CN103710648A - Long-carbon fiber reinforced titanium alloy composite material - Google Patents
Long-carbon fiber reinforced titanium alloy composite material Download PDFInfo
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- CN103710648A CN103710648A CN201410018724.9A CN201410018724A CN103710648A CN 103710648 A CN103710648 A CN 103710648A CN 201410018724 A CN201410018724 A CN 201410018724A CN 103710648 A CN103710648 A CN 103710648A
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- 229910001069 Ti alloy Inorganic materials 0.000 title claims abstract description 73
- 229920000049 Carbon (fiber) Polymers 0.000 title claims abstract description 59
- 239000004917 carbon fiber Substances 0.000 title claims abstract description 59
- 239000002131 composite material Substances 0.000 title claims abstract description 28
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 53
- 239000000843 powder Substances 0.000 claims abstract description 20
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims abstract description 18
- 238000010438 heat treatment Methods 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 13
- 230000008569 process Effects 0.000 claims abstract description 11
- 229910052759 nickel Inorganic materials 0.000 claims abstract description 9
- 238000005245 sintering Methods 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims abstract description 8
- 238000003892 spreading Methods 0.000 claims abstract description 6
- 230000007480 spreading Effects 0.000 claims abstract description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052804 chromium Inorganic materials 0.000 claims abstract description 5
- 239000011651 chromium Substances 0.000 claims abstract description 5
- 238000001816 cooling Methods 0.000 claims abstract description 5
- 230000008021 deposition Effects 0.000 claims abstract description 5
- 238000007747 plating Methods 0.000 claims abstract description 5
- 230000032683 aging Effects 0.000 claims description 30
- 238000002791 soaking Methods 0.000 claims description 14
- 239000010936 titanium Substances 0.000 claims description 14
- 229910052726 zirconium Inorganic materials 0.000 claims description 14
- 229910045601 alloy Inorganic materials 0.000 claims description 13
- 239000000956 alloy Substances 0.000 claims description 13
- 238000000137 annealing Methods 0.000 claims description 12
- 229910052718 tin Inorganic materials 0.000 claims description 10
- 230000004913 activation Effects 0.000 claims description 8
- 238000005097 cold rolling Methods 0.000 claims description 8
- 238000002844 melting Methods 0.000 claims description 8
- 230000008018 melting Effects 0.000 claims description 8
- 238000005096 rolling process Methods 0.000 claims description 8
- 238000007669 thermal treatment Methods 0.000 claims description 7
- 229920002120 photoresistant polymer Polymers 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- 229910004349 Ti-Al Inorganic materials 0.000 claims description 4
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 4
- 229910004692 Ti—Al Inorganic materials 0.000 claims description 4
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 4
- 238000001035 drying Methods 0.000 claims description 4
- 238000005242 forging Methods 0.000 claims description 4
- 238000000265 homogenisation Methods 0.000 claims description 4
- 238000005098 hot rolling Methods 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- 230000003647 oxidation Effects 0.000 claims description 4
- 238000007254 oxidation reaction Methods 0.000 claims description 4
- 239000002994 raw material Substances 0.000 claims description 4
- 230000009467 reduction Effects 0.000 claims description 4
- 239000007787 solid Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 101150003085 Pdcl gene Proteins 0.000 claims description 2
- 229910021607 Silver chloride Inorganic materials 0.000 claims description 2
- 235000011114 ammonium hydroxide Nutrition 0.000 claims description 2
- 238000001354 calcination Methods 0.000 claims description 2
- 230000003472 neutralizing effect Effects 0.000 claims description 2
- HKZLPVFGJNLROG-UHFFFAOYSA-M silver monochloride Chemical compound [Cl-].[Ag+] HKZLPVFGJNLROG-UHFFFAOYSA-M 0.000 claims description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 239000011248 coating agent Substances 0.000 abstract 1
- 238000000576 coating method Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 8
- 238000005275 alloying Methods 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
Abstract
The invention relates to a long-carbon fiber reinforced titanium alloy composite material. A preparation method of the composite material comprises the following steps: preparing a titanium alloy; performing pretreatment on carbon fiber, nickel plating and chromium deposition; uniformly spreading the titanium alloy powder in a mould; arranging the sheared coating carbon fiber on the titanium alloy powder layer, and spreading a layer of titanium alloy powder; repeating the process until the mould is full; performing heating operation on the powder; sintering in a vacuum furnace; and cooling to obtain a sintered body to obtain the carbon fiber reinforced titanium alloy composite material. The composite material has the technical effect of extremely high strength.
