CN103696122A - Multipurpose nylon lace and manufacturing method thereof - Google Patents
Multipurpose nylon lace and manufacturing method thereof Download PDFInfo
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- CN103696122A CN103696122A CN201310676669.8A CN201310676669A CN103696122A CN 103696122 A CN103696122 A CN 103696122A CN 201310676669 A CN201310676669 A CN 201310676669A CN 103696122 A CN103696122 A CN 103696122A
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Abstract
The invention relates to a multipurpose nylon lace and a manufacturing method thereof. The multipurpose nylon lace adopts a two-layer combined structure. A surface layer is arranged on the base layer; the surface layer is made of positive ion polyester fibers; the base layer is made of spandex fibers and multipurpose polyamide fabrics; the mass ratio of the spandex fibers to the multipurpose polyamide fabrics is 1:49. Nano zinc oxide of the multipurpose nylon lace is high in capacity for absorbing ultraviolet, can shield both long-wave ultraviolet (UVA) with the wavelength of 320-400mm and middle-wave ultraviolet (UVB) with the wavelength of 280-320nm, is non-toxic and odorless, cannot stimulate the skin, cannot be decomposed and go bad, is high in stability and white, can be colored according to different objects, is low in cost, can be used for producing odor-resistant, antimicrobial and anti-ultraviolet fibers and can absorb odor and purify air.
Description
[technical field]
The present invention relates to lace technical field, specifically, is a kind of multipurpose roses and lace and manufacture method thereof.
[background technology]
The colored shape structure of lace was not knitting in the past or tatting obtains, but obtained by twisted yarn.In the Europe of 16th century and the 17th century, use core to weave the revenue source that lace becomes individual handicraftsman, and the divert oneself means of time of noble women.Society at that time makes very greatly lace workman's work very tired to the demand of lace, and they usually work in mouldy basement, and light is faint, can only see spinning wheel.
After John Heathcoat invention bobbinet frame (patented in 1809), the lace manufacture of Britain has entered industrial age, at the bottom of this machine can be produced very meticulous and regular hexagon lace.It is just passable that handicraftsman only need to be made into figure on the net, and this net is generally real silk material.After several years, John Leavers has invented a kind of machine, and this machine uses the principle of French jacquard weaving machine, can produce lace figure and lace net, and it has also established the lace tradition of Nottingham, GBR simultaneously.The machine of Leavers is very complicated, 40000 parts and 50000 kinds of lines, consists of, need to be from different angle work.
Today some very the lace company of high-quality still using the machine of Leavers, Karl Mayer to release warp knitting machine if Jacquardtronic and Textronic are in order to produce the silky lace of leavers flower bud, but more economically, meticulous and light and handy.Synthetic threads is as artificial silk, nylon, and terylene and spandex have also changed the character of lace, and still, the quality that is used for producing the yarn of lace must be very good, and twisting count is than higher for yarn knitting or tatting.
Nottingham Trent University has held and has been called " lace: 75000 kinds of laces having shown school's collection.These lace archives have excited weaving fashion and decorative art Major and teachers' inspiration, and everybody wishes to design more new works, and the past of lace and current art and design are merged.These new works will be put on display in SPINEXPO exhibition, and title is " route of lace ", to expect that more designers, buyer and manufacturer are used lace in product.The works of putting on display comprise stamp and the pattern that new lace structure, embroidery lace and lace develop.
Today, lace has become the fashion in daily life, and all there is production in Asia and west, and it is the indispensable part of underclothes, also can be used for decorating household, the especially favorite of catwalk and street style.
[summary of the invention]
The object of the invention is to overcome the deficiencies in the prior art, a kind of multipurpose roses and lace and manufacture method thereof are provided.
The object of the invention is to be achieved through the following technical solutions:
A multipurpose roses and lace, is two layer composite structure, is provided with top layer in basic unit; The material on described top layer is CATION terylene fiber; The material of described basic unit is Modal fibre and multipurpose nylon fibre, and the mass ratio of Modal fibre and multipurpose nylon fibre is 1:49.
Described Modal fibre can be replaced by silk.
Described top layer be shaped as various geometric figures, such as flower, bird, insect, and fish, and personalized design configuration.
A multipurpose roses and lace, its concrete preparation method is: adopt Modal fibre and multipurpose nylon fibre, and CATION terylene fibrous raw material forms through the braiding of lace machine, after having weaved, through dyeing finishing process, obtain roses and lace.
