CN103724514B - A kind of preparation method of vinyl modified polyvinyl alcohol - Google Patents
A kind of preparation method of vinyl modified polyvinyl alcohol Download PDFInfo
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Abstract
A kind of preparation method of vinyl modified polyvinyl alcohol, it is for raw material with 82 ~ 88 parts, water, reductive agent 0.02 ~ 0.08 part, emulsifying agent 0.2 ~ 0.6 part, Vinyl Acetate Monomer 10 ~ 40 parts, 0.045 ~ 0.065 part, oxygenant and vinyl monomer, displacement in initial charge, still, polyreaction, breakdown of emulsion purification and saponification step obtain vinyl modified polyvinyl alcohol, wherein the consumption of vinyl monomer is the still internal pressure controlled when passing into vinyl monomer is 3 ~ 20bar, passes into the vinyl monomer consumption that the reaction times is 3.5 ~ 4.5 hours meters; Described emulsifying agent is reactive sulfonate.Be applied in letex polymerization using obtained ethylene modified polyvinyl alcohol as reagent and additive in polymerization, its water tolerance significantly improves; Good water solubility, can meet its service requirements as reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
Description
Technical field
The present invention relates to a kind of preparation method of the reagent and additive in polymerization be applied in the letex polymerization such as vinyl acetate between to for plastic, VAE, particularly relate to a kind of preparation method of modified polyvinyl alcohol.
Background technology
Polyvinyl alcohol (PVA) is a kind of letex polymerization auxiliary agent of important, excellent performance, is applied in the letex polymerization of vinyl acetate between to for plastic, VAE etc. usually used as protective colloid.The general PVA using partial alcoholysis in common technical recipe, if but require that emulsion has good water tolerance, just should not use the PVA of partial alcoholysis, because the PVA of partial alcoholysis itself does not have water tolerance.In order to improve water tolerance, just require the PVA using full alcoholysis, but the surface tension of the complete alcoholysis type PVA aqueous solution is high, is difficult to obtain stable letex polymerization.
Summary of the invention
The object of the present invention is to provide a kind of water-tolerant, for the good vinyl modified polyvinyl alcohol of stability of emulsion polymerization.
The object of the invention is to be achieved through the following technical solutions:
A kind of preparation method of vinyl modified polyvinyl alcohol, it is characterized in that: it is for raw material with 82 ~ 88 parts, water, reductive agent 0.02 ~ 0.08 part, emulsifying agent 0.2 ~ 0.6 part, Vinyl Acetate Monomer 10 ~ 40 parts, 0.045 ~ 0.065 part, oxygenant and vinyl monomer, displacement in initial charge, still, polyreaction, breakdown of emulsion purification and saponification step obtain vinyl modified polyvinyl alcohol, wherein the consumption of vinyl monomer is the still internal pressure controlled when passing into vinyl monomer is 3 ~ 20bar, passes into the vinyl monomer consumption that the reaction times is 3.5 ~ 4.5 hours meters; Described emulsifying agent is reactive sulfonate.
The water tolerance of the modified polyvinyl alcohol that above-mentioned preparation method obtains, good water solubility, use the excellent in stability of polymerization system simultaneously as reagent and additive in polymerization using obtained modified polyvinyl alcohol.Contriver finds in long-term R & D process, if the usage ratio of above each reaction raw materials controls bad, although the water tolerance of modification PVOH can be improved and increase the stability of polymerization system as during reagent and additive in polymerization, easily greatly reduce that it is water-soluble thus limit the application that it can be used as reagent and additive in polymerization in polymerization system.
Mentioned emulsifier is reactive sulfonate, and reactive sulfonate is clearly to this area, and reactive sulfonate refers to the alkylsulfonate (all can buy) having carbon-carbon double bond or other side chains and have reaction active groups; In a word, reactive sulfonate refers to the sulfonate that reactive behavior is higher.The reactive sulfonate of the present invention is preferably alkyl vinylformic acid-2-ethanesulfonic acid sodium, vinyl alkyl sulfonate, 2.2-acrylamide-2.2-dimethyl ethyl sulfonic acid sodium, sodium p styrene sulfonate or maleic acid higher alcohols monoesters sodium, be more preferably vinyl sulfonic acid an alkali metal salt, most preferably be sodium vinyl sulfonate or vinyl sulfonic acid potassium.
Above-mentioned initiator (oxygenant, reductive agent) is ammonium persulphate/sodium bisulfite, Potassium Persulphate/sodium bisulfite, hydrogen peroxide/tartrate, hydrogen peroxide/rongalite, ammonium persulphate/ferrous sulfate, hydrogen peroxide/sulfuric acid ferrous iron, Potassium Persulphate/Silver Nitrate, persulphate/mercaptan, Potassium Persulphate/iron protochloride or hydrogen peroxide/iron protochloride; Preferably adopt ammonium persulphate/sodium bisulfite further.
