CN103694809A - White bamboo charcoal purification anti-doodling interior wall paint - Google Patents

White bamboo charcoal purification anti-doodling interior wall paint Download PDF

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Publication number
CN103694809A
CN103694809A CN201310683173.3A CN201310683173A CN103694809A CN 103694809 A CN103694809 A CN 103694809A CN 201310683173 A CN201310683173 A CN 201310683173A CN 103694809 A CN103694809 A CN 103694809A
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CN
China
Prior art keywords
bamboo charcoal
emulsion
organosilicon
good
interior wall
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310683173.3A
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Chinese (zh)
Inventor
董善刚
刘全英
刘永屏
祝洒虎
王伯凤
张喆
李春波
殷晓燕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Qingdao Yiqun Paint Industry Group Co Ltd
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Qingdao Yiqun Paint Industry Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Publication date
Application filed by Qingdao Yiqun Paint Industry Group Co Ltd filed Critical Qingdao Yiqun Paint Industry Group Co Ltd
Priority to CN201310683173.3A priority Critical patent/CN103694809A/en
Publication of CN103694809A publication Critical patent/CN103694809A/en
Pending legal-status Critical Current

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Abstract

A white bamboo charcoal purification anti-doodling interior wall paint comprises the following components in percentage by weight: 15-25% of water, 0.1-0.2% of a wetting agent, 0.4-0.8% of a dispersant, 0.3-0.8% of a defoamer, 5-8% of ground calcium carbonate, 15-20% of Anatase white titanium pigment, 10-20% of white bamboo charcoal powder, 5-8% of light calcium carbonate, 3-5% of washed kaolin, 1-2% of aluminium silicate, 5-10% of an organosilicon charge emulsion, 15-20% of an emulsion, 0.1-0.2% of a levelling agent, 0.1-0.2% of an anticorrosive agent, and 0.6-0.9% of a thickening agent. The white bamboo charcoal purification anti-doodling interior wall paint has low VOC (volatile organic compound) content and super high scrub resistance and can purify the air, effectively adsorb the harmful gas in the air, and release negative ion; the paint has dense paint film and has a certain hydrophobic function.

