CN103724767A - Anti-aging fishing net - Google Patents

Anti-aging fishing net Download PDF

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Publication number
CN103724767A
CN103724767A CN201310669728.9A CN201310669728A CN103724767A CN 103724767 A CN103724767 A CN 103724767A CN 201310669728 A CN201310669728 A CN 201310669728A CN 103724767 A CN103724767 A CN 103724767A
Authority
CN
China
Prior art keywords
fishing net
aging
raw material
softening agent
parts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310669728.9A
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Chinese (zh)
Inventor
凌必双
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
CHAOHU RUI QIANG FISHING GEAR Co Ltd
Original Assignee
CHAOHU RUI QIANG FISHING GEAR Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by CHAOHU RUI QIANG FISHING GEAR Co Ltd filed Critical CHAOHU RUI QIANG FISHING GEAR Co Ltd
Priority to CN201310669728.9A priority Critical patent/CN103724767A/en
Publication of CN103724767A publication Critical patent/CN103724767A/en
Pending legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/04—Homopolymers or copolymers of ethene
    • C08L23/06—Polyethene
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/10—Other agents for modifying properties
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/08—Stabilised against heat, light or radiation or oxydation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00—Applications
    • C08L2203/12—Applications used for fibers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/068—Ultra high molecular weight polyethylene

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention discloses an anti-aging fishing net. The anti-aging fishing net comprises the following raw materials in parts by weight: 97-100 parts of UHMWPE, 3-4 parts of EVA resin, 0.1-0.2 part of N-cyclohexyl-N'-phenyl p-phenylenediamine, 1-2 parts of tetrachloroisophthalonitrile, 3-4 parts of cis-1, 4-polyisoprene rubber, 0.2-0.4 part of 2-mercapto benzimidazole, and 3-4 parts of a modified plasticizer; according to the anti-aging fishing net provided by the invention, the N-cyclohexyl-N'-phenyl p-phenylenediamine and the 2-mercapto benzimidazole are adopted so as to improve the anti-aging function and the thermostability of the fishing net.

Description

A kind of anti-aging fishing net
Technical field
The present invention relates generally to a kind of fishing net, relates in particular to a kind of anti-aging fishing net.
Background technology
Modern fishing net mainly adopts polyethylene, the raw materials such as nylon are processed, polythene fishing net wherein, to adopt polythene material through fusion plastification, spinning, plying is twisted thread and is made into, use Yu Haiyang trawlnet, purse seine, wind resistance sea net cage etc., there is longer life cycle, higher catching rate, but the mechanical property of polyethylene itself is general, tensile strength is lower, creep resistance is bad, the intensity that just causes conventional polyethylene fishing net, wear resisting property, at the bottom of toughness is unwell to Complex Sea and wind and waves environment fishing operation, reduced the work-ing life of fishing gear, not only waste resource, also directly affect catch.
Summary of the invention
The object of the invention is just to provide a kind of anti-aging fishing net.
The present invention is achieved by the following technical solutions:
An anti-aging fishing net, it is comprised of the raw material of following weight parts:
Ultrahigh molecular weight polyethylene(UHMWPE) 97-100, EVA resin 3-4, N cyclohexyl N' phenyl P phenylene diamine 0.1-0.2, termil 1-2, cis Isosorbide-5-Nitrae-polyisoprene rubber 3-4,2-mercaptobenzimidazole 0.2-0.4, modification softening agent 3-4;
Described modification softening agent is comprised of the raw material of following weight parts: Union carbide A-162 1-1.2, dioctyl ester 2-2.3, tributyl citrate 1.2-1.4, peanut oil 2-2.3, turps 1-1.2, Oil of Eucalyptus 0.3-0.4, poly-different diene 1.2-1.4, morpholine 0.2-0.3, antioxidant MB 1-1.2, methylethyl ketone peroxide 0.2-0.3, vinylbenzene 1.2-1.4, nano titanium oxide 0.2-0.3;
Above-mentioned methylethyl ketone peroxide is added drop-wise in other each mixtures of materials, and stirring reaction 60-90 minute, is warming up to 120-130 ℃, and stirring reaction 2-3 hour obtains described modification softening agent.
A preparation method for anti-aging fishing net, comprises the following steps:
Get above-mentioned EVA resin and cis 1,4-polyisoprene rubber mixes, at 80-100 ℃, mix 6-10 minute, reduction temperature is 60-70 ℃, adds termil, after fully mixing, is cooled to normal temperature, add each raw material of residue, by forcing machine, melt extrude, drawing-off, sizing, spinning, obtain described anti-aging fishing net.
Advantage of the present invention is:
The fishing net that the present invention produces, by N cyclohexyl N' phenyl P phenylene diamine and 2-mercaptobenzimidazole, has improved the ageing resistance of fishing net, has strengthened thermostability.
Embodiment
Embodiment 1
An anti-aging fishing net, it is characterized in that it by following weight parts (kilogram) raw material form:
Ultrahigh molecular weight polyethylene(UHMWPE) 100, EVA resin 4, N cyclohexyl N' phenyl P phenylene diamine 0.2, termil 1, cis Isosorbide-5-Nitrae-polyisoprene rubber 4,2-mercaptobenzimidazole 0.4, modification softening agent 3;
Described modification softening agent is comprised of the raw material of following weight parts: Union carbide A-162 1.2, dioctyl ester 2.3, tributyl citrate 1.4, peanut oil 2.3, turps 1.2, Oil of Eucalyptus 0.4, poly-different diene 1.4, morpholine 0.3, antioxidant MB 1.2, methylethyl ketone peroxide 0.3, vinylbenzene 1.4, nano titanium oxide 0.3;
Above-mentioned methylethyl ketone peroxide is added drop-wise in other each mixtures of materials, and stirring reaction 90 minutes, is warming up to 130 ℃, and stirring reaction 3 hours obtains described modification softening agent.
A preparation method for anti-aging fishing net, comprises the following steps:
Get above-mentioned EVA resin and cis 1,4-polyisoprene rubber mixes, at 100 ℃, mix 10 minutes, reducing temperature is 60 ℃, adds termil, after fully mixing, is cooled to normal temperature, add each raw material of residue, by forcing machine, melt extrude, drawing-off, sizing, spinning, obtain described anti-aging fishing net.
Filament properties test: elongation at break 16.4%;
Anti-tensile degree (KG) 55.5;
Knotting strength (KG) 38.36.

