CN103723973A - Fiber-reinforced cement lightweight insulating FLIC board and preparation method thereof - Google Patents

Fiber-reinforced cement lightweight insulating FLIC board and preparation method thereof Download PDF

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Publication number
CN103723973A
CN103723973A CN201310694167.8A CN201310694167A CN103723973A CN 103723973 A CN103723973 A CN 103723973A CN 201310694167 A CN201310694167 A CN 201310694167A CN 103723973 A CN103723973 A CN 103723973A
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China
Prior art keywords
cement
water
fibre reinforced
thistle board
board
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Pending
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CN201310694167.8A
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Chinese (zh)
Inventor
徐建军
周永峰
杨江金
雷文晗
蒋青青
孙寅斌
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CHANGZHOU ARCHITECTURAL RESEARCH INSTITUTE Co Ltd
JIANGSU NIGAO TECHNOLOGY Co Ltd
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CHANGZHOU ARCHITECTURAL RESEARCH INSTITUTE Co Ltd
JIANGSU NIGAO TECHNOLOGY Co Ltd
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Priority to CN201310694167.8A priority Critical patent/CN103723973A/en
Publication of CN103723973A publication Critical patent/CN103723973A/en
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/50Reuse, recycling or recovery technologies
    • Y02W30/91Use of waste materials as fillers for mortars or concrete

Abstract

The invention discloses a fiber-reinforced cement lightweight insulating FLIC board and a preparation method thereof. The insulating board comprises a composite foamed cement board, alkali-resistant glass fiber meshes and polymer cement mortar reinforcing layers; the alkali-resistant glass fiber meshes are adhered to the upper and lower surfaces of the composite foamed cement board; the polymer cement mortar reinforcing layers are arranged on the upper and lower surfaces and four lateral surfaces of the composite foamed cement board in manners of spraying, dipping or scraping and the like. The preparation method of the fiber-reinforced cement lightweight insulating FLIC board comprises the following steps: preparing the composite foamed cement board; adhering the alkali-resistant glass fiber meshes to the upper and lower surfaces of the prepared composite foamed cement board; preparing polymer cement mortar; coating the polymer cement mortar on the upper and lower surfaces and four lateral surfaces of the composite foamed cement board in a manner of spraying, dipping or scraping and the like and placing for 1 to 3 days. The fiber-reinforced cement lightweight insulating FLIC board has the advantages of low water absorption, excellent mechanical property, low heat conductivity coefficient, good integrity, no cracking phenomenon, A-level fire prevention, same service life with a building and the like.

