CN103724514A - Preparation method for vinyl modified polyvinyl alcohol - Google Patents
Preparation method for vinyl modified polyvinyl alcohol Download PDFInfo
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- CN103724514A CN103724514A CN201210387854.0A CN201210387854A CN103724514A CN 103724514 A CN103724514 A CN 103724514A CN 201210387854 A CN201210387854 A CN 201210387854A CN 103724514 A CN103724514 A CN 103724514A
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Abstract
The invention relates to a preparation method for vinyl modified polyvinyl alcohol. With 82-88 parts of water, 0.02-0.08 part of a reducing agent, 0.2-0.6 part of an emulsifier, 10-40 parts of a vinyl acetate monomer, 0.045-0.065 part of an oxidizing agent and vinyl monomer as raw materials, the vinyl modified polyvinyl alcohol is prepared by the steps of initial charging, replacement in kettle, polymerization reaction, demulsification purification and saponification. Specifically, the dosage of the vinyl monomer is calculated according to a dosage needed by an introduction reaction time of 3.5-4.5h when introducing the vinyl monomer into the kettle with an internal pressure of 3-20bar. The emulsifier is reactive sulfonate. The prepared vinyl modified polyvinyl alcohol is applied as a polymerization additive into emulsion polymerization, overcomes the disadvantages of poor water resistance, unstable polymerization system and the like in conventional PVA (polyvinyl alcohol), and has significantly enhanced water resistance. With good water solubility, the vinyl modified polyvinyl alcohol can fully satisfy the requirements of being used as a polymerization additive. At the same time, when the vinyl modified polyvinyl alcohol is used as a polymerization additive, the polymerization system has excellent stability, and the particle size distribution is improved significantly.
Description
Technical field
The present invention relates to a kind of preparation method who is applied to the reagent and additive in polymerization in the letex polymerizations such as vinyl acetate between to for plastic, VAE, relate in particular to a kind of preparation method of modified polyvinyl alcohol.
Background technology
Polyvinyl alcohol (PVA) is a kind of letex polymerization auxiliary agent of important, excellent performance, is applied in the letex polymerization of vinyl acetate between to for plastic, VAE etc. usually used as protective colloid.The general PVA that uses partial alcoholysis in common technical recipe, if but require emulsion to have good water tolerance, the PVA of partial alcoholysis just should not be used, because the PVA of partial alcoholysis itself does not have water tolerance.In order to improve water tolerance, just require to use the PVA of full alcoholysis, but the surface tension of the complete alcoholysis type PVA aqueous solution is high, is difficult to obtain stable letex polymerization.
Summary of the invention
The object of the present invention is to provide a kind of water-tolerant, for the good vinyl modified polyvinyl alcohol of stability of emulsion polymerization.
The object of the invention is to be achieved through the following technical solutions:
A kind of preparation method of vinyl modified polyvinyl alcohol, it is characterized in that: it is that to take 82～88 parts, water, 0.02～0.08 part of reductive agent, 0.2～0.6 part of emulsifying agent, 10～40 parts of Vinyl Acetate Monomers, 0.045～0.065 part, oxygenant and vinyl monomer be raw material, displacement in initial charge, still, polyreaction, breakdown of emulsion are purified and saponification step makes vinyl modified polyvinyl alcohol, the consumption of therein ethylene monomer be the still internal pressure of controlling while passing into vinyl monomer be 3～20bar, pass into the reaction times and be the vinyl monomer consumption of 3.5～4.5 hours meters; Described emulsifying agent is reactive sulfonate.
The water tolerance of the modified polyvinyl alcohol that above-mentioned preparation method makes, good water solubility, the simultaneously excellent in stability of use polymerization system using the modified polyvinyl alcohol making as reagent and additive in polymerization.Contriver finds in long-term R & D process, if it is bad that the usage ratio of above each reaction raw materials is controlled, although can improve the water tolerance of modification PVOH and increase the stability of polymerization system during as reagent and additive in polymerization, thereby easily greatly reduce its water-soluble application having limited using it as reagent and additive in polymerization in polymerization system.
Mentioned emulsifier is reactive sulfonate, and reactive sulfonate is clearly to this area, and reactive sulfonate refers to and has the alkylsulfonate (all can buy) that carbon-carbon double bond or other side chains have reaction active groups; In a word, reactive sulfonate refers to the sulfonate that reactive behavior is higher.The reactive sulfonate of the present invention is preferably alkyl vinylformic acid-2-ethanesulfonic acid sodium, vinyl alkylsulfonate, 2.2-acrylamide-2.2-dimethyl ethyl sulfonic acid sodium, sodium p styrene sulfonate or maleic acid higher alcohols monoesters sodium, more preferably vinyl sulfonic acid an alkali metal salt, most preferably is sodium vinyl sulfonate or vinyl sulfonic acid potassium.
Above-mentioned initiator (oxygenant, reductive agent) is ammonium persulphate/sodium bisulfite, Potassium Persulphate/sodium bisulfite, hydrogen peroxide/tartrate, hydrogen peroxide/rongalite, ammonium persulphate/ferrous sulfate, hydrogen peroxide/sulfuric acid ferrous iron, Potassium Persulphate/Silver Nitrate, persulphate/mercaptan, Potassium Persulphate/iron protochloride or hydrogen peroxide/iron protochloride; Further preferably adopt ammonium persulphate/sodium bisulfite.