In order to improve water-soluble, the water tolerance of obtained vinyl modified polyvinyl alcohol further, and when using as reagent and additive in polymerization, improve the stability of polymerization system further, above-mentioned each raw material is preferably 84 ~ 87 parts, water, reductive agent 0.04 ~ 0.06 part, emulsifying agent vinyl sulfonic acid an alkali metal salt 0.4 ~ 0.6 part, Vinyl Acetate Monomer 20 ~ 25 parts, 0.05 ~ 0.06 part, oxygenant and vinyl monomer, wherein vinyl monomer consumption by still internal pressure when passing into vinyl monomer be 3 ~ 10bar, to pass into the reaction times be 3.5 ~ 4.5 hours.Its water tolerance significantly improves, particle diameter 0.501 ~ 2.106 μm, solubility rate can be low to moderate 1 ~ 2%; Good water solubility, can meet its service requirements as reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, surface tension can be low to moderate 42.12 ~ 53.46(mN/M), size distribution is significantly improved.
More preferably say, above-mentioned each raw material is preferably soft water 86 parts, reductive agent sodium bisulfite 0.05 part, emulsifying agent sodium vinyl sulfonate 0.4 part, Vinyl Acetate Monomer 23 parts, oxygenant ammonium persulphate 0.05 part and vinyl monomer, wherein vinyl monomer consumption by still internal pressure when passing into vinyl monomer be 6 ~ 8bar, to pass into the reaction times be 3.5 ~ 4.5 hours.
If it is improper that order of addition(of ingredients) controls, although also can obtain vinyl modified polyvinyl alcohol of the present invention, yield rate is unstable, minimum is only about 45%, in order to make preparation method's yield rate of the present invention high and stable, above-mentioned preparation method most preferably is, it is with soft water 86 parts, reductive agent sodium bisulfite 0.05 part, emulsifying agent sodium vinyl sulfonate 0.4 part, Vinyl Acetate Monomer 23 parts, oxygenant ammonium persulphate 0.05 part and vinyl monomer are raw material, through initial charge, displacement in still, polyreaction, breakdown of emulsion is purified and saponification step obtains vinyl modified polyvinyl alcohol, described initial charge is by above-mentioned soft water, reductive agent and emulsifying agent add in reactor, described polyreaction adds above-mentioned Vinyl Acetate Monomer in a kettle., pass into vinyl monomer, controlling still internal pressure is 6 ~ 8bar, when temperature in the kettle reaches temperature of reaction 55 ~ 65 DEG C, add above-mentioned oxygenant, start at from adding oxygenant, reaction is terminated after reaction 3.5 ~ 4.5h.
Specifically, a kind of preparation method of vinyl modified polyvinyl alcohol, as follows:
1), initial charge
86 parts of soft water, 0.05 part of reductive agent sodium bisulfite, 0.4 part of emulsifying agent sodium vinyl sulfonate are added in high pressure stainless steel cauldron, tighten lid, under rotating speed is 150 ~ 210rpm, stirring at normal temperature is even, leaves standstill 25 ~ 35min;
2), displacement in still
With the N of 8 ~ 12bar
2displacement twice, then replace twice with the ethene of 8 ~ 12bar, each displacement continues 3 ~ 5min;
3), add monomer, oxygenant is polymerized
Add 23 parts of Vinyl Acetate Monomers at full speed with high-pressure metering pump, pass into vinyl monomer after displacement in above-mentioned still, controlling still internal pressure is 6 ~ 8bar, when to reach temperature of reaction be 55 ~ 65 DEG C to temperature in the kettle, 0.05 part of oxygenant ammonium persulphate is added at full speed with high-pressure metering pump, start at from adding ammonium persulphate, terminate reaction after reaction 3.5 ~ 4.5h, close ethene intake valve, be cooled to less than 40 DEG C pressure release dischargings and obtain polymeric reaction product;
4), breakdown of emulsion is purified
The method that breakdown of emulsion is purified can adopt conventional breaking method, preferred employing freeze-thaw method: by above-mentioned polymeric reaction product under-10 DEG C ~-5 DEG C conditions, freezing 5 ~ 12 hours, then the polymeric reaction product after freezing is placed at 20 DEG C ~ 25 DEG C and thaw for 2 ~ 5 hours, filter, dry in the air dry oven of 75 ~ 85 DEG C and obtain PE modified vinyl acetate resin in 6 ~ 8 hours;
5), saponification is dissolved
The PE modified vinyl acetate resin obtained after above-mentioned drying is dissolved in methyl alcohol, is mixed with the solution that massfraction is 10 ~ 14%, add alkali lye and carry out alcoholysis, namely obtain vinyl modified polyvinyl alcohol product; Described alkali lye is the methanol solution of NaOH, the mass percentage of solute NaOH is 33.15%, and the mol ratio of described alkali lye and PE modified vinyl acetate resin is 0.02:1.
The present invention has following beneficial effect:
The vinyl modified polyvinyl alcohol that preparation method of the present invention obtains, contents of ethylene is 3 ~ 15%(mol), the content of sodium vinyl sulfonate group is 0.2 ~ 2%(mol), alcoholysis degree is 95.67 ~ 99.72%(mol); It is applied in the letex polymerization such as vinyl acetate between to for plastic, VAE as reagent and additive in polymerization, and overcome the shortcoming such as conventional PVA poor water resistance, polymerization system instability, its water tolerance significantly improves, particle diameter 0.508 μm, solubility rate can be low to moderate 0%; Good water solubility, its service requirements as reagent and additive in polymerization can be met completely, its excellent in stability as reagent and additive in polymerization use polymerization system, surface tension can be low to moderate 42.24(mN/M simultaneously), size distribution is significantly improved, see the compliance test result of embodiment part.
