CN103709583A - Glass fiber enhanced K resin composite material and preparation method thereof - Google Patents
Glass fiber enhanced K resin composite material and preparation method thereof Download PDFInfo
- Publication number
- CN103709583A CN103709583A CN201310745101.7A CN201310745101A CN103709583A CN 103709583 A CN103709583 A CN 103709583A CN 201310745101 A CN201310745101 A CN 201310745101A CN 103709583 A CN103709583 A CN 103709583A
- Authority
- CN
- China
- Prior art keywords
- glass
- resin composite
- composite materials
- strengthens
- district
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/36—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die
- B29C48/395—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders
- B29C48/40—Means for plasticising or homogenising the moulding material or forcing it through the nozzle or die using screws surrounded by a cooperating barrel, e.g. single screw extruders using two or more parallel screws or at least two parallel non-intermeshing screws, e.g. twin screw extruders
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/78—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling
- B29C48/875—Thermal treatment of the extrusion moulding material or of preformed parts or layers, e.g. by heating or cooling for achieving a non-uniform temperature distribution, e.g. using barrels having both cooling and heating zones
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92876—Feeding, melting, plasticising or pumping zones, e.g. the melt itself
- B29C2948/92895—Barrel or housing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92819—Location or phase of control
- B29C2948/92857—Extrusion unit
- B29C2948/92904—Die; Nozzle zone
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a glass fiber enhanced K resin composite material. The glass fiber enhanced K resin composite material comprises the following components by weight percent: 37.6%-87.4% of K resin, 2%-10% of a compatilizer, 0.1%-0.3% of liquid water, 0.2%-0.6% of an antioxidant, 10%-50% of glass fibers and 0.3%-1.5% of a lubricant. The composite material has high strength, high transparency and good tenacity, and can be widely applied to the household appliance fields such as televisions and sound systems. The invention also discloses a preparation method of the glass fiber enhanced K resin composite material; and the preparation method is simple in process, easy to control in conditions, low in cost, low in requirements for equipment, and applicable for industrial production.
Description
Technical field
The present invention relates to technical field of polymer materials, relate in particular to a kind of glass and strengthen K resin composite materials and preparation method thereof.
Background technology
K resin is that to take vinylbenzene, divinyl be monomer, take lithium alkylide as initiator, adopt the synthetic a kind of segmented copolymer of anionic solution polymerization technology, its main characteristic is to have high transparent concurrently and good shock resistance, density is little, strong coloring force, processing characteristics is excellent, nontoxicity, the fields such as it and other material (as GPPS, SAN, SMA, PP, HIPS etc.) blending modification, Application Areas is comparatively extensive.
In view of the development of the high temperature and high speed forming technique (being RHCM technology) of processing industry is with ripe, design of material is also in continuous breakthrough.The present invention makes K resin and alkali-free chopped glass fiber form mixture by blend method, has improved intensity, the toughness of mixture, and thermotolerance.The matrix material of preparing by above invention can show more advantages under RHCM technology, and as Gao Guang, transparent, easy coloring etc., can be widely used in the field of household appliances such as televisor, sound equipment.
Summary of the invention
The object of the present invention is to provide a kind of glass to strengthen K resin composite materials, the technical problems such as the intensity of K resin composite materials in prior art is lower to overcome, high-light transparent deficiency.
Another object of the present invention is to provide a kind of technique simple, cost is low, and the glass being easy to operate and control strengthens the preparation method of K resin composite materials.
In order to realize foregoing invention object, technical scheme of the present invention is as follows:
Glass strengthens a K resin composite materials, comprises the recipe ingredient of following weight percent:
And a kind of glass strengthens the preparation method of K resin composite materials, comprises the following steps:
According to above-mentioned glass, strengthen K resin composite materials formula and take respectively each component;
Described in inciting somebody to action, take each component and carry out mixing treatment, obtain mixture;
Described mixture is melt extruded, and granulation, obtains described glass and strengthens K resin composite materials.
Above-mentioned glass strengthens K resin composite materials and take K resin as matrix, acts synergistically in melt extruding process with oxidation inhibitor, compatilizer and other components, has given this glass and has strengthened the advantages such as K resin composite materials high strength, high transparent.Particularly, described matrix material has strengthened the intensity of material by adding glass fibre, adopt volatile, transparent liquid water simultaneously, and the water molecules that impurity composition is volatilized is taken away, and has strengthened the transparency of material, and with low cost, easy handling.
