CN103718091B

CN103718091B - Silicon-containing liquid crystal aligning agent, liquid crystal orientation film and liquid crystal display cells

Info

Publication number: CN103718091B
Application number: CN201280036983.3A
Authority: CN
Inventors: 坂本谦治; 军司里枝; 桥本淳; 高山祐树; 佐久间大辅; 桧森章吾; 平贺浩二; 元山贤; 元山贤一
Original assignee: Nissan Chemical Corp
Current assignee: Nissan Chemical Corp
Priority date: 2011-05-27
Filing date: 2012-05-25
Publication date: 2016-08-31
Anticipated expiration: 2032-05-25
Also published as: TW201313786A; KR101883521B1; KR20140035959A; CN103718091A; JPWO2012165354A1; TWI553040B; JP6079626B2; WO2012165354A1

Abstract

The present invention provides a kind of aligning agent for liquid crystal, even if this aligning agent for liquid crystal use without the liquid crystal of polymerizable compound and carry out processing in the same manner as PSA mode and make UV irradiate after response speed improve mode liquid crystal display cells in, it is also possible to formed do not make vertical orientated power decline and can make UV irradiate after response speed improve liquid crystal orientation film.This aligning agent for liquid crystal is characterised by, containing polysiloxane (A), the alkoxy silane polycondensation of the alkoxy silane that this polysiloxanes (A) is represented by the alkoxy silane represented containing following formula (1) and following formula (3) and obtain.R¹Si(OR²)₃(1) (R¹Represent the structure of following formula (2), R²Represent the alkyl of carbon number 1～5.)(Y¹Represent singly-bound etc., Y²Represent singly-bound etc., Y³Represent singly-bound etc., Y⁴Represent selected from phenyl ring, cyclohexyl ring or the bivalent cyclic base etc. of heterocycle, Y⁵Represent that n represents the integer of 0～4, Y selected from phenyl ring, cyclohexyl ring and the bivalent cyclic base etc. of heterocycle⁶Represent hydrogen atom etc..) R³Si(OR⁴)₃(3) (R³Represent the alkyl of carbon number 1～30, the R replaced by acryloyl group etc.⁴Represent the alkyl of carbon number 1～5).

Description

Silicon-containing liquid crystal aligning agent, liquid crystal orientation film and liquid crystal display cells

Technical field

The present invention relates to containing by polysiloxanes obtained by alkoxy silane polycondensation silicon-containing liquid crystal aligning agent and by The liquid crystal orientation film that described aligning agent for liquid crystal prepares and the liquid crystal display cells with this liquid crystal orientation film.

Background technology

In recent years, in the display mode of liquid crystal display cells, the liquid crystal display cells of vertical (VA) mode is by extensively The mobile device purposes (digital camera and the display part of mobile phone) of the general LCD TV being applied to big picture and fine Deng.In VA mode, it is known that formed in TFT substrate or colored filter substrate and be used for controlling liquid crystal and topple over MVA mode (multi-domain vertical alignment (the Multi Vertical of the projection in direction (Ru of falling れ direction) Alignment)), form slit and in the ITO electrode of substrate and by electric field controls liquid crystal toppling direction PVA (the vertical orientated configuration (Patterned Vertical Alignment) of patterning) mode.As it It is aligned, has PSA (polymer stabilizing orientation (Polymer sustained Alignment)) mode. In VA mode, PSA mode is the technology got most of the attention in recent years.

In which, in liquid crystal add photopolymerizable compound, after making liquid crystal panel, apply electric field and To liquid crystal panel irradiation ultraviolet radiation (UV) under the state that liquid crystal is toppled over.As a result of which it is, by polymerism chemical combination The photopolymerization of thing, the differently-oriented directivity immobilization of liquid crystal, produce tilt angle, response speed improves.The feature of which It is, even making slit on the electrode of side constituting liquid crystal panel on the electrode pattern of opposite side not Arrange as MVA projection or as PVA the structure of slit can also work, it is possible to realize system The simplification made, it is thus achieved that good panel absorbance (with reference to patent documentation 1).

But, in the liquid crystal display cells of this mode, there is the dissolving of the polymerizable compound making an addition to liquid crystal If property low increase addition, the problem that can separate out when low temperature.On the other hand, if reducing polymerism chemical combination The addition of thing then cannot obtain good state of orientation, response speed.Residue in liquid crystal additionally, there is also Unreacted polymerizable compound becomes the impurity in liquid crystal so that the asking of reliability decrease of liquid crystal display cells Topic.

To this, it is proposed that below scheme: i.e., will employ in polymer molecule import photoreactivity side chain and The aligning agent for liquid crystal of polymer become is coated substrate, is prepared liquid crystal orientation film through burning till, and arranges and takes with this liquid crystal To the liquid crystal layer of film contact, this liquid crystal layer is applied voltage and irradiates UV and make liquid crystal display cells, Thereby, even if not adding polymerizable compound in liquid crystal, it is also possible to obtain the liquid crystal display cells of fast response time (with reference to patent documentation 2).

On the other hand, the most known liquid crystal aligning membrane material having the organics such as the polyimides that uses up to now, It is known that the liquid crystal aligning membrane material of mineral-type.Such as, as the material of the mineral-type alignment films of application type, carry Go out to have to comprise tetraalkoxysilane, trialkoxy silane and alcohol and the alignment agent compositions of the product of oxalic acid, have Report that it forms the liquid that vertical orientated property, thermostability and homogeneity are good on the electrode base board of liquid crystal display cells Brilliant alignment films (with reference to patent documentation 3).In addition, it is also proposed that have and comprise tetraalkoxysilane, specific tri-alkoxy The product of silane and water and the aligning agent for liquid crystal compositions of specific glycol ethers solvent, it has been reported that it is formed Prevent display defect, long-time drive after image retention characteristic also very well, the ability of liquid crystal aligning will not be made to decline and Voltage retention declines few liquid crystal orientation film (with reference to patent documentation 4) with light and heat.

Prior art literature

Patent documentation

Patent documentation 1: Japanese Patent Laid-Open 2004-302061 publication

Patent documentation 2: Japanese Patent Laid-Open 2011-95967 publication

Patent documentation 3: Japanese Patent Laid-Open 09-281502 publication

Patent documentation 4: Japanese Patent Laid-Open 2005-250244 publication

Summary of the invention

Invent technical problem to be solved

Carry out in vertical orientated VA pattern, do not use needing to make its vertical orientated strong vertical orientated power In which of polymerizable compound, if making vertical orientated power improve, then the response speed after UV irradiates becomes Slowly, and if make UV irradiate after response speed improve, the most vertical orientated power decline.Vertical orientated power and U Shifting relation is there is between the raising of the response speed after V irradiation.

The technical problem to be solved is to provide a kind of aligning agent for liquid crystal, prepared by this aligning agent for liquid crystal Liquid crystal orientation film and there is the liquid crystal display cells of this liquid crystal orientation film, even if this aligning agent for liquid crystal is using Without the liquid crystal of polymerizable compound and carry out processing in the same manner as PSA mode and make UV irradiate after sound Answer in the liquid crystal display cells of the mode that speed improves, it is also possible to formed and do not make vertical orientated power decline and UV can be made The liquid crystal orientation film that response speed after irradiation improves.

Solve the technical scheme that technical problem is used

It is a feature of the present invention that following main points.

(1) aligning agent for liquid crystal, containing polysiloxane (A), this polysiloxanes (A) is by containing following formula (1) The alkoxy silane polycondensation of alkoxy silane that the alkoxy silane represented and following formula (3) represent and obtain.

R¹Si(OR²)₃(1)

(R¹Represent the structure of following formula (2), R²Represent the alkyl of carbon number 1～5.)

[changing 1]

(Y¹For singly-bound ,-(CH₂)_A-the integer of 1～15 (a be) ,-O-,-CH₂O-,-COO-or-OCO-.Y²For singly-bound, the straight-chain of carbon number 3～8 containing double bond Or branched alkyl or-(CR¹⁷R¹⁸)_B-(b represents the integer of 1～15, R¹⁷, R¹⁸ Separately represent hydrogen atom or the alkyl of carbon number 1～3.).Y³For singly-bound ,-(CH₂)_C- The integer of 1～15 (c be) ,-O-,-CH₂O-,-COO-or-OCO-. Y⁴For the bivalent cyclic base selected from phenyl ring, cyclohexyl ring and heterocycle, or have steroid skeleton carbon number 12～ The divalent organic base of 25, any hydrogen atom in these cyclic group can be selected from the alkyl of carbon number 1～3, carbon number 1～ The alkoxyl of 3, the group containing fluoroalkyl, the fluoroalkoxy of carbon number 1～3 and fluorine atom of carbon number 1～3 replace. Y⁵For the bivalent cyclic base selected from phenyl ring, cyclohexyl ring and heterocycle, any hydrogen atom in these cyclic group can quilt The alkyl of carbon number 1～3, the alkoxyl of carbon number 1～3, carbon number 1～3 containing fluoroalkyl, carbon number 1～3 fluorine-containing Alkoxyl or fluorine atom replace.N is the integer of 0～4.Y⁶For hydrogen atom, the alkyl of carbon number 1～18, carbon Several 1～18 containing fluoroalkyl, carbon number 1～18 alkoxyl or the fluoroalkoxy of carbon number 1～18.)

R³Si(OR⁴)₃(3)

(R³For by acryloyl group, acryloxy, methylacryloyl, methacryloxy or benzene second The alkyl of the carbon number 1～30 of alkenyl substituted, R⁴Alkyl for carbon number 1～5.)

(2) aligning agent for liquid crystal as described in above-mentioned (1), wherein, in described formula (3), R³For by third The substituted carbon number of enoyl-, acryloxy, methylacryloyl, methacryloxy or styryl 3～ The alkyl of 10.

(3) aligning agent for liquid crystal as described in above-mentioned (1) or (2), wherein, possibly together with polysiloxanes (B), The alcoxyl of the alkoxy silane that this polysiloxanes (B) is represented by the following formula (5) containing 50%～100% Base silane polycondensation and obtain.

Si(OR¹⁵)₄(5)

(R¹⁵Represent the alkyl of carbon number 1～5.)

(4) aligning agent for liquid crystal as described in above-mentioned (3), wherein, polysiloxanes (B) is by possibly together with formula (3) polysiloxanes obtained by the alkoxy silane polycondensation of the alkoxy silane represented.

(5) aligning agent for liquid crystal as described in above-mentioned (3) or (4), wherein, polysiloxanes (B) is by also Polysiloxanes obtained by the alkoxy silane polycondensation of the alkoxy silane represented containing following formula (6),

R¹⁶Si(OR¹⁷)₃(6)

(R¹⁶Represent the alkyl of carbon number 1～5, R¹⁷Represent the alkyl of carbon number 1～5.)

(6) aligning agent for liquid crystal as according to any one of above-mentioned (1)～(5), wherein, polysiloxanes (A) It is by the alcoxyl of the alkoxy silane represented possibly together with following formula (4) with at least one party of polysiloxanes (B) Polysiloxanes obtained by base silane polycondensation.

(R¹³)_NSi(OR¹⁴)_4-n(4)

(in formula (4), R¹³Represent hydrogen atom or can be by hetero atom, halogen atom, amino, epoxy third Epoxide, sulfydryl, NCO, the alkyl of carbon number 1～10 of Carbamido substituted, R¹⁴Represent carbon The alkyl of atomic number 1～5, n represents the integer of 0～3.)

(7) aligning agent for liquid crystal as according to any one of above-mentioned (1)～(6), wherein, described formula (1) Content in whole alkoxy silanes that the alkoxy silane represented is used in polysiloxanes (A) is 2～20 Mole %, and whole alcoxyls that the alkoxy silane that represents of described formula (3) is used in polysiloxanes (A) Content in base silane is 5～80 moles of %.

(8) liquid crystal orientation film, by being coated with the aligning agent for liquid crystal according to any one of above-mentioned (1)～(7) In substrate, drying, burn till and prepare.

(9) liquid crystal display cells, has the liquid crystal orientation film described in above-mentioned (8).

(10) liquid crystal display cells, has irradiated UV to liquid crystal cell under executing alive state and has formed, its Aligning agent for liquid crystal according to any one of above-mentioned (1)～(7) is coated with and through burning till by middle liquid crystal cell by employing Two blocks of substrate clamping liquid crystal form.

(11) manufacture method of liquid crystal display cells, employing is by the liquid according to any one of above-mentioned (1)～(7) Brilliant alignment agent coating two blocks of substrate clamping liquid crystal through burning till, irradiate UV under executing alive state.

The effect of invention

In accordance with the invention it is possible to provide use be not added with polymerizable compound liquid crystal and with PSA mode with The liquid crystal that response speed after not making the decline of vertical orientated power that UV can be made to irradiate during sample ground irradiation UV improves takes To agent, this aligning agent for liquid crystal liquid crystal orientation film for preparing and the liquid crystal display cells with this liquid crystal orientation film.