Description
Technical field
The invention belongs to alloy composite materials field, particularly relate to a kind of long carbon fiber and strengthen titanium alloy composite material.
Background technology
Carbon fiber strengthens titanium alloy composite material and is composited by the carbon fiber that has the titanium alloy of high specific strength and have high ratio modulus, a stretch-proof, has that density is low, specific tenacity is high, stretch-proof and a specific modulus advantages of higher.Its mechanical property can be carried out the adjustment in certain limit by adjusting the distribution of carbon fiber in titanium alloy and the control of titanium alloy component, is a kind of high performance lightweight structural material.
Summary of the invention
The object of the invention is to propose a kind of long carbon fiber and strengthen titanium alloy composite material;
For reaching this object, the present invention by the following technical solutions:
Long carbon fiber strengthens a titanium alloy composite material, it is characterized in that, it is compound by long carbon fiber and titanium alloy stratiform that this long carbon fiber strengthens titanium alloy composite material, and its preparation method comprises following steps:
(1) prepare titanium alloy, described titanium alloy is grouped into by following one-tenth according to weight percentage: Nb:21 ~ 24%, and Zr:8.2 ~ 9.1%, Sn:12 ~ 18.6%, O:0.012 ~ 0.180%, RE:1.0 ~ 1.6%, Al:2.2 ~ 3.1%, surplus is Ti;
(2) carbon fiber remove photoresist, neutralize, activation, reduction pretreatment;
(3) at carbon fiber surface, carry out chemical nickel plating;
(4) the nickel-coated carbon fibers surface chemistry deposition layer of metal chromium obtaining in step (3) after cleaning-drying;
(5) plated carbon fiber step (4) being obtained is cut into the length of 1 ~ 20mm;
(6) by the titanium alloys powdered of step (1), by titanium alloy powder uniform spreading in mould, thickness is 1 ~ 5cm, then the plated carbon fiber that alignment step (5) shears on titanium alloy powder layer, and then laying one deck titanium alloy powder, thickness is 1 ~ 5mm, repeats said process to mould and fills up;
(8) powder is implemented to pressurized, heated operation, temperature is 110 ~ 182 ℃, and pressure is 560 ~ 800MPa, and the dwell time is 10 ~ 180s;
(9) in vacuum oven, carry out sintering, sintering temperature is 1010 ~ 1480 ℃, and the sintered heat insulating time is 1 ~ 6h;
(10) the sintered compact that cooling step (9) obtains obtains this long carbon fiber and strengthens titanium alloy composite material;
Described titanium alloy is made by following steps:
(a) batching: according to Nb:21 ~ 24%, Zr:8.2 ~ 9.1%, Sn:12 ~ 18.6%, O:0.012 ~ 0.180%, RE:1.0 ~ 1.6%, Al:2.2 ~ 3.1%, surplus is Ti; Prepare burden, wherein Ti is with titanium sponge, and Zr adopts Ti-52Nb master alloy, Sn to adopt Ti-68Sn master alloy, RE to adopt mishmetal, Al to adopt Ti-Al master alloy with zirconium sponge, Nb, and O is relict element in above-mentioned raw materials;
(b) melting: the material that step (a) is prepared is pressed into electrode, in vacuum consumable electrode arc furnace, melting is 2 times;
(c) homogenizing annealing: homogenization temperature is 992 ~ 1210 ℃, and the hold-time is 11 ~ 18h, removal zone of oxidation strips off the skin after annealing;
(d) forge: Forge Heating temperature is 925 ~ 990 ℃, and soaking time is 68 ~ 86min, and final forging temperature is 810 ~ 860 ℃;
(e) hot rolling: process annealing is not carried out in rolling, rolling pass is 8;
(f) cold rolling: cold rolling total deformation is 80%;
(g) solution heat treatment: cold-reduced sheet is carried out in chamber type electric resistance furnace to solution heat treatment, solid solubility temperature is 835-860 ℃, and soaking time is 0.8-1.8h, shrend;
(h) timeliness thermal treatment: be divided into following four steps: aging temp is 300 ~ 320 ℃, soaking time is 5 ~ 18min, shrend; Carry out ageing treatment for the second time being heated to 400 ~ 420 ℃, aging time is 1 ~ 1.8h, shrend; Reheat 480 ~ 495 ℃ and carry out timeliness for the third time, aging time is 2 ~ 2.5h, shrend; Reheat 520 ~ 550 ℃ and carry out timeliness the 4th time, aging time is 5 ~ 8h, shrend; Obtain titanium alloy finished product.