In order further to improve water-soluble, the water tolerance of the vinyl modified polyvinyl alcohol making, and further improve the stability of polymerization system while using as reagent and additive in polymerization, above-mentioned each raw material is preferably 84～87 parts, water, 0.04～0.06 part of reductive agent, 0.4～0.6 part of emulsifying agent vinyl sulfonic acid an alkali metal salt, 20～25 parts of Vinyl Acetate Monomers, 0.05～0.06 part, oxygenant and vinyl monomer, and the still internal pressure of the consumption of therein ethylene monomer when passing into vinyl monomer be 3～10bar, pass into the reaction times is 3.5～4.5 hours.Its water tolerance obviously improves, particle diameter 0.501～2.106 μ m, solubility rate can be low to moderate 1～2%; Good water solubility, can meet it as the service requirements of reagent and additive in polymerization completely, it uses excellent in stability, surface tension of polymerization system can be low to moderate 42.12～53.46(mN/M as reagent and additive in polymerization simultaneously), size distribution is significantly improved.
More preferably say, above-mentioned each raw material is preferably 86 parts of soft water, 0.05 part of reductive agent sodium bisulfite, 0.4 part of emulsifying agent sodium vinyl sulfonate, 23 parts of Vinyl Acetate Monomers, 0.05 part of oxygenant ammonium persulphate and vinyl monomer, and the still internal pressure of the consumption of therein ethylene monomer when passing into vinyl monomer be 6～8bar, pass into the reaction times is 3.5～4.5 hours.
If it is improper that order of addition(of ingredients) is controlled, although also can make vinyl modified polyvinyl alcohol of the present invention, yield rate is unstable, minimum is only 45% left and right, in order to make preparation method's yield rate of the present invention high and stable, above-mentioned preparation method most preferably is, it is with 86 parts of soft water, 0.05 part of reductive agent sodium bisulfite, 0.4 part of emulsifying agent sodium vinyl sulfonate, 23 parts of Vinyl Acetate Monomers, 0.05 part of oxygenant ammonium persulphate and vinyl monomer are raw material, through initial charge, displacement in still, polyreaction, breakdown of emulsion is purified and saponification step makes vinyl modified polyvinyl alcohol, described initial charge is by above-mentioned soft water, reductive agent and emulsifying agent add in reactor, described polyreaction is in reactor, to add above-mentioned Vinyl Acetate Monomer, pass into vinyl monomer, controlling still internal pressure is 6～8bar, when temperature in the kettle reaches 55～65 ℃ of temperature of reaction, add above-mentioned oxygenant, from adding oxygenant, start at, after reaction 3.5～4.5h, finish reaction.
Specifically, a kind of preparation method of vinyl modified polyvinyl alcohol, as follows:
1), initial charge
86 parts of soft water, 0.05 part of reductive agent sodium bisulfite, 0.4 part of emulsifying agent sodium vinyl sulfonate being added in high pressure stainless steel cauldron, tighten lid, is that under 150～210rpm, stirring at normal temperature is even at rotating speed, standing 25～35min;
2), displacement in still
N with 8～12bar
2displacement twice, then replace twice with the ethene of 8～12bar, each displacement continues 3～5min;
3), add monomer, oxygenant carries out polymerization
In above-mentioned still, after displacement, with high-pressure metering pump, add at full speed 23 parts of Vinyl Acetate Monomers, pass into vinyl monomer, controlling still internal pressure is 6～8bar, when temperature in the kettle reaches temperature of reaction and is 55～65 ℃, with high-pressure metering pump, add at full speed 0.05 part of oxygenant ammonium persulphate, from adding ammonium persulphate, start at, after reaction 3.5～4.5h, finish reaction, close ethene intake valve, be cooled to 40 ℃ of following pressure release dischargings and obtain polymeric reaction product;
4), breakdown of emulsion is purified
The method that breakdown of emulsion is purified can adopt conventional breaking method, preferably adopt freeze-thaw method: by above-mentioned polymeric reaction product under-10 ℃～-5 ℃ conditions, freezing 5～12 hours, then the polymeric reaction product after freezing is placed and thawed for 2～5 hours at 20 ℃～25 ℃, filter, in the air dry oven of 75～85 ℃, dry and within 6～8 hours, obtain PE modified vinyl acetate resin;
5), dissolve saponification
The above-mentioned PE modified vinyl acetate resin obtaining after dry is dissolved in methyl alcohol, is mixed with massfraction and is 10～14% solution, add alkali lye to carry out alcoholysis, obtain vinyl modified polyvinyl alcohol product; Described alkali lye be the methanol solution of NaOH, the quality percentage composition of solute NaOH is 33.15%, the mol ratio of described alkali lye and PE modified vinyl acetate resin is 0.02:1.