Detailed description of the invention

Polysiloxanes (A) is the alcoxyl represented by the alkoxy silane represented containing formula (1) and formula (3) Polysiloxanes obtained by the alkoxy silane polycondensation of base silane.Wherein, the manufacture of silane to siloxanes embody For hydrolytie polycondensation, but it is referred to as polycondensation in this manual.

R¹Si(OR²)₃(1)

The R of the alkoxy silane that formula (1) represents¹(the most specific organic group) represents following formula (2) Structure, R²Represent the alkyl of carbon number 1～5, preferably 1～the alkyl of 3.)

[changing 2]

R³Si(OR⁴)₃(3)

R³Represent by acrylic acryloyl group, acryloxy, methacrylic acid group acryloyl group, methyl Acryloxy or the substituted carbon number of styryl 1～30, preferably 3～the alkyl of 10, R⁴Represent carbon number 1～5 Alkyl.

In formula (2), Y¹Represent singly-bound ,-(CH₂)_A-the integer of 1～15 (a be) ,- O-,-CH₂Any one in O-,-COO-or-OCO-.Wherein, single by selecting Key ,-(CH₂)_A-the integer of 1～15 (a be) ,-O-,-CH₂O-or-CO Any one in O-, is preferred from the viewpoint of being readily synthesized side-chain structure.Then, more preferably select Select singly-bound ,-(CH₂)_A-the integer of 1～15 (a be) ,-O-,-CH₂O-or- Any one in COO-.

In formula (2), Y²Represent singly-bound, the straight-chain of carbon number 3～8 containing double bond or branched alkyl, Or-(CR¹⁷R¹⁸)_B-(b represents the integer of 1～15, R¹⁷, R¹⁸Separately represent hydrogen Atom or the alkyl of carbon number 1～3.).Wherein, it is able to significantly more from the response speed making liquid crystal display cells From the viewpoint of improvement, preferably-(CH₂)_B-the integer of 1～10 (b be).

In formula (2), Y³Represent singly-bound ,-(CH₂)_C-the integer of 1～15 (c be) ,- O-,-CH₂Any one in O-,-COO-or-OCO-.Wherein, by selecting Singly-bound ,-(CH₂)_C-the integer of 1～15 (c be) ,-O-,-CH₂O-,-C Any one in OO-or-OCO-, is preferred from the viewpoint of being readily synthesized side-chain structure. Then, singly-bound ,-(CH are more preferably selected₂)_C-the integer of 1～15 (c be) ,-O-,- CH₂Any one in O-,-COO-or-OCO-.

In formula (2), Y⁴Represent selected from phenyl ring, cyclohexyl ring and the cyclic group of heterocycle, in these cyclic group Any hydrogen atom can be selected from the alkyl of carbon number 1～3, the alkoxyl of carbon number 1～3, carbon number 1～3 fluorine-containing Any one of alkyl, the fluoroalkoxy of carbon number 1～3 or fluorine atom replace.Y⁴Can also is that selected from tool There is the divalent organic base of the organic group of the carbon number 12～25 of steroid skeleton.Wherein, preferably there is phenyl ring, hexamethylene The organic group of the carbon number 12～25 of any one in basic ring or steroid skeleton.

In formula (2), Y⁵Represent selected from phenyl ring, cyclohexyl ring and the cyclic group of heterocycle, in these cyclic group Any hydrogen atom can be selected from the alkyl of carbon number 1～3, the alkoxyl of carbon number 1～3, carbon number 1～3 fluorine-containing Any one in alkyl, the fluoroalkoxy of carbon number 1～3 or fluorine atom replaces.

In formula (2), n is the integer of 0～4.The integer of preferably 0～2.

In formula (2), Y⁶For hydrogen atom, the alkyl of carbon number 1～18, carbon number 1～18 containing fluoroalkyl, Carbon number 1～18 alkoxyl or carbon number 1～18 fluoroalkoxy in any one.Wherein, preferably carbon number 1～ The alkyl of 18, carbon number 1～10 containing fluoroalkyl, carbon number 1～18 alkoxyl or carbon number 1～10 fluorine-containing Any one in alkoxyl.More preferably any one in the alkyl of carbon number 1～12 or the alkoxyl of carbon number 1～12. Any one in the further preferred alkyl of carbon number 1～9 or the alkoxyl of carbon number 1～9.

The aligning agent for liquid crystal using this polysiloxanes having imported side chain and photoreactivity base can get both and respond speed Degree characteristic and the reason of good vertical orientated property are still not clear, but are presumably due to be had and liquid crystal bone by use The side chain of the structure that frame is similar, obtains the usual response speed in shifting relation and vertical orientated property simultaneously.

Y in formula (2)¹, Y², Y³, Y⁴, Y⁵, Y⁶Following with being preferably combined in of n Table 1～table 42 illustrate with (2-1)～(2-629).

