CN203126083U - Self-cleaning coating with photocatalysis and antistatic composite functions - Google Patents
Self-cleaning coating with photocatalysis and antistatic composite functions Download PDFInfo
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- CN203126083U CN203126083U CN 201320094031 CN201320094031U CN203126083U CN 203126083 U CN203126083 U CN 203126083U CN 201320094031 CN201320094031 CN 201320094031 CN 201320094031 U CN201320094031 U CN 201320094031U CN 203126083 U CN203126083 U CN 203126083U
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Abstract
The utility model relates to a self-cleaning coating with photocatalytic and antistatic composite functions. The self-cleaning coating comprises a closing layer (2), an antistatic layer (3) and a photocatalytic layer (4), wherein the closing layer (2) is coated on the surface of a base material (1), the antistatic layer (3) is compounded on the closing layer (2), and finally, the photocatalytic layer (4) is compounded on the antistatic layer (3). Specifically, the method that the photocatalytic material with visible light response and the antistatic material are combined in the way of being attached to the surface of the base material is used, so that the antifouling, dustproof and photocatalytic self-cleaning functions are achieved on the surfaces of external decorative materials of different buildings; the closing layer, the antistatic layer and the photocatalytic layer constitute the self-cleaning coating; and the closing layer is coated on the surface of the base material, the antistatic layer is compounded on the closing layer, and finally, the photocatalytic layer is compounded on the antistatic layer, and therefore, the self-cleaning coating is a novel self-cleaning coating with self-cleaning function in visible light and dustproof function, and mainly applied in building roofs, building curtain walls, wall decoration, glass surface, municipal traffic engineering construction and reform engineering projects.
Description
Technical field
The utility model relates to self-cleaning coat and the production method thereof of a kind of photocatalysis and antistatic complex function, refers to adopt cladding process to realize antifouling, dustproof, photocatalysis self-cleaning function on different building external decorative materials surface specifically.Product is mainly used in building roof, building curtain wall, wall decoration, glass surface and municipal traffic engineering construction and the improvement project.
Background technology
The used for building exterior wall self-cleaning coat normally by surperficial Superhydrophilic, makes pollutant come off naturally under rain-out, thereby realizes self-cleaning function.But in actual applications, owing to the super hydrophilicity of traditional self-cleaning coat material is realized under the solar light irradiation condition, so the super hydrophilicity of traditional self-cleaning coat material is had a greatly reduced quality under rainy weather.Gan Zao weather in addition, substrate surface is easy accumulate static charge under the natural environment effect, tiny dust in the easy absorbed air of these electrostatic charges, can not it be decomposed by light-catalyzed reaction, lose self-cleaning effect thereby the long-term accumulation of these tiny dust can allow coating lose the former hydrophilicity that has.These 2 deficiencies cause common self-cleaning coat to use the self-cleaning effect that does not reach theoretical design at exterior wall.
Raising along with the progressive quality of life of modern society, people pursue the life style of healthy fashion day by day, outside the building the demand of aspect self-cleaning coats such as portion's decoration, wall decoration, glass surface, public work construction grows with each passing day, and particularly the demand market of the outstanding self-cleaning coat of antifouling, anti-dust performance is huge.All there are defectives such as poor, the self-cleaning effect of workability is not remarkable in traditional self-cleaning coat material in the world at present.
Summary of the invention
The utility model purpose is at above-mentioned weak point, a kind of photocatalysis and antistatic complex function coating are proposed, it is characterized in that by making visible light-responded catalysis material and antistatic material adhere to way of combining at substrate surface, realized a kind of external wall field that is applied in, both possessed automatically cleaning under the visible light condition, the novel self-cleaning coat of dust reduction capability had been arranged again.
A kind of self-cleaning coat with photocatalysis and antistatic complex function of the utility model is to be achieved through the following technical solutions:
The self-cleaning coat of a kind of photocatalysis and antistatic complex function comprises confining bed, antistatic backing, photocatalysis layer; Confining bed is coated in substrate surface, compounded antistatic layer on confining bed, composite photocatalyst layer on antistatic backing at last.
Described base material is selected a kind of in cement plate, glass, aluminium sheet, marble, artificial stone, the pottery for use.
Described confining bed adopts one or more in waterproofing agent of organosilicon, epoxy resin latex, the polypropylene emulsion, is configured to agent suspension at the bottom of the sealing that mass percentage concentration is 0.5%-5%, with 0.01-0.2 L/m
2Amount forms in the substrate surface spraying.
Described antistatic backing adopts nano SnO
2, nanometer SiO
2, nanometer Ag
2O, film forming agent, coalescents are dispersed in by a certain percentage and make antistatic stoste in the alcohols solvent, and after high-speed stirred was even, evenly spraying was made for 2-4 time on the confining bed surface.