The present invention has following beneficial effect:
The vinyl modified polyvinyl alcohol that preparation method of the present invention makes, contents of ethylene is 3～15%(mol), the content of sodium vinyl sulfonate group is 0.2～2%(mol), alcoholysis degree is 95.67～99.72%(mol); It is applied in the letex polymerizations such as vinyl acetate between to for plastic, VAE as reagent and additive in polymerization, has overcome the shortcomings such as conventional PVA poor water resistance, polymerization system be unstable, and its water tolerance obviously improves, particle diameter 0.508 μ m, solubility rate can be low to moderate 0%; Good water solubility, can meet it as the service requirements of reagent and additive in polymerization completely, it uses excellent in stability, the surface tension of polymerization system can be low to moderate 42.24(mN/M as reagent and additive in polymerization simultaneously), size distribution is significantly improved, referring to the compliance test result of embodiment part.
Preparation method of the present invention has realized under lower pressure and has prepared complete alcoholysis type vinyl modified polyvinyl alcohol by letex polymerization, through the yield rate of its vinyl modified polyvinyl alcohol making of control of order of addition(of ingredients), reaches 95%～99.8%.In preparation polymerization process, used micro-reactive emulsifier, make on macromolecular chain with micro-emulsifying agent segment, the complete alcoholysis type polyvinyl alcohol of this modification kind is due to the introducing of vinyl and appropriate emulsifying agent segment, make macromolecular chain form the hydrophilic two ends of oleophylic, the surfactivity of comparing conventional its aqueous solution of complete alcoholysis type polyvinyl alcohol increases, when meeting water tolerance, also make emulsion polymerization systems stable, while is due to the unique texture of ethene modified polyvinyl alcohol, viscosity stability is better, uses more convenient.
Accompanying drawing explanation
Fig. 1 is the qualitative infrared analysis collection of illustrative plates that modified polyvinyl alcohol medium vinyl of the present invention is rolled into a ball.
Fig. 2 is the quantitative nmr analysis collection of illustrative plates that modified polyvinyl alcohol medium vinyl of the present invention is rolled into a ball.
Fig. 3 is that modified polyvinyl alcohol of the present invention is for letex polymerization emulsion particle diameter distribution tests figure.
Embodiment
Below by embodiment, the present invention is specifically described; be necessary to be pointed out that at this; following examples are only for being further detailed the present invention; can not be interpreted as limiting the scope of the invention, the person skilled in the art in this field can make some nonessential improvement and adjustment to the present invention according to foregoing invention content.
The preparation of vinyl modified polyvinyl alcohol, as follows:
1), initial charge
84～87 parts of soft water, 0.04～0.06 part of reductive agent sodium bisulfite, 0.4～0.6 part of emulsifying agent sodium vinyl sulfonate being added in high pressure stainless steel cauldron, tighten lid, is that under 150～210rpm, stirring at normal temperature is even at rotating speed, standing 25～35min;
2), displacement in still
N with 8～12bar
2displacement twice, then replace twice with the ethene of 8～12bar, each displacement continues 3～5min;
3), add monomer, oxygenant carries out polymerization
In above-mentioned still, after displacement, with high-pressure metering pump, add at full speed 20～25 parts of Vinyl Acetate Monomers, pass into vinyl monomer, controlling still internal pressure is 3～10bar, when temperature in the kettle reaches temperature of reaction and is 55～65 ℃, with high-pressure metering pump, add at full speed 0.05～0.06 part of oxygenant ammonium persulphate, from adding oxygenant, start at, after reaction 3.5～4.5h, finish reaction, close ethene intake valve, be cooled to 40 ℃ of following pressure release dischargings and obtain polymeric reaction product;
4), breakdown of emulsion is purified
The method that breakdown of emulsion is purified can adopt conventional breaking method, preferably adopt freeze-thaw method: by above-mentioned polymeric reaction product under-10 ℃～-5 ℃ conditions, freezing 5～12 hours, then the polymeric reaction product after freezing is placed and thawed for 2～5 hours at 20 ℃～25 ℃, filter, in the air dry oven of 75～85 ℃, dry and within 6～8 hours, obtain PE modified vinyl acetate resin;
5), dissolve saponification
The above-mentioned PE modified vinyl acetate resin obtaining after dry is dissolved in methyl alcohol, is mixed with massfraction and is 10～14% solution, add alkali lye to carry out alcoholysis, obtain vinyl modified polyvinyl alcohol product; Described alkali lye be the methanol solution of NaOH, the quality percentage composition of solute NaOH is 33.15%, the mol ratio of described alkali lye and PE modified vinyl acetate resin is 0.02:1.
The vinyl modified polyvinyl alcohol making by above-mentioned preparation method, its structural formula is as follows:
r wherein
1=C
nh
2n+1, n=0～16, R
2for H, R
3for Na; Wherein record according to a conventional method a/a+b=97～99% (mol), recording as follows c is 0.2～0.8%(mol), to record d be 3～7%(mol).