Table 1

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-1

Singly-bound

Phenyl ring

The alkyl of carbon number 1～9

0

2-2

Singly-bound

Phenyl ring

The alkyl of carbon number 1～9

1

2-3

Singly-bound

Phenyl ring

The alkyl of carbon number 1～9

2

2-4

Singly-bound

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-5

Singly-bound

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-6

Singly-bound

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-7

Singly-bound

Phenyl ring

The alkyl of carbon number 1～9

0

2-8

Singly-bound

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-9

Singly-bound

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-10

Singly-bound

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-11

Singly-bound

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-12

Singly-bound

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-13

Singly-bound

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-14

Singly-bound

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-15

Singly-bound

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

Table 2

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-16

Singly-bound

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-17

Singly-bound

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-18

Singly-bound

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-19

Singly-bound

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-20

Singly-bound

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-21

Singly-bound

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-22

Singly-bound

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-23

Singly-bound

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-24

Singly-bound

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-25

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl of carbon number 1～9

0

2-26

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl of carbon number 1～9

1

2-27

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl of carbon number 1～9

2

2-28

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-29

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-30

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl of carbon number 1～9

2

C is the integer of carbon number 1～10

Table 3

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-31

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl of carbon number 1～9

0

2-32

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-33

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-34

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-35

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-36

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-37

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-38

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-39

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-40

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-41

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-42

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-43

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-44

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-45

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

C is the integer of carbon number 1～10

Table 4

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-46

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-47

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-48

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-49

Singly-bound

-O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-50

Singly-bound

-O-

Phenyl ring

The alkyl of carbon number 1～9

1

2-51

Singly-bound

-O-

Phenyl ring

The alkyl of carbon number 1～9

2

2-52

Singly-bound

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-53

Singly-bound

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-54

Singly-bound

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-55

Singly-bound

-O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-56

Singly-bound

-O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-57

Singly-bound

-O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-58

Singly-bound

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-59

Singly-bound

-O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-60

Singly-bound

-O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

C is the integer of carbon number 1～10

Table 5

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-61

Singly-bound

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-62

Singly-bound

-O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-63

Singly-bound

-O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-64

Singly-bound

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-65

Singly-bound

-O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-66

Singly-bound

-O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-67

Singly-bound

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-68

Singly-bound

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-69

Singly-bound

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-70

Singly-bound

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-71

Singly-bound

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-72

Singly-bound

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-73

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-74

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

1

2-75

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

2

Table 6

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-76

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-77

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-78

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-79

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-80

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-81

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-82

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-83

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-84

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-85

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-86

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-87

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-88

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-89

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-90

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

Table 7

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-91

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-92

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-93

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-94

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-95

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-96

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-97

Singly-bound

-COO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-98

Singly-bound

-COO-

Phenyl ring

The alkyl of carbon number 1～9

1

2-99

Singly-bound

-COO-

Phenyl ring

The alkyl of carbon number 1～9

2

2-100

Singly-bound

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-101

Singly-bound

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-102

Singly-bound

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-103

Singly-bound

-COO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-104

Singly-bound

-COO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-105

Singly-bound

-COO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

Table 8

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-106

Singly-bound

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-107

Singly-bound

-COO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-108

Singly-bound

-COO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-109

Singly-bound

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-110

Singly-bound

-COO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-111

Singly-bound

-COO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-112

Singly-bound

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-113

Singly-bound

-COO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-114

Singly-bound

-COO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-115

Singly-bound

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-116

Singly-bound

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-117

Singly-bound

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-118

Singly-bound

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-119

Singly-bound

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-120

Singly-bound

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

Table 9

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-121

Singly-bound

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-122

Singly-bound

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

1

2-123

Singly-bound

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

2

2-124

Singly-bound

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-125

Singly-bound

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-126

Singly-bound

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-127

Singly-bound

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-128

Singly-bound

-OCO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-129

Singly-bound

-OCO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-130

Singly-bound

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-131

Singly-bound

-OCO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-132

Singly-bound

-OCO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-133

Singly-bound

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-134

Singly-bound

-OCO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-135

Singly-bound

-OCO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

Table 10

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-136

Singly-bound

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-137

Singly-bound

-OCO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-138

Singly-bound

-OCO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-139

Singly-bound

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-140

Singly-bound

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-141

Singly-bound

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-142

Singly-bound

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-143

Singly-bound

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-144

Singly-bound

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-145

-(CH₂)_A-

Singly-bound

-O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-146

-(CH₂)_A-

Singly-bound

-O-

Phenyl ring

The alkyl of carbon number 1～9

1

2-147

-(CH₂)_A-

Singly-bound

-O-

Phenyl ring

The alkyl of carbon number 1～9

2

2-148

-(CH₂)_A-

Singly-bound

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-149

-(CH₂)_A-

Singly-bound

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-150

-(CH₂)_A-

Singly-bound

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

2

A is the integer of carbon number 1～10

Table 11

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-151

-(CH₂)_A-

Singly-bound

-O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-152

-(CH₂)_A-

Singly-bound

-O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-153

-(CH₂)_A-

Singly-bound

-O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-154

-(CH₂)_A-

Singly-bound

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-155

-(CH₂)_A-

Singly-bound

-O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-156

-(CH₂)_A-

Singly-bound

-O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-157

-(CH₂)_A-

Singly-bound

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-158

-(CH₂)_A-

Singly-bound

-O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-159

-(CH₂)_A-

Singly-bound

-O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-160

-(CH₂)_A-

Singly-bound

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-161

-(CH₂)_A-

Singly-bound

-O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-162

-(CH₂)_A-

Singly-bound

-O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-163

-(CH₂)_A-

Singly-bound

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-164

-(CH₂)_A-

Singly-bound

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-165

-(CH₂)_A-

Singly-bound

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

A is the integer of carbon number 1～10

Table 12

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-166

-(CH₂)_A-

Singly-bound

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-167

-(CH₂)_A-

Singly-bound

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-168

-(CH₂)_A-

Singly-bound

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-169

-(CH₂)_A-

Singly-bound

-COO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-170

-(CH₂)_A-

Singly-bound

-COO-

Phenyl ring

The alkyl of carbon number 1～9

1

2-171

-(CH₂)_A-

Singly-bound

-COO-

Phenyl ring

The alkyl of carbon number 1～9

2

2-172

-(CH₂)_A-

Singly-bound

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-173

-(CH₂)_A-

Singly-bound

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-174

-(CH₂)_A-

Singly-bound

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-175

-(CH₂)_A-

Singly-bound

-COO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-176

-(CH₂)_A-

Singly-bound

-COO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-177

-(CH₂)_A-

Singly-bound

-COO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-178

-(CH₂)_A-

Singly-bound

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-179

-(CH₂)_A-

Singly-bound

-COO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-180

-(CH₂)_A-

Singly-bound

-COO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

A is the integer of carbon number 1～10

Table 13

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-181

-(CH₂)_A-

Singly-bound

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-182

-(CH₂)_A-

Singly-bound

-COO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-183

-(CH₂)_A-

Singly-bound

-COO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-184

-(CH₂)_A-

Singly-bound

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-185

-(CH₂)_A-

Singly-bound

-COO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-186

-(CH₂)_A-

Singly-bound

-COO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-187

-(CH₂)_A-

Singly-bound

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-188

-(CH₂)_A-

Singly-bound

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-189

-(CH₂)_A-

Singly-bound

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-190

-(CH₂)_A-

Singly-bound

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-191

-(CH₂)_A-

Singly-bound

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-192

-(CH₂)_A-

Singly-bound

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-193

-(CH₂)_A-

Singly-bound

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-194

-(CH₂)_A-

Singly-bound

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

1

2-195

-(CH₂)_A-

Singly-bound

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

2

A is the integer of carbon number 1～10

Table 14

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-196

-(CH₂)_A-

Singly-bound

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-197

-(CH₂)_A-

Singly-bound

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-198

-(CH₂)_A-

Singly-bound

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-199

-(CH₂)_A-

Singly-bound

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-200

-(CH₂)_A-

Singly-bound

-OCO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-201

-(CH₂)_A-

Singly-bound

-OCO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-202

-(CH₂)_A-

Singly-bound

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-203

-(CH₂)_A-

Singly-bound

-OCO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-204

-(CH₂)_A-

Singly-bound

-OCO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-205

-(CH₂)_A-

Singly-bound

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-206

-(CH₂)_A-

Singly-bound

-OCO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-207

-(CH₂)_A-

Singly-bound

-OCO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-208

-(CH₂)_A-

Singly-bound

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-209

-(CH₂)_A-

Singly-bound

-OCO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-210

-(CH₂)_A-

Singly-bound

-OCO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

A is the integer of carbon number 1～10

Table 15

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶N

2-211

-(CH₂)_A-

Singly-bound

-OCO-

Cyclohexyl ring

The alkyl 0 of carbon number 1～9

2-212

-(CH₂)_A-

Singly-bound

-OCO-

Cyclohexyl ring

The alkyl 1 of carbon number 1～9

2-213

-(CH₂)_A-

Singly-bound

-OCO-

Cyclohexyl ring

The alkyl 2 of carbon number 1～9

2-214

-(CH₂)_A-

Singly-bound

-OCO-

Cyclohexyl ring

The alkoxyl 0 of carbon number 1～9

2-215

-(CH₂)_A-

Singly-bound

-OCO-

Cyclohexyl ring

The alkoxyl 1 of carbon number 1～9

2-216

-(CH₂)_A-

Singly-bound

-OCO-

Cyclohexyl ring

The alkoxyl 2 of carbon number 1～9

2-217

-O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl 0 of carbon number 1～9

2-218

-O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl 1 of carbon number 1～9

2-219

-O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl 2 of carbon number 1～9

2-220

-O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl 0 of carbon number 1～9

2-221

-O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl 1 of carbon number 1～9

2-222

-O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl 2 of carbon number 1～9

2-223

-O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl 0 of carbon number 1～9

2-224

-O-

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkyl 1 of carbon number 1～9

2-225

-O-

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkyl 2 of carbon number 1～9

A, c are separately the integer of carbon number 1～10

Table 16

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶N

2-226

-O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl 0 of carbon number 1～9

2-227

-O-

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkoxyl 1 of carbon number 1～9

2-228

-O-

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkoxyl 2 of carbon number 1～9

2-229

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl 0 of carbon number 1～9

2-230

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkyl 1 of carbon number 1～9

2-231

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkyl 2 of carbon number 1～9

2-232

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl 0 of carbon number 1～9

2-233

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkoxyl 1 of carbon number 1～9

2-234

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkoxyl 2 of carbon number 1～9

2-235

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl 0 of carbon number 1～9

2-236

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl 1 of carbon number 1～9

2-237

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl 2 of carbon number 1～9

2-238

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl 0 of carbon number 1～9

2-239

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl 1 of carbon number 1～9

2-240

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl 2 of carbon number 1～9

C is the integer of carbon number 1～10

Table 17

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-241

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-242

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-243

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-244

-O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-245

-O-

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-246

-O-

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

1

2-247

-O-

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

2

2-248

-O-

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-249

-O-

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-250

-O-

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-251

-O-

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-252

-O-

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-253

-O-

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-254

-O-

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-255

-O-

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

Table 18

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-256

-O-

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-257

-O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-258

-O-

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-259

-O-

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-260

-O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-261

-O-

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-262

-O-

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-263

-O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-264

-O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-265

-O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-266

-O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-267

-O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-268

-O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-269

-CH₂O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl of carbon number 1～9

0

2-270

-CH₂O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl of carbon number 1～9

1

C is the integer of carbon number 1～10

Table 19

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-271

-CH₂O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl of carbon number 1～9

2

2-272

-CH₂O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-273

-CH₂O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-274

-CH₂O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-275

-CH₂O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl of carbon number 1～9

0

2-276

-CH₂O-

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-277

-CH₂O-

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-278

-CH₂O-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-279

-CH₂O-

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-280

-CH₂O-

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-281

-CH₂O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-282

-CH₂O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-283

-CH₂O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-284

-CH₂O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-285

-CH₂O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

C is the integer of carbon number 1～10

Table 20

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-286

-CH₂O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-287

-CH₂O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-288

-CH₂O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-289

-CH₂O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-290

-CH₂O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-291

-CH₂O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-292

-CH₂O-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-293

-CH₂O-

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-294

-CH₂O-

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

1

2-295

-CH₂O-

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

2

2-296

-CH₂O-

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-297

-CH₂O-

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-298

-CH₂O-

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-299

-CH₂O-

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-300

-CH₂O-

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

C is the integer of carbon number 1～10

Table 21

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-301

-CH₂O-

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-302

-CH₂O-

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-303

-CH₂O-

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-304

-CH₂O-

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-305

-CH₂O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-306

-CH₂O-

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-307

-CH₂O-

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-308

-CH₂O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-309

-CH₂O-

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-310

-CH₂O-

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-311

-CH₂O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-312

-CH₂O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-313

-CH₂O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-314

-CH₂O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-315

-CH₂O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

Table 22

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-316

-CH₂O-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-317

-COO-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl of carbon number 1～9

0

2-318

-COO-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl of carbon number 1～9

1

2-319

-COO-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl of carbon number 1～9

2

2-320

-COO-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-321

-COO-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-322

-COO-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-323

-COO-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkyl of carbon number 1～9

0

2-324

-COO-

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-325

-COO-

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-326

-COO-

Singly-bound

-(CH₂)_C-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-327

-COO-

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-328

-COO-

Singly-bound

-(CH₂)_C-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-329

-COO-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-330

-COO-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

C is the integer of carbon number 1～10

Table 23

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-331

-COO-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-332

-COO-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-333

-COO-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-334

-COO-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-335

-COO-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-336

-COO-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-337

-COO-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-338

-COO-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-339

-COO-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-340

-COO-

Singly-bound

-(CH₂)_C-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

C is the integer of carbon number 1～10

Table 24

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-341

-COO-

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-342

-COO-

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

1

2-343

-COO-

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

2

2-344

-COO-

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-345

-COO-

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-346

-COO-

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-347

-COO-

Singly-bound

-CH₂O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-348

-COO-

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-349

-COO-

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-350

-COO-

Singly-bound

-CH₂O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-351

-COO-

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-352

-COO-

Singly-bound

-CH₂O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-353

-COO-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-354

-COO-

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-355

-COO-

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

Table 25

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-356

-COO-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-357

-COO-

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-358

-COO-

Singly-bound

-CH₂O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-359

-COO-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-360

-COO-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-361

-COO-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-362

-COO-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-363

-COO-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-364

-COO-

Singly-bound

-CH₂O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-365

-O-

-(CH₂)_B-

-O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-366

-O-

-(CH₂)_B-

-O-

Phenyl ring

The alkyl of carbon number 1～9

1

2-367

-O-

-(CH₂)_B-

-O-

Phenyl ring

The alkyl of carbon number 1～9

2

2-368

-O-

-(CH₂)_B-

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-369

-O-

-(CH₂)_B-

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-370

-O-

-(CH₂)_B-

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

2

B is the integer of carbon number 1～10

Table 26

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-371

-O-

-(CH₂)_B-

-O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-372

-O-

-(CH₂)_B-

-O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-373

-O-

-(CH₂)_B-

-O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-374

-O-

-(CH₂)_B-

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-375

-O-

-(CH₂)_B-

-O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-376

-O-

-(CH₂)_B-

-O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-377

-O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-378

-O-

-(CH₂)_B-

-O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-379

-O-

-(CH₂)_B-

-O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-380

-O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-381

-O-

-(CH₂)_B-

-O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-382

-O-

-(CH₂)_B-

-O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-383

-O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-384

-O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-385

-O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-386

-O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-387

-O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-388

-O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-389

-O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-390

-O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 27

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-391

-O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkyl of carbon number 1～9

2

2-392

-O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-393

-O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-394

-O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-395

-O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-396

-O-

-(CH₂)_B-

-COO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-397

-O-

-(CH₂)_B-

-COO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-398

-O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-399

-O-

-(CH₂)_B-

-COO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-400

-O-

-(CH₂)_B-

-COO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-401

-O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-402

-O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-403

-O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-404

-O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-405

-O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 28

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-406

-O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-407

-O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-408

-O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-409

-O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-410

-O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-411

-O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-412

-O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-413

-O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-414

-O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

1

2-415

-O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

2

2-416

-O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-417

-O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-418

-O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-419

-O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-420

-O-

-(CH₂)_B-

-OCO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 29

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-421

-O-

-(CH₂)_B-

-OCO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-422

-O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-423

-O-

-(CH₂)_B-

-OCO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-424

-O-

-(CH₂)_B-

-OCO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-425

-O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-426

-O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-427

-O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-428

-O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-429

-O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-430

-O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-431

-O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-432

-O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-433

-O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-434

-O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-435

-O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 30

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-436

-O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-437

-CH₂O-

-(CH₂)_B-

Singly-bound

Phenyl ring

The alkyl of carbon number 1～9

0

2-438

-CH₂O-

-(CH₂)_B-

Singly-bound

Phenyl ring

The alkyl of carbon number 1～9

1

2-439

-CH₂O-

-(CH₂)_B-

Singly-bound

Phenyl ring

The alkyl of carbon number 1～9

2

2-440

-CH₂O-

-(CH₂)_B-

Singly-bound

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-441

-CH₂O-

-(CH₂)_B-

Singly-bound

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-442

-CH₂O-

-(CH₂)_B-

Singly-bound

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-443

-CH₂O-

-(CH₂)_B-

Singly-bound

Phenyl ring

The alkyl of carbon number 1～9

0

2-444

-CH₂O-

-(CH₂)_B-

Singly-bound

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-415

-CH₂O-

-(CH₂)_B-

Singly-bound

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-446

-CH₂O-

-(CH₂)_B-

Singly-bound

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-447

-CH₂O-

-(CH₂)_B-

Singly-bound

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-448

-CH₂O-

-(CH₂)_B-

Singly-bound

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-449

-CH₂O-

-(CH₂)_B-

Singly-bound

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-450

-CH₂O-

-(CH₂)_B-

Singly-bound

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 31

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-451

-CH₂O-

-(CH₂)_B-

Singly-bound

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-452

-CH₂O-

-(CH₂)_B-

Singly-bound

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-453

-CH₂O-

-(CH₂)_B-

Singly-bound

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-454

-CH₂O-

-(CH₂)_B-

Singly-bound

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-455

-CH₂O-

-(CH₂)_B-

Singly-bound

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-456

-CH₂O-

-(CH₂)_B-

Singly-bound

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-457

-CH₂O-

-(CH₂)_B-

Singly-bound

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-458

-CH₂O-

-(CH₂)_B-

Singly-bound

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-459

-CH₂O-

-(CH₂)_B-

Singly-bound

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-460

-CH₂O-

-(CH₂)_B-

Singly-bound

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-461

-CH₂O-

-(CH₂)_B-

-O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-462

-CH₂O-

-(CH₂)_B-

-O-

Phenyl ring

The alkyl of carbon number 1～9

1

2-463

-CH₂O-

-(CH₂)_B-

-O-

Phenyl ring

The alkyl of carbon number 1～9

2

2-464

-CH₂O-

-(CH₂)_B-

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-465

-CH₂O-

-(CH₂)_B-

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 32

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-466

-CH₂O-

-(CH₂)_B-

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-467

-CH₂O-

-(CH₂)_B-

-O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-468

-CH₂O-

-(CH₂)_B-

-O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-469

-CH₂O-

-(CH₂)_B-

-O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-470

-CH₂O-

-(CH₂)_B-

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-471

-CH₂O-

-(CH₂)_B-

-O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-472

-CH₂O-

-(CH₂)_B-

-O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-473

-CH₂O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-474

-CH₂O-

-(CH₂)_B-

-O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-475

-CH₂O-

-(CH₂)_B-

-O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-476

-CH₂O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-477

-CH₂O-

-(CH₂)_B-

-O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-478

-CH₂O-

-(CH₂)_B-

-O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-479

-CH₂O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-480

-CH₂O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 33

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-481

-CH₂O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-482

-CH₂O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-483

-CH₂O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-484

-CH₂O-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-485

-CH₂O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-486

-CH₂O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkyl of carbon number 1～9

1

2-487

-CH₂O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkyl of carbon number 1～9