Described multipurpose nylon fibre, is cut into slices and modification capsule forms by nylon-66, and wherein, the mass fraction that tea charcoal capsule accounts for multipurpose nylon fibre is 0.5～2.5%; By two kinds of raw material melt-spun methods, be prepared from.
A preparation method for tea charcoal capsule, its concrete steps are:
(1) pretreatment of raw material:
Tea grounds is dried to 2 hours at 50 ℃, obtains processing rear tea grounds;
(2) charing is processed:
Tea grounds after the processing that step (1) is obtained, then carries out charing simultaneously, then obtains modification powder;
Described charring process is for adopting quartz tube furnace to carry out segmentation charing: the heating rate with 6 ℃/min rises to 200 ℃, tea grounds is charing 60min at 200 ℃, then the heating rate with 12 ℃/min rises to 400 ℃, again at 400 ℃ of charing 120min, finally the heating rate with 24 ℃/min rises to 500 ℃, and 240min is processed in charing at this temperature; After charing, obtained product is ground at high energy ball mill, until fine-powdered obtains modification powder, the particle diameter of modification powder is 0.1～1 μ m; Adopt low-temperature carbonization, save on the one hand cost, keep on the one hand in addition the original function of tea charcoal, can be used as the carrier performance tea charcoal effect of absorption, the excess Temperature of charing and long, will destroy original performance of tea charcoal, advantage and the strong point of Here it is low-temperature carbonization; This is also the reason that does not adopt high temperature carbonization.
(3) aging modification:
Step (2) modification powder is carried out to aging modification, obtain composite powder;
The modification powder that step (2) is obtained is dissolved in strong acid solution, and the solution of the modification powder obtaining adds functional material and aging dose, stir again and ultrasonic dispersion, then centrifugation obtains solid material, and solid material is dried to 1～2 hour at 45～65 ℃, obtains composite powder;
Described functional material is nano boron carbide powder, nano indium tin metal oxide and nano zine oxide; Three's mass ratio is 1:1:1～1:5:5, is preferably 1:3:3;
The mass ratio of described functional material and aging dose is 5:1;
Described strong acid is the concentrated sulfuric acid, red fuming nitric acid (RFNA), hydrofluoric acid or other.
The described addition of aging dose is 1～3% of modification powder mass fraction;
Described aging dose is antioxidant, ultraviolet absorber and light stabilizer, and three's mass ratio is 1:2:3;
Described antioxidant is commercially available prod, such as antioxidant 1010 and irgasfos 168;
Described ultraviolet absorber is the ultraviolet absorber of hydroxyl, such as ESCALOL 567, and Octabenzone, the materials such as 2,4-DihydroxyBenzophenone; For commercially available prod;
Described light stabilizer is the light stabilizer of hydroxyl, such as O-hydroxyl-diphenyl ketone, and 2-(2 ', 4 '-dihydroxy phenyl)-5, the materials such as 6-dihydroxy benzo triazole and 1,6-dihydroxy benzo triazole; For commercially available prod;
The aging modification of this step has 2 effects, be that physical absorption and valence bond cooperation are used, after tea powder and nano material acidifying, its surface forms hydrogen bond, and carry out chemical strong closing with the hydroxyl of aging dose, moreover utilize the space of modification powder and nano material self more, carry out the suction-operated of a physics.
(4) tea charcoal capsule
By sandwich layer be composite powder to be wrapped in cystoblast be chitosan material the inside, make the tea charcoal capsule containing composite powder; Wherein, the Thickness Ratio of cystoblast and sandwich layer is 1:18; The diameter of function reagent is 0.4～4 μ m;
Tea charcoal capsule adopts complex coacervation synthetic, also can adopt interfacial polymerization or situ aggregation method, is ripe technology.
The diameter of tea charcoal capsule is 0.4～4 μ m, and it is conducive to capsule smoothly by spinneret orifice, and guarantees that the combination of capsule and fiber is firm, can't affect the mechanical performance of fiber;
Capsule/the core of tea charcoal capsule is greater than 1:15 than generally, guarantees that microcapsules have certain mechanical strength and heat resistance;
The effect of tea charcoal capsule is, plays the effect of slow release nano functional particle, is conducive to its nanometer effect and is able to permanent maintenance; The preparation that its nanometer effect is better than conventional master batch type functional particles is used further to the technique effect of spinning.