Preparation method of the present invention achieves and has prepared complete alcoholysis type vinyl modified polyvinyl alcohol by letex polymerization at low pressures, and the yield rate through its obtained vinyl modified polyvinyl alcohol of control of order of addition(of ingredients) reaches 95% ~ 99.8%.The reactive emulsifier of trace is employed in preparation polymerization process, make the emulsifying agent segment with trace on macromolecular chain, the complete alcoholysis type polyvinyl alcohol of this transformed lines show is due to the introducing of vinyl and appropriate emulsifying agent segment, macromolecular chain is made to form the hydrophilic two ends of oleophylic, the surfactivity comparing conventional its aqueous solution of complete alcoholysis type polyvinyl alcohol increases, also emulsion polymerization systems is made to stablize while meeting water tolerance, simultaneously due to the unique texture of ethylene modified polyvinyl alcohol, viscosity stability is better, uses more convenient.
Accompanying drawing explanation
Fig. 1 is the qualitative infrared analysis collection of illustrative plates of modified polyvinyl alcohol medium vinyl of the present invention group.
Fig. 2 is the quantitative nmr analysis collection of illustrative plates of modified polyvinyl alcohol medium vinyl of the present invention group.
Fig. 3 is that modified polyvinyl alcohol of the present invention is for emulsion particle diameter distribution tests figure in letex polymerization.
Embodiment
Below by embodiment, the present invention is specifically described; what be necessary to herein means out is; following examples are only for being further detailed the present invention; can not be interpreted as limiting the scope of the invention, the person skilled in the art in this field can make some nonessential improvement and adjustment according to foregoing invention content to the present invention.
Embodiment 1
The preparation of vinyl modified polyvinyl alcohol, as follows:
1), initial charge
84 ~ 87 parts of soft water, 0.04 ~ 0.06 part of reductive agent sodium bisulfite, 0.4 ~ 0.6 part of emulsifying agent sodium vinyl sulfonate are added in high pressure stainless steel cauldron, tighten lid, under rotating speed is 150 ~ 210rpm, stirring at normal temperature is even, leaves standstill 25 ~ 35min;
2), displacement in still
With the N of 8 ~ 12bar
2displacement twice, then replace twice with the ethene of 8 ~ 12bar, each displacement continues 3 ~ 5min;
3), add monomer, oxygenant is polymerized
Add 20 ~ 25 parts of Vinyl Acetate Monomers at full speed with high-pressure metering pump, pass into vinyl monomer after displacement in above-mentioned still, controlling still internal pressure is 3 ~ 10bar, when to reach temperature of reaction be 55 ~ 65 DEG C to temperature in the kettle, 0.05 ~ 0.06 part of oxygenant ammonium persulphate is added at full speed with high-pressure metering pump, start at from adding oxygenant, terminate reaction after reaction 3.5 ~ 4.5h, close ethene intake valve, be cooled to less than 40 DEG C pressure release dischargings and obtain polymeric reaction product;
4), breakdown of emulsion is purified
The method that breakdown of emulsion is purified can adopt conventional breaking method, preferred employing freeze-thaw method: by above-mentioned polymeric reaction product under-10 DEG C ~-5 DEG C conditions, freezing 5 ~ 12 hours, then the polymeric reaction product after freezing is placed at 20 DEG C ~ 25 DEG C and thaw for 2 ~ 5 hours, filter, dry in the air dry oven of 75 ~ 85 DEG C and obtain PE modified vinyl acetate resin in 6 ~ 8 hours;
5), saponification is dissolved
The PE modified vinyl acetate resin obtained after above-mentioned drying is dissolved in methyl alcohol, is mixed with the solution that massfraction is 10 ~ 14%, add alkali lye and carry out alcoholysis, namely obtain vinyl modified polyvinyl alcohol product; Described alkali lye is the methanol solution of NaOH, the mass percentage of solute NaOH is 33.15%, and the mol ratio of described alkali lye and PE modified vinyl acetate resin is 0.02:1.
The vinyl modified polyvinyl alcohol obtained by above-mentioned preparation method, its structural formula is as follows:
wherein R
1=C
nh
2n+1, n=0 ~ 16, R
2for H, R
3for Na; Wherein record a/a+b=97 ~ 99% (mol) according to a conventional method, recording c is as follows 0.2 ~ 0.8%(mol), to record d be 3 ~ 7%(mol).
Above-mentioned initiator also can adopt ammonium persulphate/sodium bisulfite, Potassium Persulphate/sodium bisulfite, hydrogen peroxide/tartrate, hydrogen peroxide/rongalite, ammonium persulphate/ferrous sulfate, hydrogen peroxide/sulfuric acid ferrous iron, Potassium Persulphate/Silver Nitrate, persulphate/mercaptan, Potassium Persulphate/iron protochloride or hydrogen peroxide/iron protochloride; Mentioned emulsifier also can adopt alkyl vinylformic acid-2-ethanesulfonic acid sodium, 2.2-acrylamide-2.2-dimethyl ethyl sulfonic acid sodium, sodium p styrene sulfonate or maleic acid higher alcohols monoesters sodium.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, and overcome the shortcoming such as conventional PVA poor water resistance, polymerization system instability, its water tolerance significantly improves; Good water solubility, can meet its service requirements as reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
Below qualitative, quantitative verification is carried out to above-mentioned obtained vinyl modified polyvinyl alcohol:
(1), vinyl group qualitative and quantitative measures
(1) infared spectrum
Ethylene modified polyvinyl alcohol and vinyl acetate homopolymer difference have a small peak at wave number 745cm-1 place as can be seen from Figure 1, this is-characteristic peak of continuous more than 4 unit of CH2-exist in macromolecular chain, but wave number is bigger than normal, illustrate-CH2-CH2-content less, demonstrate the constitutional features of ethylene modified polyvinyl alcohol.
