, after reactive ion etching process, and described grid polycrystalline silicon 3, described metal The sidewall surfaces of tungsten silicide 4 and described silicon nitride protective layer 5 forms a rough layer 7, and this rough layer 7 is easier to by oxygen Change and form silicon oxide.
Step 3, the described silicon substrate 1 after reactive ion etching process is carried out deionized water rinsing.
Step 4, as shown in Figure 3 C, carries out rapid thermal oxidation annealing to the described silicon substrate 1 after deionized water rinsing Process;The annealing of described rapid thermal oxidation makes described silicon nitride protective layer 5, described metal silication tungsten 4, described grid many The sidewall surfaces of crystal silicon 3 forms the monox lateral wall 8 that a thickness is 100 angstroms~150 angstroms.Described rapid thermal oxidation moves back The technological temperature of fire is 975 DEG C, the process time is 20 seconds~30 seconds, and process gas is made up of oxygen and nitrogen, nitrogen Throughput is 20 centimetres3/ minute~50 centimetres3/ minute, the content of oxygen is the 1%~2% of the total amount of process gas.
After forming above-mentioned grid and sidewall structure, follow-up the technique identical with other existing MOS technique can be used to walk Suddenly, forming a complete MOS device, subsequent technique is as formed lightly-doped source drain region, forming source-drain area, and formation connects The steps such as contact hole and formation metal connecting line.
By containing CF in the embodiment of the present invention4、CHF3And O2The reactive ion etching process sidewall to grid structure After surface processes, define one layer of rough layer 7 being more prone to oxidation, the formation of rough layer 7 so that this Unnecessary employing furnace process in bright embodiment, and just can form monox lateral wall 8 only with rapid thermal oxidation annealing. So can not only reduce process costs, moreover it is possible to the formation of hemisphere jut when avoiding using furnace process, it is thus possible to prevent Puncturing of grid curb wall, improves the voltage endurance capability of grid curb wall.The monox lateral wall 8 that the inventive method is formed can also be very The stress reduced between silicon nitride layer and grid polycrystalline silicon 3 sidewall got well and the crystalline substance that grid polycrystalline silicon 3 sidewall can be repaired Lattice defect.
Above by specific embodiment, the present invention is described in detail, but these have not constituted the limit to the present invention System.Without departing from the principles of the present invention, those skilled in the art it may also be made that many deformation and improves, this Also should be regarded as protection scope of the present invention a bit.

Claims (4)

1. the method for the monox lateral wall forming metallic silicon tangsten silicide grid, it is characterised in that comprise the steps:
Step one, sequentially form grid oxic horizon, grid polycrystalline silicon and metal silication tungsten in surface of silicon;Use light Carving technology defines grid structure graphics field with photoresist, uses etching technics successively to described with photoresist for mask Metal silication tungsten, described grid polycrystalline silicon and described grid oxic horizon perform etching formation grid structure figure;
Step 2, carry out reactive ion etching process, utilize reactive ion etching process that described photoresist is ashed Process and described photoresist is removed;The process gas of reactive ion etching process includes carbon tetrafluoride, reaction from In sub-etching process, the fluorion by producing bombards the sidewall surfaces of described metal silication tungsten and utilizes fluorion The sidewall surfaces making described metal silication tungsten with the chemical reaction of tungsten silicide is roughening, thus improves described metal silication tungsten The oxidized speed of sidewall surfaces;
Step 3, the described silicon substrate after reactive ion etching process is carried out deionized water rinsing;
Step 4, the described silicon substrate after deionized water rinsing is carried out rapid thermal oxidation annealing;Described Rapid Thermal It is 100 angstroms~150 that oxidizing annealing makes described metal silication tungsten, the sidewall surfaces of described grid polycrystalline silicon form a thickness Angstrom monox lateral wall.
2. the method for the monox lateral wall forming metallic silicon tangsten silicide grid as claimed in claim 1, it is characterised in that: In step one, the surface at described metal silication tungsten is also formed with silicon nitride protective layer, for entering described metal silication tungsten Row protection.
3. the method for the monox lateral wall forming metallic silicon tangsten silicide grid as claimed in claim 1, it is characterised in that: The process gas of reactive ion etching process described in step 2 also includes fluoroform and oxygen.
4. the method for the monox lateral wall forming metallic silicon tangsten silicide grid as claimed in claim 1, it is characterised in that: The technological temperature of the described rapid thermal oxidation annealing in step 4 is 975 DEG C, the process time is 20 seconds~30 seconds, work Process gases is made up of oxygen and nitrogen, and nitrogen flow is 20 centimetres3/ minute~50 centimetres3/ minute, the content of oxygen For the total amount of process gas 1%~2%.
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CN104485280A (en) * 2014-12-31 2015-04-01 上海华虹宏力半导体制造有限公司 Method for manufacturing grid electrode

Citations (3)

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CN1263357A (en) * 1998-12-28 2000-08-16 因芬尼昂技术北美公司 Semiconductor device and its production method
CN1571144A (en) * 2003-07-15 2005-01-26 旺宏电子股份有限公司 Self-alignment process for flash memory
CN102074466A (en) * 2009-11-20 2011-05-25 中芯国际集成电路制造(上海)有限公司 Grid manufacturing method

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TW465061B (en) * 2000-11-16 2001-11-21 Promos Technologies Inc Method for avoiding protrusion on the gate side wall of metal silicide layer
KR100435805B1 (en) * 2002-08-14 2004-06-10 삼성전자주식회사 Method of fabricating MOS transistors
WO2012109572A1 (en) * 2011-02-11 2012-08-16 Brookhaven Science Associates, Llc Technique for etching monolayer and multilayer materials

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1263357A (en) * 1998-12-28 2000-08-16 因芬尼昂技术北美公司 Semiconductor device and its production method
CN1571144A (en) * 2003-07-15 2005-01-26 旺宏电子股份有限公司 Self-alignment process for flash memory
CN102074466A (en) * 2009-11-20 2011-05-25 中芯国际集成电路制造(上海)有限公司 Grid manufacturing method

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