Above-mentioned initiator also can adopt ammonium persulphate/sodium bisulfite, Potassium Persulphate/sodium bisulfite, hydrogen peroxide/tartrate, hydrogen peroxide/rongalite, ammonium persulphate/ferrous sulfate, hydrogen peroxide/sulfuric acid ferrous iron, Potassium Persulphate/Silver Nitrate, persulphate/mercaptan, Potassium Persulphate/iron protochloride or hydrogen peroxide/iron protochloride; Mentioned emulsifier also can adopt alkyl vinylformic acid-2-ethanesulfonic acid sodium, 2.2-acrylamide-2.2-dimethyl ethyl sulfonic acid sodium, sodium p styrene sulfonate or maleic acid higher alcohols monoesters sodium.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, has overcome the shortcomings such as conventional PVA poor water resistance, polymerization system be unstable, and its water tolerance obviously improves; Good water solubility, can meet it as the service requirements of reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
Below the above-mentioned vinyl modified polyvinyl alcohol making is carried out to qualitative, quantitative verification:
(1), vinyl group qualitative and quantitative is measured
(1) infared spectrum
Ethene modified polyvinyl alcohol and vinyl acetate between to for plastic homopolymer difference are to have a small peak at wave number 745cm-1 place as can be seen from Figure 1, this is-continuous more than 4 characteristic peak of unit of CH2-exist in macromolecular chain, but wave number is bigger than normal, illustrate-CH2-CH2-content less, proved the constitutional features of ethene modified polyvinyl alcohol.
(2) nuclear magnetic spectrum
Fig. 2 is shown in the quantitative assay of vinyl group,
By calculating methylene radical and methyne two peak intensity ratios, show that ethylene content is 3-7%(mol).The test of above-mentioned ethylene content is to adopt nuclear-magnetism method.
(2), the mensuration of reactive sodium group
The test of reactive sodium group is to adopt elemental microanalysis method, specific as follows: vinyl modified polyvinyl alcohol is clean with formic acid extraction, 70 ℃ of vacuum-dryings 20 hours, again sample is cooled in moisture eliminator to room temperature, adopt elemental analyser, measure the content of element S, and then the content that calculates vinylsulfonate is 0.2～0.8%(mol).
A preparation method for vinyl modified polyvinyl alcohol, what this preparation method adopted is emulsion polymerization; It comprises following step:
1, the sodium bisulfite of 0.08 weight part is dissolved in water, 0.6 parts by weight of ethylene base sodium sulfonate is dissolved in water and adds together in 10L autoclave, total consumption of water is 82 parts, tighten the lid of charging opening, leak test pressure testing, open and stir, speed setting is 210rpm, stirs, standing 35min;
2, adopt the N of 12bar
2displacement twice, then replace twice with the ethene of 12bar, each time swap continues 3min;
3, the Vinyl Acetate Monomer that adds at full speed 40 weight parts with high-pressure metering pump, pass into vinyl monomer, setting still internal pressure is 3bar, when temperature in the kettle reaches 65 ℃, 0.045 weight part ammonium persulphate is soluble in water, with high-pressure metering pump, squeeze at full speed in still, setting top temperature in still is 80 ℃, when temperature in the kettle surpasses 80 ℃ of programs, automatically open still inner coil pipe water of condensation fast cooling, lower than 80 ℃ of programs, automatically close still inner coil pipe water of condensation;
From adding ammonium persulphate to count, after reaction 4.5h, finish reaction, close ethene intake valve, be cooled to 40 ℃ of following pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 12h at-10 ℃, the 2h that then thaws under room temperature, filters and to obtain PE modified vinyl acetate resin, and is placed in the air dry oven of 85 ℃ and dries 6 hours;
5, the above-mentioned PE modified vinyl acetate resin obtaining after dry is dissolved in methyl alcohol, is mixed with massfraction and is 8% solution, add alkali lye to carry out alcoholysis, obtain vinyl modified polyvinyl alcohol product of the present invention; Described alkali lye be the methanol solution of NaOH, the quality percentage composition of solute NaOH is 35%, the mol ratio of described alkali lye and PE modified vinyl acetate resin is 0.02:1; Measuring its ethylene content is 3%(mol), sodium vinyl sulfonate group content is 2%(mol).
The test of above-mentioned contents of ethylene is to adopt nuclear-magnetism method.
The test of above-mentioned reactive sodium group is to adopt elemental microanalysis method, specific as follows: vinyl modified polyvinyl alcohol is clean with formic acid extraction, 70 ℃ of vacuum-dryings 20 hours, again sample is cooled in moisture eliminator to room temperature, adopt elemental analyser, measure the content of element S, and then calculate the content of sodium vinyl sulfonate.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, has overcome the shortcomings such as conventional PVA poor water resistance, polymerization system be unstable, and its water tolerance obviously improves; Good water solubility, can meet it as the service requirements of reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
A preparation method for vinyl modified polyvinyl alcohol, it carries out according to the following steps:
1, the sodium bisulfite of 0.02 weight part is dissolved in water, 0.2 parts by weight of ethylene base sodium sulfonate is dissolved in water and adds together in 10L autoclave, total consumption of water is 88 parts, tighten the lid of charging opening, leak test pressure testing, open and stir, speed setting is 150rpm, stirs, standing 30min;
2, adopt the N of 8bar
2displacement twice, then replace twice with the ethene of 8bar, each time swap continues 4min;
3, the Vinyl Acetate Monomer that adds at full speed 10 weight parts with high-pressure metering pump, pass into vinyl monomer, setting still internal pressure is 20bar, when temperature in the kettle reaches 55 ℃, 0.065 weight part ammonium persulphate is soluble in water, with high-pressure metering pump, squeeze at full speed in still, setting top temperature in still is 65 ℃, when temperature in the kettle surpasses 65 ℃ of programs, automatically open still inner coil pipe water of condensation fast cooling, lower than 65 ℃ of programs, automatically close still inner coil pipe water of condensation;
From adding ammonium persulphate to count, after reaction 4.0h, finish reaction, close ethene intake valve, be cooled to 40 ℃ of following pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 5h at-7 ℃, the 3h that then thaws under room temperature, filters and to obtain PE modified vinyl acetate resin, and is placed in the air dry oven of 78 ℃ and dries 7 hours;
5, the above-mentioned PE modified vinyl acetate resin obtaining after dry is dissolved in methyl alcohol, is mixed with massfraction and is 20% solution, add alkali lye to carry out alcoholysis, obtain vinyl modified polyvinyl alcohol product of the present invention; Described alkali lye be the methanol solution of NaOH, the quality percentage composition of solute NaOH is 30%, the mol ratio of described alkali lye and PE modified vinyl acetate resin is 0.02:1; Measuring its ethylene content is 15%(mol), sodium vinyl sulfonate group content is 0.2%(mol).