(2) nuclear magnetic spectrum
Fig. 2 is shown in the quantitative assay of vinyl group,
Show that ethylene content is 3-7%(mol by calculating methylene radical and methyne two peak intensity ratio).The test of above-mentioned ethylene content adopts nuclear-magnetism method.
(2), the mensuration of reactive sodium group
The test of reactive sodium group adopts elemental microanalysis method, specific as follows: by clean for vinyl modified polyvinyl alcohol formic acid extraction, 70 DEG C of vacuum-dryings 20 hours, again sample is cooled to room temperature in moisture eliminator, adopt elemental analyser, measure the content of element S, and then the content calculating vinylsulfonate is 0.2 ~ 0.8%(mol).
Embodiment 2
A preparation method for vinyl modified polyvinyl alcohol, what this preparation method adopted is emulsion polymerization; It comprises following step:
1, the sodium bisulfite of 0.08 weight part is dissolved in water, 0.6 parts by weight of ethylene base sodium sulfonate is dissolved in water and adds in 10L autoclave together, total consumption of water is 82 parts, tighten the lid of charging opening, leak test pressure testing, open and stir, speed setting is 210rpm, stirs, leaves standstill 35min;
2, the N of 12bar is adopted
2displacement twice, then replace twice with the ethene of 12bar, each time swap continues 3min;
3, the Vinyl Acetate Monomer of 40 weight parts is added at full speed with high-pressure metering pump, pass into vinyl monomer, setting still internal pressure is 3bar, when temperature in the kettle reaches 65 DEG C, by soluble in water for 0.045 weight part ammonium persulphate, squeeze in still at full speed with high-pressure metering pump, in setting still, top temperature is 80 DEG C, when temperature in the kettle opens still inner coil pipe water of condensation fast cooling automatically more than 80 DEG C of programs, automatically close still inner coil pipe water of condensation lower than 80 DEG C of programs;
Counting from adding ammonium persulphate, terminating reaction after reaction 4.5h, closing ethene intake valve, be cooled to less than 40 DEG C pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 12h at-10 DEG C, then in thawed at room temperature 2h, filter and obtain PE modified vinyl acetate resin, and dry 6 hours in the air dry oven being placed on 85 DEG C;
5, the PE modified vinyl acetate resin obtained after above-mentioned drying is dissolved in methyl alcohol, is mixed with the solution that massfraction is 8%, add alkali lye and carry out alcoholysis, namely obtain vinyl modified polyvinyl alcohol product of the present invention; Described alkali lye is the methanol solution of NaOH, the mass percentage of solute NaOH is 35%, and the mol ratio of described alkali lye and PE modified vinyl acetate resin is 0.02:1; Measuring its ethylene content is 3%(mol), sodium vinyl sulfonate group content is 2%(mol).
The test of above-mentioned contents of ethylene adopts nuclear-magnetism method.
The test of above-mentioned reactive sodium group adopts elemental microanalysis method, specific as follows: by clean for vinyl modified polyvinyl alcohol formic acid extraction, 70 DEG C of vacuum-dryings 20 hours, again sample is cooled to room temperature in moisture eliminator, adopt elemental analyser, measure the content of element S, and then calculate the content of sodium vinyl sulfonate.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, and overcome the shortcoming such as conventional PVA poor water resistance, polymerization system instability, its water tolerance significantly improves; Good water solubility, can meet its service requirements as reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
Embodiment 3
A preparation method for vinyl modified polyvinyl alcohol, it carries out according to the following steps:
1, the sodium bisulfite of 0.02 weight part is dissolved in water, 0.2 parts by weight of ethylene base sodium sulfonate is dissolved in water and adds in 10L autoclave together, total consumption of water is 88 parts, tighten the lid of charging opening, leak test pressure testing, open and stir, speed setting is 150rpm, stirs, leaves standstill 30min;
2, the N of 8bar is adopted
2displacement twice, then replace twice with the ethene of 8bar, each time swap continues 4min;
3, the Vinyl Acetate Monomer of 10 weight parts is added at full speed with high-pressure metering pump, pass into vinyl monomer, setting still internal pressure is 20bar, when temperature in the kettle reaches 55 DEG C, by soluble in water for 0.065 weight part ammonium persulphate, squeeze in still at full speed with high-pressure metering pump, in setting still, top temperature is 65 DEG C, when temperature in the kettle opens still inner coil pipe water of condensation fast cooling automatically more than 65 DEG C of programs, automatically close still inner coil pipe water of condensation lower than 65 DEG C of programs;
Counting from adding ammonium persulphate, terminating reaction after reaction 4.0h, closing ethene intake valve, be cooled to less than 40 DEG C pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 5h at-7 DEG C, then in thawed at room temperature 3h, filter and obtain PE modified vinyl acetate resin, and dry 7 hours in the air dry oven being placed on 78 DEG C;
5, the PE modified vinyl acetate resin obtained after above-mentioned drying is dissolved in methyl alcohol, is mixed with the solution that massfraction is 20%, add alkali lye and carry out alcoholysis, namely obtain vinyl modified polyvinyl alcohol product of the present invention; Described alkali lye is the methanol solution of NaOH, the mass percentage of solute NaOH is 30%, and the mol ratio of described alkali lye and PE modified vinyl acetate resin is 0.02:1; Measuring its ethylene content is 15%(mol), sodium vinyl sulfonate group content is 0.2%(mol).
