CN103725873A - High-magnesium concretion agent for cold concretion ball pressing process and use method of high-magnesium concretion agent - Google Patents

High-magnesium concretion agent for cold concretion ball pressing process and use method of high-magnesium concretion agent Download PDF

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Publication number
CN103725873A
CN103725873A CN201310656635.2A CN201310656635A CN103725873A CN 103725873 A CN103725873 A CN 103725873A CN 201310656635 A CN201310656635 A CN 201310656635A CN 103725873 A CN103725873 A CN 103725873A
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magnesium
concretion
agent
solidifying agent
percent
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CN103725873B (en
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吴道洪
李胜利
王敬慧
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Shenwu Technology Group Corp Co Ltd
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Beijing Shenwu Environmental and Energy Technology Co Ltd
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  • Treatment Of Sludge (AREA)
  • Manufacture And Refinement Of Metals (AREA)

Abstract

The invention provides a high-magnesium concretion agent for a cold concretion ball pressing process. The high-magnesium concretion agent comprises the following ingredients by weight: 15 to 45 percent of magnesium oxide, 0.5 to 2 percent of calcium oxide, 15 to 45 percent of magnesium sulphate, 0 to 1 percent of silicon dioxide, 0 to 0.1 percent of aluminum oxide, and sulphur; the feeding quantity of the high-magnesium concretion agent is 2 to 6 percent of the total weight of a material. The concretion strength of the novel high-magnesium concretion agent is up to 1000 to 2000 N, so that the high-magnesium concretion agent is suitable for not only various materials containing iron, dust and mud, but also large particles of oxide scale or metallurgical powder of poor cohesiveness; dioxine pollution caused by a chlorine-containing concretion agent can be prevented; the raw materials of the high-magnesium concretion agent are highly available and low in price, so that the cost can be reduced.