Description

The anti-scribble inner wall surface of a kind of white bamboo charcoal purification paint
Technical field the present invention relates to a kind of interior wall coating; be particularly related to a kind of protection for exterior wall surface in buildings and decoration; there is low VOC content, high scrubbing resistance and can purify air, adsorb the anti-scribble inner wall surface paint of obnoxious flavour, anion releasing, belong to chemistry painting industry technical field.
Background technology is in China, and interior wall coating has experienced the development of more than 30 year, has replaced gradually the decorative material for wall surface such as wallpaper, wall cloth, and interior wall coating is more and more applied in the middle of indoor decorating.Therefore also more and more to the functional requirement of interior wall coating, interior wall coating not merely plays the effect of protection, decorating wall, and green, environmental protection, multi-functional interior wall coating are more and more subject to liking of people.But interior wall coating can give out objectionable impurities in production and use procedure, and HUMAN HEALTH is caused to adverse influence, and wherein formaldehyde and benzene class are healthy maximum killers, easily cause respiratory tract system disease and leukemia of children etc.This has just caused people to comprising the concern of decorating and renovating material and the worry of its safety performance of coating.Along with enhancing and the concern to HUMAN HEALTH of people's environmental consciousness, desired interior wall coating is not only to rest in the function of protection body of wall, decorated wall surface, the prior feature of environmental protection, health and practicality.Therefore utilize the powerful adsorption function research and development of white bamboo charcoal a kind ofly can either adsorb obnoxious flavour, purify air; Have again certain hydrophobic function, can form fine and close filming, the practicality interior wall coating that ink that body of wall is infected with, spot etc. can easierly be cleaned out is very significant.
Summary of the invention the object of this invention is to provide the anti-scribble inner wall surface of a kind of white bamboo charcoal purification paint, this product not only has the scrub performance of low VOC content, superelevation, and can purify air, the airborne obnoxious flavour of active adsorption, anion releasing, and paint film fine and close, there is certain hydrophobic function.
Concrete component and the part by weight of the anti-scribble inner wall surface of a kind of white bamboo charcoal purification of the present invention paint are: water: 15-25%; Wetting agent: 0.1-0.2%; Dispersion agent: 0.4-0.8%; Defoamer: 0.3-0.8%; Water-ground limestone: 5-8%; Anatase thpe white powder: 15-20%; White bamboo charcoal powder: 10-20%; Fine particle calcium carbonate: 5-8%; Water-washed kaoline: 3-5%; Pure aluminium silicate: 1-2%; Organosilicon lotus property emulsion: 5-10%; Emulsion: 15-20%; Flow agent: 0.1-0.2%; Sanitas: 0.1-0.2%; Thickening material: 0.6-0.9%.
In general, interior wall coating all likely produces objectionable impurities in production and use procedure, causes the pollution to environment, affects the mankind's health, especially the total organic volatile content in interior wall coating, usually said VOC content directly works the mischief to environment, HUMAN HEALTH.The present invention has utilized the powerful adsorption function of white bamboo charcoal, and effectively the objectionable impurities such as free formaldehyde, benzene class in adsorption-decomposition function air, has the function purifying air, and can anion releasing.Meanwhile, the use of organosilicon lotus property emulsion, makes product have extremely low surface tension, has good hydrophobic effect, can form fine and close paint film, easierly wipes out ink, the spot that metope is infected with.
The organic siloxane modified polymerized emulsion that the emulsion that the present invention uses is novel special construction, in drying and forming-film wherein between Si-OH and and base material on-there is multiple cross-linked chemical reaction in OH-, can make coating have extremely low surface tension, can keep splendid hydrophobic effect, stain resistant performance is good, and there are good Compositional type, stable performance with other emulsions.
The synthetic latex RS-998A that the present invention uses is a kind of polymkeric substance being produced by vinylbenzene and acrylic ester copolymer; have that particle is tiny, the feature of modest viscosity; there is high color stuffing supporting capacity; there is good consistency with numerous color stuffings; not containing protective colloid; low VOC content, and make product there is good scrub resistance, water tolerance and alkali resistance.
The anatase thpe white powder that the titanium dioxide that the present invention uses is made for chlorination process, is characterized in having good light scattering ability, and whiteness is good, tinting strength is high, strong covering power, there is higher chemical stability and good weather resistance simultaneously, nonpoisonous and tasteless, non-stimulated to human body.Its performance and opacifying power, weathering resistance and the chalking resistance close relation of filming.
The bamboo charcoal that the present invention uses is a kind of natural bamboo charcoal factor, is to fire and form for a long time under 800 degree high temperature with 5 years above mao bamboons of growth, and outward appearance is glittering silver color.The bamboo charcoal of approximately 1 gram of size as little finger, its surface-area can reach 700 square metres, in air, the obnoxious flavour such as free formaldehyde, benzene class, amine is adsorbed and decomposes, reach the object purifying air, and the atomic structure due to bamboo charcoal self, make it there is excellent oxidation-resistance, can releasing far infrared and negative ion, be a kind of multi-functional filler of rare pure natural.
The dispersion agent that the present invention uses is low-molecular-weight polypropylene amine acid salt dispersion agent, can significantly improve concentration and the stability thereof of color stuffing dispersion pulp, by this dispersion agent, can surround a layer charge at color stuffing particle surface, make repulsion mutually between particle, thereby reach the effect of stable slurry.
The flow agent that the present invention uses is modified polyurethane rheology modifier, it not only has outstanding shear viscosity thickening effectiveness, and its thickened systems has excellent mobility and levelling property, can make paint film in dry process, form film forming thickness and the paint film fullness ratio of uniformity, make paint film present the silks and satins texture that silk is sliding.
Thickening material used in the present invention mainly contains newton-type nonionic polyoxyalkylene class rheology modifier and alkali swelling class thickening material.
Production technique of the present invention is mixed the component of above-mentioned weight ratio at normal temperatures, under stirring at low speed, add part water, wetting agent, dispersion agent, early stage defoamer, coarse whiting, titanium dioxide, white bamboo charcoal powder, fine particle calcium carbonate, water-washed kaoline, pure aluminium silicate, after high speed dispersion, be ground to after slurry fineness≤30um, stirring at low speed adds organosilicon lotus property emulsion, emulsion, later stage defoamer, flow agent, sanitas, thickening material, excess water, meet the requirements of after viscosity, stirring at low speed 10min again, then through checking, filter, weigh packing.
Below embodiment, be one embodiment of the present of invention.
Composition (weight percent) and the production technique of the anti-scribble inner wall surface of a kind of white bamboo charcoal purification of the present invention paint are: the stirring at low speed stage adds 18 parts of deionized waters according to order, the wetting agent X405 of 0.1 part, 0.55 part of poly amic acid dipersant PR03, the defoamer NXZ of 0.15 part, 5 parts of fineness are 800 object water-ground limestones, the titanium dioxide PTA120 of 18 parts, 15 parts of white bamboo charcoal powder of fineness 400-600 object, 5 parts of fineness are 800 object fine particle calcium carbonates, 3 parts of water-washed kaolines 551, 2 parts of pure aluminium silicate AS881 enter the high-speed stirring stage after all adding, and after stirring, speed lapping, to fineness≤30um, then adds successively 10 parts of organosilicon lotus property emulsions under stirring at low speed, 18 parts of benzene emulsion 998A, the defoamer NXZ of 0.15 part, 0.2 part of flow agent, the sanitas MV of 0.15 part, the newton-type nonionic polyoxyalkylene class rheology modifier thickening material DSX2000 of 0.4 part and 0.3 part of alkali swelling thickening material TT935, the deionized water and stirring of 4 parts is even, then stirring at low speed 10min, then through check, filter, the packing of weighing.
Its indices of the anti-scribble inner wall surface of a kind of white bamboo charcoal purification paint of making according to the present invention all reaches GB/T9756-2009 about limits of harmful substances in the requirement of resin latex dope defined and GB18582 indoor decorating and refurnishing materials interior wall coating, there is ultralow VOC content, good scrub resistance, water tolerance and alkali resistance; And there is the effect purifying air, the obnoxious flavoures such as the formaldehyde effectively discharging in adsorption-decomposition function inner wall decoration finishing material, benzene class, protection people's health; And coating surface has extremely low surface tension, there is good hydrophobic effect, for the materials such as the oil stain of being infected with on body of wall, spot and ink wiped clean easily, effectively kept the neat and artistic of indoor environment, environmental protection is applicable to using at home very much.Be widely used in the multiple places such as house, hotel, school, hospital.Customer response is respond well.

