CN103709614A - PBT flame-retardant master batch - Google Patents
PBT flame-retardant master batch Download PDFInfo
- Publication number
- CN103709614A CN103709614A CN201210368740.1A CN201210368740A CN103709614A CN 103709614 A CN103709614 A CN 103709614A CN 201210368740 A CN201210368740 A CN 201210368740A CN 103709614 A CN103709614 A CN 103709614A
- Authority
- CN
- China
- Prior art keywords
- pbt
- retardant
- fire
- coupling agent
- master granule
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a PBT flame-retardant master batch. The PBT flame-retardant master batch comprises components by mass: 10%-15% of a PBT carrier, 50%-70% of a main flame retardant, 15%-35% of an auxiliary flame retardant, 1%-3% of a coupling agent, 3%-5% of a dispersant and 1%-2% of an antioxidant. The prepared master batch has the characteristics of high concentration, low cost and convenient use. Besides, by using the master batch in producing the PBT, a production process can be simplified; production efficiency is increased; dust flying is reduced; environment pollution is prevented; and clean production is facilitated. The master batch can be easily mixed with a PBT raw material uniformly; and mixing quality and performance indexes of the product can be further increased.
Description
Technical field
The present invention relates to a kind of fire-retardant master granule, specifically a kind of PBT fire-retardant master granule.
Background technology
Polybutylene terephthalate (PBT) is the linear saturated polyester resin of a kind of crystal type, owing to having good electric property, resistance toheat, fatigue performance, low-friction coefficient and lower-price characteristic, is widely used in the industries such as electronic apparatus, household electrical appliances, automotive industry, mechanical means, material of construction.Yet, because PBT easily burns, so it is flame-retardant modified conventionally need to add amount of retardant to carry out at production PBT, using the fire retardant overwhelming majority is at present powder, like this when mixing with PBT raw material, the utmost point is not easy to mix, and the dust of kicking up while mixing pollutes surrounding environment and unhealthful etc. especially, is unfavorable for cleaner production.
Summary of the invention
The object of the present invention is to provide a kind of high density, low cost, cleaner production and PBT fire-retardant master granule easy to use.
The technical solution adopted for the present invention to solve the technical problems is: a kind of PBT fire-retardant master granule, its component by mass percent proportioning is: PBT carrier 10%~15%, main flame retardant 50%~70%, auxiliary fire retardant 15%~35%, coupling agent 1%~3%, dispersion agent 3%~5%, oxidation inhibitor 1%~2%.
Described PBT carrier is polybutylene terephthalate.
Described main flame retardant is TDE, decabromodiphenyl oxide, tetra bromobisphenol A ether, poly-2,6-dibromo phenylene ether, tricresyl phosphate (2, the chloro-2-propyl group of 3-bis-) ester, 1, a kind of in two (tetrabromo phthalimide) ethane, three (2, the 4-dibromo phenyl) phosphoric acid ester of 2-, Wrapped up Phosphorus Fire Retardant.
Described auxiliary fire retardant is a kind of in antimonous oxide, aluminium hydroxide, magnesium hydroxide.
Described coupling agent is a kind of in silane coupling agent, titanate coupling agent, aluminate coupling agent and phosphate coupling agent.
Described dispersion agent is one or more the mixture in polyethylene wax, Poly Propylene Wax, EVA wax, OP wax, TAS-2A.
Described oxidation inhibitor is the compound of antioxidant 1076 and irgasfos 168.
The preparation method of above-mentioned a kind of PBT fire-retardant master granule, comprises the following steps:
(1) each component is weighed up stand-by by weight ratio;
(2) PBT carrier and main flame retardant, auxiliary fire retardant, coupling agent, dispersion agent, oxidation inhibitor are added in high-speed mixer, fully mix 3~5 minutes;
(3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of PBT fire-retardant master granule.
Compared with prior art, the invention has the beneficial effects as follows, made master batch has high density, low cost and the feature such as easy to use, at production PBT, use this master batch can simplify production technique simultaneously, enhance productivity, can reduce dust from flying again, avoid environmental pollution, be conducive to cleaner production, and use this master batch easily to mix with PBT raw material, thereby further improve performance index of mixing and goods etc.
Embodiment
Below in conjunction with specific embodiment, further illustrate technical scheme of the present invention.
Embodiment 1:
A kind of PBT fire-retardant master granule, its component by mass percent proportioning is: the compound 1% of PBT carrier 12 %, TDE 60%, antimonous oxide 20%, silane coupling agent 3%, polyethylene wax 4%, antioxidant 1076 and irgasfos 168, wherein, described PBT carrier is polybutylene terephthalate.