Above-mentioned glass strengthens K resin composite materials preparation method and only need mixed being incorporated at suitable temperature of each component be melt extruded and can obtain product by formula, its preparation method technique is simple, and condition is easily controlled, with low cost, feature low for equipment requirements, is suitable for suitability for industrialized production.
Embodiment
In order to make the technical problem to be solved in the present invention, technical scheme and beneficial effect clearer, below in conjunction with embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
The embodiment of the present invention provides a kind of glass to strengthen K resin composite materials, and it comprises the formula and prescription of following weight percent:
Particularly, above-mentioned K resin is that to take vinylbenzene, divinyl be monomer, take lithium alkylide as initiator, adopt the synthetic a kind of segmented copolymer of anionic solution polymerization technology, because it has high transparent and good shock resistance, and density is little, strong coloring force, and processing characteristics excellence is nontoxic again, be therefore selected as the matrix component of described matrix material to obtain the well behaved matrix material that can be widely used in the field of household appliances such as televisor, sound equipment.Preferably, the notched Izod impact strength of described K resin is greater than 20J/M, and transmittance is between 86-92%, and as strange beautiful PB-5903, PB-5925, can meet application demand so well.
Above-mentioned compatilizer is for merging each component of formula, to play good synergy.In a preferred embodiment, described compatilizer is alternate styrene-maleic anhydride copolymer, and its second-order transition temperature is 135-155 ℃, and weight-average molecular weight is 7500-21000, as French Cray Willie SMA2021, SMA2000.
Above-mentioned liquid water has higher transparency, can be doped in material and not affect the transparency of material, and it has compared with lower boiling, volatile removing in melt extruding process, when volatilization, take away a large amount of impurity substances simultaneously, further improved the transparency of matrix material.The preferred high cleanliness water of described liquid water, it is in the time of 0 ℃, and density is 0.99987 * 103kg/m
3, be the transparent liquid of colorless and odorless at normal temperatures and pressures, can reduce mixing of impurity like this, guarantee the transparency of matrix material.
Above-mentioned antioxidant component can effectively suppress the oxidation of material in the course of processing, reduces the xanthochromia speed of material, improves the antioxidant property of matrix material in the various embodiments described above, extends its work-ing life.In a preferred embodiment, described oxidation inhibitor is Hinered phenols antioxidant, and its fusing point is 115-150(℃), as vapour bar IRGANOX1098, IRGANOX1010.
Above-mentioned glass fibre is for the intensity of reinforced composite, and it realizes good combination with K resin under the effect of compatilizer, gives composite material high strength degree performance.Described glass fibre preferred alkali-free short glass fiber, especially Fibre diameter are 9-13 μ m, water ratio :≤0.1% alkali-free short glass fiber, better with the consistency of other each component, can significantly improve the intensity of matrix material, as megalith group 526,510.
Above-mentioned lubricant, for reducing friction resistance, is realized the good fusion of each component.Described lubricant is preferably amide waxe class modifier, its fusing point: 141.5 ℃-144.5 ℃, and as Guangzhou Ou Ying chemical industry TAF, EBS.
By suitable combination of materials, there is synergistic effect in above-mentioned matrix material, the glass that has obtained excellent performance strengthens K resin composite materials.Its notched Izod impact strength is according to ASTMD256 standard, and batten thickness is 3.2mm, and its transmittance is according to ASTMD1003 standard, and batten thickness is 3.2mm, can well meet the materials demand of the appliance fields such as televisor.
Correspondingly, the embodiment of the present invention also provides above-mentioned glass to strengthen the preparation method of K resin composite materials, and the method comprises the steps:
S01, according to above-mentioned glass, strengthen K resin composite materials formula and take respectively each component;
Described in S02, general, take each component and carry out mixing treatment, obtain mixture;
S03, described mixture is melt extruded, granulation, obtains described glass and strengthens K resin composite materials.
Particularly, the formula of the glass enhancing K resin composite materials in above-mentioned steps S01 and each component preferred content in formula and kind as described above, in order to save length, do not repeat them here.
In above-mentioned steps S02, each component is carried out the time of mixing treatment and can be adjusted flexibly according to actual production conditions, as long as each component premix fully, if the equipment of mixing can be mixing machine etc.In a preferred embodiment, mixing treatment be by each component (as rotating speed is greater than 300r/min) combination treatment at a high speed 10～15 minutes, each component is mixed.