Description

Fibre reinforced cement light thermal-insulation FLIC plate and preparation method thereof
Technical field
The present invention relates to building thermal insulation material field, particularly relate to a kind of fibre reinforced cement FC thistle board and preparation method thereof.
Background technology
Composite foaming cement plate is certificate A level fire-retardant heat-insulation material complete, free from controversy few in number in the market, have that intensity is high, light weight, thermal conductivity be low, and synchronize work-ing life with buildings, be greatly better than the advantages such as styrofoam (general work-ing life 20-25).But because its market threshold is low, small business is in the majority, state of the art is not high, and the equipment of buying is given formula, though can send bubble, inner quality is poor, loose (intensity is low), fragility is large, dry linting, cracking, water-intake rate are high, and density is large, heat insulation effect is poor.Some durability of product are poor, put crisper and crisper, and efflorescence, obscission appear in upper wall, and these have all seriously ruined the overall image of composite foaming cement board industry.
Summary of the invention
The technical problem that the present invention mainly solves be to provide a kind ofly have that water-intake rate is low, mechanical property is excellent, thermal conductivity is low, good integrity, do not ftracture, with same life-span of buildings, A level fp fibre reinforced cement FC thistle board and preparation method thereof.
For solving the problems of the technologies described above, the technical scheme that the present invention adopts is: a kind of fibre reinforced cement FC thistle board is provided, comprise composite foaming cement flaggy, alkali-resisting glass fiber scrim layer and polymer cement mortar enhancement layer, polymer cement mortar enhancement layer is by spraying, soaking paste or scrape the mode brushing of slurry in upper and lower surface and four sides thereof of composite foaming cement flaggy, and alkali-resisting glass fiber scrim layer is located between composite foaming cement flaggy and polymer cement mortar enhancement layer.
In a preferred embodiment of the present invention, described composite foaming cement plate is made by cement, flyash, hydrophober, water reducer, exciting agent, anti-crack fiber, water and composite foamable agent, and the parts by weight proportioning of each component is:
Cement 70-90 part,
Flyash 10-30 part,
Hydrophober 0.6-3.0 part,
Water reducer 0.12-0.30 part,
Exciting agent 1.0-2.5 part
Anti-crack fiber 0.3-0.50 part,
Water 30-60 part,
Composite foamable agent 4-8 part.
In a preferred embodiment of the present invention, the dry density of described composite foaming cement plate is less than 250 kg/m 3.
In a preferred embodiment of the present invention, described polymer cement mortar is made by the raw material of following weight proportion: cement 60-80 part, redispersable latex powder 5-10 part and water 30-40 part.
In a preferred embodiment of the present invention, described cement is ordinary Portland cement or silicate cement, and described flyash is I level flyash.
In a preferred embodiment of the present invention, described hydrophober is stearate, and described hydrophober is stearate, and described water reducer is a kind of in naphthalene series high-efficiency water-reducing agent, melamine series high-efficiency water-reducing agent and polycarboxylic acid series high efficiency water reducing agent.
In a preferred embodiment of the present invention, described exciting agent is one or more mixing in trolamine, potassium hydroxide, nitrate, nitrite, sodium sulfate, sodium carbonate and lithium chloride, and described anti-crack fiber is one or more mixing in modified polypropylene fiber, trevira and vinylon fibre.
In a preferred embodiment of the present invention, a kind of in the multipolymer that described redispersable latex powder is ethylene/vinyl acetate, vinyl acetate between to for plastic/tertiary monocarboxylic acid ethylene copolymer and acrylic acid multipolymer.
For solving the problems of the technologies described above, another technical solution used in the present invention is: a kind of preparation method of fibre reinforced cement FC thistle board is provided, comprises the following steps:
(1) prepare composite foaming cement plate;
(2) in composite foaming cement plate upper and lower surface, paste alkali-resisting glass fiber screen cloth;
(3) prepare polymer cement mortar: cement, redispersable latex powder, according to weight proportion mixing 3-6 minute, are mixed, then add water to stir 2-4 minute, make polymer cement mortar;
(4) polymer cement mortar is brushed to upper and lower surface and four sides thereof at composite foaming cement plate by spraying, soaking paste or the mode of scraping slurry, place 1-3 days, make fibre reinforced cement FC thistle board.
In a preferred embodiment of the present invention, the preparation of described composite foaming cement plate is according to following steps:
(1) according to proportioning, weigh each component;
(2) first add water, anti-crack fiber, water reducer, hydrophober, cement and flyash, stir 2-3 minute, then add exciting agent, stir 1-2 minute, then add composite foamable agent, stir 5-10 second, make slurry;
(3) slurry of step (2) being made is put into mould, quietly stops form removal in 4-6 hour, cutting after 24 hours, packing, maintenance to 14 day.