Description

One is high magnesium solidifying agent and using method for cold fixed ball press technique
Technical field
The present invention relates to ferrous metallurgy field, particularly a kind of high magnesium solidifying agent and using method for cold fixed ball press technique.
Background technology
In metallurgical industry production process, can produce a large amount of flue dust, mud, iron scale and other powdery regenerants, the iron-holder of these powdery regenerants up to 45% and more than, utilize cold-consolidation pellet process to process these pulverulent materials, have that technique is simple, a less investment, instant effect, the saving energy, low cost and other advantages.3.5 hundred million tons of China's iron and steel annual production according to statistics, the iron content secondary iron-containing resource of association approximately produces more than ten million ton every year, generally adopt wilkinite, water glass, cement as binding agent, mostly have the problem that green-ball Pulverization ratio is high, rate of drying is slow, intensity is low, ferrous grade reduces.
200510026046.1 disclose a kind of adhesive for fast consolidation of cold solidified pellet, and its component comprises calcium oxide, silicon-dioxide, magnesium oxide, aluminium sesquioxide, ferric oxide and manganese oxide.Its solidifying agent is applied in the cold fixed ball press technique that ion dust mud contaning or ion dust mud contaning contain.But this binding agent is smelted for metallurgical, has certain material limitation, is not suitable for the cold fixed ball press technique of the poor material of the macrobeads such as iron scale or agglutinating value(of coal).
200610031958.2 disclose a kind of adhesive for fast consolidation of cold solidified pellet, and its component comprises magnesium chloride, calcium chloride, iron(ic) chloride, sodium-chlor, ammonium chloride.The 1.5-2.0% for raw material gross weight with addition of amount of binding agent.But this binding agent is under the metallurgical smelting process condition of high temperature, chlorion enters flue gas, pipeline and fume treatment auxiliary is worked the mischief, and use this binding agent, and chlorion enters in atmosphere with flue gas, also can increase the generation of toxicant dioxin.
Summary of the invention
The object of the invention be to provide a kind of use range more extensively, cost is lower and meet solidifying agent and the using method of the cold consolidation technique service requirements of metallurgy powder, and solves the chloride difficult problem of cold fixed pressure ball solidifying agent.
Realize a kind of high magnesium solidifying agent for cold fixed ball press technique of the object of the invention, comprise magnesium oxide, calcium oxide, magnesium sulfate, silicon-dioxide, aluminium sesquioxide and sulphur, in mass parts, each component concentration is as follows:
Figure BDA0000432259730000021
A kind of high magnesium solidifying agent, in mass parts, each component concentration is as follows:
Figure BDA0000432259730000022
A kind of high magnesium solidifying agent, in mass parts, each component concentration is as follows:
Figure BDA0000432259730000023
A kind of high magnesium solidifying agent, in mass parts, each component concentration is as follows:
Figure BDA0000432259730000024
A kind of high magnesium solidifying agent, in mass parts, each component concentration is as follows:
Magnesium oxide 21.6
Calcium oxide 0.8
Magnesium sulfate 36.9
Silicon-dioxide 0.3
The using method of above-mentioned arbitrary high magnesium solidifying agent, the amount of allocating into of described high magnesium solidifying agent is the 2-6wt% of material total mass.
After described material and described high magnesium solidifying agent mix, control the moisture of mixture lower than 10wt%.
Described material is ion dust mud contaning and iron scale, and wherein said iron scale pulverizing and jevigating is less than 5mm to granularity, and the mass ratio of ion dust mud contaning and iron scale is 1 or is greater than 1.
This novel solidifying agent consolidation strength is up to 1000-2000N.Be not only applicable to all kinds of ion dust mud contaning materials, be also applicable to the poor metallurgy powder of iron scale class macrobead or agglutinating value(of coal); And can solve chloride solidifying agent and bring the pollution problem of dioxin.And this solidifying agent raw material drawing is extensive, cheap, can large-scale production and application.
Embodiment
For better explanation the present invention, below the technical scheme in the embodiment of the present invention is clearly and completely described.
Embodiment 1
(1) become granularity to be less than the powder of 5mm iron scale crushing grinding;
(2) prepare novel solidifying agent, meter is got MgO content 37.9kg, CaO content 1.4kg, MgSO4 content 20kg, SiO2 content 0.4kg, Al2O3 content 0.1kg;
(3) under normal temperature and pressure conditions, solidifying agent by outer dosage 2Wt% join iron containing sludge and iron scale (proportioning 1:1) in, material is mixed, guarantee that mixture moisture is 5-10%;
(4) by conveyor, will mix material and be delivered to ball press feed bin, pressure ball is transported to smelting furnace after balling-up after stacking 12-24h under finished ball normal temperature and pressure, uses.
Embodiment 2
(1) become granularity to be less than the powder of 5mm iron scale crushing grinding;
(2) prepare novel solidifying agent, meter is got MgO content 42.1kg, CaO content 1.6kg, MgSO4 content 44.4kg, SiO2 content 0.4kg, Al2O3 content 0.1kg;
(3) under normal temperature and pressure conditions, solidifying agent joins in iron containing sludge and iron scale (proportioning 1:1) by outer dosage 2-2.5Wt%, and material is mixed, and guarantees that mixture moisture is 6-10%;
(4) by conveyor, will mix material and be delivered to ball press feed bin, pressure ball is transported to smelting furnace after balling-up after stacking 12-24h under finished ball normal temperature and pressure, uses.
Embodiment 3
(1) become granularity to be less than the powder of 5mm iron scale crushing grinding;
(2) prepare novel solidifying agent, meter is got MgO content 37.9kg, CaO content 1.4kg, MgSO4 content 36.9kg, SiO2 content 0.4kg, Al2O3 content 0.1kg;
(3) under normal temperature and pressure conditions, solidifying agent by outer dosage 6Wt% join iron containing sludge and iron scale (proportioning 1:1) in, material is mixed, guarantee mixture moisture < 5%;
(4) by conveyor, will mix material and be delivered to ball press feed bin, pressure ball is transported to smelting furnace after balling-up after stacking 12-24h under finished ball normal temperature and pressure, uses.
Case study on implementation 4
(1) become granularity to be less than the powder of 5mm iron scale crushing grinding;
(2) prepare novel solidifying agent, meter is got MgO content 21.6kg, CaO content 0.8kg, MgSO4 content 36.9kg, SiO2 content 0.3kg;
(3) under normal temperature and pressure conditions, by outer dosage 3-4Wt% join iron containing sludge and iron scale (proportioning 1:1) in, material is mixed, guarantee mixture moisture < 5%;
(4) by conveyor, will mix material and be delivered to ball press feed bin, pressure ball is transported to smelting furnace after balling-up after stacking 12-24h under finished ball normal temperature and pressure, uses.
The beneficial effect that technical solution of the present invention is brought: this novel solidifying agent consolidation strength is up to 1000-2000N.Applied widely, be not only applicable to all kinds of ion dust mud contaning materials, be also applicable in the poor metallurgy powder of iron scale class macrobead or agglutinating value(of coal); And can solve chloride solidifying agent and bring the pollution problem of dioxin, and this solidifying agent raw material drawing is extensive, cheap.
The above; only for preferably embodiment of the present invention, but protection scope of the present invention is not limited to this, is anyly familiar with in technical scope that those skilled in the art disclose in the present invention; the variation that can expect easily or replacement, within all should being encompassed in protection scope of the present invention.Therefore, protection scope of the present invention should be as the criterion with the protection domain of claims.