In above-mentioned steps S03, mixture melt extrude the technique that can adopt this area routine.For each component is better acted synergistically in melt extruding, give above-mentioned glass and strengthen the more excellent transparency and the mechanical property of K resin composite materials, in a preferred embodiment, it is to adopt twin screw extruder to melt extrude that mixture melt extrudes, and expressing technique condition is:
One district's temperature is 160～190 ℃, and two district's temperature are 185～220 ℃, and three district's temperature are 180～210 ℃, and four district's temperature are 160～200 ℃, head temperature: 200-220 ℃.
Above-mentioned glass strengthens K resin composite materials preparation method and only need mixed being incorporated at suitable temperature of each component be melt extruded and can obtain product by formula, in melt extruding process, only need to control the temperature and time melt extruding, therefore, its preparation method technique is simple, condition is easily controlled, feature with low cost, low for equipment requirements, is suitable for suitability for industrialized production.
It is example that the concrete glass of now take strengthens K resin composite materials and preparation method thereof, and the present invention is further elaborated.Wherein, in embodiment and comparative example, the strange beautiful PB-5903 of K Choice of Resin, PB-5925; Liquid water, food grade; Compatilizer is selected French Cray Willie SMA2021(or SMA2000); Alkali-free short glass fiber is selected the 526(of megalith group or 510); Oxidation inhibitor is selected the IRGANOX1098(or 1010 of vapour bar chemical industry); Lubricant is selected Guangzhou Ou Ying chemical industry TAF(or EBS).The unit of quantity of the recipe ingredient of following example be all weight percentage (%).
Embodiment 1
Take K resin 37.6%, compatilizer 10%, liquid water 0.3%, oxidation inhibitor 0.6%, alkali-free short glass fiber 50%, lubricant 1.5%, premix starting material, then raw material is placed in twin screw extruder through melt extruding, granulation, its expressing technique is: 160 ℃, a district, 190 ℃, 2nd district, 200 ℃, 3rd district, 170 ℃, 4th district, 220 ℃ of heads.
Embodiment 2
Take K resin 50%, compatilizer 8%, liquid water 0.3%, oxidation inhibitor 0.5%, alkali-free short glass fiber 40%, lubricant 0.2%, premix starting material, then raw material is placed in twin screw extruder through melt extruding, granulation, its expressing technique is: 170 ℃, a district, 185 ℃, 2nd district, 195 ℃, 3rd district, 200 ℃, 4th district, 210 ℃ of heads.
Embodiment 3
Take K resin 62.5%, compatilizer 6%, liquid water 0.2%, oxidation inhibitor 0.4%, alkali-free short glass fiber 30%, lubricant 0.9%, premix starting material, then raw material is placed in twin screw extruder through melt extruding, granulation, its expressing technique is: 180 ℃, a district, 220 ℃, 2nd district, 210 ℃, 3rd district, 160 ℃, 4th district, 200 ℃ of heads.
Embodiment 4
Take K resin 74.9%, compatilizer 4%, liquid water 0.2%, oxidation inhibitor 0.3%, alkali-free short glass fiber 20%, lubricant 0.6%, premix starting material, then raw material is placed in twin screw extruder through melt extruding, granulation, its expressing technique is: 190 ℃, a district, two districts 210,180 ℃, 3rd district, 200 ℃, 4th district, 210 ℃ of heads.
Embodiment 5
Take K resin 87.4%, compatilizer 2%, liquid water 0.1%, oxidation inhibitor 0.2%, alkali-free short glass fiber 10%, lubricant 0.3%, premix starting material, then raw material is placed in twin screw extruder through melt extruding, granulation, its expressing technique is: 170 ℃, a district, 190 ℃, 2nd district, 195 ℃, 3rd district, 195 ℃, 4th district, 220 ℃ of heads.
Comparative example 1
Take K resin 62.5%, compatilizer 6%, liquid water 0.2%, oxidation inhibitor 0.4%, 2000 order talcum powder 30%, lubricant 0.9%, premix starting material, then raw material is placed in twin screw extruder through melt extruding, granulation, its expressing technique is: 180 ℃, a district, 220 ℃, 2nd district, 210 ℃, 3rd district, 160 ℃, 4th district, 200 ℃ of heads.
Comparative example 2
Take K resin 100%, preparation technology the same any.