The invention has the beneficial effects as follows: the present invention pastes alkali-resisting glass fiber screen cloth by the upper and lower surface of composite foaming cement plate, polymer cement mortar enhancement layer is by spraying, soaking paste or scrape the mode brushings such as slurry in upper and lower surface and four sides thereof of composite foaming cement plate, overcome composite foaming cement plate fragility large, easy to crack, water-intake rate is high, the shortcomings such as dry linting is serious, this composite insulation boards has water-intake rate low (water-intake rate is less than 5%), mechanical property is excellent, thermal conductivity is low, good integrity, do not ftracture, the fire prevention of A level, with buildings with advantages such as life-spans, can be applied to external thermal insulation system, fire-blocking belt, in heat preservation decoration integrative, it can be widely used in external thermal insulation system as an A level fire-retardant heat-insulation material.
Accompanying drawing explanation
Fig. 1 is the structural representation of fibre reinforced cement FC thistle board of the present invention one preferred embodiment;
In accompanying drawing, the mark of each parts is as follows: 1, composite foaming cement flaggy, 2, alkali-resisting glass fiber scrim layer, 3, polymer cement mortar enhancement layer.
Embodiment
Below preferred embodiment of the present invention is described in detail, thereby so that advantages and features of the invention can be easier to be it will be appreciated by those skilled in the art that, protection scope of the present invention is made to more explicit defining.
Refer to Fig. 1, a kind of fibre reinforced cement FC thistle board, comprise composite foaming cement flaggy 1, alkali-resisting glass fiber scrim layer 2 and polymer cement mortar enhancement layer 3, polymer cement mortar enhancement layer 3 is by spraying, soaking paste or scrape the mode brushing of slurry in upper and lower surface and four sides thereof of composite foaming cement flaggy 1, and alkali-resisting glass fiber scrim layer 2 is located between composite foaming cement flaggy 1 and polymer cement mortar enhancement layer 3.
Wherein, described light porous plate is made by cement, flyash, hydrophober, water reducer, exciting agent, anti-crack fiber, water and composite foamable agent, and the parts by weight proportioning of each component is:
Cement 70-90 part,
Flyash 10-30 part,
Hydrophober 0.6-3.0 part,
Water reducer 0.12-0.30 part,
Exciting agent 1.0-2.5 part
Anti-crack fiber 0.3-0.50 part,
Water 30-60 part,
Composite foamable agent 4-8 part.
Wherein, the dry density of described composite foaming cement plate is less than 250 kg/m 3.
Wherein, described tackiness agent is made by the raw material of following weight proportion: cement 60-80 part, redispersable latex powder 5-10 part and water 30-40 part.
Preferably, described cement is ordinary Portland cement or silicate cement, and described flyash is I level flyash.
Preferably, described hydrophober is stearate, and described water reducer is a kind of in naphthalene series high-efficiency water-reducing agent, melamine series high-efficiency water-reducing agent and polycarboxylic acid series high efficiency water reducing agent.
Preferably, described exciting agent is one or more mixing in trolamine, potassium hydroxide, nitrate, nitrite, sodium sulfate, sodium carbonate and lithium chloride, and described anti-crack fiber is one or more mixing in modified polypropylene fiber, trevira and vinylon fibre.
Preferably, a kind of in the multipolymer that described redispersable latex powder is ethylene/vinyl acetate, vinyl acetate between to for plastic/tertiary monocarboxylic acid ethylene copolymer and acrylic acid multipolymer.
The preparation method of fibre reinforced cement FC thistle board, its preparation process is as follows:
(1) preparation of composite foaming cement plate;
(2) prepare tackiness agent: cement, redispersable latex powder, according to weight proportion mixing 3-6 minute, are mixed, then add water to stir 2-4 minute;
(3) composite foaming cement plate upper and lower surface utilizes tackiness agent to paste alkali-resisting glass fiber screen cloth;
(4) prepare polymer cement mortar: cement, redispersable latex powder, according to weight proportion mixing 3-6 minute, are mixed, then add water to stir 2-4 minute;
(5) polymer cement mortar is brushed to upper and lower surface and four sides thereof at composite foaming cement plate by spraying, soaking paste or the mode of scraping slurry, place 1-3 days, obtain fibre reinforced cement FC thistle board.
Preferably, the preparation of described composite foaming cement plate is according to following steps:
(1) according to proportioning, weigh each component;
(2) first add water, anti-crack fiber, water reducer, hydrophober, cement and flyash, stir 2-3 minute, then add exciting agent, stir 1-2 minute, then add composite foamable agent, stir 5-10 second, make slurry;
(3) slurry of step (2) being made is put into mould, quietly stops form removal in 4-6 hour, cutting after 24 hours, packing, maintenance to 14 day.
Embodiment 1
The preparation method of fibre reinforced cement FC thistle board, its preparation process is as follows:
(1) preparation of composite foaming cement plate: a, according to proportioning, weigh 80 parts of ordinary Portland cements, 20 parts, flyash, 1.0 parts of hydrophober, 0.20 part of water reducer, 1.5 parts of exciting agents, 0.36 part of anti-crack fiber, 50 parts, water, 5 parts of composite foamable agents; B, first add water, anti-crack fiber, water reducer, hydrophober, ordinary Portland cement and flyash, stir 3 minutes, then add exciting agent, stir 1 minute, then add composite foamable agent, stir 5 seconds, make slurry; C, slurry is put into mould, quietly stop form removal in 5 hours, cutting after 24 hours, packing, maintenance 14 days;