As preferably, described carbon fiber removes photoresist to process and adopts air calcination method to carry out.
As preferably, it is characterized in that, described carbon fiber neutralizing treatment adopts KOH or ammoniacal liquor to neutralize.
As preferably, described carbon fiber activation treatment adopts PdCl
2with AgCl be activation solution.
As preferably, in titanium alloy preparation process, timeliness thermal treatment is divided into following four steps: aging temp is 310 ℃, and soaking time is 8min, shrend; Reheat 420 ℃ and carry out ageing treatment for the second time, aging time is 1h, shrend; Reheat 485 ℃ and carry out timeliness for the third time, aging time is 2h, shrend; Reheat 535 ℃ and carry out timeliness the 4th time, aging time is 5h, shrend.
As preferably, described titanium alloy is grouped into by following one-tenth according to weight percentage: Nb:22%, and Zr:8.9%, Sn:16.6%, O:0.14%, RE:1.52%, Al:2.9%, surplus is Ti.
effect of the present invention is:
Titanium alloy by specific specific concrete carbon fiber and concrete component content coordinates, and final composite property is largely increased;
By heat treated cooperations such as concrete timeliness thermal treatment and concrete solid solutions, make to there is high strength as the titanium alloy of matrix, high elastic coefficient, the elongation of becoming reconciled and fracture toughness property, finally cause end properties high;
By the restriction of above-mentioned concrete preparation method's parameter and coordinating of concrete alloying constituent, stability has been reached more than 90%.
Embodiment
embodiment 1
Long carbon fiber strengthens a titanium alloy composite material, and it is compound by long carbon fiber and titanium alloy stratiform that this long carbon fiber strengthens titanium alloy composite material, and its preparation method comprises following steps:
(1) prepare titanium alloy, described titanium alloy is grouped into by following one-tenth according to weight percentage: Nb:23%, and Zr:8.8%, Sn:15.6%, O:0.018%, RE:1.56%, Al:2.8%, surplus is Ti;
(2) carbon fiber remove photoresist, neutralize, activation, reduction pretreatment;
(3) at carbon fiber surface, carry out chemical nickel plating;
(4) the nickel-coated carbon fibers surface chemistry deposition layer of metal chromium obtaining in step (3) after cleaning-drying;
(5) plated carbon fiber step (4) being obtained is cut into the length of 18mm;
(6), by the titanium alloys powdered of step (1), by titanium alloy powder uniform spreading, in mould, thickness is 4cm, then the plated carbon fiber that alignment step (5) shears on titanium alloy powder layer, and then lay one deck titanium alloy powder, thickness is 4mm, repeats said process to mould and fills up;
(8) powder is implemented to pressurized, heated operation, temperature is 150 ℃, and pressure is 700MPa, and the dwell time is 98s;
(9) in vacuum oven, carry out sintering, sintering temperature is 1100 ℃, and the sintered heat insulating time is 4h;
(10) the sintered compact that cooling step (9) obtains obtains this long carbon fiber and strengthens titanium alloy composite material;
Described titanium alloy is made by following steps:
(a) batching: according to Nb:23%, Zr:8.8%, Sn:15.6%, O:0.018%, RE:1.56%, Al:2.8%, surplus is that Ti prepares burden, wherein Ti is with titanium sponge, and Zr adopts Ti-52Nb master alloy, Sn to adopt Ti-68Sn master alloy, RE to adopt mishmetal, Al to adopt Ti-Al master alloy with zirconium sponge, Nb, and O is relict element in above-mentioned raw materials;
(b) melting: the material that step (a) is prepared is pressed into electrode, in vacuum consumable electrode arc furnace, melting is 2 times;
(c) homogenizing annealing: homogenization temperature is 990 ℃, and the hold-time is 12h, removal zone of oxidation strips off the skin after annealing;
(d) forge: Forge Heating temperature is 960 ℃, and soaking time is 69min, and final forging temperature is 820 ℃;