Performance test:
Tensile strength is tested by ASTMD-638 standard.Specimen types is I type, batten size (mm): (176 ± 2) (length) * (12.6 ± 0.2) (end width) * (3.05 ± 0.2) (thickness), and draw speed is 50mm/min;
Flexural strength and modulus in flexure are tested by ASTMD-790 standard.Specimen types is specimen size (mm): (128 ± 2) * (12.67 ± 0.2) * (3.11 ± 0.2), and rate of bending is 20mm/min;
Socle girder notched Izod impact strength is tested by ASTMD-256 standard.Specimen types is I type, specimen size (mm): (63 ± 2) * (12.45 ± 0.2) * (3.1 ± 0.2); Breach type is category-A, and breach residual thickness is 1.9mm;
The performance test of embodiment 1-5 is in Table 1:
Table 1
By embodiment in table 1, can be found out along with the successively decreasing of alkali-free chopped glass fiber content, the tensile strength of matrix material, flexural strength, and modulus in flexure constantly reduces, but there is a peak value in shock strength.When the glass fiber content of embodiment is 30%, when compatibilizer content is 6%, the shock strength of material is maximum, and now material over-all properties is best, and color is translucent.The present invention is when being less than 30% glass enhancing, and product surface is saturating in vain, the smooth glass emergence on the surface that there is no.The present invention when higher than 30% glass fiber content, the opaque real look of mixture moulding, and have glass emergence on the surface phenomenon.It is that water vapour is easily taken away the small molecules processing procedure process from vacuum port when through twin screw blend that the present invention uses the principle of liquid water, thereby makes mixture outward appearance reach the penetrating effect of white.
Comparative example 1 and 2 performance test are in Table 2:
Table 2
Two of whole comparative example kinds of typical result as can be seen from Table 2, comparative example 1 is talc Modified K resin, comparative example 2 is for not strengthening K resin, the low surface difference of the former intensity, the latter's intensity is low, but appearance transparent.Through more known with comparative example, the whole inventive embodiment of the application has well solved the contradiction of surface and intensity.Known above, use a kind of glass of the present invention to strengthen K resin composite materials in conjunction with suitable formula system, the adjustable matrix material that goes out to have high strength and kinds of surface effect, carries out diversified selection according to different appearance designs.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.
Claims (10)
1. glass strengthens a K resin composite materials, it is characterized in that, comprises the recipe ingredient of following weight percent:
2. glass as claimed in claim 1 strengthens K resin composite materials, it is characterized in that, described glass fibre is alkali-free short glass fiber.
3. glass as claimed in claim 2 strengthens K resin composite materials, it is characterized in that, the diameter of described glass fibre is 9-13 μ m, and water ratio is less than or equal to 0.1%.
4. glass as claimed in claim 1 strengthens K resin composite materials, it is characterized in that, described compatilizer is alternate styrene-maleic anhydride copolymer, and its second-order transition temperature is 135-155 ℃, and weight-average molecular weight is 7500-21000.
5. glass as claimed in claim 1 strengthens K resin composite materials, it is characterized in that, described liquid water is high cleanliness water, and it is in the time of 0 ℃, and density is 0.99987 * 10
3kg/m
3, be the transparent liquid of colorless and odorless at normal temperatures and pressures.
6. the glass as described in claim 1-5 any one strengthens K resin composite materials, it is characterized in that, described oxidation inhibitor is Hinered phenols antioxidant, and its fusing point is 115-150 ℃.
7. the glass as described in claim 1-5 any one strengthens K resin composite materials, it is characterized in that, described lubricant is amide waxe class modifier, and its fusing point is 141.5 ℃-144.5 ℃.
8. the glass as described in claim 1-5 any one strengthens K resin composite materials, it is characterized in that, the notched Izod impact strength of described K resin is greater than 20J/M, and transmittance is 86%-92%.
9. glass strengthens a preparation method for K resin composite materials, it is characterized in that, comprises following preparation process:
According to glass described in claim 1-8, strengthen K resin composite materials formula and take respectively each component;
Described in inciting somebody to action, take each component and carry out mixing treatment, obtain mixture;
Described mixture is melt extruded, and granulation, obtains described glass and strengthens K resin composite materials.