Compared with prior art, good effect of the present invention is:
(1) technique of the present invention is simple, is easy to promote;
(2) nano indium tin metal oxide, has good electric conductivity and the transparency, can cut off harmful electron radiation, ultraviolet ray and far infrared;
(3) the present invention adopts the nano boron carbide powder that plasma arc gas chemistry synthetic method is produced, and its purity is high, particle diameter is little, be evenly distributed, and specific area is large, high surface, and apparent density is low; Nanoscale carbonization boron powder has stable physics and chemistry character, nonmagnetic, resistance to strong acid, resistance to highly basic; Be added on material, be beneficial to extend the service life of material;
(4) to absorb ultraviolet ability strong for nano zine oxide of the present invention, long wave ultraviolet (UVA) wavelength (320～400mm) and ultraviolet B radiation (UVB) wavelength (280～320nm) are all had to shielding action. nano zine oxide is nontoxic, tasteless, non-stimulated to skin, do not decompose, never degenerate, good stability, this is as white, can be in addition painted according to different objects, low price; Can be used for producing deodorization, antibacterial, anti-ultraviolet fiber. can absorb stink, purify air.
(5) the present invention will carry out modification after composite powder and nano material mixing, can make like this nano material be more prone to be dispersed in the space of composite powder, the carrier the inside of nano material absorption composite powder, make its effect be able to permanent maintenance, be conducive to bring into play the special role of nano material, effect is significantly higher than direct employing nano material and adds the technique effect that carries out spinning.
[specific embodiment]
The specific embodiment of a kind of multipurpose roses and lace of the present invention and manufacture method thereof is below provided.
Embodiment 1
A multipurpose roses and lace, is two layer composite structure, is provided with top layer in basic unit; The material on described top layer is CATION terylene fiber; The material of described basic unit is Modal fibre and multipurpose nylon fibre, and the mass ratio of Modal fibre and multipurpose nylon fibre is 1:49.
Described top layer be shaped as various geometric figures, such as flower, bird, insect, and fish, and personalized design configuration.
A multipurpose roses and lace, its concrete preparation method is: adopt Modal fibre and multipurpose nylon fibre, and CATION terylene fibrous raw material forms through the braiding of lace machine, after having weaved, through dyeing finishing process, obtain roses and lace.
Described multipurpose nylon fibre, is cut into slices and modification capsule forms by nylon-66, and wherein, the mass fraction that tea charcoal capsule accounts for multipurpose nylon fibre is 0.6%; By two kinds of raw material melt-spun methods, be prepared from.
A preparation method for tea charcoal capsule, its concrete steps are:
(1) pretreatment of raw material:
Tea grounds is dried to 2 hours at 50 ℃, obtains processing rear tea grounds;
(2) charing is processed:
Tea grounds after the processing that step (1) is obtained, then carries out charing simultaneously, then obtains modification powder;
Described charring process is for adopting quartz tube furnace to carry out segmentation charing: the heating rate with 6 ℃/min rises to 200 ℃, tea grounds is charing 60min at 200 ℃, then the heating rate with 12 ℃/min rises to 400 ℃, again at 400 ℃ of charing 120min, finally the heating rate with 24 ℃/min rises to 500 ℃, and 240min is processed in charing at this temperature; After charing, obtained product is ground at high energy ball mill, until fine-powdered obtains modification powder, the particle diameter of modification powder is 0.1～1 μ m; Adopt low-temperature carbonization, save on the one hand cost, keep on the one hand in addition the original function of tea charcoal, can be used as the carrier performance tea charcoal effect of absorption, the excess Temperature of charing and long, will destroy original performance of tea charcoal, advantage and the strong point of Here it is low-temperature carbonization; This is also the reason that does not adopt high temperature carbonization.
(3) aging modification:
The modification powder that step (2) is obtained is dissolved in strong acid solution, and the solution of the modification powder obtaining adds functional material and aging dose, stir again and ultrasonic dispersion, then centrifugation obtains solid material, and solid material is dried to 1～2 hour at 45～65 ℃, obtains composite powder;
Described functional material is nano boron carbide powder, nano indium tin metal oxide and nano zine oxide; Three's mass ratio is 1:1:1;
The mass ratio of described functional material and aging dose is 5:1;
Described strong acid is the concentrated sulfuric acid, red fuming nitric acid (RFNA), hydrofluoric acid or other.