Claims (2)

1. an anti-aging fishing net, is characterized in that what it was comprised of the raw material of following weight parts:
Ultrahigh molecular weight polyethylene(UHMWPE) 97-100, EVA resin 3-4, N cyclohexyl N' phenyl P phenylene diamine 0.1-0.2, termil 1-2, cis Isosorbide-5-Nitrae-polyisoprene rubber 3-4,2-mercaptobenzimidazole 0.2-0.4, modification softening agent 3-4;
Described modification softening agent is comprised of the raw material of following weight parts: Union carbide A-162 1-1.2, dioctyl ester 2-2.3, tributyl citrate 1.2-1.4, peanut oil 2-2.3, turps 1-1.2, Oil of Eucalyptus 0.3-0.4, poly-different diene 1.2-1.4, morpholine 0.2-0.3, antioxidant MB 1-1.2, methylethyl ketone peroxide 0.2-0.3, vinylbenzene 1.2-1.4, nano titanium oxide 0.2-0.3;
Above-mentioned methylethyl ketone peroxide is added drop-wise in other each mixtures of materials, and stirring reaction 60-90 minute, is warming up to 120-130 ℃, and stirring reaction 2-3 hour obtains described modification softening agent.
2. a preparation method for anti-aging fishing net as claimed in claim 1, is characterized in that comprising the following steps:
Get above-mentioned EVA resin and cis 1,4-polyisoprene rubber mixes, at 80-100 ℃, mix 6-10 minute, reduction temperature is 60-70 ℃, adds termil, after fully mixing, is cooled to normal temperature, add each raw material of residue, by forcing machine, melt extrude, drawing-off, sizing, spinning, obtain described anti-aging fishing net.
CN201310669728.9A 2013-12-11 2013-12-11 Anti-aging fishing net Pending CN103724767A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310669728.9A CN103724767A (en) 2013-12-11 2013-12-11 Anti-aging fishing net

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310669728.9A CN103724767A (en) 2013-12-11 2013-12-11 Anti-aging fishing net

Publications (1)

Publication Number Publication Date
CN103724767A true CN103724767A (en) 2014-04-16

Family

ID=50449081

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201310669728.9A Pending CN103724767A (en) 2013-12-11 2013-12-11 Anti-aging fishing net

Country Status (1)

Country Link
CN (1) CN103724767A (en)