The test of above-mentioned contents of ethylene is to adopt nuclear-magnetism method.
The test of above-mentioned reactive sodium group is to adopt elemental microanalysis method, specific as follows: vinyl modified polyvinyl alcohol is clean with formic acid extraction, 70 ℃ of vacuum-dryings 20 hours, again sample is cooled in moisture eliminator to room temperature, adopt elemental analyser, measure the content of element S, and then calculate the content of vinylsulfonate.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, has overcome the shortcomings such as conventional PVA poor water resistance, polymerization system be unstable, and its water tolerance obviously improves; Good water solubility, can meet it as the service requirements of reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
A preparation method for vinyl modified polyvinyl alcohol, what this preparation method adopted is emulsion polymerization; It comprises following step:
1,2.3172g sodium bisulfite is dissolved in 200g water, 16.25g sodium vinyl sulfonate is dissolved in 1000g water and adds in 10L autoclave together with 3447g water, tighten the lid of charging opening, leak test pressure testing, opens and stirs, speed setting is 160rpm, stirs, standing 25min;
2, adopt the N of 10bar
2displacement twice, then replace twice with the ethene of 10bar, each time swap continues 5min;
3, with high-pressure metering pump, add at full speed 810.32g Vinyl Acetate Monomer, pass into vinyl monomer, setting still internal pressure is 7bar, when temperature in the kettle reaches 58 ℃, 2.6025g ammonium persulphate is dissolved in 100g water, with high-pressure metering pump, squeezes at full speed in still, setting top temperature in still is 70 ℃, when temperature in the kettle surpasses 70 ℃ of programs, automatically open still inner coil pipe water of condensation fast cooling, lower than 70 ℃ of programs, automatically close still inner coil pipe water of condensation;
From adding ammonium persulphate to count, after reaction 3.5h, finish reaction, close ethene intake valve, be cooled to 40 ℃ of following pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 12h at-5 ℃, the 5h that then thaws under room temperature, filters and to obtain PE modified vinyl acetate resin, and is placed in the air dry oven of 75 ℃ and dries 8 hours;
5, by this resin after drying, it according to weight ratio, is the proportioning wiring solution-forming of resin: methyl alcohol=1:10, at 45 ℃, constant temperature is after half an hour, adding mass percent is 34% sodium hydrate methanol solution alcoholysis 1.5 hours, refilter afterwards, dry, can obtain product of the present invention, measuring its contents of ethylene is 5%(mol), sodium vinyl sulfonate group content is 0.3%(mol).
The test of above-mentioned contents of ethylene is to adopt nuclear-magnetism method.
The test of above-mentioned reactive sodium group is to adopt elemental microanalysis method, specific as follows: vinyl modified polyvinyl alcohol is clean with formic acid extraction, 70 ℃ of vacuum-dryings 20 hours, again sample is cooled in moisture eliminator to room temperature, adopt elemental analyser, measure the content of element S, and then calculate the content of vinylsulfonate.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, has overcome the shortcomings such as conventional PVA poor water resistance, polymerization system be unstable, and its water tolerance obviously improves; Good water solubility, can meet it as the service requirements of reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
A preparation method for vinyl modified polyvinyl alcohol, what this preparation method adopted is emulsion polymerization; It comprises following step:
1,2.6536g sodium bisulfite is dissolved in 200g water, 17.35g vinyl sulfonic acid potassium is dissolved in 1000g water and adds in 10L autoclave together with 3528g water, tighten the lid of charging opening, leak test pressure testing, opens and stirs, speed setting is 175rpm, stirs, standing 28min;
2, use the N of 10bar
2displacement twice, then replace twice with the ethene of 10bar;
3, with high-pressure metering pump, add at full speed 815.36g Vinyl Acetate Monomer, setting still internal pressure is 7bar, when temperature in the kettle reaches 61 ℃, 2.7023g Potassium Persulphate is dissolved in 100g water, with high-pressure metering pump, squeeze at full speed in still, setting top temperature in still is 73 ℃, when temperature in the kettle surpasses 73 ℃ of programs, automatically opens still inner coil pipe water of condensation fast cooling, lower than 73 ℃ of programs, automatically closes still inner coil pipe water of condensation;
From adding Potassium Persulphate to count, after reaction 4h, finish reaction, close ethene intake valve, be cooled to 40 ℃ of following pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 5h at-10 ℃, the 2h that then thaws under room temperature, filters and to obtain PE modified vinyl acetate resin, and is placed in the air dry oven of 78 ℃ and dries 6 hours;
5, by this resin after drying, it according to weight ratio, is the proportioning wiring solution-forming of resin: methyl alcohol=1:9, at 40 ℃, constant temperature is after half an hour, adding mass percent is 33.15% sodium hydroxide solution alcoholysis 2 hours, refilter afterwards, dry, can obtain finished product of the present invention, measuring its contents of ethylene is 5%(mol), vinyl sulfonic acid potassium group content is 0.35%(mol); Measuring method is the same.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, has overcome the shortcomings such as conventional PVA poor water resistance, polymerization system be unstable, and its water tolerance obviously improves; Good water solubility, can meet it as the service requirements of reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
A preparation method for vinyl modified polyvinyl alcohol, what this preparation method adopted is emulsion polymerization; It comprises following step:
1,2.7098g ferrous sulfate is dissolved in 200g water, 18.28g sodium p styrene sulfonate is dissolved in 1000g water and adds in 10L autoclave together with 3578g water, tighten the lid of charging opening, leak test pressure testing, opens and stirs, speed setting is 180rpm, stirs, standing 32min;