The described addition of aging dose is 1% of modification powder mass fraction;
Described aging dose is antioxidant, ultraviolet absorber and light stabilizer, and three's mass ratio is 1:2:3;
Described antioxidant is commercially available prod, such as antioxidant 1010 and irgasfos 168;
Described ultraviolet absorber is the ultraviolet absorber of hydroxyl, such as ESCALOL 567, and Octabenzone, the materials such as 2,4-DihydroxyBenzophenone; For commercially available prod;
Described light stabilizer is the light stabilizer of hydroxyl, such as O-hydroxyl-diphenyl ketone, and 2-(2 ', 4 '-dihydroxy phenyl)-5, the materials such as 6-dihydroxy benzo triazole and 1,6-dihydroxy benzo triazole; For commercially available prod;
The aging modification of this step has 2 effects, be that physical absorption and valence bond cooperation are used, after tea powder and nano material acidifying, its surface forms hydrogen bond, and carry out chemical strong closing with the hydroxyl of aging dose, moreover utilize the space of modification powder and nano material self more, carry out the suction-operated of a physics.
(4) tea charcoal capsule
By sandwich layer be composite powder to be wrapped in cystoblast be chitosan material the inside, make the tea charcoal capsule containing composite powder; Wherein, the Thickness Ratio of cystoblast and sandwich layer is 1:18; The diameter of function reagent is 0.4～4 μ m;
Tea charcoal capsule adopts complex coacervation synthetic, also can adopt interfacial polymerization or situ aggregation method, is ripe technology.
The diameter of tea charcoal capsule is 0.4～4 μ m, and it is conducive to capsule smoothly by spinneret orifice, and guarantees that the combination of capsule and fiber is firm, can't affect the mechanical performance of fiber;
Capsule/the core of tea charcoal capsule is greater than 1:15 than generally, guarantees that microcapsules have certain mechanical strength and heat resistance;
The effect of tea charcoal capsule is, plays the effect of slow release nano functional particle, is conducive to its nanometer effect and is able to permanent maintenance; The preparation that its nanometer effect is better than conventional master batch type functional particles is used further to the technique effect of spinning.
The Modal fibre of the present embodiment can be replaced by silk, and other is constant, obtains a kind of the more purposes roses and lace containing silk.
Embodiment 2
A multipurpose roses and lace, is two layer composite structure, is provided with top layer in basic unit; The material on described top layer is CATION terylene fiber; The material of described basic unit is Modal fibre and multipurpose nylon fibre, and the mass ratio of Modal fibre and multipurpose nylon fibre is 1:49.
Described top layer be shaped as various geometric figures, such as flower, bird, insect, and fish, and personalized design configuration.
A multipurpose roses and lace, its concrete preparation method is: adopt Modal fibre and multipurpose nylon fibre, and CATION terylene fibrous raw material forms through the braiding of lace machine, after having weaved, through dyeing finishing process, obtain roses and lace.
Described multipurpose nylon fibre, is cut into slices and modification capsule forms by nylon-66, and wherein, the mass fraction that tea charcoal capsule accounts for multipurpose nylon fibre is 1.5%; By two kinds of raw material melt-spun methods, be prepared from.
A preparation method for tea charcoal capsule, its concrete steps are:
(1) pretreatment of raw material:
Tea grounds is dried to 2 hours at 50 ℃, obtains processing rear tea grounds;
(2) charing is processed:
Tea grounds after the processing that step (1) is obtained, then carries out charing simultaneously, then obtains modification powder;
Charring process is with embodiment 1;
(3) aging modification:
The modification powder that step (2) is obtained is dissolved in strong acid solution, and the solution of the modification powder obtaining adds functional material and aging dose, stir again and ultrasonic dispersion, then centrifugation obtains solid material, and solid material is dried to 1～2 hour at 45～65 ℃, obtains composite powder;
Described functional material is nano boron carbide powder, nano indium tin metal oxide and nano zine oxide; Three's mass ratio is 1:3:3;
The mass ratio of described functional material and aging dose is 5:1;
Described strong acid is the concentrated sulfuric acid, red fuming nitric acid (RFNA), hydrofluoric acid or other.
The described addition of aging dose is 2% of modification powder mass fraction;
Described aging dose is antioxidant, ultraviolet absorber and light stabilizer, and three's mass ratio is 1:2:3;
(4) tea charcoal capsule
By sandwich layer be composite powder to be wrapped in cystoblast be chitosan material the inside, make the tea charcoal capsule containing composite powder; Wherein, the Thickness Ratio of cystoblast and sandwich layer is 1:18; The diameter of function reagent is 0.4～4 μ m;
Tea charcoal capsule adopts complex coacervation synthetic, also can adopt interfacial polymerization or situ aggregation method, is ripe technology.