Preparation method: (1) weighs up stand-by by each component by weight ratio; (2) compound of PBT carrier and TDE, antimonous oxide, silane coupling agent, polyethylene wax, antioxidant 1076 and irgasfos 168 is added in high-speed mixer, fully mix 3~5 minutes; (3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of PBT fire-retardant master granule.
Embodiment 2:
A kind of PBT fire-retardant master granule, its component by mass percent proportioning is: PBT carrier 10%, poly-2, the compound 1% of 6-dibromo phenylene ether 70%, antimonous oxide 15%, titanate coupling agent 1%, Poly Propylene Wax 3%, antioxidant 1076 and irgasfos 168, wherein, described PBT carrier is polybutylene terephthalate.
Preparation method: (1) weighs up stand-by by each component by weight ratio; (2) compound of PBT carrier and poly-2,6-dibromo phenylene ether, antimonous oxide, titanate coupling agent, Poly Propylene Wax, antioxidant 1076 and irgasfos 168 is added in high-speed mixer, fully mix 3~5 minutes; (3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of PBT fire-retardant master granule.
Embodiment 3:
A kind of PBT fire-retardant master granule, its component by mass percent proportioning is: PBT carrier 15%, three (2,4-dibromo phenyl) compound 2% of phosphoric acid ester 50%, aluminium hydroxide 25%, aluminate coupling agent 3%, OP wax 5%, antioxidant 1076 and irgasfos 168, wherein, described PBT carrier is polybutylene terephthalate.
Preparation method: (1) weighs up stand-by by each component by weight ratio; (2) compound of PBT carrier and three (2,4-dibromo phenyl) phosphoric acid ester, aluminium hydroxide, aluminate coupling agent, OP wax, antioxidant 1076 and irgasfos 168 is added in high-speed mixer, fully mix 3~5 minutes; (3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of PBT fire-retardant master granule.
Claims (7)
1. a PBT fire-retardant master granule, is characterized in that, its component by mass percent proportioning is: PBT carrier 10%~15%, main flame retardant 50%~70%, auxiliary fire retardant 15%~35%, coupling agent 1%~3%, dispersion agent 3%~5%, oxidation inhibitor 1%~2%.
2. a kind of PBT fire-retardant master granule according to claim 1, it is characterized in that, described main flame retardant is TDE, decabromodiphenyl oxide, tetra bromobisphenol A ether, poly-2,6-dibromo phenylene ether, tricresyl phosphate (2, the chloro-2-propyl group of 3-bis-) ester, 1, a kind of in two (tetrabromo phthalimide) ethane, three (2, the 4-dibromo phenyl) phosphoric acid ester of 2-, Wrapped up Phosphorus Fire Retardant.
3. a kind of PBT fire-retardant master granule according to claim 1, is characterized in that, described auxiliary fire retardant is a kind of in antimonous oxide, aluminium hydroxide, magnesium hydroxide.
4. a kind of PBT fire-retardant master granule according to claim 1, is characterized in that, described coupling agent is a kind of in silane coupling agent, titanate coupling agent, aluminate coupling agent and phosphate coupling agent.
5. a kind of PBT fire-retardant master granule according to claim 1, is characterized in that, described dispersion agent is one or more the mixture in polyethylene wax, Poly Propylene Wax, EVA wax, OP wax, TAS-2A.
6. a kind of PBT fire-retardant master granule according to claim 1, is characterized in that, described oxidation inhibitor is the compound of antioxidant 1076 and irgasfos 168.