Claims (8)

1. a high magnesium solidifying agent for cold fixed ball press technique, is characterized in that, comprises magnesium oxide, calcium oxide, magnesium sulfate, silicon-dioxide, aluminium sesquioxide and sulphur, and in mass parts, each component concentration is as follows:
Figure FDA0000432259720000011
2. high magnesium solidifying agent for knot ball press technique according to claim 1, is characterized in that, in mass parts, each component concentration is as follows:
Figure FDA0000432259720000012
3. high magnesium solidifying agent for knot ball press technique according to claim 1, is characterized in that, in mass parts, each component concentration is as follows:
Figure FDA0000432259720000013
4. high magnesium solidifying agent for knot ball press technique according to claim 1, is characterized in that, in mass parts, each component concentration is as follows:
Figure FDA0000432259720000014
Figure FDA0000432259720000021
5. high magnesium solidifying agent for knot ball press technique according to claim 1, is characterized in that, in mass parts, each component concentration is as follows:
Magnesium oxide 21.6
Calcium oxide 0.8
Magnesium sulfate 36.9
Silicon-dioxide 0.3.
6. the using method of high magnesium solidifying agent for the knot ball press technique described in claim 1-5 any one, is characterized in that, the amount of allocating into of described high magnesium solidifying agent is the 2-6wt% of material total mass.
7. using method according to claim 6, is characterized in that, after described material and described high magnesium solidifying agent mix, controls the moisture of mixture lower than 10wt%.
8. using method according to claim 6, is characterized in that, described material is ion dust mud contaning and iron scale, and wherein said iron scale pulverizing and jevigating is less than 5mm to granularity, and the mass ratio of ion dust mud contaning and iron scale is 1 or is greater than 1.
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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112080633A (en) * 2020-10-09 2020-12-15 河南钰镁新材料科技有限公司 Non-bentonite alkaline pellet and preparation method thereof
CN112080634A (en) * 2020-10-09 2020-12-15 河南钰镁新材料科技有限公司 Acidic pellet binder and preparation method thereof
CN112126782A (en) * 2020-10-09 2020-12-25 河南钰镁新材料科技有限公司 Binder for alkaline pellet mine and preparation method thereof
CN112176181A (en) * 2020-10-09 2021-01-05 河南钰镁新材料科技有限公司 Bentonite-free acidic pellet and preparation method thereof

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CN1737170A (en) * 2005-09-06 2006-02-22 季建梅 Iron concentrate pelletization binder of calcium magnesium reaction type
CN101270410A (en) * 2007-03-20 2008-09-24 尚国洪 Cold bonded pellet and method of producing the same
CN101525689A (en) * 2009-03-27 2009-09-09 莱芜钢铁股份有限公司 Method for preparing carbonaceous autoreduction cold pressing block and application thereof
CN102061359A (en) * 2004-11-17 2011-05-18 Ism有限公司 A slag conditioner composition, process for manufacture and method of use in steel production
CN102268543A (en) * 2011-08-30 2011-12-07 北京科技大学 Shaping adhesive for chromium powder ore cold-pressed pellets and using method of shaping adhesive

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CN102061359A (en) * 2004-11-17 2011-05-18 Ism有限公司 A slag conditioner composition, process for manufacture and method of use in steel production
CN1737170A (en) * 2005-09-06 2006-02-22 季建梅 Iron concentrate pelletization binder of calcium magnesium reaction type
CN101270410A (en) * 2007-03-20 2008-09-24 尚国洪 Cold bonded pellet and method of producing the same
CN101525689A (en) * 2009-03-27 2009-09-09 莱芜钢铁股份有限公司 Method for preparing carbonaceous autoreduction cold pressing block and application thereof
CN102268543A (en) * 2011-08-30 2011-12-07 北京科技大学 Shaping adhesive for chromium powder ore cold-pressed pellets and using method of shaping adhesive

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Title
西安建筑科技大学等编: "《建筑材料》", 31 October 2003 *

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112080633A (en) * 2020-10-09 2020-12-15 河南钰镁新材料科技有限公司 Non-bentonite alkaline pellet and preparation method thereof
CN112080634A (en) * 2020-10-09 2020-12-15 河南钰镁新材料科技有限公司 Acidic pellet binder and preparation method thereof
CN112126782A (en) * 2020-10-09 2020-12-25 河南钰镁新材料科技有限公司 Binder for alkaline pellet mine and preparation method thereof
CN112176181A (en) * 2020-10-09 2021-01-05 河南钰镁新材料科技有限公司 Bentonite-free acidic pellet and preparation method thereof

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