The diameter of tea charcoal capsule is 0.4～4 μ m, and it is conducive to capsule smoothly by spinneret orifice, and guarantees that the combination of capsule and fiber is firm, can't affect the mechanical performance of fiber;
Capsule/the core of tea charcoal capsule is greater than 1:15 than generally, guarantees that microcapsules have certain mechanical strength and heat resistance;
The effect of tea charcoal capsule is, plays the effect of slow release nano functional particle, is conducive to its nanometer effect and is able to permanent maintenance; The preparation that its nanometer effect is better than conventional master batch type functional particles is used further to the technique effect of spinning.
The Modal fibre of the present embodiment can be replaced by silk, and other is constant, obtains a kind of the more purposes roses and lace containing silk.
Embodiment 3
A multipurpose roses and lace, is two layer composite structure, is provided with top layer in basic unit; The material on described top layer is CATION terylene fiber; The material of described basic unit is Modal fibre and multipurpose nylon fibre, and the mass ratio of Modal fibre and multipurpose nylon fibre is 1:49.
Described top layer be shaped as various geometric figures, such as flower, bird, insect, and fish, and personalized design configuration.
A multipurpose roses and lace, its concrete preparation method is: adopt Modal fibre and multipurpose nylon fibre, and CATION terylene fibrous raw material forms through the braiding of lace machine, after having weaved, through dyeing finishing process, obtain roses and lace.
Described multipurpose nylon fibre, is cut into slices and modification capsule forms by nylon-66, and wherein, the mass fraction that tea charcoal capsule accounts for multipurpose nylon fibre is 2.3%; By two kinds of raw material melt-spun methods, be prepared from.
A preparation method for tea charcoal capsule, its concrete steps are:
(1) pretreatment of raw material:
Tea grounds is dried to 2 hours at 50 ℃, obtains processing rear tea grounds;
(2) charing is processed:
Tea grounds after the processing that step (1) is obtained, then carries out charing simultaneously, then obtains modification powder;
Described charring process is with embodiment 1.
(3) aging modification:
The modification powder that step (2) is obtained is dissolved in strong acid solution, and the solution of the modification powder obtaining adds functional material and aging dose, stir again and ultrasonic dispersion, then centrifugation obtains solid material, and solid material is dried to 1～2 hour at 45～65 ℃, obtains composite powder;
Described functional material is nano boron carbide powder, nano indium tin metal oxide and nano zine oxide; Three's mass ratio is 1:5:5;
The mass ratio of described functional material and aging dose is 5:1;
Described strong acid is the concentrated sulfuric acid, red fuming nitric acid (RFNA), hydrofluoric acid or other.
The described addition of aging dose is 2.5% of modification powder mass fraction;
Described aging dose is antioxidant, ultraviolet absorber and light stabilizer, and three's mass ratio is 1:2:3;
Described antioxidant is commercially available prod, such as antioxidant 1010 and irgasfos 168;
(4) tea charcoal capsule
By sandwich layer be composite powder to be wrapped in cystoblast be chitosan material the inside, make the tea charcoal capsule containing composite powder; Wherein, the Thickness Ratio of cystoblast and sandwich layer is 1:18; The diameter of function reagent is 0.4～4 μ m;
Tea charcoal capsule adopts complex coacervation synthetic, also can adopt interfacial polymerization or situ aggregation method, is ripe technology.
The diameter of tea charcoal capsule is 0.4～4 μ m, and it is conducive to capsule smoothly by spinneret orifice, and guarantees that the combination of capsule and fiber is firm, can't affect the mechanical performance of fiber;
Capsule/the core of tea charcoal capsule is greater than 1:15 than generally, guarantees that microcapsules have certain mechanical strength and heat resistance;
The effect of tea charcoal capsule is, plays the effect of slow release nano functional particle, is conducive to its nanometer effect and is able to permanent maintenance; The preparation that its nanometer effect is better than conventional master batch type functional particles is used further to the technique effect of spinning.
The Modal fibre of the present embodiment can be replaced by silk, and other is constant, obtains a kind of the more purposes roses and lace containing silk.
The above is only the preferred embodiment of the present invention; it should be pointed out that for those skilled in the art, without departing from the inventive concept of the premise; can also make some improvements and modifications, these improvements and modifications also should be considered within the scope of protection of the present invention.
Claims (10)
1. a multipurpose roses and lace, is characterized in that, is two layer composite structure, is provided with top layer in basic unit; The material on described top layer is CATION terylene fiber; The material of described basic unit is Modal fibre and multipurpose nylon fibre, and the mass ratio of Modal fibre and multipurpose nylon fibre is 1:49.
