One is high magnesium solidifying agent and using method for cold fixed ball press technique
Technical field
The present invention relates to ferrous metallurgy field, particularly a kind of high magnesium solidifying agent and using method for cold fixed ball press technique.
Background technology
In metallurgical industry production process, can produce a large amount of flue dust, mud, iron scale and other powdery regenerants, the iron-holder of these powdery regenerants up to 45% and more than, utilize cold-consolidation pellet process to process these pulverulent materials, have that technique is simple, a less investment, instant effect, the saving energy, low cost and other advantages.3.5 hundred million tons of China's iron and steel annual production according to statistics, the iron content secondary iron-containing resource of association approximately produces more than ten million ton every year, generally adopt wilkinite, water glass, cement as binding agent, mostly have the problem that green-ball Pulverization ratio is high, rate of drying is slow, intensity is low, ferrous grade reduces.
200510026046.1 disclose a kind of adhesive for fast consolidation of cold solidified pellet, and its component comprises calcium oxide, silicon-dioxide, magnesium oxide, aluminium sesquioxide, ferric oxide and manganese oxide.Its solidifying agent is applied in the cold fixed ball press technique that ion dust mud contaning or ion dust mud contaning contain.But this binding agent is smelted for metallurgical, has certain material limitation, is not suitable for the cold fixed ball press technique of the poor material of the macrobeads such as iron scale or agglutinating value(of coal).
200610031958.2 disclose a kind of adhesive for fast consolidation of cold solidified pellet, and its component comprises magnesium chloride, calcium chloride, iron(ic) chloride, sodium-chlor, ammonium chloride.The 1.5-2.0% for raw material gross weight with addition of amount of binding agent.But this binding agent is under the metallurgical smelting process condition of high temperature, chlorion enters flue gas, pipeline and fume treatment auxiliary is worked the mischief, and use this binding agent, and chlorion enters in atmosphere with flue gas, also can increase the generation of toxicant dioxin.
Summary of the invention
The object of the invention be to provide a kind of use range more extensively, cost is lower and meet solidifying agent and the using method of the cold consolidation technique service requirements of metallurgy powder, and solves the chloride difficult problem of cold fixed pressure ball solidifying agent.
Realize a kind of high magnesium solidifying agent for cold fixed ball press technique of the object of the invention, comprise magnesium oxide, calcium oxide, magnesium sulfate, silicon-dioxide, aluminium sesquioxide and sulphur, in mass parts, each component concentration is as follows:
A kind of high magnesium solidifying agent, in mass parts, each component concentration is as follows:
A kind of high magnesium solidifying agent, in mass parts, each component concentration is as follows:
A kind of high magnesium solidifying agent, in mass parts, each component concentration is as follows:
A kind of high magnesium solidifying agent, in mass parts, each component concentration is as follows:
Magnesium oxide 21.6
Calcium oxide 0.8
Magnesium sulfate 36.9
Silicon-dioxide 0.3
The using method of above-mentioned arbitrary high magnesium solidifying agent, the amount of allocating into of described high magnesium solidifying agent is the 2-6wt% of material total mass.
After described material and described high magnesium solidifying agent mix, control the moisture of mixture lower than 10wt%.
Described material is ion dust mud contaning and iron scale, and wherein said iron scale pulverizing and jevigating is less than 5mm to granularity, and the mass ratio of ion dust mud contaning and iron scale is 1 or is greater than 1.
This novel solidifying agent consolidation strength is up to 1000-2000N.Be not only applicable to all kinds of ion dust mud contaning materials, be also applicable to the poor metallurgy powder of iron scale class macrobead or agglutinating value(of coal); And can solve chloride solidifying agent and bring the pollution problem of dioxin.And this solidifying agent raw material drawing is extensive, cheap, can large-scale production and application.
Embodiment
For better explanation the present invention, below the technical scheme in the embodiment of the present invention is clearly and completely described.
Embodiment 1
(1) become granularity to be less than the powder of 5mm iron scale crushing grinding;
(2) prepare novel solidifying agent, meter is got MgO content 37.9kg, CaO content 1.4kg, MgSO4 content 20kg, SiO2 content 0.4kg, Al2O3 content 0.1kg;
(3) under normal temperature and pressure conditions, solidifying agent by outer dosage 2Wt% join iron containing sludge and iron scale (proportioning 1:1) in, material is mixed, guarantee that mixture moisture is 5-10%;
(4) by conveyor, will mix material and be delivered to ball press feed bin, pressure ball is transported to smelting furnace after balling-up after stacking 12-24h under finished ball normal temperature and pressure, uses.
Embodiment 2
(1) become granularity to be less than the powder of 5mm iron scale crushing grinding;
(2) prepare novel solidifying agent, meter is got MgO content 42.1kg, CaO content 1.6kg, MgSO4 content 44.4kg, SiO2 content 0.4kg, Al2O3 content 0.1kg;
(3) under normal temperature and pressure conditions, solidifying agent joins in iron containing sludge and iron scale (proportioning 1:1) by outer dosage 2-2.5Wt%, and material is mixed, and guarantees that mixture moisture is 6-10%;
(4) by conveyor, will mix material and be delivered to ball press feed bin, pressure ball is transported to smelting furnace after balling-up after stacking 12-24h under finished ball normal temperature and pressure, uses.
Embodiment 3
(1) become granularity to be less than the powder of 5mm iron scale crushing grinding;
(2) prepare novel solidifying agent, meter is got MgO content 37.9kg, CaO content 1.4kg, MgSO4 content 36.9kg, SiO2 content 0.4kg, Al2O3 content 0.1kg;
(3) under normal temperature and pressure conditions, solidifying agent by outer dosage 6Wt% join iron containing sludge and iron scale (proportioning 1:1) in, material is mixed, guarantee mixture moisture < 5%;
(4) by conveyor, will mix material and be delivered to ball press feed bin, pressure ball is transported to smelting furnace after balling-up after stacking 12-24h under finished ball normal temperature and pressure, uses.
Case study on implementation 4
(1) become granularity to be less than the powder of 5mm iron scale crushing grinding;
(2) prepare novel solidifying agent, meter is got MgO content 21.6kg, CaO content 0.8kg, MgSO4 content 36.9kg, SiO2 content 0.3kg;
(3) under normal temperature and pressure conditions, by outer dosage 3-4Wt% join iron containing sludge and iron scale (proportioning 1:1) in, material is mixed, guarantee mixture moisture < 5%;
(4) by conveyor, will mix material and be delivered to ball press feed bin, pressure ball is transported to smelting furnace after balling-up after stacking 12-24h under finished ball normal temperature and pressure, uses.
The beneficial effect that technical solution of the present invention is brought: this novel solidifying agent consolidation strength is up to 1000-2000N.Applied widely, be not only applicable to all kinds of ion dust mud contaning materials, be also applicable in the poor metallurgy powder of iron scale class macrobead or agglutinating value(of coal); And can solve chloride solidifying agent and bring the pollution problem of dioxin, and this solidifying agent raw material drawing is extensive, cheap.
The above; only for preferably embodiment of the present invention, but protection scope of the present invention is not limited to this, is anyly familiar with in technical scope that those skilled in the art disclose in the present invention; the variation that can expect easily or replacement, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claims.