CN103709474A - Flame-retardant master batch used for plastic - Google Patents
Flame-retardant master batch used for plastic Download PDFInfo
- Publication number
- CN103709474A CN103709474A CN201210370797.5A CN201210370797A CN103709474A CN 103709474 A CN103709474 A CN 103709474A CN 201210370797 A CN201210370797 A CN 201210370797A CN 103709474 A CN103709474 A CN 103709474A
- Authority
- CN
- China
- Prior art keywords
- retardant master
- antioxidant
- plastic cement
- master granule
- fire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
- C08L25/06—Polystyrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L53/02—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers of vinyl-aromatic monomers and conjugated dienes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L55/00—Compositions of homopolymers or copolymers, obtained by polymerisation reactions only involving carbon-to-carbon unsaturated bonds, not provided for in groups C08L23/00 - C08L53/00
- C08L55/02—ABS [Acrylonitrile-Butadiene-Styrene] polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
- C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a flame-retardant master batch used for plastic. The flame-retardant master batch comprises the following components by mass: 10%-15% of a carrier, 30%-40% of decabromodiphenylethane, 30%-40% of poly 2,6-dibromo phenylene ether, 10%-30% of antimony trioxide, 3%-5% of a dispersing agent and 1%-3% of an antioxidant. The flame-retardant master batch has the beneficial effects that in secondary use of the prepared master batch, a production process for blending with plastic raw materials can be simplified; dust flying and abrasion for devices can be reduced; raw materials can be saved; the raw materials can be mixed conveniently; and blending is uniform, so that production efficiency and performance indexes of products can be increased.
Description
Technical field
The present invention relates to a kind of fire-retardant master granule, specifically a kind of plastic cement fire-retardant master granule.
Background technology
Therefore plastic cement is mainly consisted of carbon, oxygen, hydrogen and nitrogen and other organic or inorganic elements, and finished product is solid, is the liquid of molten in manufacturing processed, can make its fusing, plus-pressure they be flowed, coolingly make it be solidified to form different shape with heating.Each field in the current widespread use modern life of plasthetics, such as household electrical appliance, instrument, electric wire, construction equipment, communication electronics, automotive industry, space flight and aviation, haberdashery and hardware etc.Yet, owing to containing the combustible elements such as carbon, sulphur, oxygen in plastic cement, some plastics easy firing, such as polypropylene, ABS, PBT, PET etc.It is flame-retardant modified that prior art normally directly adds fire retardant to carry out in plastic material, but fire retardant is powder, when mixing with raw material, be faced with problems such as disperseing inequality, dust pollution, and prepare plastic cement fire-retardant master granule, can simplify technique, improve mixing, reduce dust from flying.
Summary of the invention
The object of the present invention is to provide a kind of high density, low cost and plastic cement fire-retardant master granule easy to use.
The technical solution adopted for the present invention to solve the technical problems is: a kind of plastic cement fire-retardant master granule, its component by mass percent proportioning is: carrier 10%～15%, TDE 30%～40%, poly-2,6-dibromo phenylene ether 30%～40%, antimonous oxide 10%～30%, dispersion agent 3%～5%, oxidation inhibitor 1%～3%.
Described carrier is resin or elastomerics, is chosen as a kind of in polypropylene (PP), polyethylene (PE), polystyrene (PS), acrylonitrile-butadiene-styrene copolymer (ABS), polybutylene terephthalate (PBT), polyethylene terephthalate (PET), styrene-butadiene-styrene block copolymer (SBS), polyolefin elastomer (POE), terpolymer EP rubber (EPDM), ethylene-vinyl acetate copolymer (EVA), urethanes (TPU).
Described dispersion agent is one or more the mixture in polyethylene wax, Poly Propylene Wax, EVA wax, OP wax, ethylene bis stearic amide.
Described oxidation inhibitor is a kind of in compound, antioxidant 1010 or the antioxidant 1076 of antioxidant 1010, antioxidant 1076, antioxidant 1010 or antioxidant 1076 and irgasfos 168 and the compound of oxidation inhibitor JC-242.
The preparation method of fire-retardant master granule for above-mentioned a kind of plastic cement, comprises the following steps:
(1) each component is weighed up stand-by by weight ratio;
(2) carrier and TDE, poly-2,6-dibromo phenylene ether, antimonous oxide, dispersion agent, oxidation inhibitor are added in high-speed mixer, fully mix 3～15 minutes, discharging is stand-by;
(3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of plastic cement fire-retardant master granule.