The test of above-mentioned contents of ethylene adopts nuclear-magnetism method.
The test of above-mentioned reactive sodium group adopts elemental microanalysis method, specific as follows: by clean for vinyl modified polyvinyl alcohol formic acid extraction, 70 DEG C of vacuum-dryings 20 hours, again sample is cooled to room temperature in moisture eliminator, adopt elemental analyser, measure the content of element S, and then calculate the content of vinylsulfonate.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, and overcome the shortcoming such as conventional PVA poor water resistance, polymerization system instability, its water tolerance significantly improves; Good water solubility, can meet its service requirements as reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
Embodiment 4
A preparation method for vinyl modified polyvinyl alcohol, what this preparation method adopted is emulsion polymerization; It comprises following step:
1,2.3172g sodium bisulfite is dissolved in 200g water, 16.25g sodium vinyl sulfonate is dissolved in 1000g water and adds together with 3447g water in 10L autoclave, tighten the lid of charging opening, leak test pressure testing, open and stir, speed setting is 160rpm, stirs, leaves standstill 25min;
2, the N of 10bar is adopted
2displacement twice, then replace twice with the ethene of 10bar, each time swap continues 5min;
3,810.32g Vinyl Acetate Monomer is added at full speed with high-pressure metering pump, pass into vinyl monomer, setting still internal pressure is 7bar, when temperature in the kettle reaches 58 DEG C, be dissolved in by 2.6025g ammonium persulphate in 100g water, squeeze in still at full speed with high-pressure metering pump, in setting still, top temperature is 70 DEG C, when temperature in the kettle opens still inner coil pipe water of condensation fast cooling automatically more than 70 DEG C of programs, automatically close still inner coil pipe water of condensation lower than 70 DEG C of programs;
Counting from adding ammonium persulphate, terminating reaction after reaction 3.5h, closing ethene intake valve, be cooled to less than 40 DEG C pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 12h at-5 DEG C, then in thawed at room temperature 5h, filter and obtain PE modified vinyl acetate resin, and dry 8 hours in the air dry oven being placed on 75 DEG C;
5, by this resin after oven dry, it is resin according to weight ratio: the proportioning wiring solution-forming of methyl alcohol=1:10, at 45 DEG C after constant temperature half an hour, add the sodium hydrate methanol solution alcoholysis 1.5 hours that mass percent is 34%, refilter afterwards, dry, can obtain product of the present invention, measuring its contents of ethylene is 5%(mol), sodium vinyl sulfonate group content is 0.3%(mol).
The test of above-mentioned contents of ethylene adopts nuclear-magnetism method.
The test of above-mentioned reactive sodium group adopts elemental microanalysis method, specific as follows: by clean for vinyl modified polyvinyl alcohol formic acid extraction, 70 DEG C of vacuum-dryings 20 hours, again sample is cooled to room temperature in moisture eliminator, adopt elemental analyser, measure the content of element S, and then calculate the content of vinylsulfonate.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, and overcome the shortcoming such as conventional PVA poor water resistance, polymerization system instability, its water tolerance significantly improves; Good water solubility, can meet its service requirements as reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
Embodiment 5
A preparation method for vinyl modified polyvinyl alcohol, what this preparation method adopted is emulsion polymerization; It comprises following step:
1,2.6536g sodium bisulfite is dissolved in 200g water, 17.35g vinyl sulfonic acid potassium is dissolved in 1000g water and adds together with 3528g water in 10L autoclave, tighten the lid of charging opening, leak test pressure testing, open and stir, speed setting is 175rpm, stirs, leaves standstill 28min;
2, with the N of 10bar
2displacement twice, then replace twice with the ethene of 10bar;
3,815.36g Vinyl Acetate Monomer is added at full speed with high-pressure metering pump, setting still internal pressure is 7bar, when temperature in the kettle reaches 61 DEG C, 2.7023g Potassium Persulphate is dissolved in 100g water, squeeze in still at full speed with high-pressure metering pump, in setting still, top temperature is 73 DEG C, when temperature in the kettle opens still inner coil pipe water of condensation fast cooling automatically more than 73 DEG C of programs, automatically closes still inner coil pipe water of condensation lower than 73 DEG C of programs;
Counting from adding Potassium Persulphate, terminating reaction after reaction 4h, closing ethene intake valve, be cooled to less than 40 DEG C pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 5h at-10 DEG C, then in thawed at room temperature 2h, filter and obtain PE modified vinyl acetate resin, and dry 6 hours in the air dry oven being placed on 78 DEG C;
5, by this resin after oven dry, it is resin according to weight ratio: the proportioning wiring solution-forming of methyl alcohol=1:9, at 40 DEG C after constant temperature half an hour, add the sodium hydroxide solution alcoholysis 2 hours that mass percent is 33.15%, refilter afterwards, dry, can obtain finished product of the present invention, measuring its contents of ethylene is 5%(mol), vinyl sulfonic acid potassium group content is 0.35%(mol); Measuring method is the same.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, and overcome the shortcoming such as conventional PVA poor water resistance, polymerization system instability, its water tolerance significantly improves; Good water solubility, can meet its service requirements as reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