2, use the N of 11bar
2displacement twice, then replace twice with the ethene of 11bar;
3, with high-pressure metering pump, add at full speed 856.37g Vinyl Acetate Monomer, setting still internal pressure is 8bar, when temperature in the kettle reaches 62 ℃, 2.9576g ammonium persulphate is dissolved in 100g water, with high-pressure metering pump, squeeze at full speed in still, setting top temperature in still is 75 ℃, when temperature in the kettle surpasses 75 ℃ of programs, automatically opens still inner coil pipe water of condensation fast cooling, lower than 75 ℃ of programs, automatically closes still inner coil pipe water of condensation;
From adding ammonium persulphate to count, after reaction 4h, finish reaction, close ethene intake valve, be cooled to 40 ℃ of following pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 8h at-8 ℃, the 3.5h that then thaws under room temperature, filters and to obtain PE modified vinyl acetate resin, and is placed in the air dry oven of 73 ℃ and dries 7 hours;
5, by this resin after drying, it according to weight ratio, is the proportioning wiring solution-forming of resin: methyl alcohol=1:11, at 38 ℃, constant temperature is after half an hour, adding mass percent is 32% sodium hydroxide solution alcoholysis 1 hour, refilter afterwards, dry, can obtain finished product of the present invention, measuring its contents of ethylene is 6%(mol), sodium p styrene sulfonate group content is 0.4%(mol); Measuring method is the same.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, has overcome the shortcomings such as conventional PVA poor water resistance, polymerization system be unstable, and its water tolerance obviously improves; Good water solubility, can meet it as the service requirements of reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
A preparation method for vinyl modified polyvinyl alcohol, what this preparation method adopted is emulsion polymerization; It comprises following step:
1,3.0174g Silver Nitrate is dissolved in 200g water, 19.57g sodium p styrene sulfonate is dissolved in 1000g water and adds in 10L autoclave together with 3654g water, tighten the lid of charging opening, leak test pressure testing, opens and stirs, speed setting is 180rpm, stirs, standing 32min;
2, use the N of 9bar
2displacement twice, then replace twice with the ethene of 9bar;
3, with high-pressure metering pump, add at full speed 862.95g Vinyl Acetate Monomer, setting still internal pressure is 10bar, when temperature in the kettle reaches 65 ℃, 3.2546g Potassium Persulphate is dissolved in 100g water, with high-pressure metering pump, squeeze at full speed in still, setting top temperature in still is 78 ℃, when temperature in the kettle surpasses 78 ℃ of programs, automatically opens still inner coil pipe water of condensation fast cooling, lower than 78 ℃ of programs, automatically closes still inner coil pipe water of condensation;
From adding Potassium Persulphate to count, after reaction 4h, finish reaction, close ethene intake valve, be cooled to 40 ℃ of following pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 6h at-10 ℃, the 4h that then thaws under room temperature, filters and to obtain PE modified vinyl acetate resin, and is placed in the air dry oven of 72.5 ℃ and dries 8 hours;
5, by this resin after drying, it according to weight ratio, is the proportioning wiring solution-forming of resin: methyl alcohol=1:10, at 40 ℃, constant temperature is after half an hour, adding mass percent is 33% sodium hydroxide solution alcoholysis 1.5 hours, refilter afterwards, dry, can obtain finished product of the present invention, measuring its contents of ethylene is 8%(mol), sodium p styrene sulfonate group content is 0.43%(mol); Measuring method is the same.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, has overcome the shortcomings such as conventional PVA poor water resistance, polymerization system be unstable, and its water tolerance obviously improves; Good water solubility, can meet it as the service requirements of reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
A preparation method for vinyl modified polyvinyl alcohol, what this preparation method adopted is emulsion polymerization; It comprises following step:
1,3.3269g iron protochloride is dissolved in 200g water, 25.49g p styrene sulfonic acid potassium is dissolved in 1000g water and adds in 10L autoclave together with 3689g water, tighten the lid of charging opening, leak test pressure testing, opens and stirs, speed setting is 200rpm, stirs, standing 34min;
2, use the N of 10bar
2displacement twice, then replace twice with the ethene of 10bar;
3, with high-pressure metering pump, add at full speed 875.26g Vinyl Acetate Monomer, setting still internal pressure is 12bar, when temperature in the kettle reaches 64 ℃, 3.5197g Potassium Persulphate is dissolved in 100g water, with high-pressure metering pump, squeeze at full speed in still, setting top temperature in still is 80 ℃, when temperature in the kettle surpasses 80 ℃ of programs, automatically opens still inner coil pipe water of condensation fast cooling, lower than 80 ℃ of programs, automatically closes still inner coil pipe water of condensation;
From adding Potassium Persulphate to count, after reaction 4h, finish reaction, close ethene intake valve, be cooled to 40 ℃ of following pressure release dischargings and obtain polymeric reaction product;
4, by gained polymeric reaction product freezing 10h at-7 ℃, the 3.5h that then thaws under room temperature, filters and to obtain PE modified vinyl acetate resin, and is placed in the air dry oven of 76 ℃ and dries 6 hours;
5, by this resin after drying, it according to weight ratio, is the proportioning wiring solution-forming of resin: methyl alcohol=1:10, at 40 ℃, constant temperature is after half an hour, adding mass percent is 31% sodium hydroxide solution alcoholysis 2 hours, refilter afterwards, dry, can obtain finished product of the present invention, measuring its contents of ethylene is 9%(mol), p styrene sulfonic acid potassium group content is 0.53%(mol); Measuring method is the same.
