CN103700814A - 一种碳固体酸铝锆酸酯掺杂磷酸钛锂三组份表面改性氟化铁正极材料及制备方法 - Google Patents
一种碳固体酸铝锆酸酯掺杂磷酸钛锂三组份表面改性氟化铁正极材料及制备方法 Download PDFInfo
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- CN103700814A CN103700814A CN201310446173.1A CN201310446173A CN103700814A CN 103700814 A CN103700814 A CN 103700814A CN 201310446173 A CN201310446173 A CN 201310446173A CN 103700814 A CN103700814 A CN 103700814A
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- 239000011973 solid acid Substances 0.000 title claims abstract description 33
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 32
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 32
- 239000007822 coupling agent Substances 0.000 title claims abstract description 14
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- SHXXPRJOPFJRHA-UHFFFAOYSA-K iron(iii) fluoride Chemical class F[Fe](F)F SHXXPRJOPFJRHA-UHFFFAOYSA-K 0.000 title claims abstract description 9
- MKGYHFFYERNDHK-UHFFFAOYSA-K P(=O)([O-])([O-])[O-].[Ti+4].[Li+] Chemical compound P(=O)([O-])([O-])[O-].[Ti+4].[Li+] MKGYHFFYERNDHK-UHFFFAOYSA-K 0.000 title abstract description 4
- 239000010406 cathode material Substances 0.000 title abstract description 3
- DNXNYEBMOSARMM-UHFFFAOYSA-N alumane;zirconium Chemical compound [AlH3].[Zr] DNXNYEBMOSARMM-UHFFFAOYSA-N 0.000 title abstract 5
- 239000000463 material Substances 0.000 claims abstract description 36
- 238000000498 ball milling Methods 0.000 claims abstract description 23
- 239000004411 aluminium Substances 0.000 claims abstract description 13
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 13
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 13
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 22
- 239000000843 powder Substances 0.000 claims description 21
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 18
- 239000007789 gas Substances 0.000 claims description 18
- 238000006277 sulfonation reaction Methods 0.000 claims description 16
- 238000001816 cooling Methods 0.000 claims description 14
- 239000007784 solid electrolyte Substances 0.000 claims description 14
- 229910052786 argon Inorganic materials 0.000 claims description 11
- 238000000034 method Methods 0.000 claims description 11
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 10
- DDFHBQSCUXNBSA-UHFFFAOYSA-N 5-(5-carboxythiophen-2-yl)thiophene-2-carboxylic acid Chemical compound S1C(C(=O)O)=CC=C1C1=CC=C(C(O)=O)S1 DDFHBQSCUXNBSA-UHFFFAOYSA-N 0.000 claims description 7
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 claims description 7
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 7
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 7
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 7
- ZGUQGPFMMTZGBQ-UHFFFAOYSA-N [Al].[Al].[Zr] Chemical compound [Al].[Al].[Zr] ZGUQGPFMMTZGBQ-UHFFFAOYSA-N 0.000 claims description 7
- 238000003763 carbonization Methods 0.000 claims description 7
- 239000008103 glucose Substances 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 7
- 239000001257 hydrogen Substances 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 7
- 238000009413 insulation Methods 0.000 claims description 7
- QAOWNCQODCNURD-UHFFFAOYSA-N sulfuric acid Substances OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 7
- 238000001291 vacuum drying Methods 0.000 claims description 7
- 239000010405 anode material Substances 0.000 claims description 6
- 229910052757 nitrogen Inorganic materials 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- OUWHFNSCTSNLPL-UHFFFAOYSA-N [Li].[Ti].P(O)(O)(O)=O Chemical compound [Li].[Ti].P(O)(O)(O)=O OUWHFNSCTSNLPL-UHFFFAOYSA-N 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 claims description 4
- 238000002425 crystallisation Methods 0.000 claims description 4
- 230000008025 crystallization Effects 0.000 claims description 4
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 4