Claims (5)

1. concrete component and the part by weight of the self-cleaning environmental protection exterior coating of a kind of organosilicon of the present invention are: water: 20-25%; Multifunctional assistant: 0.1-0.3%; Wetting agent: 0.05-0.1%; Dispersion agent: 0.1-0.3%; Defoamer: 0.1-0.3%; Organosilicon lotus property emulsion: 10-15%; Emulsion: 60-65%; Texanol:1-2%; Sanitas: 0.1-0.2%; Thickening material: 0.6-0.9%.
2. the self-cleaning environmental protection exterior coating of a kind of organosilicon according to claim 1, it is characterized in that said organosilicon lotus property emulsion, there is extremely low surface tension, there is good hydrophobic effect, can form fine and close paint film, easierly wipe out ink, the spot that metope is infected with.
3. the self-cleaning environmental protection exterior coating of a kind of organosilicon according to claim 1, it is characterized in that said emulsion is the organic siloxane modified polymerized emulsion of novel special construction, stain resistant performance is good, and has good Compositional type, stable performance with other emulsions.
4. the self-cleaning environmental protection exterior coating of a kind of organosilicon according to claim 1, is characterized in that said bamboo charcoal is a kind of natural bamboo charcoal factor, is to fire and form for a long time under 800 degree high temperature with 5 years above mao bamboons of growth, and outward appearance is glittering silver color.
5. the self-cleaning environmental protection exterior coating of a kind of organosilicon according to claim 1, it is characterized in that said anatase thpe white powder, be characterized in thering is good light scattering ability, whiteness is good, tinting strength is high, strong covering power, there is higher chemical stability and good weather resistance simultaneously, nonpoisonous and tasteless, non-stimulated to human body.
CN201310683173.3A 2013-12-14 2013-12-14 White bamboo charcoal purification anti-doodling interior wall paint Pending CN103694809A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201310683173.3A CN103694809A (en) 2013-12-14 2013-12-14 White bamboo charcoal purification anti-doodling interior wall paint

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201310683173.3A CN103694809A (en) 2013-12-14 2013-12-14 White bamboo charcoal purification anti-doodling interior wall paint

Publications (1)

Publication Number Publication Date
CN103694809A true CN103694809A (en) 2014-04-02

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104987783A (en) * 2015-07-29 2015-10-21 刘善江 Interior wall water paint for children's bedroom and preparation method for interior wall water paint
CN106675243A (en) * 2015-11-11 2017-05-17 江苏冠军涂料科技集团有限公司 Environment-friendly and healthy white bamboo charcoal functional coating for interior walls
CN108002744A (en) * 2016-10-28 2018-05-08 贵州省漆彩金州涂料有限公司 A kind of interior wall paint and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104987783A (en) * 2015-07-29 2015-10-21 刘善江 Interior wall water paint for children's bedroom and preparation method for interior wall water paint
WO2017016091A1 (en) * 2015-07-29 2017-02-02 河北晨阳工贸集团有限公司 Interior wall water paint for children's bedroom and preparation method therefor
CN106675243A (en) * 2015-11-11 2017-05-17 江苏冠军涂料科技集团有限公司 Environment-friendly and healthy white bamboo charcoal functional coating for interior walls
CN108002744A (en) * 2016-10-28 2018-05-08 贵州省漆彩金州涂料有限公司 A kind of interior wall paint and preparation method thereof

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Application publication date: 20140402