(e) hot rolling: process annealing is not carried out in rolling, rolling pass is 8;
(f) cold rolling: cold rolling total deformation is 80%;
(g) solution heat treatment: cold-reduced sheet is carried out in chamber type electric resistance furnace to solution heat treatment, solid solubility temperature is 845 ℃, and soaking time is 0.9h, shrend;
(h) timeliness thermal treatment: be divided into following four steps: aging temp is 310 ℃, soaking time is 12min, shrend; Carry out ageing treatment for the second time being heated to 410 ℃, aging time is 1h, shrend; Reheat 480 ℃ and carry out timeliness for the third time, aging time is 2h, shrend; Reheat 520 ℃ and carry out timeliness the 4th time, aging time is 5h, shrend; Obtain titanium alloy finished product.
embodiment 2:
Long carbon fiber strengthens a titanium alloy composite material, and it is compound by long carbon fiber and titanium alloy stratiform that this long carbon fiber strengthens titanium alloy composite material, and its preparation method comprises following steps:
(1) prepare titanium alloy, described titanium alloy is grouped into by following one-tenth according to weight percentage: Nb:22%, and Zr:8.9%, Sn:16.6%, O:0.14%, RE:1.52%, Al:2.9%, surplus is Ti;
(2) carbon fiber remove photoresist, neutralize, activation, reduction pretreatment;
(3) at carbon fiber surface, carry out chemical nickel plating;
(4) the nickel-coated carbon fibers surface chemistry deposition layer of metal chromium obtaining in step (3) after cleaning-drying;
(5) plated carbon fiber step (4) being obtained is cut into the length of 18mm;
(6), by the titanium alloys powdered of step (1), by titanium alloy powder uniform spreading, in mould, thickness is 4cm, then the plated carbon fiber that alignment step (5) shears on titanium alloy powder layer, and then lay one deck titanium alloy powder, thickness is 4mm, repeats said process to mould and fills up;
(8) powder is implemented to pressurized, heated operation, temperature is 150 ℃, and pressure is 700MPa, and the dwell time is 98s;
(9) in vacuum oven, carry out sintering, sintering temperature is 1100 ℃, and the sintered heat insulating time is 4h;
(10) the sintered compact that cooling step (9) obtains obtains this long carbon fiber and strengthens titanium alloy composite material;
Described titanium alloy is made by following steps:
(a) batching: according to Nb:22%, Zr:8.9%, Sn:16.6%, O:0.14%, RE:1.52%, Al:2.9%, surplus is that Ti prepares burden, wherein Ti is with titanium sponge, and Zr adopts Ti-52Nb master alloy, Sn to adopt Ti-68Sn master alloy, RE to adopt mishmetal, Al to adopt Ti-Al master alloy with zirconium sponge, Nb, and O is relict element in above-mentioned raw materials;
(b) melting: the material that step (a) is prepared is pressed into electrode, in vacuum consumable electrode arc furnace, melting is 2 times;
(c) homogenizing annealing: homogenization temperature is 990 ℃, and the hold-time is 12h, removal zone of oxidation strips off the skin after annealing;
(d) forge: Forge Heating temperature is 960 ℃, and soaking time is 69min, and final forging temperature is 820 ℃;
(e) hot rolling: process annealing is not carried out in rolling, rolling pass is 8;
(f) cold rolling: cold rolling total deformation is 80%;
(g) solution heat treatment: cold-reduced sheet is carried out in chamber type electric resistance furnace to solution heat treatment, solid solubility temperature is 845 ℃, and soaking time is 0.9h, shrend;
(h) timeliness thermal treatment: be divided into following four steps: aging temp is 310 ℃, soaking time is 12min, shrend; Carry out ageing treatment for the second time being heated to 410 ℃, aging time is 1h, shrend; Reheat 480 ℃ and carry out timeliness for the third time, aging time is 2h, shrend; Reheat 520 ℃ and carry out timeliness the 4th time, aging time is 5h, shrend; Obtain titanium alloy finished product.