Described photocatalysis layer adopts commercially available nano titanium oxide solid powder or solvent, is configured to the suspension that mass percentage concentration is 0.1%-2%, with 0.01-0.1L/m
2Amount is in the spraying preparation of anti-static coating surface.
A kind of production method of the self-cleaning coat with photocatalysis and antistatic complex function is as follows:
1) substrate surface is washed or pickling processes, removes substrate surface dust, dirt, impurity, adopts nature oven dry 2-8h or forced air drying 1-4h again.Guarantee the substrate surface clean dried.
Described base material is selected at least a in cement plate, glass, aluminium sheet, marble, artificial stone, the pottery for use;
2) the configuration quality percentage concentration is agent suspension at the bottom of the sealing of 0.5%-5%, evenly sprays with the substrate surface of spray gun after clean dried, and quantity for spray is controlled at 0.01-0.2L/m
2, air dry 30 minutes-90 minutes or forced air drying were 10 minutes-60 minutes after spraying was finished, and formed confining bed;
One or more in waterproofing agent of organosilicon, epoxy resin latex, the polypropylene emulsion are adopted in agent at the bottom of the described sealing;
3) with solvent, nano SnO
2, SiO
2, Ag
2O, film forming agent, coalescents mix according to the following weight per distribution ratio, make antistatic material stoste after stirring.Wherein the raw material weight per distribution ratio is:
Film forming agent 1-10%
Coalescents 0-1.5%
Nano SnO
20-2%
Nanometer Ag
2O 0-1.5%
Nanometer SiO
20-5%
Solvent 35-55%
Deionized water 35-60%
Described film forming agent is selected one or more in fluorocarbon resin, silane resin, acrylic resin, butadiene resin, polyurethane film-forming agent, the cellulose nitrate film forming agent for use;
Described coalescents is selected one or more in low-molecular-weight wax class dispersant, ether alcohol class high polymer, poly-hexylene glycol, the alcohol ester 12 for use;
Described nano SnO
2Select for use solid content at the wire crystal transparency liquid of 10% particle diameter in the 5-10 nanometer;
Described nanometer Ag
2O selects the silver oxide colloidal solution of particle diameter about the 5-20 nanometer for use;
Described nanometer SiO
2Select for use particle diameter at the sheet SiO of 5-10 nanometer
2The colloidal sol body;
Described solvent is selected at least a in methyl alcohol, ethanol, propyl alcohol, ethylene glycol, the glycerine for use;
4) will configure antistatic material stoste and inject the chemosynthesis reaction still, rotating speed is controlled at 300-600 rev/min, and temperature is controlled at 60-80 ℃, stirs 5-10 hour, stirs;
5) will stir liquid after finishing under 20-40 ℃ of condition ageing 1-5 hour, naturally cool to room temperature, namely get antistatic material;
6) adopt above-mentioned antistatic material, utilize bore at the automatic air spray gun below 1.2, gun slot is apart from substrate surface 10-20cm, laterally, vertically evenly spray 2-4 time, examine the substrate surface that is sprayed after the spraying, guarantee not have obvious became uneven, no sag, no bubble, no decorative pattern, do not have and omit, spraying finishes to form antistatic backing;
7) treat can make filmogen generation condensation reaction by the mode of maintenance under low-temperature heat or the normal temperature after substrate surface forms anti-static coating, form hardened coating film, this hardening process was decided according to concrete construction environment temperature between 1-48 hour;
8) the configuration quality percentage concentration is the visible light photocatalyst suspension of 0.1%-2%, evenly sprays with the substrate surface of spray gun after being coated with anti-static coating, and quantity for spray is controlled at 0.01-0.1L/m
2, back air-dry 5 minutes-30 minutes or air dry 10 minutes-60 minutes finished in spraying, the self-cleaning coat of formation photocatalysis and antistatic complex function;
Described visible light photocatalyst adopts commercially available nano titanium oxide solid powder or solvent, preferably uses Japanese CON company's visible light photocatalyst or TOTO company visible light photocatalyst;
The beneficial effects of the utility model are:
1 uses the coating after this self-cleaning system construction can show good super hydrophilicity, even under the situation of unglazed photograph, as night, the cloudy day good super hydrophilicity is also arranged, overcoming single photocatalysis coating must have the weakness that just has self-cleaning function under the UV-irradiation condition.
The hydrophilicity of 2 coatings is very good, and the water contact angle test result is below 5 °.
3 coating surface resistance values are 10
6-10
8Ω .cm can play fine anti-static effect.
Nanometer wire crystal structure forms small nanometer fine hair shape concaveconvex structure at outer surface in 4 coatings, reaches to reduce dust and the van der Waals' force that is coated with interlayer, and it is clean to make that dust is easy to by the rainwater normal erosion.
5 coating material water white transparencies do not influence substrate surface color and decorative effect.
6 coating layer thicknesses are the 0.5-2 micron only, are convenient to control cost, simultaneously better large tracts of land popularization in market.