(2) prepare tackiness agent: by 60 parts of cement, 9 parts of redispersable latex powders, mixing 3 minutes, mix, then add 31 parts of water to stir 2 minutes;
(3) composite foaming cement plate upper and lower surface is pasted alkali-resisting glass fiber screen cloth;
(4) prepare polymer cement mortar: by 60 parts of cement, 9 parts of redispersable latex powders, mixing 3 minutes, mix, then add 31 parts of water to stir 2 minutes;
(5) polymer cement mortar is brushed to upper and lower surface and four sides thereof at composite foaming cement plate by the mode of spraying, place 1-3 days.Obtain fibre reinforced cement FC thistle board.
Embodiment 2
Fibrocement strengthens the preparation method of FC warming plate, and its preparation process is as follows:
(1) preparation of composite foaming cement plate: a, according to proportioning, weigh 90 parts of ordinary Portland cements, 10 parts, flyash, 2.0 parts of hydrophober, 0.25 part of water reducer, 2.0 parts of exciting agents, 0.36 part of anti-crack fiber, 48 parts, water, 6 parts of composite foamable agents; B, first add water, anti-crack fiber, water reducer, hydrophober, ordinary Portland cement and flyash, stir 3 minutes, then add exciting agent, stir 2 minutes, then add composite foamable agent, stir 7 seconds, make slurry; C, slurry is put into mould, quietly stop form removal in 4 hours, cutting after 24 hours, packing, maintenance 14 days;
(2) prepare tackiness agent: by 70 parts of cement, 8 parts of redispersable latex powders, mixing 4 minutes, mix, then add 35 parts of water to stir 3 minutes;
(3) composite foaming cement plate upper and lower surface is pasted alkali-resisting glass fiber screen cloth;
(4) prepare polymer cement mortar: by 70 parts of cement, 8 parts of redispersable latex powders, mixing 4 minutes, mix, then add 35 parts of water to stir 3 minutes;
(5) polymer cement mortar is brushed to upper and lower surface and four sides thereof at composite foaming cement plate by the mode of soaking paste, place 1-3 days.Obtain fibre reinforced cement FC thistle board.
Embodiment 3
The preparation method of fibre reinforced cement FC thistle board, its preparation process is as follows:
(1) preparation of composite foaming cement plate: a, according to proportioning, weigh 80 parts of ordinary Portland cements, 20 parts, flyash, 1.8 parts of hydrophober, 0.25 part of water reducer, 1.8 parts of exciting agents, 0.40 part of anti-crack fiber, 48 parts, water, 7 parts of composite foamable agents; B, first add water, anti-crack fiber, water reducer, hydrophober, ordinary Portland cement and flyash, stir 2 minutes, then add exciting agent, stir 2 minutes, then add composite foamable agent, stir 10 seconds, make slurry; C, slurry is put into mould, quietly stop form removal in 6 hours, cutting after 24 hours, packing, maintenance 14 days;
(2) prepare tackiness agent: by 80 parts of cement, 5 parts of redispersable latex powders, mixing 6 minutes, mix, then add 40 parts of water to stir 3 minutes;
(3) composite foaming cement plate upper and lower surface is pasted alkali-resisting glass fiber screen cloth;
(4) prepare polymer cement mortar: by 80 parts of cement, 5 parts of redispersable latex powders, mixing 6 minutes, mix, then add 40 parts of water to stir 3 minutes;
(5) polymer cement mortar is brushed to upper and lower surface and four sides thereof at composite foaming cement plate by scraping the mode of slurry, place 1-3 days.Obtain fibre reinforced cement FC thistle board.
The physicals detection index of implementing 1-embodiment 3 is as shown in table 1.
Table 1
Project Unit Embodiment 1 Embodiment 2 Embodiment 3
Dry density kg/m 33 220 225 210
Thermal conductivity W/(m·k) 0.0564 0.0565 0.0560
Ultimate compression strength MPa 0.52 0.56 0.50
Tensile strength MPa 0.15 0.15 0.15
Water-intake rate (V/V) % 3.6 3.0 3.2
Drying shrinkage value mm/m 0.50 0.42 0.38
Carbonation coefficient - 0.88 0.85 0.87
Coefficient of softening - 0.86 0.86 0.82
The present invention will provide a kind of fibre reinforced cement FC thistle board, comprise composite foaming cement plate, alkali-resisting glass fiber screen cloth and polymer cement mortar enhancement layer, polymer cement mortar enhancement layer is by spraying, soaking paste or scrape the mode brushings such as slurry in upper and lower surface and four sides thereof of composite foaming cement plate, overcome composite foaming cement plate fragility large, easy to crack, water-intake rate is high, the shortcomings such as dry linting is serious, this composite insulation boards has water-intake rate low (water-intake rate is less than 5%), mechanical property is excellent, thermal conductivity is low, good integrity, do not ftracture, the fire prevention of A level, with buildings with advantages such as life-spans, can be applied to external thermal insulation system, fire-blocking belt, in heat preservation decoration integrative, it can be widely used in external thermal insulation system as an A level fire-retardant heat-insulation material.
The foregoing is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or conversion of equivalent flow process that utilizes specification sheets of the present invention to do, or be directly or indirectly used in other relevant technical fields, be all in like manner included in scope of patent protection of the present invention.