Compared with prior art, the invention has the beneficial effects as follows:
1, adopting resin or elastomerics as carrier, for the fire-retardant master granule of resin carrier, is to be mainly same resin for plastic raw material substrate and carrier, thereby eliminates the bad problem of consistency; Fire-retardant master granule for elastomerics carrier, because material is added in the modification that elastomerics is widespread use in current plastic cement, so be mainly for using such elastomeric process systems in plastic cement processing formula, thereby can not bring any unfavorable factor to whole product system yet, so fundamentally guaranteed the stable of system aspect raw material, adopt cheap carrier to replace other auxiliary agents with high costs simultaneously, can significantly reduce the cost of master batch.
2, the fire-retardant master granule that the present invention makes, in secondary is used, can be simplified the production process with plastic material blend, reduces dust from flying and the wearing and tearing to equipment, conservation, raw material is mixed convenient, mixing evenly, thereby enhance productivity and the performance index of goods etc.
Embodiment
Below in conjunction with specific embodiment, further illustrate technical scheme of the present invention.
Embodiment 1:
A plastic cement fire-retardant master granule, its component by mass percent proportioning is: polypropylene (PP) 15%, TDE 30%, poly-2,6-dibromo phenylene ether 30%, antimonous oxide 20%, Poly Propylene Wax 3%, antioxidant 1010 2%.
Preparation method: (1) weighs up stand-by by each component by weight ratio; (2) polypropylene (PP) and TDE, poly-2,6-dibromo phenylene ether, antimonous oxide, Poly Propylene Wax, antioxidant 1010 are added in high-speed mixer, fully mix 3～15 minutes, discharging is stand-by; (3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of plastic cement fire-retardant master granule.
Embodiment 2:
A kind of plastic cement fire-retardant master granule, its component by mass percent proportioning is: the compound 3% of polyethylene (PE) 10%, TDE 40%, poly-2,6-dibromo phenylene ether 30%, antimonous oxide 15%, polyethylene wax 5%, antioxidant 1010 and irgasfos 168.
Preparation method: (1) weighs up stand-by by each component by weight ratio; (2) compound of polyethylene (PE) and TDE, poly-2,6-dibromo phenylene ether, antimonous oxide, polyethylene wax, antioxidant 1010 and irgasfos 168 is added in high-speed mixer, fully mix 3～15 minutes, discharging is stand-by; (3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of plastic cement fire-retardant master granule.
Embodiment 3:
A kind of plastic cement fire-retardant master granule, its component by mass percent proportioning is: the compound 2% of terpolymer EP rubber (EPDM) 12%, TDE 30%, poly-2,6-dibromo phenylene ether 40%, antimonous oxide 12%, EVA wax 4%, antioxidant 1076 and oxidation inhibitor JC-242.
Preparation method: (1) weighs up stand-by by each component by weight ratio; (2) compound of terpolymer EP rubber (EPDM) and TDE, poly-2,6-dibromo phenylene ether, antimonous oxide, EVA wax, antioxidant 1076 and oxidation inhibitor JC-242 is added in high-speed mixer, fully mix 3～15 minutes, discharging is stand-by; (3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of plastic cement fire-retardant master granule.
Claims (5)
1. a plastic cement fire-retardant master granule, it is characterized in that, its component by mass percent proportioning is: carrier 10%～15%, TDE 30%～40%, poly-2,6-dibromo phenylene ether 30%～40%, antimonous oxide 10%～30%, dispersion agent 3%～5%, oxidation inhibitor 1%～3%.
2. a kind of plastic cement fire-retardant master granule according to claim 1, it is characterized in that, described carrier is resin or elastomerics, be chosen as polypropylene (PP), polyethylene (PE), polystyrene (PS), acrylonitrile-butadiene-styrene copolymer (ABS), polybutylene terephthalate (PBT), polyethylene terephthalate (PET), styrene-butadiene-styrene block copolymer (SBS), polyolefin elastomer (POE), terpolymer EP rubber (EPDM), ethylene-vinyl acetate copolymer (EVA), a kind of in urethanes (TPU).
3. a kind of plastic cement fire-retardant master granule according to claim 1, is characterized in that, described dispersion agent is one or more the mixture in polyethylene wax, Poly Propylene Wax, EVA wax, OP wax, ethylene bis stearic amide.
4. a kind of plastic cement fire-retardant master granule according to claim 1, it is characterized in that, described oxidation inhibitor is a kind of in compound, antioxidant 1010 or the antioxidant 1076 of antioxidant 1010, antioxidant 1076, antioxidant 1010 or antioxidant 1076 and irgasfos 168 and the compound of oxidation inhibitor JC-242.