Embodiment 6
A preparation method for vinyl modified polyvinyl alcohol, what this preparation method adopted is emulsion polymerization; It comprises following step:
1,2.7098g ferrous sulfate is dissolved in 200g water, 18.28g sodium p styrene sulfonate is dissolved in 1000g water and adds together with 3578g water in 10L autoclave, tighten the lid of charging opening, leak test pressure testing, open and stir, speed setting is 180rpm, stirs, leaves standstill 32min;
2, with the N of 11bar
2displacement twice, then replace twice with the ethene of 11bar;
3,856.37g Vinyl Acetate Monomer is added at full speed with high-pressure metering pump, setting still internal pressure is 8bar, when temperature in the kettle reaches 62 DEG C, 2.9576g ammonium persulphate is dissolved in 100g water, squeeze in still at full speed with high-pressure metering pump, in setting still, top temperature is 75 DEG C, when temperature in the kettle opens still inner coil pipe water of condensation fast cooling automatically more than 75 DEG C of programs, automatically closes still inner coil pipe water of condensation lower than 75 DEG C of programs;
Counting from adding ammonium persulphate, and terminating reaction after reaction 4h, closing ethene intake valve, be cooled to less than 40 DEG C pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 8h at-8 DEG C, then in thawed at room temperature 3.5h, filter and obtain PE modified vinyl acetate resin, and dry 7 hours in the air dry oven being placed on 73 DEG C;
5, by this resin after oven dry, it is resin according to weight ratio: the proportioning wiring solution-forming of methyl alcohol=1:11, at 38 DEG C after constant temperature half an hour, add the sodium hydroxide solution alcoholysis 1 hour that mass percent is 32%, refilter afterwards, dry, can obtain finished product of the present invention, measuring its contents of ethylene is 6%(mol), sodium p styrene sulfonate group content is 0.4%(mol); Measuring method is the same.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, and overcome the shortcoming such as conventional PVA poor water resistance, polymerization system instability, its water tolerance significantly improves; Good water solubility, can meet its service requirements as reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
Embodiment 7
A preparation method for vinyl modified polyvinyl alcohol, what this preparation method adopted is emulsion polymerization; It comprises following step:
1,3.0174g Silver Nitrate is dissolved in 200g water, 19.57g sodium p styrene sulfonate is dissolved in 1000g water and adds together with 3654g water in 10L autoclave, tighten the lid of charging opening, leak test pressure testing, open and stir, speed setting is 180rpm, stirs, leaves standstill 32min;
2, with the N of 9bar
2displacement twice, then replace twice with the ethene of 9bar;
3,862.95g Vinyl Acetate Monomer is added at full speed with high-pressure metering pump, setting still internal pressure is 10bar, when temperature in the kettle reaches 65 DEG C, 3.2546g Potassium Persulphate is dissolved in 100g water, squeeze in still at full speed with high-pressure metering pump, in setting still, top temperature is 78 DEG C, when temperature in the kettle opens still inner coil pipe water of condensation fast cooling automatically more than 78 DEG C of programs, automatically closes still inner coil pipe water of condensation lower than 78 DEG C of programs;
Counting from adding Potassium Persulphate, terminating reaction after reaction 4h, closing ethene intake valve, be cooled to less than 40 DEG C pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 6h at-10 DEG C, then in thawed at room temperature 4h, filter and obtain PE modified vinyl acetate resin, and dry 8 hours in the air dry oven being placed on 72.5 DEG C;
5, by this resin after oven dry, it is resin according to weight ratio: the proportioning wiring solution-forming of methyl alcohol=1:10, at 40 DEG C after constant temperature half an hour, add the sodium hydroxide solution alcoholysis 1.5 hours that mass percent is 33%, refilter afterwards, dry, can obtain finished product of the present invention, measuring its contents of ethylene is 8%(mol), sodium p styrene sulfonate group content is 0.43%(mol); Measuring method is the same.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, and overcome the shortcoming such as conventional PVA poor water resistance, polymerization system instability, its water tolerance significantly improves; Good water solubility, can meet its service requirements as reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
Embodiment 8
A preparation method for vinyl modified polyvinyl alcohol, what this preparation method adopted is emulsion polymerization; It comprises following step:
1,3.3269g iron protochloride is dissolved in 200g water, 25.49g p styrene sulfonic acid potassium is dissolved in 1000g water and adds together with 3689g water in 10L autoclave, tighten the lid of charging opening, leak test pressure testing, open and stir, speed setting is 200rpm, stirs, leaves standstill 34min;
2, with the N of 10bar
2displacement twice, then replace twice with the ethene of 10bar;