2

2-488

-CH₂O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-489

-CH₂O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-490

-CH₂O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-491

-CH₂O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-492

-CH₂O-

-(CH₂)_B-

-COO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-493

-CH₂O-

-(CH₂)_B-

-COO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-494

-CH₂O-

-(CH₂)_B-

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-495

-CH₂O-

-(CH₂)_B-

-COO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 34

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-496

-CH₂O-

-(CH₂)_B-

-COO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-497

-CH₂O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-498

-CH₂O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-499

-CH₂O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-500

-CH₂O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-501

-CH₂O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-502

-CH₂O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-503

-CH₂O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-504

-CH₂O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-505

-CH₂O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-506

-CH₂O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-507

-CH₂O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-508

-CH₂O-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-509

-CH₂O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-510

-CH₂O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 35

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-511

-CH₂O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

2

2-512

-CH₂O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-513

-CH₂O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-514

-CH₂O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-515

-CH₂O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-516

-CH₂O-

-(CH₂)_B-

-OCO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-517

-CH₂O-

-(CH₂)_B-

-OCO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-518

-CH₂O-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-519

-CH₂O-

-(CH₂)_B-

-OCO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-520

-CH₂O-

-(CH₂)_B-

-OCO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-521

-CH₂O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-522

-CH₂O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-523

-CH₂O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-524

-CH₂O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-525

-CH₂O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 36

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-526

-CH₂O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-527

-CH₂O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-528

-CH₂O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-529

-CH₂O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-530

-CH₂O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-531

-CH₂O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-532

-CH₂O-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-533

-COO-

-(CH₂)_B-

-O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-534

-COO-

-(CH₂)_B-

-O-

Phenyl ring

The alkyl of carbon number 1～9

1

2-535

-COO-

-(CH₂)_B-

-O-

Phenyl ring

The alkyl of carbon number 1～9

2

2-536

-COO-

-(CH₂)_B-

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-537

-COO-

-(CH₂)_B-

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-538

-COO-

-(CH₂)_B-

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-539

-COO-

-(CH₂)_B-

-O-

Phenyl ring

The alkyl of carbon number 1～9

0

2-540

-COO-

-(CH₂)_B-

-O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 37

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-541

-COO-

-(CH₂)_B-

-O-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-542

-COO-

-(CH₂)_B-

-O-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-543

-COO-

-(CH₂)_B-

-O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-544

-COO-

-(CH₂)_B-

-O-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-545

-COO-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-546

-COO-

-(CH₂)_B-

-O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-547

-COO-

-(CH₂)_B-

-O-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-548

-COO-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-549

-COO-

-(CH₂)_B-

-O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-550

-COO-

-(CH₂)_B-

-O-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-551

-COO-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-552

-COO-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-553

-COO-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-554

-COO-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-555

-COO-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 38

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-556

-COO-

-(CH₂)_B-

-O-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-557

-COO-

-(CH₂)_B-

-COO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-558

-COO-

-(CH₂)_B-

-COO-

Phenyl ring

The alkyl of carbon number 1～9

1

2-559

-COO-

-(CH₂)_B-

-COO-

Phenyl ring

The alkyl of carbon number 1～9

2

2-560

-COO-

-(CH₂)_B-

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-561

-COO-

-(CH₂)_B-

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-562

-COO-

-(CH₂)_B-

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-563

-COO-

-(CH₂)_B-

-COO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-564

-COO-

-(CH₂)_B-

-COO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-565

-COO-

-(CH₂)_B-

-COO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-566

-COO-

-(CH₂)_B-

-COO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-567

-COO-

-(CH₂)_B-

-COO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-568

-COO-

-(CH₂)_B-

-COO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-569

-COO-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-570

-COO-

-(CH₂)_B-

-COO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 39

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-571

-COO-

-(CH₂)_B-

-COO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-572

-COO-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-573

-COO-

-(CH₂)_B-

-COO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-574

-COO-

-(CH₂)_B-

-COO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-575

-COO-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-576

-COO-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-577

-COO-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-578

-COO-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-579

-COO-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-580

-COO-

-(CH₂)_B-

-COO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-581

-COO-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-582

-COO-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

1

2-583

-COO-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

2

2-584

-COO-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-585

-COO-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 40

Y¹

Y²

Y³

Y⁴

Y⁵

Y⁶

N

2-586

-COO-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-587

-COO-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkyl of carbon number 1～9

0

2-588

-COO-

-(CH₂)_B-

-OCO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

1

2-589

-COO-

-(CH₂)_B-

-OCO-

Phenyl ring

Cyclohexyl ring

The alkyl of carbon number 1～9

2

2-590

-COO-

-(CH₂)_B-

-OCO-

Phenyl ring

The alkoxyl of carbon number 1～9

0

2-591

-COO-

-(CH₂)_B-

-OCO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

1

2-592

-COO-

-(CH₂)_B-

-OCO-

Phenyl ring

Cyclohexyl ring

The alkoxyl of carbon number 1～9

2

2-593

-COO-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-594

-COO-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

1

2-595

-COO-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

Phenyl ring

The alkyl of carbon number 1～9

2

2-596

-COO-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkoxyl of carbon number 1～9

0

2-597

-COO-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

1

2-598

-COO-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

Phenyl ring

The alkoxyl of carbon number 1～9

2

2-599

-COO-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

0

2-600

-COO-

-(CH₂)_B-

-OCO-

Cyclohexyl ring

The alkyl of carbon number 1～9

1

B is the integer of carbon number 1～10

Table 41

B, c are separately the integer of carbon number 1～10

Table 42

B, c are separately the integer of carbon number 1～10

The R of the alkoxy silane that formula (1) represents²For carbon number 1～5, preferably 1～the alkyl of 3.More excellent Choosing is R²For methyl or ethyl.

The alkoxy silane that such formula (1) represents can be by known synthetic method (such as Japanese Patent Laid-Open Clear 61-286393 publication) synthesize.Its concrete example exemplified below, but it is not limited to this.

[changing 3]

[changing 4]

[changing 5]

[changing 6]

[changing 7]

[changing 8]

(in formula ［ 1-19 ］～［ 1-21 ］, R⁵Represent-O-,-OCH₂-, -CH₂O-,-COOCH₂-or-CH₂OCO-, R⁶Represent carbon number 1～22 Alkyl, alkoxyl, containing fluoroalkyl or fluoroalkoxy.)

[changing 9]

(in formula ［ 1-22 ］～［ 1-24 ］, R⁷Represent singly-bound ,-COO-,-O CO-,-COOCH₂-,-CH₂OCO-,-(CH₂)_NO-(n be 1～ The integer of 5) ,-OCH₂-or CH₂-, R⁸Represent the alkyl of carbon number 1～22, alkoxyl, Containing fluoroalkyl or fluoroalkoxy.)

[changing 10]

(in formula ［ 1-25 ］ and ［ 1-26 ］, R⁹Represent-COO-,-OCO-, -COOCH₂-,-CH₂OCO-,-CH₂O-,-OCH₂-,-CH₂-or O-, R¹⁰Represent fluorine-based, cyano group, fluoroform alkyl, nitro, azo group, formoxyl, second Acyl group, acetoxyl group or hydroxyl.)

[changing 11]

(in formula ［ 1-27 ］ and ［ 1-28 ］, R¹¹The alkyl of expression carbon number 3～12, Isosorbide-5-Nitrae- The cis-trans isomerization of cyclohexyl is respectively transisomer.)

[changing 12]

(in formula ［ 1-29 ］ and ［ 1-30 ］, R¹²Represent the alkyl of carbon number 3～12, Isosorbide-5-Nitrae-hexamethylene The cis-trans isomerization of base is respectively transisomer.)

[changing 13]

(in formula ［ 1-31 ］, B₄The alkyl of the carbon number 3～20 for being replaced by fluorine atoms, B₃For 1,4- Cyclohexylidene or Isosorbide-5-Nitrae-phenylene, B₂Wherein key with " * " and B for oxygen atom or-COO-*(₃ In conjunction with), B₁Wherein key with " * " and (CH for oxygen atom or-COO-*(₂) a₂) combine). Additionally, a₁It is the integer of 0 or 1, a₂It is the integer of 2～10, a₃It it is the integer of 0 or 1.

According to the dissolubility to solvent when making siloxane polymer, make liquid crystal orientation film time liquid crystal aligning Property, the characteristic of tilt angle characteristic, voltage retention, accumulated charge etc., the alkoxyl silicone that above-mentioned formula (1) represents Alkane uses after can using one or more mixing.In addition, it is possible to the chain alkyl containing carbon number 10～18 Alkoxy silane together and use.

The alkoxy silane that above-mentioned formula (1) represents can be with known method manufacture.

For obtaining good liquid crystal aligning, the alkoxy silane that above-mentioned formula (1) represents is for preparing poly-silicon Preferably at 1 mole of more than % in whole alkoxy silanes of oxygen alkane.More preferably at 1.5 moles of more than %.Further Preferably at 2 moles of more than %.Additionally, by the sufficient curing characteristics obtaining formed liquid crystal orientation film, preferably At 30 moles of below %.More preferably at 25 moles of below %.

The R of the alkoxy silane that formula (3) represents³(the hereinafter also referred to second specific organic group) is by propylene The substituted alkyl of acyl group, acryloxy, methylacryloyl, methacryloxy or styryl.Taken The hydrogen atom in generation at more than one, preferably one.The carbon number of this alkyl is 1～30, more preferably 3～10, More preferably 5～10.

The R of the alkoxy silane that formula (3) represents⁴For carbon number 1～5, preferred carbon number 1～3, particularly preferred carbon The alkyl of several 1 or 2.

The concrete example of the alkoxy silane represented as formula (3) enumerates as follows, but is not limited to this.Such as, 3- Methacryloxypropyl trimethoxy silane, 3-methacryloxypropyl, methyl-prop Alkene pivaloyloxymethyl trimethoxy silane, methacryloxymethyl triethoxysilane, 3-acryloxy third Base trimethoxy silane, 3-acryloxypropyl triethoxysilane, acryloyl-oxyethyl trimethoxy silane, Acryloyl-oxyethyl triethoxysilane, styryl ethyl trimethoxy silane, styryl ethyl three ethoxy Base silane, 3-(N-styrylmethyl-2-aminoethylamino) propyl trimethoxy silicane, 3-methacryloxypropyl Base hexyl trimethoxy silane, 3-Methacryloxyhexyl triethoxysilane, 3-acryloxy hexyl three Methoxy silane, 3-acryloxy hexyl triethoxysilane, 3-methacryloxy octyl group trimethoxy silicon Alkane, 3-methacryloxy octyltri-ethoxysilane, 3-acryloxy octyl group trimethoxy silane, 3-third Alkene acyloxy octyltri-ethoxysilane.

For obtaining good liquid crystal response speed, the alkoxy silane that formula (3) represents is for preparing poly-silica Preferably at 5 moles of more than % in whole alkoxy silanes of alkane.More preferably at 10 moles of more than %.The most excellent It is selected in 20 moles of more than %.Additionally, for improving vertical orientated property, preferably at 70 moles of below %.More preferably exist 60 moles of below %.

In the manufacture of polysiloxanes (A), except the alkoxy silane that represents with formula (1) and formula (3) with Outward, for the purpose of affinity improvement with the adaptation and liquid crystal molecule of substrate etc., if the effect of the lossless present invention Really, it is possible to use the alkoxy silane that one or more following formula (4) represent.The alcoxyl that formula (4) represents Base silane can give polysiloxanes with various characteristics, therefore one or more can be selected to use according to desirable characteristics.

(R¹³)_NSi(OR¹⁴)_4-n(4)

(in formula (4), R¹³Represent hydrogen atom or can by hetero atom, halogen atom, amino, glycidoxy, The alkyl of the carbon number 1～10 of sulfydryl, NCO or Carbamido substituted.R¹⁴Expression carbon number 1～5, The alkyl of preferably 1～3, n represents 0～3, preferably 0～the integer of 2.)

The R of the alkoxy silane that formula (4) represents¹³For hydrogen atom or carbon number be 1～10 organic Base (the hereinafter also referred to the 3rd organic group).As the example of the 3rd organic group, there is aliphatic hydrocarbon；Aliphatic ring, Aromatic ring and the such ring structure of heterocycle；Unsaturated bond；And oxygen atom, nitrogen-atoms, sulphur atom etc. can be contained Hetero atom, can have the organic group that carbon number is 1～6 of apparatus derivatorius.In addition, this organic group can quilt Halogen atom, amino, glycidoxy, sulfydryl, NCO or urea groups etc. replace.

The concrete example of the alkoxy silane that such formula (4) represents enumerates as follows, but is not limited to this.Can enumerate 3-(2-aminoethylaminopropyl) trimethoxy silane, 3-(2-aminoethylaminopropyl) triethoxysilane, 2- Aminoethylaminomethyl trimethoxy silane, 2-(2-amino-ethyl sulfur ethyl) triethoxysilane, 3-sulfydryl third Ethyl triethoxy silicane alkane, mercapto methyl trimethoxy silane, VTES, 3-NCO third Ethyl triethoxy silicane alkane, trifluoro propyl trimethoxy silane, chloropropyl triethoxysilane, bromopropyl triethoxy Silane, 3-mercaptopropyi trimethoxy silane, dimethyldiethoxysilane, dimethyldimethoxysil,ne, two Ethyl diethoxy silane, diethyldimethoxysilane, dimethoxydiphenylsilane, diphenyl diethoxy Silane, 3-amino propyl methyl diethoxy silane, 3-dimethyl Ethoxysilane, trimethyl ethoxy Base silane, trimethylmethoxysilane, γ-ureidopropyltriethoxysilane, γ-ureido-propyl trimethoxy silicon Alkane and γ-ureido-propyl tripropoxy silane etc..