5. the preparation method of fire-retardant master granule for a kind of plastic cement according to claim 1, is characterized in that, comprises the following steps:
(1) each component is weighed up stand-by by weight ratio;
(2) carrier and TDE, poly-2,6-dibromo phenylene ether, antimonous oxide, dispersion agent, oxidation inhibitor are added in high-speed mixer, fully mix 3～15 minutes, discharging is stand-by;
(3) said mixture added to twin screw extruder is extruded, after granulation, drying, pack and obtain a kind of plastic cement fire-retardant master granule.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210370797.5A CN103709474A (en) | 2012-09-29 | 2012-09-29 | Flame-retardant master batch used for plastic |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201210370797.5A CN103709474A (en) | 2012-09-29 | 2012-09-29 | Flame-retardant master batch used for plastic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103709474A true CN103709474A (en) | 2014-04-09 |
Family
ID=50402851
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201210370797.5A Pending CN103709474A (en) | 2012-09-29 | 2012-09-29 | Flame-retardant master batch used for plastic |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103709474A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674332A (en) * | 2017-10-24 | 2018-02-09 | 江苏中鹏新材料股份有限公司 | A kind of environmental protection flame retardant master batch and preparation method thereof, application, fire proofing |
| CN109181271A (en) * | 2018-08-17 | 2019-01-11 | 凌云工业股份有限公司上海凌云汽车研发分公司 | A kind of polyphenyl ether modified material of high fire-retardance low-density and preparation method thereof |
| CN110033891A (en) * | 2019-04-28 | 2019-07-19 | 江苏亨通电子线缆科技有限公司 | A kind of scratch-resistant notch sensitive type cable for new-energy automobile |
| CN110753718A (en) * | 2017-06-14 | 2020-02-04 | 旭化成株式会社 | Masterbatch composition, method for producing resin composition, and resin composition |
-
2012
- 2012-09-29 CN CN201210370797.5A patent/CN103709474A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110753718A (en) * | 2017-06-14 | 2020-02-04 | 旭化成株式会社 | Masterbatch composition, method for producing resin composition, and resin composition |
| CN107674332A (en) * | 2017-10-24 | 2018-02-09 | 江苏中鹏新材料股份有限公司 | A kind of environmental protection flame retardant master batch and preparation method thereof, application, fire proofing |
| CN109181271A (en) * | 2018-08-17 | 2019-01-11 | 凌云工业股份有限公司上海凌云汽车研发分公司 | A kind of polyphenyl ether modified material of high fire-retardance low-density and preparation method thereof |
| CN110033891A (en) * | 2019-04-28 | 2019-07-19 | 江苏亨通电子线缆科技有限公司 | A kind of scratch-resistant notch sensitive type cable for new-energy automobile |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104844885A (en) | Antistatic masterbatch for engineering plastics and preparation method thereof | |
| CN103709474A (en) | Flame-retardant master batch used for plastic | |
| CN103709441A (en) | Phosphor-nitrogen halogen-free flame-retardant master batch used for engineering plastics, and preparation method thereof | |
| CN102250383B (en) | Halogen-free fire retardant containing benzoxazine and polymer material comprising same | |
| CN104119556A (en) | Flame-retardant masterbatch containing heat stabilizer and preparation method thereof | |
| CN102070851B (en) | Plastic composite function master batch and manufacture method thereof | |
| CN102212243A (en) | Environment friendly thermoplastic elastomer used as fire-retardant sealing strip and preparation method thereof | |
| CN101121796A (en) | Polymer-base flame-proof composite material | |
| CN103849035A (en) | Polyethylene anti-static weather-proof master batches and preparation method thereof | |
| CN103709620A (en) | Halogen-free, flame-retardant and antistatic master batch for modifying polybutylene telephthalate | |
| CN103709614A (en) | PBT flame-retardant master batch | |
| CN104744762A (en) | Toughening modified polyethylene powder and preparation method thereof | |
| CN103160027A (en) | V-0 fire retardation antistatic polypropylene material and preparation method thereof | |
| CN104725789A (en) | High-performance low-cost flame-retardant PET/ABS composite material | |
| CN103012965B (en) | Modified polypropylene composite and preparation method thereof | |
| CN105273298A (en) | High-gloss anti-precipitation flame-retardant polypropylene material and preparation method thereof | |
| CN104744763A (en) | Antistatic fire retardant master batch for modification of polyethylene | |
| CN103881180A (en) | Flame-retardant antistatic bifunctional modified polyethylene composite material and its preparation method | |
| CN104693730A (en) | High-flame-resistant high-toughness PC/PET alloy material | |
| CN103709610A (en) | Flame-retardant antistatic master batch for polyester | |
| CN103849056A (en) | PE (polyethylene) flame retardant modified antistatic toughening masterbatch and preparation method thereof | |
| CN109517259A (en) | A kind of polypropylene direct injection molding highly effective flame-retardant antibacterial functions master batch and preparation method thereof | |
| CN105504505A (en) | Ultrahigh flame-retardant polypropylene composite material and preparation method thereof | |
| CN103146059A (en) | Polypropylene modified halogen-free flame retardant composite material and preparation method thereof | |
| CN104744764A (en) | Flame-retardant and anti-aging polyethylene powder and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20140409 |