3,875.26g Vinyl Acetate Monomer is added at full speed with high-pressure metering pump, setting still internal pressure is 12bar, when temperature in the kettle reaches 64 DEG C, 3.5197g Potassium Persulphate is dissolved in 100g water, squeeze in still at full speed with high-pressure metering pump, in setting still, top temperature is 80 DEG C, when temperature in the kettle opens still inner coil pipe water of condensation fast cooling automatically more than 80 DEG C of programs, automatically closes still inner coil pipe water of condensation lower than 80 DEG C of programs;
Counting from adding Potassium Persulphate, terminating reaction after reaction 4h, closing ethene intake valve, be cooled to less than 40 DEG C pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 10h at-7 DEG C, then in thawed at room temperature 3.5h, filter and obtain PE modified vinyl acetate resin, and dry 6 hours in the air dry oven being placed on 76 DEG C;
5, by this resin after oven dry, it is resin according to weight ratio: the proportioning wiring solution-forming of methyl alcohol=1:10, at 40 DEG C after constant temperature half an hour, add the sodium hydroxide solution alcoholysis 2 hours that mass percent is 31%, refilter afterwards, dry, can obtain finished product of the present invention, measuring its contents of ethylene is 9%(mol), p styrene sulfonic acid potassium group content is 0.53%(mol); Measuring method is the same.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, and overcome the shortcoming such as conventional PVA poor water resistance, polymerization system instability, its water tolerance significantly improves; Good water solubility, can meet its service requirements as reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
Comparison study example 1
The emulsion vinyl modified polyvinyl alcohol prepared with pressure, application experiment is done by contrasting with conventional polyvinyl alcohol, verify contribution that ethylene modified polyvinyl alcohol improves emulsion water tolerance, the improvement of emulsion particle diameter distribution and the improvement of polymerization system stability, result is as follows:
(1), PE modified polyvinyl alcohol (YPS series) is applied as the letex polymerization of protective colloid, water tolerance experimental result, in table 1:
Table 1
The vinyl modified polyvinyl alcohol that wherein YPS-I, YPS-II and YPS-III obtain for embodiment of the present invention 4-6 demonstrates by upper table the water tolerance that vinyl modified polyvinyl alcohol can significantly improve emulsion further.
(2) test the size distribution of above-mentioned emulsion, result is as Fig. 3.
Can be found out by Fig. 3 result, vinyl modified polyvinyl alcohol obviously can improve the size distribution of emulsion.
(3), PE modified polyvinyl alcohol (YPS series) is applied as the letex polymerization of protective colloid, stability experiment result, in table 2:
Table 2
| Sample number | Protective colloid | Surface tension (mN/M) |
| AP-01 | Conventional complete alcoholysis type polyvinyl alcohol | 63.63 |
| AP-02 | YPS-Ⅰ | 44.43 |
| AP-03 | YPS-Ⅱ | 46.47 |
| AP-04 | YPS-III | 42.24 |
YPS-I, YPS-II and YPS-III are for the obtained vinyl modified polyvinyl alcohol of embodiment of the present invention 4-6 is as table 2, and the surface tension of the aqueous solution is less, then surfactivity is higher, is more easy to carry out stable polymerization.
(4), solubility property measures as table 3:
Table 3
| Sample number into spectrum | Dissolution time (min) | Solvent temperature (DEG C) | Experimental phenomena |
| 1799 | 80 | 90 | Dissolve completely, clear |
| YPS-Ⅰ | 50 | 90 | Dissolve completely, clear |
| YPS-Ⅱ | 50 | 90 | Dissolve completely, clear |
| YPS-Ⅲ | 48 | 90 | Dissolve completely, clear |
The vinyl modified polyvinyl alcohol that YPS-I, YPS-II and YPS-III obtain for embodiment of the present invention 4-6
(5), viscosity stability measures as table 4:
Table 4
The vinyl modified polyvinyl alcohol viscosity test condition that YPS-I, YPS-II and YPS-III obtain for embodiment of the present invention 4-6: 20 DEG C, rotational viscosimeter.
Claims (10)
1. the preparation method of a vinyl modified polyvinyl alcohol, it is characterized in that: it is for raw material with 82 ~ 88 parts, water, reductive agent 0.02 ~ 0.08 part, emulsifying agent 0.2 ~ 0.6 part, Vinyl Acetate Monomer 10 ~ 40 parts, 0.045 ~ 0.065 part, oxygenant and vinyl monomer, displacement in initial charge, still, polyreaction, breakdown of emulsion purification and saponification step obtain vinyl modified polyvinyl alcohol, wherein the consumption of vinyl monomer is the still internal pressure controlled when passing into vinyl monomer is 3 ~ 20bar, passes into the vinyl monomer consumption that the reaction times is 3.5 ~ 4.5 hours meters; Described emulsifying agent is reactive sulfonate or maleic acid higher alcohols monoesters sodium.
2. preparation method as claimed in claim 1, is characterized in that: described reactive sulfonate emulsifier is alkyl vinylformic acid-2-ethanesulfonic acid sodium, vinyl alkyl sodium sulfonate, 2-acrylamide-2-methyl propane sulfonic sodium or sodium p styrene sulfonate.
3. preparation method as claimed in claim 1, is characterized in that: described reactive sulfonate emulsifier is vinyl sulfonic acid an alkali metal salt.
4. preparation method as claimed in claim 3, is characterized in that: described vinyl sulfonic acid an alkali metal salt emulsifying agent is sodium vinyl sulfonate or vinyl sulfonic acid potassium.