Claims (10)

1. a fibre reinforced cement FC thistle board, it is characterized in that, comprise composite foaming cement flaggy, alkali-resisting glass fiber scrim layer and polymer cement mortar enhancement layer, polymer cement mortar enhancement layer is by spraying, soaking paste or scrape the mode brushing of slurry in upper and lower surface and four sides thereof of composite foaming cement flaggy, and alkali-resisting glass fiber scrim layer is located between composite foaming cement flaggy and polymer cement mortar enhancement layer.
2. fibre reinforced cement FC thistle board according to claim 1, it is characterized in that, described composite foaming cement plate is made by cement, flyash, hydrophober, water reducer, exciting agent, anti-crack fiber, water and composite foamable agent, and the parts by weight proportioning of each component is:
Cement 70-90 part,
Flyash 10-30 part,
Hydrophober 0.6-3.0 part,
Water reducer 0.12-0.30 part,
Exciting agent 1.0-2.5 part
Anti-crack fiber 0.3-0.50 part,
Water 30-60 part,
Composite foamable agent 4-8 part.
3. fibre reinforced cement FC thistle board according to claim 1, is characterized in that, the dry density of described composite foaming cement plate is less than 250 kg/m 3.
4. fibre reinforced cement FC thistle board according to claim 1, is characterized in that, described polymer cement mortar is made by the raw material of following weight proportion: cement 60-80 part, redispersable latex powder 5-10 part and water 30-40 part.
5. fibre reinforced cement FC thistle board according to claim 2, is characterized in that, described cement is ordinary Portland cement or silicate cement, and described flyash is I level or II level flyash.
6. fibre reinforced cement FC thistle board according to claim 2, is characterized in that, described hydrophober is stearate, and described water reducer is a kind of in naphthalene series high-efficiency water-reducing agent, melamine series high-efficiency water-reducing agent and polycarboxylic acid series high efficiency water reducing agent.
7. fibre reinforced cement FC thistle board according to claim 2, it is characterized in that, described exciting agent is one or more mixing in trolamine, potassium hydroxide, nitrate, nitrite, sodium sulfate, sodium carbonate and lithium chloride, and described anti-crack fiber is one or more mixing in modified polypropylene fiber, trevira and vinylon fibre.
8. fibre reinforced cement FC thistle board according to claim 4, is characterized in that, a kind of in the multipolymer that described redispersable latex powder is ethylene/vinyl acetate, vinyl acetate between to for plastic/tertiary monocarboxylic acid ethylene copolymer and acrylic acid multipolymer.
9. the preparation method of fibre reinforced cement FC thistle board according to claim 1, is characterized in that, comprises the following steps:
(1) prepare composite foaming cement plate;
(2) in composite foaming cement plate upper and lower surface, paste alkali-resisting glass fiber screen cloth;
(3) prepare polymer cement mortar: cement, redispersable latex powder, according to weight proportion mixing 3-6 minute, are mixed, then add water to stir 2-4 minute, make polymer cement mortar;
(4) polymer cement mortar is brushed to upper and lower surface and four sides thereof at composite foaming cement plate by spraying, soaking paste or the mode of scraping slurry, place 1-3 days, make fibre reinforced cement FC thistle board.
10. the preparation method of fibre reinforced cement FC thistle board according to claim 9, is characterized in that, the preparation of described composite foaming cement plate is according to following steps:
(1) according to proportioning, weigh each component;
(2) first add water, anti-crack fiber, water reducer, hydrophober, cement and flyash, stir 2-3 minute, then add exciting agent, stir 1-2 minute, then add composite foamable agent, stir 5-10 second, make slurry;
(3) slurry of step (2) being made is put into mould, quietly stops form removal in 4-6 hour, cutting after 24 hours, packing, maintenance to 14 day.
CN201310694167.8A 2013-12-18 2013-12-18 Fiber-reinforced cement lightweight insulating FLIC board and preparation method thereof Pending CN103723973A (en)