- 230000004048 modification Effects 0.000 claims description 4
- 238000012986 modification Methods 0.000 claims description 4
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 claims description 3
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 claims description 3
- 229920000053 polysorbate 80 Polymers 0.000 claims description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 2
- 229910001416 lithium ion Inorganic materials 0.000 abstract description 26
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 abstract description 23
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 9
- 239000002245 particle Substances 0.000 abstract description 7
- 239000004020 conductor Substances 0.000 abstract description 6
- -1 FeF3 iron ion Chemical class 0.000 abstract description 3
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 abstract description 3
- 125000003545 alkoxy group Chemical group 0.000 abstract description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract description 3
- 229910052742 iron Inorganic materials 0.000 abstract description 3
- 238000006068 polycondensation reaction Methods 0.000 abstract description 3
- 229910052726 zirconium Inorganic materials 0.000 abstract description 3
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 239000010703 silicon Substances 0.000 abstract description 2
- 229910052710 silicon Inorganic materials 0.000 abstract description 2
- 150000001721 carbon Chemical class 0.000 abstract 4
- 239000006258 conductive agent Substances 0.000 abstract 2
- 150000002500 ions Chemical class 0.000 abstract 2
- 230000005518 electrochemistry Effects 0.000 abstract 1
- 239000002994 raw material Substances 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 7
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 6
- 238000007599 discharging Methods 0.000 description 6
- 229910052744 lithium Inorganic materials 0.000 description 6
- 239000000126 substance Substances 0.000 description 4
- 230000004087 circulation Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000011572 manganese Substances 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 229910010556 LiFeF Inorganic materials 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- QVQLCTNNEUAWMS-UHFFFAOYSA-N barium oxide Chemical compound [Ba]=O QVQLCTNNEUAWMS-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 239000010941 cobalt Substances 0.000 description 2
- 229910017052 cobalt Inorganic materials 0.000 description 2
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 239000011532 electronic conductor Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000012827 research and development Methods 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- 229910012851 LiCoO 2 Inorganic materials 0.000 description 1
- 229910010710 LiFePO Inorganic materials 0.000 description 1
- 229910052493 LiFePO4 Inorganic materials 0.000 description 1
- 229910015645 LiMn Inorganic materials 0.000 description 1
- 229910014689 LiMnO Inorganic materials 0.000 description 1
- 229910013292 LiNiO Inorganic materials 0.000 description 1
- KFDQGLPGKXUTMZ-UHFFFAOYSA-N [Mn].[Co].[Ni] Chemical compound [Mn].[Co].[Ni] KFDQGLPGKXUTMZ-UHFFFAOYSA-N 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- QHGJSLXSVXVKHZ-UHFFFAOYSA-N dilithium;dioxido(dioxo)manganese Chemical compound [Li+].[Li+].[O-][Mn]([O-])(=O)=O QHGJSLXSVXVKHZ-UHFFFAOYSA-N 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000005611 electricity Effects 0.000 description 1
- 238000004146 energy storage Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000002360 explosive Substances 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000000713 high-energy ball milling Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- ZAUUZASCMSWKGX-UHFFFAOYSA-N manganese nickel Chemical compound [Mn].[Ni] ZAUUZASCMSWKGX-UHFFFAOYSA-N 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 230000036632 reaction speed Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000006104 solid solution Substances 0.000 description 1