5. preparation method as claimed in claim 1 or 2, is characterized in that: described oxygenant/reductive agent is ammonium persulphate/sodium bisulfite, Potassium Persulphate/sodium bisulfite, hydrogen peroxide/tartrate, hydrogen peroxide/rongalite, ammonium persulphate/ferrous sulfate, hydrogen peroxide/sulfuric acid ferrous iron, Potassium Persulphate/Silver Nitrate, persulphate/mercaptan, Potassium Persulphate/iron protochloride or hydrogen peroxide/iron protochloride.
6. the preparation method as described in claim 3 or 4, is characterized in that: described oxygenant/reductive agent is ammonium persulphate/sodium bisulfite, Potassium Persulphate/sodium bisulfite, hydrogen peroxide/tartrate, hydrogen peroxide/rongalite, ammonium persulphate/ferrous sulfate, hydrogen peroxide/sulfuric acid ferrous iron, Potassium Persulphate/Silver Nitrate, persulphate/mercaptan, Potassium Persulphate/iron protochloride or hydrogen peroxide/iron protochloride.
7. preparation method as claimed in claim 6, it is characterized in that: described each raw materials is 84 ~ 87 parts, water, reductive agent 0.04 ~ 0.06 part, emulsifying agent vinyl sulfonic acid an alkali metal salt 0.4 ~ 0.6 part, Vinyl Acetate Monomer 20 ~ 25 parts, 0.05 ~ 0.06 part, oxygenant and vinyl monomer, wherein vinyl monomer consumption by still internal pressure when passing into vinyl monomer be 3 ~ 10bar, to pass into the reaction times be 3.5 ~ 4.5 hours.
8. preparation method as claimed in claim 1, it is characterized in that: described each raw material is soft water 86 parts, reductive agent sodium bisulfite 0.05 part, emulsifying agent sodium vinyl sulfonate 0.4 part, Vinyl Acetate Monomer 23 parts, oxygenant ammonium persulphate 0.05 part and vinyl monomer, wherein vinyl monomer consumption by still internal pressure when passing into vinyl monomer be 6 ~ 8bar, to pass into the reaction times be 3.5 ~ 4.5 hours.
9. preparation method as claimed in claim 1, it is characterized in that: described preparation method is with soft water 86 parts, reductive agent sodium bisulfite 0.05 part, emulsifying agent sodium vinyl sulfonate 0.4 part, Vinyl Acetate Monomer 23 parts, oxygenant ammonium persulphate 0.05 part and vinyl monomer are raw material, through initial charge, displacement in still, polyreaction, breakdown of emulsion is purified and saponification step obtains vinyl modified polyvinyl alcohol, described initial charge is by described soft water, reductive agent and emulsifying agent add in reactor, described polyreaction adds described Vinyl Acetate Monomer in a kettle., pass into vinyl monomer, controlling still internal pressure is 6 ~ 8bar, when temperature in the kettle reaches temperature of reaction 55 ~ 65 DEG C, add described oxygenant, start at from adding oxygenant, reaction is terminated after reaction 3.5 ~ 4.5h.
10. a preparation method for vinyl modified polyvinyl alcohol, is characterized in that, carries out as follows:
1), initial charge
86 parts of soft water, 0.05 part of reductive agent sodium bisulfite, 0.4 part of emulsifying agent sodium vinyl sulfonate are added in high pressure stainless steel cauldron, tighten lid, under rotating speed is 150 ~ 210rpm, stirring at normal temperature is even, leaves standstill 25 ~ 35min;
2), displacement in still
With the N of 8 ~ 12bar
2displacement twice, then replace twice with the ethene of 8 ~ 12bar, each displacement continues 3 ~ 5min;
3), add monomer, oxygenant is polymerized
Add 23 parts of Vinyl Acetate Monomers at full speed with high-pressure metering pump, pass into vinyl monomer after displacement in above-mentioned still, controlling still internal pressure is 6 ~ 8bar, when to reach temperature of reaction be 55 ~ 65 DEG C to temperature in the kettle, 0.05 part of oxygenant ammonium persulphate is added at full speed with high-pressure metering pump, start at from adding ammonium persulphate, terminate reaction after reaction 3.5 ~ 4.5h, close ethene intake valve, be cooled to less than 40 DEG C pressure release dischargings and obtain polymeric reaction product;
4), breakdown of emulsion is purified
The method that breakdown of emulsion is purified can adopt conventional breaking method; Described breaking method adopts freeze-thaw method: by above-mentioned polymeric reaction product under-10 DEG C ~-5 DEG C conditions, freezing 5 ~ 12 hours, then the polymeric reaction product after freezing is placed at 20 DEG C ~ 25 DEG C and thaw for 2 ~ 5 hours, filter, dry in the air dry oven of 75 ~ 85 DEG C and obtain PE modified vinyl acetate resin in 6 ~ 8 hours;
5), saponification is dissolved
The PE modified vinyl acetate resin obtained after above-mentioned drying is dissolved in methyl alcohol, is mixed with the solution that massfraction is 10 ~ 14%, add alkali lye and carry out alcoholysis, namely obtain vinyl modified polyvinyl alcohol product; Described alkali lye is the methanol solution of NaOH, the mass percentage of solute NaOH is 33.15%, and the mol ratio of described alkali lye and PE modified vinyl acetate resin is 0.02:1.
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