Above-mentioned vinyl modified polyvinyl alcohol is applied in letex polymerization as reagent and additive in polymerization, has overcome the shortcomings such as conventional PVA poor water resistance, polymerization system be unstable, and its water tolerance obviously improves; Good water solubility, can meet it as the service requirements of reagent and additive in polymerization completely, it uses excellent in stability of polymerization system as reagent and additive in polymerization simultaneously, and size distribution is significantly improved.
Application comparative example 1
The emulsion vinyl modified polyvinyl alcohol of preparing with pressure, by doing application experiment with conventional polyvinyl alcohol contrast, the contribution that checking ethene modified polyvinyl alcohol improves emulsion water tolerance, the improvement that emulsion particle diameter distributes and the improvement of polymerization system stability, result is as follows:
(1), PE modified polyvinyl alcohol (YPS series) is as the letex polymerization application of protective colloid, water tolerance experimental result, in Table 1:
Table 1
Wherein YPS-I, YPS-II and YPS-III are that the vinyl modified polyvinyl alcohol that embodiment of the present invention 4-6 makes has further verified that by upper table vinyl modified polyvinyl alcohol can obviously improve the water tolerance of emulsion.
(2) size distribution of above-mentioned emulsion is tested, result is as Fig. 3.
By Fig. 3 result, can be found out, vinyl modified polyvinyl alcohol can obviously improve the size distribution of emulsion.
(3), PE modified polyvinyl alcohol (YPS series) is as the letex polymerization application of protective colloid, stability experiment result, in Table 2:
Table 2
| Sample number | Protective colloid | Surface tension (mN/M) |
| AP-01 | Conventional complete alcoholysis type polyvinyl alcohol | 63.63 |
| AP-02 | YPS-Ⅰ | 44.43 |
| AP-03 | YPS-Ⅱ | 46.47 |
| AP-04 | YPS-III | 42.24 |
YPS-I, YPS-II and YPS-III be the vinyl modified polyvinyl alcohol that makes of embodiment of the present invention 4-6 as table 2, the surface tension of the aqueous solution is less, surfactivity is higher, is more easy to carry out stable polymerization.
(4), solubility property is measured as table 3:
Table 3
| Sample number into spectrum | Dissolution time (min) | Solvent temperature (℃) | Experimental phenomena |
| 1799 | 80 | 90 | Dissolve completely clear |
| YPS-Ⅰ | 50 | 90 | Dissolve completely clear |
| YPS- |
50 | 90 | Dissolve completely clear |
| YPS-Ⅲ | 48 | 90 | Dissolve completely clear |
YPS-I, YPS-II and YPS-III are the vinyl modified polyvinyl alcohol that embodiment of the present invention 4-6 makes
(5), viscosity stability is measured as table 4:
Table 4
YPS-I, YPS-II and YPS-III are the vinyl modified polyvinyl alcohol viscosity test condition that embodiment of the present invention 4-6 makes: 20 ℃, and rotational viscosimeter.
Claims (10)
1. the preparation method of a vinyl modified polyvinyl alcohol, it is characterized in that: it is that to take 82～88 parts, water, 0.02～0.08 part of reductive agent, 0.2～0.6 part of emulsifying agent, 10～40 parts of Vinyl Acetate Monomers, 0.045～0.065 part, oxygenant and vinyl monomer be raw material, displacement in initial charge, still, polyreaction, breakdown of emulsion are purified and saponification step makes vinyl modified polyvinyl alcohol, the consumption of therein ethylene monomer be the still internal pressure of controlling while passing into vinyl monomer be 3～20bar, pass into the reaction times and be the vinyl monomer consumption of 3.5～4.5 hours meters; Described emulsifying agent is reactive sulfonate.