With in the alkoxy silane that formula (4) represents, n be the alkoxy silane of 0 be tetraalkoxysilane.Four Alkoxy silane is easily condensed with the alkoxy silane represented with formula (1) and (3), so in the prepared present invention Polysiloxanes on be preferred.

It is the alkoxy silane of 0 as n in such formula (4), more preferably tetramethoxy-silicane, tetrem TMOS, tetrapropoxysilane or four butoxy silanes, particularly preferably tetramethoxy-silicane or tetraethoxy-silicane Alkane.

In the present invention, the alkoxy silane that formula (1) represents is at the whole alkane for manufacturing polysiloxanes (A) Content in TMOS is preferably 2～20 moles of %, particularly preferably 3～15 moles of %, and with formula (3) The alkoxy silane represented is preferably at the content being used for manufacturing in whole alkoxy silanes of polysiloxanes (A) 5～80 moles of %, particularly preferably 10 moles of %～70 moles of %.

Polysiloxanes (B) is the alkoxyl silicone represented by the formula (5) containing 50 moles of %～100 moles of % Polysiloxanes obtained by the alkoxy silane polycondensation of alkane.

Si(OR¹⁵)₄(5)

The R of the alkoxy silane that formula (5) represents¹⁵Represent carbon number 1～5, preferably 1～the alkyl of 3.

As the concrete example of the alkoxy silane that such formula (5) represents, more preferably tetramethoxy-silicane, Tetraethoxysilane, tetrapropoxysilane or four butoxy silanes, particularly preferably tetramethoxy-silicane or four ethoxies Base silane.

Polysiloxanes (B) can also be by addition to the alkoxy silane that formula (5) represents possibly together with above-mentioned The alkoxy silane R that the formula (3) described in manufacture of polysiloxanes (A) represents³Si(OR⁴)₃Alkoxy silane polycondensation obtained by polysiloxanes.Explanation to the alkoxy silane that formula (3) represents, is suitable for Explanation in above-mentioned polysiloxanes (A).

Polysiloxanes (B) can also be by addition to the alkoxy silane that formula (5) represents possibly together with formula (6) Polysiloxanes obtained by the alkoxy silane polycondensation of the alkoxy silane represented.

R¹⁶Si(OR¹⁷)₃(6)

The R of the alkoxy silane that formula (6) represents¹⁶Alkyl for carbon number 1～5.The carbon number of alkyl Preferably 1～4, more preferably 1～3.

The R of the alkoxy silane that formula (6) represents¹⁷For carbon number 1～5, more preferably carbon number 1～3, especially Preferably carbon number is the alkyl of 1 or 2.

The concrete example of the alkoxy silane that formula (6) represents enumerates as follows, but is not limited to this.Such as, methyl three Ethoxysilane, MTMS, dimethyl trimethoxy silane, dimethyl triethoxysilane, just Propyl trimethoxy silicane, n-pro-pyl triethoxysilane.

Comprise by addition to the alkoxy silane except representing with formula (5) possibly together with the alcoxyl represented with formula (6) Vertical orientated power Gao Erte of the aligning agent for liquid crystal of polysiloxanes (B) obtained by the alkoxy silane polycondensation of base silane The most preferable.

In order to be not added with the liquid crystal of polymerizable compound by use and carry out UV irradiation while applying voltage Improve the response speed of liquid crystal display cells, there is the alkoxyl silicone that the formula (3) of the second specific organic group represents Alkane is for preparing in whole alkoxy silanes of polysiloxanes preferably at 10 moles of more than %.More preferably 20 Mole more than %.Further preferably at 30 moles of more than %.Additionally, in order to make formed liquid crystal orientation film fill Divide solidification, preferably at 75 moles of below %.

In the manufacture of polysiloxanes (B), the alcoxyl represented except formula (3), formula (5) and formula (6) Beyond base silane, for the purpose of affinity improvement with the adaptation and liquid crystal molecule of substrate etc., as long as lossless The effect of invention, it is possible to use the formula (4) described in manufacture of one or more above-mentioned polysiloxanes (A) Alkoxy silane (the R represented¹³)_NSi(OR¹⁴)_4-n.The alcoxyl that formula (4) is represented The explanation of base silane, is suitable for the explanation in above-mentioned polysiloxanes (A).

The alkoxy silane that formula (4) represents can give polysiloxanes with various characteristics, therefore can be according to required Characteristic selects one or more to use.

During the aligning agent for liquid crystal that manufacture polysiloxanes (A) and polysiloxanes (B) mix, for poly-silicon Oxygen alkane (A) and the blending ratio of polysiloxanes (B), the weight ratio of (A) and (B) is preferably 10: 90～50:50, it is particularly preferably 20:80～40:60.

The method preparing the polysiloxanes for the present invention is not particularly limited.The polysiloxanes (A) of the present invention by With above-mentioned formula (1) and formula (3) for must the alkoxy silane polycondensation in organic solvent of composition and obtain, poly-silicon Oxygen alkane (B) by with above-mentioned formula (5) for must composition, be preferably any composition with formula (3), formula (6) Alkoxy silane polycondensation in organic solvent and obtain.Generally, polysiloxanes contracts as by such alkoxy silane Poly-and uniform dissolution obtains in the solution of organic solvent.

As the method by alkoxy silane polycondensation, can enumerate such as by alkoxy silane in alcohol or solvents such as glycols In be hydrolyzed condensation method.Now, during hydrolysis-condensation reaction can be partial hydrolysis and complete hydrolysis Any one.In the case of complete hydrolysis, 0.5 times that adds the whole alkoxyls in alkoxy silane in theory is rubbed Your water, but it is generally preferred to add the water of the excess more than 0.5 times mole.

In the present invention, the water yield used in above-mentioned reaction can the most suitably select, but preferably generally alkane 0.5 of whole alkoxyls in TMOS～2.5 times moles.

Additionally, in order to promote hydrolysis-condensation reaction, generally can use following catalyst: hydrochloric acid, sulphuric acid, nitre The acid such as acid, acetic acid, formic acid, ethanedioic acid, maleic acid, fumaric acid, ammonia, methylamine, ethamine, ethanolamine, three second The alkali such as amine, the slaine etc. of hydrochloric acid, sulphuric acid, nitric acid etc..In addition, by being dissolved with alkoxy silane Solution carries out heating and promotes that hydrolysis-condensation reaction is also conventional method further.Now, heating-up temperature and adding The heat time can the most suitably select.Such as, can enumerate 50 DEG C of heated and stirred 24 hours, or in backflow The method that lower heated and stirred waits for 1 hour.

Additionally, as other method, can enumerate and such as the mixture of alkoxy silane, solvent and ethanedioic acid be entered The method that row heating carrys out polycondensation.Specifically, it is in alcohol, to add ethanedioic acid in advance and make the alcoholic solution of ethanedioic acid Afterwards, the method for mixed oxyalkyl silane when heating this solution.Now, the consumption of ethanedioic acid is relative to alkane Whole alkoxyls that TMOS is had 1 mole are preferably 0.2～2 mole.Heating in the method can 50～ Carry out under the liquid temperature of 180 DEG C.Preferably do not occur liquid evaporation, be vaporized etc. under conditions of heat under reflux Dozens of minutes～the method for tens hours.

When obtaining polysiloxanes, in the case of using multiple alkoxy silane, alkoxy silane can be mixed in advance Close and be mixed into mixture, it is also possible to multiple alkoxy silane is mixed successively.

By solvent (being also referred to as polymer solvent below) used during alkoxy silane polycondensation as long as dissolve alkoxy silane Solvent, be not particularly limited.Even if additionally, in the case of alkoxy silane is undissolved, as long as can be The polycondensation reaction of alkoxy silane carries out the solvent dissolved while carrying out.Generally, by alkoxy silane Polycondensation reaction generates alcohol, therefore can use alcohols, glycols, glycol ethers or good the having with the intermiscibility of alcohols Machine solvent.

As the object lesson of such polymer solvent, methanol, ethanol, propanol, butanol, diacetone can be enumerated The alcohols such as alcohol；Ethylene glycol, diethylene glycol, propylene glycol, dipropylene glycol, hexanediol, 1,3-propylene glycol, 1,2-fourth Glycol, 1,3 butylene glycol, 1,4-butanediol, 2,3-butanediol, 1,2-pentanediol, 1,3-pentanediol, 1,4-pentanediol, The glycolss such as 1,5-pentanediol, 2,4-PD, 2,3-pentanediol, 1,6-HD；Glycol monoethyl ether, second two Alcohol list ether, ethylene glycol ether, ethylene glycol monobutyl ether, glycol dimethyl ether, ethylene glycol diethyl ether, ethylene glycol Dipropyl ether, butyl cellosolve, diethylene glycol monomethyl ether, diethylene glycol monoethyl ether, Diethylene glycol monopropyl ether, two Ethylene glycol monobutyl ether, diethylene glycol dimethyl ether, diethylene glycol diethyl ether, diethylene glycol dipropyl ether, diethylene glycol two Butyl ether, propylene glycol monomethyl ether, dihydroxypropane single-ether, propylene glycol monopropyl ether, propylene glycol monobutyl ether, propylene glycol diformazan The glycol ethers such as ether, propylene glycol diethyl ether, propylene glycol dipropyl ether, propylene glycol butyl oxide；N-methyl-2-pyrrolidine Ketone, N,N-dimethylformamide, DMAC N,N' dimethyl acetamide, gamma-butyrolacton, dimethyl sulfoxide, tetramethylurea, HMPA, metacresol etc..

In the present invention, above-mentioned polymer solvent can multiple be used in mixed way.

By above-mentioned method prepare polysiloxanes polymeric solution (hereinafter also referred to polymeric solution) in, using as The silicon atom of whole alkoxy silanes that raw material adds is scaled SiO₂Obtained by concentration (hereinafter referred to as SiO₂Converted score) preferably below 20 mass %, more preferably 5～15 mass %.By in this concentration range Select arbitrary concentration, the generation of gel can be suppressed, it is thus achieved that the solution of homogenizing.

In the present invention, can be by the polymeric solution that prepared by above-mentioned method directly as the solution of polysiloxanes. Additionally, also can be concentrated by the solution that be prepared by above-mentioned method as required, or addition solvent dilution also or is replaced For other solvent, thus make the solution of polysiloxanes.

Solvent (hereinafter also referred to adding solvent) now used can be identical with polymer solvent, it is also possible to is that other is molten Agent.As long as this interpolation solvent can uniform dissolution polysiloxanes, be not particularly limited, can arbitrarily select one or many Plant and use.

As the concrete example of such interpolation solvent, except the above-mentioned solvent enumerated as the example of polymer solvent with Outward, it is also possible to enumerate the ketones such as acetone, methyl ethyl ketone, methyl iso-butyl ketone (MIBK), methyl acetate, ethyl acetate, The esters such as ethyl lactate.

These solvents can realize the viscosity of aligning agent for liquid crystal and adjust or improve by spin coating, hectographic printing, ink-jet Deng coating when aligning agent for liquid crystal is coated on substrate.

In the present invention, as long as the effect of the lossless present invention, also can comprise other composition beyond polysiloxanes, example Such as inorganic particles, metal oxygen alkane (Japanese: メタロキサ Application) oligomer, metal oxygen alkane polymer, homogenizing The composition such as agent, surfactant.

As inorganic particles, preferably silicon dioxide microparticle, alumina particulate, titanium oxide microparticle or Afluon (Asta) is micro- The microgranule of grain etc., particularly preferably in the microgranule of colloid solution state.This colloid solution can be by inorganic microparticle-dispersed Solution in disperse medium, it is also possible to be the colloid solution of commercially available product.In the present invention, inorganic micro-by comprising Grain, it is possible to give surface configuration and other function of the solidification tunicle formed.As inorganic particles, its average particle Footpath is preferably 0.001～0.2 μm, more preferably 0.001～0.1 μm.The mean diameter of inorganic particles is more than 0.2 During μm, there is the situation that the transparency of the solidification tunicle that the coating fluid made by use is formed declines.

As the disperse medium of inorganic particles, water or organic solvent can be enumerated.As colloid solution, from tunicle shape From the viewpoint of the stability of one-tenth coating fluid, preferably pH or pKa adjust to 1～10, more preferably adjust to 2～7.