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Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104533010A (en) * 2014-12-16 2015-04-22 沈阳嘉宝建材有限公司 Manufacturing method of foam concrete batten
CN106007543A (en) * 2016-05-30 2016-10-12 兰州交通大学 Light-weight and high-strength heatproof composite cement board and production method thereof
CN106630899A (en) * 2017-01-10 2017-05-10 胡金涛 Waterproof fiber cement board
CN107324714A (en) * 2017-06-08 2017-11-07 赵青山 Inorganic fire heat insulation decoration integrated plate and preparation method thereof
CN108930342A (en) * 2017-05-26 2018-12-04 高巧锦 A kind of two-sided inorganic cracking resistance insulation board
CN110498642A (en) * 2019-09-05 2019-11-26 许言言 A kind of sandwich parts light energy conservation material, preparation method and applications

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CN202031187U (en) * 2011-03-07 2011-11-09 营口象圆新材料工程技术有限公司 Phenolic aldehyde composite fireproof insulation board for building
CN102850024A (en) * 2012-09-28 2013-01-02 江苏尼高科技有限公司 Fireproof foaming compound insulation board and preparation method thereof
CN103266674A (en) * 2013-05-24 2013-08-28 常州市建筑科学研究院股份有限公司 Fiber cement strengthening FC heat-insulation board and preparation method thereof
CN203905187U (en) * 2013-12-18 2014-10-29 江苏尼高科技有限公司 Fiber reinforced cement lightweight insulation board

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100741311B1 (en) * 2006-08-17 2007-08-01 주식회사 대흥 Insulating pannel consisted of synthetic resin foam
CN202031187U (en) * 2011-03-07 2011-11-09 营口象圆新材料工程技术有限公司 Phenolic aldehyde composite fireproof insulation board for building
CN102850024A (en) * 2012-09-28 2013-01-02 江苏尼高科技有限公司 Fireproof foaming compound insulation board and preparation method thereof
CN103266674A (en) * 2013-05-24 2013-08-28 常州市建筑科学研究院股份有限公司 Fiber cement strengthening FC heat-insulation board and preparation method thereof
CN203905187U (en) * 2013-12-18 2014-10-29 江苏尼高科技有限公司 Fiber reinforced cement lightweight insulation board

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104533010A (en) * 2014-12-16 2015-04-22 沈阳嘉宝建材有限公司 Manufacturing method of foam concrete batten
CN106007543A (en) * 2016-05-30 2016-10-12 兰州交通大学 Light-weight and high-strength heatproof composite cement board and production method thereof
CN106630899A (en) * 2017-01-10 2017-05-10 胡金涛 Waterproof fiber cement board
CN108930342A (en) * 2017-05-26 2018-12-04 高巧锦 A kind of two-sided inorganic cracking resistance insulation board
CN107324714A (en) * 2017-06-08 2017-11-07 赵青山 Inorganic fire heat insulation decoration integrated plate and preparation method thereof
CN110498642A (en) * 2019-09-05 2019-11-26 许言言 A kind of sandwich parts light energy conservation material, preparation method and applications

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