7. the preparation method of a kind of PBT fire-retardant master granule according to claim 1, is characterized in that, comprises the following steps:
(1) each component is weighed up stand-by by weight ratio;
(2) PBT carrier and main flame retardant, auxiliary fire retardant, coupling agent, dispersion agent, oxidation inhibitor are added in high-speed mixer, fully mix 3~5 minutes;
(3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of PBT fire-retardant master granule.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210368740.1A CN103709614A (en) | 2012-09-29 | 2012-09-29 | PBT flame-retardant master batch |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201210368740.1A CN103709614A (en) | 2012-09-29 | 2012-09-29 | PBT flame-retardant master batch |
Publications (1)
Publication Number | Publication Date |
---|---|
CN103709614A true CN103709614A (en) | 2014-04-09 |
Family
ID=50402989
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201210368740.1A Pending CN103709614A (en) | 2012-09-29 | 2012-09-29 | PBT flame-retardant master batch |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103709614A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104140648A (en) * | 2014-07-17 | 2014-11-12 | 滁州优胜高分子材料有限公司 | Permanent inflaming-retarding pbt material |
CN104962048A (en) * | 2015-07-12 | 2015-10-07 | 朱雪梅 | Glass fiber reinforced flame-retardant PBT (polybutylene terephthalate) material and preparation method thereof |
CN105440597A (en) * | 2015-12-16 | 2016-03-30 | 北京航天试验技术研究所 | High-glow-wire flame-retardant reinforced type PBT composite material and preparation method thereof |
CN106947253A (en) * | 2017-03-27 | 2017-07-14 | 六安载丰新材料有限公司 | A kind of fire-retardant master granule and preparation method thereof |
CN108034117A (en) * | 2017-12-28 | 2018-05-15 | 广东宇星阻燃新材股份有限公司 | A kind of fire-retardant master granule for wear well polythene and its preparation method and application |
-
2012
- 2012-09-29 CN CN201210368740.1A patent/CN103709614A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104140648A (en) * | 2014-07-17 | 2014-11-12 | 滁州优胜高分子材料有限公司 | Permanent inflaming-retarding pbt material |
CN104140648B (en) * | 2014-07-17 | 2016-01-20 | 滁州优胜高分子材料有限公司 | A kind of permanent fire retardant PBT material |
CN104962048A (en) * | 2015-07-12 | 2015-10-07 | 朱雪梅 | Glass fiber reinforced flame-retardant PBT (polybutylene terephthalate) material and preparation method thereof |
CN105440597A (en) * | 2015-12-16 | 2016-03-30 | 北京航天试验技术研究所 | High-glow-wire flame-retardant reinforced type PBT composite material and preparation method thereof |
CN106947253A (en) * | 2017-03-27 | 2017-07-14 | 六安载丰新材料有限公司 | A kind of fire-retardant master granule and preparation method thereof |
CN108034117A (en) * | 2017-12-28 | 2018-05-15 | 广东宇星阻燃新材股份有限公司 | A kind of fire-retardant master granule for wear well polythene and its preparation method and application |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103709614A (en) | PBT flame-retardant master batch | |
CN103709609A (en) | Flame-retardant nanometer master batch for polyester plastic | |
CN103849025A (en) | Polyethylene flame retardant antistatic masterbatch | |
CN103849024A (en) | Antistatic and flame-retardant modified polyethylene powder and preparation method thereof | |
CN103849035A (en) | Polyethylene anti-static weather-proof master batches and preparation method thereof | |
CN103013028A (en) | Flame-retardant glass fiber-reinforced ABS material with high CTI value and high GWIT value | |
CN102952340A (en) | Environment-friendly flame-retardant PP (Propylene) material and preparation method thereof | |
CN103709620A (en) | Halogen-free, flame-retardant and antistatic master batch for modifying polybutylene telephthalate | |
CN102942738B (en) | A kind of high CTI value, high GWIT value environment-protection flame-proof fiberglass strengthen PP/PPO alloy material and preparation method thereof | |
CN103073825A (en) | Composition for solid plasticized high-flame-retardant PVC sheath material and preparation method of composition | |
CN103160027A (en) | V-0 fire retardation antistatic polypropylene material and preparation method thereof | |
CN111187512B (en) | Flame-retardant wear-resistant scratch-resistant PA66 composite material and preparation method thereof | |
CN103849050A (en) | Reinforcing, whitening and brightening master batch for polyethylene and preparation method thereof | |
CN104744763A (en) | Antistatic fire retardant master batch for modification of polyethylene | |
CN103709474A (en) | Flame-retardant master batch used for plastic | |
CN103881202A (en) | Anti-aging polyethylene flame-retardant master batch and preparation method thereof | |
CN103881180A (en) | Flame-retardant antistatic bifunctional modified polyethylene composite material and its preparation method | |
CN103709610A (en) | Flame-retardant antistatic master batch for polyester | |
CN104419166A (en) | PC flame retardant master batch | |
CN103073853A (en) | Environmental-protection fire retardation enhancement PBT/PET/PA6 alloy and manufacturing method thereof | |
CN103709635A (en) | Glass fiber flame-retardant nanoparticle/PBT composite material | |
CN104725794A (en) | Glass-fiber-reinforced flame-retardant PBT-PET alloy | |
CN103146059A (en) | Polypropylene modified halogen-free flame retardant composite material and preparation method thereof | |
CN103709622A (en) | Polyester anti-static and weather-resistant master batch and preparation method thereof | |
CN103849042A (en) | Halogen-free flame retardant anti-static master batches for modifying polyethylene |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140409 |