- 229910052596 spinel Inorganic materials 0.000 description 1
- 239000011029 spinel Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000007704 transition Effects 0.000 description 1
- LSGOVYNHVSXFFJ-UHFFFAOYSA-N vanadate(3-) Chemical compound [O-][V]([O-])([O-])=O LSGOVYNHVSXFFJ-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/36—Selection of substances as active materials, active masses, active liquids
- H01M4/58—Selection of substances as active materials, active masses, active liquids of inorganic compounds other than oxides or hydroxides, e.g. sulfides, selenides, tellurides, halogenides or LiCoFy; of polyanionic structures, e.g. phosphates, silicates or borates
- H01M4/582—Halogenides
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/62—Selection of inactive substances as ingredients for active masses, e.g. binders, fillers
- H01M4/624—Electric conductive fillers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Inorganic Chemistry (AREA)
- Battery Electrode And Active Subsutance (AREA)
- Secondary Cells (AREA)
Abstract
Description
Claims (5)
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CN201310446173.1A CN103700814B (zh) | 2013-09-18 | 2013-09-18 | 一种碳固体酸铝锆酸酯掺杂磷酸钛锂三组份表面改性氟化铁正极材料及制备方法 |
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CN201310446173.1A CN103700814B (zh) | 2013-09-18 | 2013-09-18 | 一种碳固体酸铝锆酸酯掺杂磷酸钛锂三组份表面改性氟化铁正极材料及制备方法 |
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CN103700814A true CN103700814A (zh) | 2014-04-02 |
CN103700814B CN103700814B (zh) | 2016-06-08 |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104157836A (zh) * | 2014-07-14 | 2014-11-19 | 宁波大学 | 一种Cu2+,Co2+,Zr4+,Ag+掺杂氟化铁复合正极材料及制备方法 |
CN104157837A (zh) * | 2014-07-14 | 2014-11-19 | 宁波大学 | 一种Cu2+,Mn2+,Zr4+,Ag+掺杂氟化铁复合正极材料及制备方法 |
CN104150542A (zh) * | 2014-07-14 | 2014-11-19 | 宁波大学 | 一种Cu2+,Co2+,Ag+掺杂氟化铁复合正极材料及制备方法 |
CN104176785A (zh) * | 2014-07-14 | 2014-12-03 | 宁波大学 | 一种Cu2+,Co2+,Ce4+,Ag+掺杂氟化铁复合正极材料及制备方法 |
CN109792081A (zh) * | 2016-09-29 | 2019-05-21 | Tdk株式会社 | 锂离子传导性固体电解质及全固体锂离子二次电池 |
Citations (3)
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US20090029237A1 (en) * | 2005-10-05 | 2009-01-29 | Rachid Yazami | Fluoride ion electrochemical cell |
CN102623707A (zh) * | 2012-04-02 | 2012-08-01 | 湘潭大学 | 一种掺钴包碳的氟化铁正极材料及其制备方法 |
CN103199253A (zh) * | 2013-03-31 | 2013-07-10 | 马军昌 | 一种石墨烯-氟化铁复合正极材料的制备方法 |
-
2013
- 2013-09-18 CN CN201310446173.1A patent/CN103700814B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20090029237A1 (en) * | 2005-10-05 | 2009-01-29 | Rachid Yazami | Fluoride ion electrochemical cell |
CN102623707A (zh) * | 2012-04-02 | 2012-08-01 | 湘潭大学 | 一种掺钴包碳的氟化铁正极材料及其制备方法 |
CN103199253A (zh) * | 2013-03-31 | 2013-07-10 | 马军昌 | 一种石墨烯-氟化铁复合正极材料的制备方法 |
Non-Patent Citations (1)
Title |
---|
伍文等: "锂二次电池新型正极材料FeF3(H2O)0 .33的制备及电化学性能研究", 《功能材料》 * |
Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104157836A (zh) * | 2014-07-14 | 2014-11-19 | 宁波大学 | 一种Cu2+,Co2+,Zr4+,Ag+掺杂氟化铁复合正极材料及制备方法 |
CN104157837A (zh) * | 2014-07-14 | 2014-11-19 | 宁波大学 | 一种Cu2+,Mn2+,Zr4+,Ag+掺杂氟化铁复合正极材料及制备方法 |
CN104150542A (zh) * | 2014-07-14 | 2014-11-19 | 宁波大学 | 一种Cu2+,Co2+,Ag+掺杂氟化铁复合正极材料及制备方法 |
CN104176785A (zh) * | 2014-07-14 | 2014-12-03 | 宁波大学 | 一种Cu2+,Co2+,Ce4+,Ag+掺杂氟化铁复合正极材料及制备方法 |
CN104150542B (zh) * | 2014-07-14 | 2015-12-09 | 宁波大学 | 一种Cu2+,Co2+,Ag+掺杂氟化铁复合正极材料及制备方法 |
CN104176785B (zh) * | 2014-07-14 | 2016-06-29 | 宁波大学 | 一种Cu2+,Co2+,Ce4+,Ag+掺杂氟化铁复合正极材料及制备方法 |
CN104157836B (zh) * | 2014-07-14 | 2016-08-17 | 宁波大学 | 一种Cu2+,Co2+,Zr4+,Ag+掺杂氟化铁复合正极材料及制备方法 |
CN104157837B (zh) * | 2014-07-14 | 2016-08-24 | 宁波大学 | 一种Cu2+,Mn2+,Zr4+,Ag+掺杂氟化铁复合正极材料及制备方法 |
CN109792081A (zh) * | 2016-09-29 | 2019-05-21 | Tdk株式会社 | 锂离子传导性固体电解质及全固体锂离子二次电池 |
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