10. glass as claimed in claim 9 strengthens the preparation method of K resin composite materials, it is characterized in that, described in to melt extrude be to adopt twin-screw extrusion, its expressing technique condition is:
One district's temperature is 160～190 ℃, and two district's temperature are 185～220 ℃, and three district's temperature are 180～210 ℃, and four district's temperature are 160～200 ℃, head temperature: 200-220 ℃.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310745101.7A CN103709583A (en) | 2013-12-27 | 2013-12-27 | Glass fiber enhanced K resin composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310745101.7A CN103709583A (en) | 2013-12-27 | 2013-12-27 | Glass fiber enhanced K resin composite material and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103709583A true CN103709583A (en) | 2014-04-09 |
Family
ID=50402958
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310745101.7A Pending CN103709583A (en) | 2013-12-27 | 2013-12-27 | Glass fiber enhanced K resin composite material and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103709583A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107446291A (en) * | 2017-08-20 | 2017-12-08 | 佛山市北朝源科技服务有限公司 | A kind of high glaze toughness reinforcing AS composites and preparation method thereof |
| CN112724615A (en) * | 2020-12-16 | 2021-04-30 | 金发科技股份有限公司 | PBT resin composition and preparation method and application thereof |
Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1930217A (en) * | 2004-03-16 | 2007-03-14 | 陶氏环球技术公司 | Method for preparing long glass fiber-reinforced composition and fabricated articles therefrom |
| CN101081929A (en) * | 2007-06-08 | 2007-12-05 | 深圳市科聚新材料有限公司 | Composite material easy for coating thermoplastic elastomer and preparation method thereof |
| CN101220198A (en) * | 2007-12-26 | 2008-07-16 | 深圳市科聚新材料有限公司 | Fiberglass reinforcing PBT alloy material and method for producing the same |
| CN101302323A (en) * | 2008-05-21 | 2008-11-12 | 深圳市科聚新材料有限公司 | Toughened and reinforced ABS material and preparation thereof |
| CN101311222A (en) * | 2007-05-25 | 2008-11-26 | 佛山市顺德区汉达精密电子科技有限公司 | High impact resistance fiberglass reinforced engineering plastics and preparation method |
| CN101845188A (en) * | 2009-03-25 | 2010-09-29 | 上海锦湖日丽塑料有限公司 | Glass fiber reinforced styrene maleic anhydride copolymer compound and preparation method thereof |
| CN102093677A (en) * | 2009-12-11 | 2011-06-15 | 第一毛织株式会社 | Glass fiber-reinforced polyester resin composition and molded product using the same |
| CN102617997A (en) * | 2012-03-30 | 2012-08-01 | 深圳市科聚新材料有限公司 | Glass fiber-reinforced PBT/PET (Polybutylece Terephthalate/Polyethyleneglycol Terephthalate) composite material and preparation method thereof |
| CN102702638A (en) * | 2012-05-30 | 2012-10-03 | 宁波镇洋化工发展有限公司 | Glass fiber-reinforced styrene-acrylonitrile-cycloolefin (SAN) copolymer composition |
| CN103044843A (en) * | 2011-10-17 | 2013-04-17 | 合肥杰事杰新材料股份有限公司 | Continuous long-fiber reinforced ABS (acrylonitrile-butadiene-styrene) composite material and preparation method thereof |
-
2013
- 2013-12-27 CN CN201310745101.7A patent/CN103709583A/en active Pending
Patent Citations (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1930217A (en) * | 2004-03-16 | 2007-03-14 | 陶氏环球技术公司 | Method for preparing long glass fiber-reinforced composition and fabricated articles therefrom |
| CN101311222A (en) * | 2007-05-25 | 2008-11-26 | 佛山市顺德区汉达精密电子科技有限公司 | High impact resistance fiberglass reinforced engineering plastics and preparation method |
| CN101081929A (en) * | 2007-06-08 | 2007-12-05 | 深圳市科聚新材料有限公司 | Composite material easy for coating thermoplastic elastomer and preparation method thereof |
| CN101220198A (en) * | 2007-12-26 | 2008-07-16 | 深圳市科聚新材料有限公司 | Fiberglass reinforcing PBT alloy material and method for producing the same |
| CN101302323A (en) * | 2008-05-21 | 2008-11-12 | 深圳市科聚新材料有限公司 | Toughened and reinforced ABS material and preparation thereof |
| CN101845188A (en) * | 2009-03-25 | 2010-09-29 | 上海锦湖日丽塑料有限公司 | Glass fiber reinforced styrene maleic anhydride copolymer compound and preparation method thereof |