As the organic solvent of the disperse medium for colloid solution, methanol, propanol, butanol, second two can be enumerated Alcohol, propylene glycol, butanediol, pentanediol, hexanediol, diethylene glycol, dipropylene glycol, ethylene glycol ether etc. Alcohols, the ketone of methyl ethyl ketone, methyl iso-butyl ketone (MIBK) etc., toluene, dimethylbenzene etc. aromatic hydrocarbon, diformazan The amide-type of base Methanamide, dimethyl acetylamide, N-Methyl pyrrolidone etc., ethyl acetate, butyl acetate, The esters of gamma-butyrolacton etc., oxolane, Isosorbide-5-Nitrae-twoThe ethers etc. of alkane etc..Wherein, preferably alcohols or ketone. These organic solvents can be used as disperse medium after mixing alone or in any combination.

As metal oxygen alkane oligomer, metal oxygen alkane polymer, can use silicon, titanium, aluminum, tantalum, antimony, bismuth, The single oxide precursor of stannum, indium, zinc etc. or precursor of compound oxide.As metal oxygen alkane oligomer, metal Oxygen alkane polymer, can be commercially available product, it is also possible to by metal alkoxide, nitrate, hydrochlorate, carboxylate etc. The compound that monomer is prepared by conventional methods such as hydrolysis.

As metal oxygen alkane oligomer, the concrete example of metal oxygen alkane polymer of commercially available product, Ke Er button spy can be enumerated Methyl silicate 51 that Co., Ltd. (コルコト society) makes, methyl silicate 53A, ethyl silicate 40, silicon Acetoacetic ester 48, the siloxane oligomer of EMS-485, SS-101 etc. or siloxane polymer, The titanoxane oligomer of the normal-butyl titanium tetramer etc. that Kanto Kagaku K. K. (chemistry society) makes.They can It is used alone or mixed use of two or more.

Additionally, levelling agent and surfactant etc. can use known reagent, particularly commercially available product because being readily available And it is preferred.

Additionally, the method mixing other above-mentioned composition in polysiloxanes can be to mix with polysiloxanes simultaneously, Can also mix behind, be not particularly limited.

The aligning agent for liquid crystal of the present invention is comprise above-mentioned polysiloxanes and other composition of using as required molten Liquid.Now, as solvent, the polymer solvent selected from above-mentioned polysiloxanes and the solvent of interpolation solvent can be used.Liquid The content of the whole polysiloxanes in brilliant alignment agent is with SiO₂Converted score meter be preferably 0.5～15 mass %, More preferably 1～6 mass %.If at such SiO₂In the range of converted score, then easily by once Thickness needed for coating acquisition, it is easy to obtain the service life of enough solution.

The method of the aligning agent for liquid crystal of the preparation present invention is not particularly limited.Polysiloxanes used by the present invention, root It is uniformly mixed state according to needing other composition added.Generally polysiloxanes polycondensation in a solvent, so Directly use the solution of polysiloxanes or to be added as needed on other composition in the solution of polysiloxanes be easy Method.And then, the method directly using the polymeric solution of polysiloxanes is the easiest.

Additionally, during the content of polysiloxanes in adjustment aligning agent for liquid crystal, can use selected from above-mentioned polysiloxanes Polymer solvent and add solvent solvent.

The liquid crystal orientation film of the present invention uses the aligning agent for liquid crystal of the present invention to prepare.Such as, can be used directly and pass through The aligning agent for liquid crystal of the present invention is coated after substrate through be dried burn till obtained by cured film as liquid crystal orientation film. In addition it is also possible to this cured film is rubbed, or irradiate polarized light or the light etc. of specific wavelength, or carry out The process of ion beam etc., or the liquid crystal display cells after filling liquid crystal is irradiated U under executing alive state V.

As the substrate of coating of liquid crystalline alignment agent, as long as the substrate that the transparency is high, it is not particularly limited, excellent Choosing is the substrate being formed with the transparency electrode for driving liquid crystal on substrate.

If act concrete example, can enumerate glass plate or Merlon, poly-(methyl) acrylate, polyether sulfone, polyarylate, Polyurethane, polysulfones, polyethers, polyether-ketone, trimethylpentene, polyolefin, polyethylene terephthalate, (first Base) acrylonitrile, tri acetyl cellulose, diacetyl cellulose, cellulose acetate-butyrate etc. plastic plate etc. on It is formed with the substrate of transparency electrode.

As the coating process of aligning agent for liquid crystal, spin-coating method, print process, ink-jet method, spraying process, roller can be enumerated Coatings etc., industrial widely used hectographic printing method from the perspective of productivity, it is also preferred that use in the present invention.

Drying process after coating of liquid crystalline alignment agent it is not absolutely required to, but from coating after to burning till time Between non-constant for each substrate or coating after burn till the most immediately in the case of, preferably include drying process.This is dried As long as removing the degree that solvent will not deform because of board carrying etc. to film shape, it is dried just Method is not particularly limited.Such as, can enumerate in temperature is 40 DEG C～150 DEG C, preferably 60 DEG C～the heating plate of 100 DEG C Upper dry 0.5～30 minute, preferably 1 minute～the method for 5 minutes.

The film formed by above-mentioned method coating of liquid crystalline alignment agent can be carried out burning till and make cured film.This Time, firing temperature can be 100 DEG C～the arbitrary temp of 350 DEG C, preferably 140 DEG C～300 DEG C, more preferably 150 DEG C～230 DEG C, be further preferred that 160 DEG C～220 DEG C.Firing time can be 5 minutes～240 minutes Random time.Preferably 10～90 minutes, more preferably 20～80 minutes.Heating can use generally well-known Method, such as heating plate, heated-air circulation oven, IR (infrared ray) stove, band oven etc..

Polysiloxanes in liquid crystal orientation film carries out polycondensation in firing process.But, in the present invention, if nothing Damage the effect of the present invention, it is not necessary to make its complete polycondensation.Preferably necessary close in than the manufacturing process of liquid crystal cell Burn till at a temperature of high more than 10 DEG C of the heat treatment temperature of envelope agent solidification etc..

The thickness of this cured film can select as required, in the feelings of preferred more than 5nm, more preferably more than 10nm Under condition, it is easy to obtain the reliability of liquid crystal display cells, it is advantageous to.Additionally, the thickness of cured film preferably exists Below 300nm, more preferably in the case of below 150nm, the power consumption of liquid crystal display cells will not be too high, It is advantageous to.

The liquid crystal display cells of the present invention can be used after formation liquid crystal orientation film with the aforedescribed process by adopting on substrate Known method makes liquid crystal cell and prepares.If enumerating the example that liquid crystal cell makes, usually with being formed with liquid A pair substrate clamping sept of brilliant alignment films, fix with sealant, inject liquid crystal and the method that seals.Now institute The size of sept be 1～30 μm, be preferably 2～10 μm.

The method injecting liquid crystal is not particularly limited, and can enumerate in making the liquid crystal cell made and inject in after decompression state The method etc. of dripping that the vacuum method of liquid crystal, the dropping laggard row of liquid crystal seal.

Carry out under alive state by executing between the electrode of the both sides substrate to the liquid crystal cell having imported liquid crystal UV irradiates, and the crosslinkable groups of acryloyl group in liquid crystal orientation film, methylacryloyl etc. is in this case It is polymerized and cross-links, thus the response speed of liquid crystal display is accelerated.Here, the voltage applied be 5～50Vp-p, It is preferably 5～30Vp-p.Irradiate UV irradiation dose be 1～60J, preferably at below 40J.UV irradiation dose is few Time, the reliability decrease that the destruction constituting the component of liquid crystal display causes can be suppressed, and make UV irradiation time Shorten, thus the running rate on manufacturing improves, it is advantageous to.

As the substrate for liquid crystal display cells, as long as the substrate that the transparency is high, it is not particularly limited, It is typically on substrate to be formed with the substrate of the transparency electrode for driving liquid crystal.Concrete example and note in [liquid crystal orientation film] The substrate carried is identical.The substrate of the electrode pattern and projection pattern with PVA and MVA of standard also can make With.On the substrate of side, the wire/slit of 1～10 μm is formed in the same manner as the liquid crystal display of PSA mode Electrode pattern, the structure not forming slit pattern or projection pattern on opposite substrate also are able to work, by this knot The liquid crystal display of structure, it is possible to simplify technique when manufacturing, it is thus achieved that high-transmission rate.

Additionally, in the such high-performance components of the element of TFT type between liquid crystal drive electrode and substrate The substrate being formed with transistor unit is used as.

In the case of transmission-type liquid crystal display element, generally use substrate as above, at reflective liquid crystal In the case of display element, it is possible to only use the such material of aluminum of reflection light at side substrate, moreover it is possible to use silicon wafer The opaque substrate such as sheet.

Embodiment

Hereinafter, carry out more specific description by embodiments of the invention, but should not be construed as and present invention is limited only to This.

[changing 14]

Equipped with in the 500ml four-hole boiling flask of magnetic stirring apparatus, add magnesium metal 1.71g, to carrying out nitrogen in container Gas displacement is the most airtight.Add THF(dehydration) after 2ml, when making its strong mixing, with 1 hour The compound 7 of 20.68g of dripping is dissolved in THF(dehydration) solution of 155ml.Then, 55 it are warming up to DEG C, stir 2 hours, confirm magnesium metal and disappear.Then, under ice-cold, (4 DEG C) disposably add tetramethoxy After silane 30.53g, it is heated to reflux, stirs 3 hours.After reactant liquor is cooled to room temperature, add saturated chlorination Aqueous ammonium 210ml, removes the insoluble matter generated by filtration under diminished pressure.Clean with the normal hexane of 260ml again and filter Thing.Remove the aqueous portion of filtrate, clean organic facies with pure water 200ml.Organic facies is carried out concentrate drying, Obtain crude product 21.65g.It is carried out decompression distillation so that it is the bar of temperature 220～230 DEG C/pressure 0.8torr outside Distillate under part, obtain the compound 8(yield 25% of 5.74g).

¹H-NMR(400MHz)in CDCl₃: 0.90ppm (t, J=7.2Hz, 3H), 1.00-1.09ppm (m, 2H),1.20-1.34ppm(m,9H),1.40-1.52ppm(m,2H),1.83-1.91ppm(m,4H), 2.41-2.51ppm(m,1H),3.62ppm(s,9H),7.23ppm(d,J=8.2Hz,2H),7.56ppm(d,J= 8.2Hz,2H)

[changing 15]

Equipped with in the 500ml four-hole boiling flask of magnetic stirring apparatus, add the compound 9 of 30.00g, 25.24g Potassium carbonate, the DMF of 120g, drip under room temperature allyl bromide, bromoallylene 22.10g.Then, at 50 DEG C, stir 11 Hour.With the diluted ethyl acetate reactant liquor of 500g, clean organic facies 3 times with the pure water of 200g.Use sodium sulfate Being dried organic facies, after being filtered, filtrate is carried out concentrate drying, the compound 10(obtaining 34.80g receives Rate 100%).

¹H-NMR(400MHz)in CDCl₃: 0.90ppm (t, J=7.2Hz, 3H), 0.99-1.09ppm (m, 2H),1.18-1.46ppm(m,11H),1.84-1.89ppm(m,4H),2.37-2.44ppm(m,1H), 4.51ppm(dt,J=5.4Hz,1.6Hz,2H),5.26ppm(dq,J=10.6Hz,1.6Hz,1H), 5.40ppm(dq,J=17.2Hz,1.6Hz,1H),6.07ppm(ddd,J=17.2Hz,10.6Hz,5.4Hz, 1H),6.83ppm(dd,J=8.8Hz,2.9Hz,2H),7.10ppm(dd,J=8.8Hz,2.9Hz,2H)

Equipped with in the 300ml four-hole boiling flask of magnetic stirring apparatus, add the compound 10 of 20.00g, the first of 120g Benzene, is stirred at room temperature.Then, Karstedt catalyst (platinum (0)-1,1,3,3-tetramethyl two silicon are added The xylene solution of oxygen 0.1 mole/L of alkane complex) after 700 μ l, drip trimethoxy silane 12.4ml.In After stirring 29 hours under room temperature, reactant liquor is carried out concentrate drying, obtains crude product.It is carried out decompression distillation, Make its outside temperature 245 DEG C/pressure 0.8torr under conditions of distillate, obtain the compound 11(yield 43 of 12.15g %).

¹H-NMR(400MHz)in CDCl₃: 0.76-0.82ppm (m, 2H), 0.89ppm (t, J=7.2Hz, 3H),0.98-1.08ppm(m,2H),1.18-1.45ppm(m,11H),1.84-1.93ppm(m,6H), 2.36-2.43ppm(m,1H),3.58ppm(s,9H),3.91ppm(t,J=6.8Hz,2H),6.81ppm(d,J= 8.8Hz,2H),7.08ppm(d,J=8.8Hz,2H)

The abbreviation of compound used in the present embodiment is as follows.