Claims (6)
1. long carbon fiber strengthens a titanium alloy composite material, it is characterized in that, it is compound by long carbon fiber and titanium alloy stratiform that this long carbon fiber strengthens titanium alloy composite material, and its preparation method comprises following steps:
(1) prepare titanium alloy, described titanium alloy is grouped into by following one-tenth according to weight percentage: Nb:21 ~ 24%, and Zr:8.2 ~ 9.1%, Sn:12 ~ 18.6%, O:0.012 ~ 0.180%, RE:1.0 ~ 1.6%, Al:2.2 ~ 3.1%, surplus is Ti;
(2) carbon fiber remove photoresist, neutralize, activation, reduction pretreatment;
(3) at carbon fiber surface, carry out chemical nickel plating;
(4) the nickel-coated carbon fibers surface chemistry deposition layer of metal chromium obtaining in step (3) after cleaning-drying;
(5) plated carbon fiber step (4) being obtained is cut into the length of 1 ~ 20mm;
(6) by the titanium alloys powdered of step (1), by titanium alloy powder uniform spreading in mould, thickness is 1 ~ 5cm, then the plated carbon fiber that alignment step (5) shears on titanium alloy powder layer, and then laying one deck titanium alloy powder, thickness is 1 ~ 5mm, repeats said process to mould and fills up;
(8) powder is implemented to pressurized, heated operation, temperature is 110 ~ 182 ℃, and pressure is 560 ~ 800MPa, and the dwell time is 10 ~ 180s;
(9) in vacuum oven, carry out sintering, sintering temperature is 1010 ~ 1480 ℃, and the sintered heat insulating time is 1 ~ 6h;
(10) the sintered compact that cooling step (9) obtains obtains this long carbon fiber and strengthens titanium alloy composite material;
Described titanium alloy is made by following steps:
(a) batching: according to Nb:21 ~ 24%, Zr:8.2 ~ 9.1%, Sn:12 ~ 18.6%, O:0.012 ~ 0.180%, RE:1.0 ~ 1.6%, Al:2.2 ~ 3.1%, surplus is Ti; Prepare burden, wherein Ti is with titanium sponge, and Zr adopts Ti-52Nb master alloy, Sn to adopt Ti-68Sn master alloy, RE to adopt mishmetal, Al to adopt Ti-Al master alloy with zirconium sponge, Nb, and O is relict element in above-mentioned raw materials;
(b) melting: the material that step (a) is prepared is pressed into electrode, in vacuum consumable electrode arc furnace, melting is 2 times;
(c) homogenizing annealing: homogenization temperature is 992 ~ 1210 ℃, and the hold-time is 11 ~ 18h, removal zone of oxidation strips off the skin after annealing;
(d) forge: Forge Heating temperature is 925 ~ 990 ℃, and soaking time is 68 ~ 86min, and final forging temperature is 810 ~ 860 ℃;
(e) hot rolling: process annealing is not carried out in rolling, rolling pass is 8;
(f) cold rolling: cold rolling total deformation is 80%;
(g) solution heat treatment: cold-reduced sheet is carried out in chamber type electric resistance furnace to solution heat treatment, solid solubility temperature is 835-860 ℃, and soaking time is 0.8-1.8h, shrend;
(h) timeliness thermal treatment: be divided into following four steps: aging temp is 300 ~ 320 ℃, soaking time is 5 ~ 18min, shrend; Carry out ageing treatment for the second time being heated to 400 ~ 420 ℃, aging time is 1 ~ 1.8h, shrend; Reheat 480 ~ 495 ℃ and carry out timeliness for the third time, aging time is 2 ~ 2.5h, shrend; Reheat 520 ~ 550 ℃ and carry out timeliness the 4th time, aging time is 5 ~ 8h, shrend; Obtain titanium alloy finished product.