2. preparation method as claimed in claim 1, is characterized in that: described emulsifying agent is alkyl vinylformic acid-2-ethanesulfonic acid sodium, vinyl alkyl sodium sulfonate, 2.2-acrylamide-2.2-dimethyl ethyl sulfonic acid sodium, sodium p styrene sulfonate or maleic acid higher alcohols monoesters sodium.
3. preparation method as claimed in claim 1, is characterized in that: described emulsifying agent is vinyl sulfonic acid an alkali metal salt.
4. preparation method as claimed in claim 3, is characterized in that: described emulsifying agent is sodium vinyl sulfonate or vinyl sulfonic acid potassium.
5. the preparation method as described in claim 1,2,3 or 4, is characterized in that: described oxygenant/reductive agent is ammonium persulphate/sodium bisulfite, Potassium Persulphate/sodium bisulfite, hydrogen peroxide/tartrate, hydrogen peroxide/rongalite, ammonium persulphate/ferrous sulfate, hydrogen peroxide/sulfuric acid ferrous iron, Potassium Persulphate/Silver Nitrate, persulphate/mercaptan, Potassium Persulphate/iron protochloride or hydrogen peroxide/iron protochloride.
6. preparation method as claimed in claim 5, is characterized in that: described oxygenant/reductive agent is ammonium persulphate/sodium bisulfite.
7. the preparation method as described in claim 5 or 6, it is characterized in that: described each raw materials is 84～87 parts, water, 0.04～0.06 part of reductive agent, 0.4～0.6 part of emulsifying agent vinyl sulfonic acid an alkali metal salt, 20～25 parts of Vinyl Acetate Monomers, 0.05～0.06 part, oxygenant and vinyl monomer, the still internal pressure of the consumption of therein ethylene monomer when passing into vinyl monomer be 3～10bar, pass into the reaction times is 3.5～4.5 hours.
8. preparation method as claimed in claim 1, it is characterized in that: described each raw material is 86 parts of soft water, 0.05 part of reductive agent sodium bisulfite, 0.4 part of emulsifying agent sodium vinyl sulfonate, 23 parts of Vinyl Acetate Monomers, 0.05 part of oxygenant ammonium persulphate and vinyl monomer, the still internal pressure of the consumption of therein ethylene monomer when passing into vinyl monomer be 6～8bar, pass into the reaction times is 3.5～4.5 hours.
9. preparation method as claimed in claim 1, it is characterized in that: described preparation method is with 86 parts of soft water, 0.05 part of reductive agent sodium bisulfite, 0.4 part of emulsifying agent sodium vinyl sulfonate, 23 parts of Vinyl Acetate Monomers, 0.05 part of oxygenant ammonium persulphate and vinyl monomer are raw material, through initial charge, displacement in still, polyreaction, breakdown of emulsion is purified and saponification step makes vinyl modified polyvinyl alcohol, described initial charge is by described soft water, reductive agent and emulsifying agent add in reactor, described polyreaction is in reactor, to add described Vinyl Acetate Monomer, pass into vinyl monomer, controlling still internal pressure is 6～8bar, when temperature in the kettle reaches 55～65 ℃ of temperature of reaction, add described oxygenant, from adding oxygenant, start at, after reaction 3.5～4.5h, finish reaction.
10. a preparation method for vinyl modified polyvinyl alcohol, is characterized in that, carries out as follows:
1), initial charge
86 parts of soft water, 0.05 part of reductive agent sodium bisulfite, 0.4 part of emulsifying agent sodium vinyl sulfonate being added in high pressure stainless steel cauldron, tighten lid, is that under 150～210rpm, stirring at normal temperature is even at rotating speed, standing 25～35min;
2), displacement in still
N with 8～12bar
2displacement twice, then replace twice with the ethene of 8～12bar, each displacement continues 3～5min;
3), add monomer, oxygenant carries out polymerization
In above-mentioned still, after displacement, with high-pressure metering pump, add at full speed 23 parts of Vinyl Acetate Monomers, pass into vinyl monomer, controlling still internal pressure is 6～8bar, when temperature in the kettle reaches temperature of reaction and is 55～65 ℃, with high-pressure metering pump, add at full speed 0.05 part of oxygenant ammonium persulphate, from adding ammonium persulphate, start at, after reaction 3.5～4.5h, finish reaction, close ethene intake valve, be cooled to 40 ℃ of following pressure release dischargings and obtain polymeric reaction product;
4), breakdown of emulsion is purified
The method that breakdown of emulsion is purified can adopt conventional breaking method, preferably adopt freeze-thaw method: by above-mentioned polymeric reaction product under-10 ℃～-5 ℃ conditions, freezing 5～12 hours, then the polymeric reaction product after freezing is placed and thawed for 2～5 hours at 20 ℃～25 ℃, filter, in the air dry oven of 75～85 ℃, dry and within 6～8 hours, obtain PE modified vinyl acetate resin;
5), dissolve saponification
The above-mentioned PE modified vinyl acetate resin obtaining after dry is dissolved in methyl alcohol, is mixed with massfraction and is 10～14% solution, add alkali lye to carry out alcoholysis, obtain vinyl modified polyvinyl alcohol product; Described alkali lye be the methanol solution of NaOH, the quality percentage composition of solute NaOH is 33.15%, the mol ratio of described alkali lye and PE modified vinyl acetate resin is 0.02:1.
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