TEOS: tetraethoxysilane

C18: octadecyltriethoxy silane

ACPS:3-acryloxypropyl trimethoxy silane

MPMS:3-methacryloxypropyl trimethoxy silane

M8MS:3-methacryloxy octyl group trimethoxy silane

MTES: MTES

HG:2-methyl-2,4-PD (another name: hexanediol)

BCS:2-butyl cellosolve

UPS:3-ureidopropyltriethoxysilane

Equipped with thermometer, the 200mL of return duct four mouthfuls of reaction flasks in, by HG, 7.2g of 21.5g BCS, 32.9g TEOS, 4.1g synthesis example 1 in the MPM of compound 8 and 5.0g for preparing S mixes, and is configured to the solution of alkoxy silane monomer.At room temperature dripped in advance in this solution with 30 minutes It is mixed with the water of BCS, 10.8g of HG, 3.6g of 10.7g and 0.4g ethanedioic acid molten as catalyst Liquid, then stirring 30 minutes at room temperature.Then, after making it reflux 30 minutes with oil bath heating, add and mix in advance Close BCS mixed of HG and 0.1g of the methanol solution of UPS content 92 mass % of 0.6g, 0.3g Close liquid.Let cool after refluxing again 30 minutes, it is thus achieved that SiO₂Converted score is the polysiloxane solution of 12 weight %.

By polysiloxane solution and the BCS mixing of 20.0g of 10.0g gained, prepare SiO₂Converted score It it is the aligning agent for liquid crystal ［ K1 ］ of 4 weight %.

Equipped with thermometer, the 200mL of return duct four mouthfuls of reaction flasks in, by HG, 6.9g of 20.8g BCS, 22.5g TEOS, 3.5g synthesis example 3 in the MP of compound 11 and 19.9g for preparing MS mixes, and is configured to the solution of alkoxy silane monomer.At room temperature dripped pre-in this solution with 30 minutes First it is mixed with the water of BCS, 10.8g of HG, 3.5g of 10.4g and the 1.1g ethanedioic acid as catalyst Solution, then stirring 30 minutes at room temperature.Then, after making it reflux 30 minutes with oil bath heating, add in advance It is mixed with the BCS's of HG and 0.1g of the methanol solution of UPS content 92 mass % of 0.6g, 0.3g Mixed liquor.Let cool after refluxing again 30 minutes, it is thus achieved that SiO₂Converted score is that the polysiloxanes of 12 weight % is molten Liquid.

By polysiloxane solution and the BCS mixing of 20.0g of 10.0g gained, prepare SiO₂Converted score It it is the aligning agent for liquid crystal intermediate (S2) of 4 weight %.

Equipped with thermometer, the 200mL of return duct four mouthfuls of reaction flasks in, by HG, 7.9g of 23.8g BCS, 37.1g TEOS and 3.6g MTES mixing, be configured to alkoxy silane monomer Solution.In this solution, the BC of HG, 4.0g of being pre-mixed 11.9g was at room temperature dripped with 30 minutes The water of S, 10.8g and 0.4g are as the solution of the ethanedioic acid of catalyst, then are stirred at room temperature 30 minutes.So After, after making it reflux 30 minutes with oil bath heating, add UPS content 92 mass being pre-mixed 0.6g The methanol solution of %, the mixed liquor of BCS of HG and 0.1g of 0.3g.Let cool after refluxing again 30 minutes, obtain Obtain SiO₂Converted score is the polysiloxane solution of 12 weight %.

By polysiloxane solution and the BCS mixing of 20.0g of 10.0g gained, prepare SiO₂Converted score It it is the aligning agent for liquid crystal intermediate (U1) of 4 weight %.

By the aligning agent for liquid crystal intermediate (S2) of gained and aligning agent for liquid crystal intermediate (U1) with 2:8 Ratio mixing, prepare SiO₂Converted score is the aligning agent for liquid crystal ［ K2 ］ of 4 weight %.

Equipped with thermometer, the 200mL of return duct four mouthfuls of reaction flasks in, by HG, 6.9g of 20.5g BCS, 22.5g TEOS, 4.1g synthesis example 3 in the MP of compound 11 and 19.9g for preparing MS mixes, and is configured to the solution of alkoxy silane monomer.At room temperature dripped pre-in this solution with 30 minutes First it is mixed with the water of BCS, 10.8g of HG, 3.4g of 10.3g and the 1.1g ethanedioic acid as catalyst Solution, then stirring 30 minutes at room temperature.Then, after making it reflux 30 minutes with oil bath heating, add in advance It is mixed with the BCS's of HG and 0.1g of the methanol solution of UPS content 92 mass % of 0.6g, 0.3g Mixed liquor.Let cool after refluxing again 30 minutes, it is thus achieved that SiO₂Converted score is that the polysiloxanes of 12 weight % is molten Liquid.

By polysiloxane solution and the BCS mixing of 20.0g of 10.0g gained, prepare SiO₂Converted score It it is the aligning agent for liquid crystal intermediate (S3) of 4 weight %.

The aligning agent for liquid crystal intermediate that will prepare in the aligning agent for liquid crystal intermediate (S3) of gained and embodiment 2 (U1) mix with the ratio of 2:8, prepare SiO₂Converted score is the aligning agent for liquid crystal ［ K of 4 weight % 3 ］.

Equipped with thermometer, the 200mL of return duct four mouthfuls of reaction flasks in, by HG, 6.3g of 19.1g BCS, 16.3g TEOS, 8.2g synthesis example 3 in the MP of compound 11 and 24.8g for preparing MS mixes, and is configured to the solution of alkoxy silane monomer.At room temperature dripped pre-in this solution with 30 minutes First it is mixed with the water of BCS, 10.8g of HG, 3.2g of 9.5g and the 1.3g ethanedioic acid as catalyst Solution, then stirring 30 minutes at room temperature.Then, after making it reflux 30 minutes with oil bath heating, add in advance It is mixed with the BCS's of HG and 0.1g of the methanol solution of UPS content 92 mass % of 0.6g, 0.3g Mixed liquor.Let cool after refluxing again 30 minutes, it is thus achieved that SiO₂Converted score is that the polysiloxanes of 12 weight % is molten Liquid.

By polysiloxane solution and the BCS mixing of 20.0g of 10.0g gained, prepare SiO₂Converted score It it is the aligning agent for liquid crystal intermediate (S4) of 4 weight %.

The aligning agent for liquid crystal intermediate that will prepare in the aligning agent for liquid crystal intermediate (S4) of gained and embodiment 2 (U1) mix with the ratio of 2:8, prepare SiO₂Converted score is the aligning agent for liquid crystal ［ K of 4 weight % 4 ］.

Equipped with thermometer, the 200mL of return duct four mouthfuls of reaction flasks in, by HG, 6.0g of 17.9g BCS, 25.0g TEOS, 8.2g synthesis example 3 in the M8 of compound 11 and 19.1g for preparing MS mixes, and is configured to the solution of alkoxy silane monomer.At room temperature dripped pre-in this solution with 30 minutes First it is mixed with the water of BCS, 10.8g of HG, 3.0g of 9.0g and the 1.1g ethanedioic acid as catalyst Solution, then stirring 30 minutes at room temperature.Then, it is made to let cool after refluxing 60 minutes with oil bath heating, it is thus achieved that SiO₂Converted score is the polysiloxane solution of 12 weight %.

By polysiloxane solution and the BCS mixing of 20.0g of 10.0g gained, prepare SiO₂Converted score It it is the aligning agent for liquid crystal ［ S5 ］ of 4 weight %.

By polysiloxane solution and the BCS mixing of 20.0g of 10.0g gained, prepare SiO₂Converted score It it is the aligning agent for liquid crystal intermediate (U2) of 4 weight %.

By the aligning agent for liquid crystal intermediate (S5) of gained and aligning agent for liquid crystal intermediate (U2) with 2:8 Ratio mixing, prepare SiO₂Converted score is the aligning agent for liquid crystal ［ K5 ］ of 4 weight %.

Equipped with thermometer, the 200mL of return duct four mouthfuls of reaction flasks in, by HG, 6.5g of 19.4g BCS, 22.5g TEOS, 8.2g synthesis example 3 in prepare compound 11, the MPM of 14.9g The M8MS mixing of S and 3.2g, is configured to the solution of alkoxy silane monomer.At room temperature with 30 minutes In this solution, dropping has been pre-mixed water and the 1.1g conduct of BCS, 10.8g of HG, 3.2g of 9.7g The solution of the ethanedioic acid of catalyst, then stirring 30 minutes at room temperature.Then, it is made to reflux 30 with oil bath heating After minute, add be pre-mixed the methanol solution of UPS content 92 mass % of 0.6g, the HG of 0.3g and The mixed liquor of the BCS of 0.1g.Let cool after refluxing again 30 minutes, it is thus achieved that SiO₂Converted score is 12 weights The polysiloxane solution of amount %.

By polysiloxane solution and the BCS mixing of 20.0g of 10.0g gained, prepare SiO₂Converted score It it is the aligning agent for liquid crystal intermediate (S6) of 4 weight %.

The aligning agent for liquid crystal intermediate that will prepare in the aligning agent for liquid crystal intermediate (S6) of gained and embodiment 5 (U2) mix with the ratio of 2:8, prepare SiO₂Converted score is the aligning agent for liquid crystal ［ K of 4 weight % 6 ］.

Equipped with thermometer, the 200mL of return duct four mouthfuls of reaction flasks in, by HG, 7.3g of 22.1g BCS, 35.0g TEOS, 4.2g C18 and 5.0g MPMS mixing, be configured to alkane The solution of TMOS monomer.In this solution, the H being pre-mixed 11.0g was at room temperature dripped with 30 minutes The water of BCS, 10.8g of G, 3.7g and 0.4g are as the solution of the ethanedioic acid of catalyst, then stir at room temperature Mix 30 minutes.Then, after making it reflux 30 minutes with oil bath heating, the UP being pre-mixed 0.6g is added The methanol solution of S content 92 mass %, the mixed liquor of BCS of HG and 0.1g of 0.3g.Reflux 30 again Let cool after minute, it is thus achieved that SiO₂Converted score is the polysiloxane solution of 12 weight %.

By polysiloxane solution and the BCS mixing of 20.0g of 10.0g gained, prepare SiO₂Converted score It it is the aligning agent for liquid crystal ［ L1 ］ of 4 weight %.

Equipped with thermometer, the 200mL of return duct four mouthfuls of reaction flasks in, by HG, 7.5g of 22.6g BCS, 39.2g TEOS, 4.2g C18 mixing, be configured to the molten of alkoxy silane monomer Liquid.At room temperature with 30 minutes in this solution dropping be pre-mixed 11.3g HG, 3.7g BCS, The water of 10.8g and 0.2g are as the solution of the ethanedioic acid of catalyst, then stirring 30 minutes at room temperature.Then, After making it reflux 30 minutes with oil bath heating, addition has been pre-mixed UPS content 92 mass % of 0.6g Methanol solution, the mixed liquor of BCS of HG and 0.1g of 0.3g.Let cool after refluxing again 30 minutes, it is thus achieved that S IO₂Converted score is the polysiloxane solution of 12 weight %.

By polysiloxane solution and the BCS mixing of 20.0g of 10.0g gained, prepare SiO₂Converted score It it is the aligning agent for liquid crystal intermediate (S5) of 4 weight %.

The aligning agent for liquid crystal intermediate that will prepare in the aligning agent for liquid crystal intermediate (S5) of gained and synthesis example 2 (U1) mix with the ratio of 2:8, prepare SiO₂Converted score is the aligning agent for liquid crystal ［ L of 4 weight % 2 ］.

Equipped with thermometer, the 200mL of return duct four mouthfuls of reaction flasks in, by HG, 6.8g of 20.5g BCS, 22.5g TEOS, 4.2g C18 and 19.9g MPMS mixing, be configured to The solution of alkoxy silane monomer.At room temperature dripped in this solution with 30 minutes and be pre-mixed 10.3g's The water of BCS, 10.8g of HG, 3.4g and 1.1g are as the solution of the ethanedioic acid of catalyst, more at room temperature Stir 30 minutes.Then, after making it reflux 30 minutes with oil bath heating, the U being pre-mixed 0.6g is added The methanol solution of PS content 92 mass %, the mixed liquor of BCS of HG and 0.1g of 0.3g.Reflux again Let cool after 30 minutes, it is thus achieved that SiO₂Converted score is the polysiloxane solution of 12 weight %.

By polysiloxane solution and the BCS mixing of 20.0g of 10.0g gained, prepare SiO₂Converted score It it is the aligning agent for liquid crystal intermediate (L3) of 4 weight %.

The aligning agent for liquid crystal ［ K1 ］ prepared in embodiment 1 is spun on the I being formed with comprehensive ITO electrode On the ito surface of TO electrode base board.After being dried 2 minutes by the heating plate of 80 DEG C, with 200 DEG C or 220 DEG C Heated air circulation type stove carries out 30 minutes burn till, and forms the liquid crystal orientation film of thickness 100nm.Prepare two pieces this Substrate, after the liquid crystal aligning face of one piece of substrate spreads the pearl sept of 4 μm or 6 μm, thereon Printing and sealing agent.After another block substrate mode with liquid crystal aligning face as inner side is fitted, make sealant cures and Make negative crystal born of the same parents.Liquid crystal MLC-6608 (Merck & Co., Inc. (メ is injected in negative crystal intracellular by decompression injection method ルク society) trade name processed), make liquid crystal cell.