2. a kind of multipurpose roses and lace as claimed in claim 1, is characterized in that, described top layer be shaped as various geometric figures.
3. a kind of multipurpose roses and lace as claimed in claim 1, it is characterized in that, the concrete preparation method of described multipurpose roses and lace is: adopt Modal fibre and multipurpose nylon fibre, and CATION terylene fibrous raw material forms through the braiding of lace machine, after having weaved, through dyeing finishing process, obtain roses and lace.
4. a kind of multipurpose roses and lace as claimed in claim 1, is characterized in that, described multipurpose nylon fibre is cut into slices and modification capsule forms by nylon-66, and wherein, the mass fraction that tea charcoal capsule accounts for multipurpose nylon fibre is 0.5～2.5%; By two kinds of raw material melt-spun methods, be prepared from.
5. a kind of multipurpose roses and lace as claimed in claim 1, is characterized in that, a kind of preparation method of tea charcoal capsule, and its concrete steps are:
(1) pretreatment of raw material:
Tea grounds is dried to 2 hours at 50 ℃, obtains processing rear tea grounds;
(2) charing is processed:
Tea grounds after the processing that step (1) is obtained, then carries out charing simultaneously, then obtains modification powder;
(3) aging modification:
Step (2) modification powder is carried out to aging modification, obtain composite powder;
(4) tea charcoal capsule
By sandwich layer be composite powder to be wrapped in cystoblast be chitosan material the inside, make the tea charcoal capsule containing composite powder; Wherein, the Thickness Ratio of cystoblast and sandwich layer is 1:18; The diameter of function reagent is 0.4～4 μ m.
6. a kind of multipurpose roses and lace as claimed in claim 5, it is characterized in that, in described step (2), described charring process is for adopting quartz tube furnace to carry out segmentation charing: the heating rate with 6 ℃/min rises to 200 ℃, tea grounds is charing 60min at 200 ℃, and then the heating rate with 12 ℃/min rises to 400 ℃, then at 400 ℃ of charing 120min, finally the heating rate with 24 ℃/min rises to 500 ℃, and 240min is processed in charing at this temperature; After charing, obtained product is ground at high energy ball mill, until fine-powdered obtains modification powder, the particle diameter of modification powder is 0.1～1 μ m.
7. a kind of multipurpose roses and lace as claimed in claim 5, it is characterized in that, in described step (3), the modification powder that step (2) is obtained is dissolved in strong acid solution, and the solution of the modification powder obtaining adds functional material and aging dose, stir again and ultrasonic dispersion, then centrifugation obtains solid material, and solid material is dried to 1～2 hour at 45～65 ℃, obtains composite powder.
8. a kind of multipurpose roses and lace as claimed in claim 7, is characterized in that, described functional material is nano boron carbide powder, nano indium tin metal oxide and nano zine oxide; Three's mass ratio is 1:1:1～1:5:5, is preferably 1:3:3.
9. a kind of multipurpose roses and lace as claimed in claim 7, is characterized in that, the mass ratio of described functional material and aging dose is 5:1.
10. a kind of multipurpose roses and lace as claimed in claim 7, is characterized in that, the described addition of aging dose is 1～3% of modification powder mass fraction.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310676669.8A CN103696122A (en) | 2013-12-11 | 2013-12-11 | Multipurpose nylon lace and manufacturing method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310676669.8A CN103696122A (en) | 2013-12-11 | 2013-12-11 | Multipurpose nylon lace and manufacturing method thereof |
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| CN103696122A true CN103696122A (en) | 2014-04-02 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104060392A (en) * | 2014-06-17 | 2014-09-24 | 福建省百凯经编实业有限公司 | Production method for nylon lace |
| CN106174727A (en) * | 2016-09-22 | 2016-12-07 | 袁惠芬 | A kind of bra ring for fixing and preparation method thereof |
-
2013
- 2013-12-11 CN CN201310676669.8A patent/CN103696122A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104060392A (en) * | 2014-06-17 | 2014-09-24 | 福建省百凯经编实业有限公司 | Production method for nylon lace |
| CN104060392B (en) * | 2014-06-17 | 2015-07-08 | 福建省百凯经编实业有限公司 | Production method for nylon lace |
| CN106174727A (en) * | 2016-09-22 | 2016-12-07 | 袁惠芬 | A kind of bra ring for fixing and preparation method thereof |
| CN106174727B (en) * | 2016-09-22 | 2017-12-01 | 袁惠芬 | A kind of brassiere retainer plate |
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Application publication date: 20140402 |