Cited By (17)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104782593A (en) * 2015-03-26 2015-07-22 巢湖市鼎盛渔具有限公司 Wear-resisting and aging-resisting fishing net
CN104805530A (en) * 2015-03-26 2015-07-29 巢湖市鼎盛渔具有限公司 Fishing net with fish inducing and heat resisting functions
CN105295169A (en) * 2015-10-29 2016-02-03 六安市沪渔网具有限公司 Sunshine resistant fishing net
CN105385099A (en) * 2015-11-13 2016-03-09 巢湖市强力渔业有限责任公司 Fishing net having low pollution
CN105386157A (en) * 2015-11-14 2016-03-09 巢湖市荷花渔网有限公司 Anti-ageing fishing net
CN105385075A (en) * 2015-10-23 2016-03-09 巢湖市荷花渔网有限公司 Fishing net with anti-corrosion property
CN105400148A (en) * 2015-11-14 2016-03-16 巢湖市荷花渔网有限公司 Antifouling fishing net
CN105483859A (en) * 2015-12-18 2016-04-13 巢湖市天宇渔具有限公司 Anti-freezing fishing net
CN105754190A (en) * 2016-04-14 2016-07-13 巢湖市荷花渔网有限公司 Anticorrosion antiaging fishing net
CN105754265A (en) * 2016-04-14 2016-07-13 巢湖市荷花渔网有限公司 Anti-alga long-life fishing net
CN105780186A (en) * 2016-04-05 2016-07-20 巢湖市俊业渔具有限公司 Anti-corrosion anti-aging fishing net
CN105802087A (en) * 2016-04-14 2016-07-27 巢湖市荷花渔网有限公司 Algae-preventing fishing net
CN105820420A (en) * 2016-05-04 2016-08-03 巢湖市强力渔业有限责任公司 Fish net prepared from surface-modified HDPE resin
CN107237000A (en) * 2017-07-17 2017-10-10 巢湖市渔郎渔具有限公司 A kind of processing technology of high-strength fishing netting twine
CN107893265A (en) * 2017-12-08 2018-04-10 巢湖市荷花渔网有限公司 A kind of antifouling high intensity fishing net of softness
CN108998855A (en) * 2018-07-02 2018-12-14 巢湖市天宇渔具有限公司 A kind of preparation method for luring type fishing lines
CN115478340A (en) * 2022-10-21 2022-12-16 济宁巨鲲新材料科技有限公司 High-strength anti-aging fishing line and preparation method thereof

Cited By (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104805530A (en) * 2015-03-26 2015-07-29 巢湖市鼎盛渔具有限公司 Fishing net with fish inducing and heat resisting functions
CN104782593A (en) * 2015-03-26 2015-07-22 巢湖市鼎盛渔具有限公司 Wear-resisting and aging-resisting fishing net
CN105385075A (en) * 2015-10-23 2016-03-09 巢湖市荷花渔网有限公司 Fishing net with anti-corrosion property
CN105295169A (en) * 2015-10-29 2016-02-03 六安市沪渔网具有限公司 Sunshine resistant fishing net
CN105385099A (en) * 2015-11-13 2016-03-09 巢湖市强力渔业有限责任公司 Fishing net having low pollution
CN105385099B (en) * 2015-11-13 2018-07-10 巢湖市强力渔业有限责任公司 A kind of fishing net with low stain
CN105386157A (en) * 2015-11-14 2016-03-09 巢湖市荷花渔网有限公司 Anti-ageing fishing net
CN105400148A (en) * 2015-11-14 2016-03-16 巢湖市荷花渔网有限公司 Antifouling fishing net
CN105483859A (en) * 2015-12-18 2016-04-13 巢湖市天宇渔具有限公司 Anti-freezing fishing net
CN105780186A (en) * 2016-04-05 2016-07-20 巢湖市俊业渔具有限公司 Anti-corrosion anti-aging fishing net
CN105754190A (en) * 2016-04-14 2016-07-13 巢湖市荷花渔网有限公司 Anticorrosion antiaging fishing net
CN105802087A (en) * 2016-04-14 2016-07-27 巢湖市荷花渔网有限公司 Algae-preventing fishing net
CN105754265A (en) * 2016-04-14 2016-07-13 巢湖市荷花渔网有限公司 Anti-alga long-life fishing net
CN105820420A (en) * 2016-05-04 2016-08-03 巢湖市强力渔业有限责任公司 Fish net prepared from surface-modified HDPE resin
CN107237000A (en) * 2017-07-17 2017-10-10 巢湖市渔郎渔具有限公司 A kind of processing technology of high-strength fishing netting twine
CN107893265A (en) * 2017-12-08 2018-04-10 巢湖市荷花渔网有限公司 A kind of antifouling high intensity fishing net of softness
CN108998855A (en) * 2018-07-02 2018-12-14 巢湖市天宇渔具有限公司 A kind of preparation method for luring type fishing lines
CN115478340A (en) * 2022-10-21 2022-12-16 济宁巨鲲新材料科技有限公司 High-strength anti-aging fishing line and preparation method thereof

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WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20140416

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