Then, the liquid crystal cell of gained is carried out in the circulating stove of 100 DEG C the annealing of 30 minutes.At polarization Under the state that sheet is cross Nicols, the structure cell taken out is carried out microscope observation, observe the district that the orientation of liquid crystal is at random The state in territory.The results are shown in table 1.

The aligning agent for liquid crystal ［ K2 ］ prepared in embodiment 2 is spun on Pixel Dimensions be 100 × 300 microns, Formed wired/space be respectively 5 microns ITO electrode pattern ITO electrode substrate ito surface on. After being dried 2 minutes by the heating plate of 80 DEG C, carry out 30 minutes with the heated air circulation type stove of 200 DEG C or 220 DEG C Burn till, form the liquid crystal orientation film of thickness 100nm.The aligning agent for liquid crystal ［ K2 ］ that will obtain in synthesis example 2 It is spun on the ito surface not forming electrode pattern, after being dried 2 minutes by the heating plate of 80 DEG C, with aforesaid substrate Similarly carry out 30 minutes burn till with the heated air circulation type stove of 200 DEG C or 220 DEG C, form thickness 100nm's Liquid crystal orientation film.Prepare two pieces of this substrates, the liquid crystal aligning face of one piece of substrate spreads the pearl of 4 μm After sept, printing and sealing agent thereon.After another block substrate mode with liquid crystal aligning face as inner side is fitted, Sealant cures is made to make negative crystal born of the same parents.Liquid crystal MLC-660 is injected in negative crystal intracellular by decompression injection method 8 (Merck & Co., Inc.'s trade names), make liquid crystal cell.

The response speed characteristic of these liquid crystal cell by reading the AC of applying ± 5V to liquid crystal cell with oscillograph Voltage, frequency 1kHz square wave time liquid crystal panel brightness obtain over time.By no applied voltage Time brightness be set to 0%, the voltage of applying ± 5V, saturated brightness value are set to 100%, by brightness flop extremely Time till 10%～90% is as the response speed hoisted.

Measured by aftermentioned method.

Then, when this liquid crystal cell being applied the D/C voltage of 20V, from the outside of this liquid crystal cell Irradiate the UV of 20J.Afterwards, again measure response speed characteristic, the response speed after UV pre-irradiation is carried out Relatively.The results are shown in table 2.

Subsequently, the liquid crystal cell of gained is carried out in the circulating stove of 100 DEG C the annealing of 30 minutes.At polarization Under the state that sheet is cross Nicols, the structure cell taken out is carried out microscope observation, observe the district that the orientation of liquid crystal is at random The state in territory.The results are shown in table 2.

In addition to aligning agent for liquid crystal ［ K2 ］ is changed in embodiment 3 aligning agent for liquid crystal ［ K3 ］ prepared, Make liquid crystal cell in the same manner as structure cell embodiment 2, measure response speed, observe the district that the orientation after annealing is at random Territory.The results are shown in table 2.

In addition to aligning agent for liquid crystal ［ K2 ］ is changed in embodiment 4 aligning agent for liquid crystal ［ K4 ］ prepared, Make liquid crystal cell in the same manner as structure cell embodiment 2, measure response speed, observe the district that the orientation after annealing is at random Territory.The results are shown in table 2.

Except aligning agent for liquid crystal ［ K2 ］ is changed in embodiment 5 prepare aligning agent for liquid crystal ［ K5 ］ with Outward, make liquid crystal cell in the same manner as structure cell embodiment 2, measure response speed, observe the orientation after annealing at random Region.The results are shown in table 2.

Except aligning agent for liquid crystal ［ K2 ］ is changed in embodiment 6 prepare aligning agent for liquid crystal ［ K6 ］ with Outward, make liquid crystal cell in the same manner as structure cell embodiment 2, measure response speed, observe the orientation after annealing at random Region.The results are shown in table 2.

Except aligning agent for liquid crystal ［ K1 ］ is changed in comparative example 1 prepare aligning agent for liquid crystal ［ L1 ］ with Outward, liquid crystal cell is made in the same manner as structure cell embodiment 1.Then, by the liquid crystal cell of gained 100 DEG C follow Circular furnace carries out the annealing of 30 minutes.When polaroid is cross Nicols, the structure cell taken out is carried out Microscope is observed, and observes the state being orientated region at random of liquid crystal.The results are shown in table 1.

Except aligning agent for liquid crystal ［ K2 ］ is changed in comparative example 2 prepare aligning agent for liquid crystal ［ L2 ］ with Outward, make liquid crystal cell in the same manner as structure cell embodiment 2, measure response speed, observe the orientation after annealing at random Region.The results are shown in table 2.

Except aligning agent for liquid crystal ［ K1 ］ is changed in comparative example 3 prepare aligning agent for liquid crystal ［ L3 ］ with Outward, make liquid crystal cell in the same manner as structure cell embodiment 1, measure response speed, observe the orientation after annealing at random Region.The results are shown in table 2.

[response speed characteristic]

For liquid crystal cell, when reading the square wave of the AC voltage of applying ± 5V, frequency 1kHz with oscillograph The brightness of liquid crystal panel is over time.Brightness during no applied voltage is set to 0%, by applying ± 5V's Voltage, saturated brightness value be set to 100%, and the time using brightness flop to 10%～90% is as hoisting Response speed.

Table 43

Structure cell	Alignment agent	Present the side chain monomer of tilt angle	Regional observation result after annealing
				Embodiment 1	K1	Compound 8	◎
Comparative example 1	L1	C18	×

Knowable to table 43, the liquid crystal cell of structure cell embodiment 1 is after annealing entirely without observing that orientation is at random Region.And the liquid crystal cell of structure cell comparative example 1 is after annealing, it was observed that the region that a large amount of orientations are at random.

Table 44

The judgement zero of response speed: fast (well) ×: slow (bad)

Regional observation result after annealing

×: observe region the most at random

Zero: good

◎: the best

Knowable to table 44, the fast response time after the UV irradiation of structure cell embodiment 2, and the region sight after annealing Examine result the best.And although regional observation result after structure cell comparative example 2 annealing is the best, but response speed is slow. Although structure cell comparative example 3 fast response time, but observe region the most at random after annealing.And then in employing In the structure cell embodiment 3,4 of compound 11, the fast response time after UV irradiation, and the regional observation after annealing Result is also very good.

And then in structure cell embodiment 5,6, the fast response time after UV irradiation, and the regional observation after annealing Result is also very good.

The probability utilized in industry

Use the aligning agent for liquid crystal of the present invention, even if using the liquid crystal without polymerizable compound and PS A mode similarly carry out processing and make UV irradiate after response speed improve mode liquid crystal display cells in, It also is able to form the liquid crystal orientation film that the response speed after not making the decline of vertical orientated power that UV can be made to irradiate improves, The present invention also provides for the liquid crystal orientation film prepared by this aligning agent for liquid crystal and the liquid crystal with this liquid crystal orientation film Show element.Therefore, can be used for TFT liquid crystal display cells, the TN liquid crystal display unit manufactured by said method Part, VA liquid crystal display cells etc..

It is hereby incorporated the Japanese patent application filed an application on May 27th, 2,011 2011-118824 and 2011 The description of Japanese patent application 2011-251377 filed an application on November 17, claims, attached All the elements of figure and summary are as the announcement of description of the invention.

Claims

1. aligning agent for liquid crystal, it is characterised in that containing polysiloxane (A), this polysiloxanes (A) is by containing There are alkoxy silane that following formula (1) represents and the alkoxyl silicone of the alkoxy silane that following formula (3) represents Alkane polycondensation and obtain,

R¹Si(OR²)₃ (1)

R¹Represent the structure of following formula (2), R²Represent the alkyl of carbon number 1～5；

Y¹For singly-bound ,-(CH₂)_a-,-O-,-CH₂O-,-COO-or- OCO-,-(CH₂)_aA in-is the integer of 1～15；Y²For singly-bound, containing double bond The straight-chain of carbon number 3～8 or branched alkyl or-(CR¹⁷R¹⁸)_b-,-(CR¹⁷R¹⁸)_b B in-represents the integer of 1～15, R¹⁷、R¹⁸Separately represent hydrogen atom or carbon number 1～3 Alkyl；Y³For singly-bound ,-(CH₂)_c-,-O-,-CH₂O-,-COO- Or-OCO-,-(CH₂)_cC in-is the integer of 1～15；Y⁴For selected from phenyl ring, ring The bivalent cyclic base of hexyl ring and heterocycle, or there is the divalent organic base of the carbon number 12～25 of steroid skeleton, this Any hydrogen atom in a little cyclic group can be selected from the alkyl of carbon number 1～3, the alkoxyl of carbon number 1～3, carbon number 1～ The group containing fluoroalkyl, the fluoroalkoxy of carbon number 1～3 and fluorine atom of 3 replaces；Y⁵For selected from phenyl ring, The bivalent cyclic base of cyclohexyl ring and heterocycle, any hydrogen atom in these cyclic group can by the alkyl of carbon number 1～3, The alkoxyl of carbon number 1～3, the taking containing fluoroalkyl, the fluoroalkoxy of carbon number 1～3 or fluorine atom of carbon number 1～3 Generation；N is the integer of 0～4；Y⁶For the alkyl of carbon number 1～18, carbon number 1～18 containing fluoroalkyl, carbon number The alkoxyl of 1～18 or the fluoroalkoxy of carbon number 1～18；

R³Si(OR⁴)₃ (3)

R³For by acryloyl group, acryloxy, methylacryloyl, methacryloxy or styrene The alkyl of the substituted carbon number of base 1～30, R⁴Alkyl for carbon number 1～5.

2. aligning agent for liquid crystal as claimed in claim 1, it is characterised in that in described formula (3), R³For The carbon number replaced by acryloyl group, acryloxy, methylacryloyl, methacryloxy or styryl The alkyl of 3～10.

3. aligning agent for liquid crystal as claimed in claim 1 or 2, it is characterised in that possibly together with polysiloxanes (B), The alcoxyl of the alkoxy silane that this polysiloxanes (B) is represented by the following formula (5) containing 50%～100% Base silane polycondensation and obtain,

Si(OR¹⁵)₄ (5)

R¹⁵Represent the alkyl of carbon number 1～5.

4. aligning agent for liquid crystal as claimed in claim 3, it is characterised in that polysiloxanes (B) is by also containing There is polysiloxanes obtained by the alkoxy silane polycondensation of the alkoxy silane that formula (3) represents.

5. aligning agent for liquid crystal as claimed in claim 3, it is characterised in that polysiloxanes (B) is by also containing There is polysiloxanes obtained by the alkoxy silane polycondensation of the alkoxy silane that following formula (6) represents,

R¹⁶Si(OR¹⁷)₃ (6)

R¹⁶Represent the alkyl of carbon number 1～5, R¹⁷Represent the alkyl of carbon number 1～5.

6. aligning agent for liquid crystal as claimed in claim 1, it is characterised in that polysiloxanes (A) and poly-silica At least one party of alkane (B) is by the alkoxy silane of the alkoxy silane represented possibly together with following formula (4) Polysiloxanes obtained by polycondensation,

(R¹³)_nSi(OR¹⁴)_4-n (4)

In formula (4), R¹³Represent hydrogen atom or can be by hetero atom, halogen atom, amino, epoxy the third oxygen Base, sulfydryl, NCO, the alkyl of carbon number 1～10 of Carbamido substituted, R¹⁴Represent that carbon is former The alkyl of subnumber 1～5, n represents the integer of 0～3.

7. aligning agent for liquid crystal as claimed in claim 1, it is characterised in that the alcoxyl that described formula (1) represents Content in whole alkoxy silanes that base silane is used in polysiloxanes (A) is 2～20 moles of %, and In whole alkoxy silanes that the alkoxy silane that described formula (3) represents is used in polysiloxanes (A) Content is 5～80 moles of %.

8. liquid crystal orientation film, by the aligning agent for liquid crystal according to any one of claim 1～7 is coated substrate, Drying, burn till and prepare.

9. liquid crystal display cells, has the liquid crystal orientation film described in claim 8.

10. liquid crystal display cells, has irradiated UV to liquid crystal cell under executing alive state and has formed, wherein Liquid crystal cell by use by according to any one of claim 1～7 aligning agent for liquid crystal be coated with and through burning till two Block substrate clamping liquid crystal forms.

The manufacture method of 11. liquid crystal display cells, uses and is taken by the liquid crystal according to any one of claim 1～7 To agent coating two blocks of substrate clamping liquid crystal through burning till, under executing alive state, irradiate UV.