| CN102093677A (en) * | 2009-12-11 | 2011-06-15 | 第一毛织株式会社 | Glass fiber-reinforced polyester resin composition and molded product using the same |
| CN103044843A (en) * | 2011-10-17 | 2013-04-17 | 合肥杰事杰新材料股份有限公司 | Continuous long-fiber reinforced ABS (acrylonitrile-butadiene-styrene) composite material and preparation method thereof |
| CN102617997A (en) * | 2012-03-30 | 2012-08-01 | 深圳市科聚新材料有限公司 | Glass fiber-reinforced PBT/PET (Polybutylece Terephthalate/Polyethyleneglycol Terephthalate) composite material and preparation method thereof |
| CN102702638A (en) * | 2012-05-30 | 2012-10-03 | 宁波镇洋化工发展有限公司 | Glass fiber-reinforced styrene-acrylonitrile-cycloolefin (SAN) copolymer composition |
Non-Patent Citations (4)
| Title |
|---|
| 叶林忠 等: "短玻璃纤维补强丁苯橡胶的性能研究", 《特种橡胶制品》, no. 1, 31 January 1992 (1992-01-31) * |
| 赵玉庭 等: "丁苯树脂模塑料（BSM）的研究", 《塑料工业》, no. 6, 27 December 1983 (1983-12-27) * |
| 赵玉庭 等: "丁苯树脂的合成及其玻璃纤维增强塑料的研究", 《华东化工学院学报》, no. 1, 2 March 1982 (1982-03-02) * |
| 陈平，廖明义 主编: "《高分子合成材料学》", 31 August 2010 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107446291A (en) * | 2017-08-20 | 2017-12-08 | 佛山市北朝源科技服务有限公司 | A kind of high glaze toughness reinforcing AS composites and preparation method thereof |
| CN112724615A (en) * | 2020-12-16 | 2021-04-30 | 金发科技股份有限公司 | PBT resin composition and preparation method and application thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103601976B (en) | Fiber glass reinforced polypropylene material of a kind of ladder of swimming pool pedal and preparation method thereof | |
| CN103772825A (en) | Long glass fiber enhanced polypropylene composite material and preparation method thereof | |
| CN103435950A (en) | PMMA/ABS composite material, and preparation method and application thereof | |
| CN102311577A (en) | Glass fiber reinforced flame-retarded polypropylene composite and preparation method thereof | |
| CN103205080A (en) | Antibacterial polystyrene modified material and preparation method thereof | |
| CN102731921A (en) | Weatherproof polymer alloy used for replacing ABS | |
| CN103724852A (en) | HIPS (High Impact Polystyrene) composite material and preparation method thereof | |
| CN103709583A (en) | Glass fiber enhanced K resin composite material and preparation method thereof | |
| CN102936372A (en) | Polypropylene composite material, preparation method and applications thereof | |
| CN104098878A (en) | High-rigidity weather-proof PBT/ASA alloy | |
| CN106751677A (en) | A kind of fire-retardant miberal powder filled polycarbonate material of superhigh tenacity and preparation method thereof | |
| CN107501771A (en) | A kind of low-shrinkage modified polypropylene material and preparation method thereof | |
| CN108912641A (en) | Low floating fiber reinforced polycarbonate material of a kind of high glaze and preparation method thereof | |
| CN104479222A (en) | Polypropylene composite material and preparation method thereof | |
| CN101759933A (en) | Glassfiber reinforced polypropylene material without fiber exposion and manufacturing process thereof | |
| CN104497463A (en) | HIPS (high impact polystyrene) composite material and preparation method thereof | |
| CN103613876A (en) | High-gloss toughening AS (acrylonitrile-styrene) composite material and preparation method thereof | |
| CN105907024A (en) | Low-cost fiber-reinforced ABS wood-plastic composite and preparation method thereof | |
| CN103613853A (en) | Transparent glass fiber reinforced polypropylene (PP) composite material and preparation method thereof | |
| KR20180077438A (en) | Thermoplastic resin composition and molded article prepared therefrom | |
| CN106084624A (en) | Chopped basalt fibre reinforced ABS resin composite materials and its preparation method and application | |
| CN105153656A (en) | PBT resin composite high in elongation at break and preparing method thereof | |
| CN102850784A (en) | Nylon 6 modified material and preparation method thereof | |
| CN106280191A (en) | A kind of fiberglass reinforced AES resin material and preparation method thereof | |
| CN104194327A (en) | Enhanced micro-transparent nylon material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140409 |