2. long carbon fiber according to claim 1 strengthens titanium alloy composite material, it is characterized in that, described carbon fiber removes photoresist to process and adopts air calcination method to carry out.
3. long carbon fiber according to claim 1 and 2 strengthens titanium alloy composite material, it is characterized in that, described carbon fiber neutralizing treatment adopts KOH or ammoniacal liquor to neutralize.
4. long carbon fiber according to claim 1 and 2 strengthens titanium alloy composite material, it is characterized in that, described carbon fiber activation treatment adopts PdCl
2with AgCl be activation solution.
5. long carbon fiber according to claim 1 and 2 strengthens titanium alloy composite material, it is characterized in that, in titanium alloy preparation process, timeliness thermal treatment is divided into following four steps: aging temp is 310 ℃, and soaking time is 8min, shrend; Reheat 420 ℃ and carry out ageing treatment for the second time, aging time is 1h, shrend; Reheat 485 ℃ and carry out timeliness for the third time, aging time is 2h, shrend; Reheat 535 ℃ and carry out timeliness the 4th time, aging time is 5h, shrend.
6. according to the long carbon fiber described in claim 1 ~ 5, strengthen titanium alloy composite material, it is characterized in that, described titanium alloy is grouped into by following one-tenth according to weight percentage: Nb:22%, Zr:8.9%, Sn:16.6%, O:0.14%, RE:1.52%, Al:2.9%, surplus is Ti.
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106756656A (en) * | 2016-12-20 | 2017-05-31 | 南京九致信息科技有限公司 | Nitinol fiberboard and preparation method thereof |
| CN109112356A (en) * | 2018-08-03 | 2019-01-01 | 燕山大学 | A kind of high-strength corrosion-resistant erosion titanium alloy and preparation method thereof |
| CN110315083A (en) * | 2019-07-25 | 2019-10-11 | 西北有色金属研究院 | A method of quickly preparing fibre reinforced titanium alloy laminar composite |
| RU2731699C1 (en) * | 2020-02-04 | 2020-09-08 | Федеральное государственное бюджетное учреждение науки Институт физики твердого тела Российской академии наук (ИФТТ РАН) | Method of producing composite materials based on carbon fiber and metal |
| CN114438425A (en) * | 2022-02-09 | 2022-05-06 | 重庆金开泰达新材料科技有限公司 | Long carbon fiber reinforced titanium alloy composite material |
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| CN102912263A (en) * | 2012-10-11 | 2013-02-06 | 北京理工大学 | Carbon fiber reinforced titanium alloy compound material and preparation method thereof |
| CN102936706A (en) * | 2012-11-13 | 2013-02-20 | 北京理工大学 | Carbon fiber cloth-titanium alloy composite material and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106756656A (en) * | 2016-12-20 | 2017-05-31 | 南京九致信息科技有限公司 | Nitinol fiberboard and preparation method thereof |
| CN109112356A (en) * | 2018-08-03 | 2019-01-01 | 燕山大学 | A kind of high-strength corrosion-resistant erosion titanium alloy and preparation method thereof |
| CN110315083A (en) * | 2019-07-25 | 2019-10-11 | 西北有色金属研究院 | A method of quickly preparing fibre reinforced titanium alloy laminar composite |
| RU2731699C1 (en) * | 2020-02-04 | 2020-09-08 | Федеральное государственное бюджетное учреждение науки Институт физики твердого тела Российской академии наук (ИФТТ РАН) | Method of producing composite materials based on carbon fiber and metal |
| CN114438425A (en) * | 2022-02-09 | 2022-05-06 | 重庆金开泰达新材料科技有限公司 | Long carbon fiber reinforced titanium alloy composite material |
| CN114438425B (en) * | 2022-02-09 | 2022-07-19 | 重庆金开泰达新材料科技有限公司 | Long carbon fiber reinforced titanium alloy composite material |
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