Description of drawings
The utility model is described in further detail below in conjunction with accompanying drawing:
Fig. 1 is the structural representation with self-cleaning coat of photocatalysis and antistatic complex function.
The specific embodiment
With reference to accompanying drawing 1, a kind of self-cleaning coat with photocatalysis and antistatic complex function comprises base material 1, confining bed 2, antistatic material 3, visible light-responded photocatalysis layer 4; Compound closure layer 2 on the coated base material 1 is compounded with antistatic backing 3 at confining bed 2, is compounded with visible light-responded photocatalysis layer 4 at antistatic backing 3.
Case study on implementation 1:
1) needs is carried out the cement plate surface that automatically cleaning handles and carry out pickling processes, remove cement plate surface dirt, dirt, impurity, adopt nature oven dry 2h again, guarantee the substrate surface clean dried.
2) the configuration quality percentage concentration is 0.5% waterproofing agent of organosilicon suspension, evenly sprays with the substrate surface of spray gun in clean dried, and quantity for spray is controlled at 0. 1L/m
2, air dry was 60 minutes after spraying was finished, and formed confining bed.
3) according to the nano tin dioxide 2kg(2% of weight percent proportioning with poly-hexylene glycol 0.1 kg (0.1%), 5nm of film forming agent fluorocarbon resin 5kg (5%), coalescents), the nano phase ag_2 o 0.5kg(0.5% of 20m), the nano silicon oxide 1kg(1% of 10nm), methyl alcohol 35kg(35%), deionized water 56.4kg(56.4%), to make antistatic material stoste after stirring standby.
4) will configure antistatic material stoste and inject the chemosynthesis reaction still, rotating speed is controlled at 300 rev/mins, and temperature is controlled at 80 ℃, stirs 5 hours, stirs;
5) will stir the ageing 4 hours under 40 ℃ of conditions of liquid after finishing, naturally cool to room temperature, namely get antistatic material;
6) adopt above-mentioned antistatic material, utilize the automatic air spray gun of bore 1, gun slot is apart from substrate surface 10cm, laterally, vertically evenly spray 2 times, examine the substrate surface that is sprayed after the spraying, guarantee not have obvious became uneven, no sag, no bubble, no decorative pattern, do not have and omit, spraying finishes to form antistatic backing.
7) treating that substrate surface forms was positioned under the normal temperature maintenance behind the anti-static coating 6 hours, made filmogen generation condensation reaction, formed hardened coating film.
8) the configuration quality percentage concentration is 0.1% visible light photocatalyst suspension, evenly sprays with the substrate surface of spray gun after being coated with anti-static coating, and quantity for spray is controlled at 0.1L/m
2, spraying was finished the back air-dry 30 minutes, the self-cleaning coat of formation photocatalysis and antistatic complex function.
Case study on implementation 2:
1) needs are carried out the glass surface that automatically cleaning handles and wash processing, remove glass surface dust, dirt, impurity,, adopt nature oven dry 8h again, guarantee the substrate surface clean dried.
2) the configuration quality percentage concentration is 1% waterproofing agent of organosilicon suspension, evenly sprays with the substrate surface of spray gun in clean dried, and quantity for spray is controlled at 0. 01L/m
2, air dry was 30 minutes after spraying was finished, and formed confining bed.
3) according to the nano tin dioxide 1kg(1% of weight percent proportioning with film forming agent butadiene resin 10kg (10%), 8nm), the nano phase ag_2 o 0.5kg(0.5% of 15nm), the nano silicon oxide 5kg(5% of 8nm), ethanol 45kg(45%), deionized water 38.5kg(38.5%), to make antistatic material stoste after stirring standby.
4) will configure antistatic material stoste and inject the chemosynthesis reaction still, rotating speed is controlled at 400 rev/mins, and temperature is controlled at 60 ℃, stirs 10 hours, stirs;
5) will stir the ageing 1 hour under 20 ℃ of conditions of liquid after finishing, naturally cool to room temperature, namely get antistatic material;
6) adopt above-mentioned antistatic material, utilize the automatic air spray gun of bore 0.5, gun slot is apart from substrate surface 20cm, laterally, vertically evenly spray 3 times, examine the substrate surface that is sprayed after the spraying, guarantee not have obvious became uneven, no sag, no bubble, no decorative pattern, do not have and omit, spraying finishes to form antistatic backing.
7) treating that substrate surface forms was positioned under the normal temperature maintenance behind the anti-static coating 24 hours, made filmogen generation condensation reaction, formed hardened coating film.
8) the configuration quality percentage concentration is 1% visible light photocatalyst suspension, evenly sprays with the substrate surface of spray gun after being coated with anti-static coating, and quantity for spray is controlled at 0.01L/m
2, air dry was 10 minutes after spraying was finished, and formed the self-cleaning coat of photocatalysis and antistatic complex function.
Case study on implementation 3:
1) needs is carried out the surface of aluminum plate that automatically cleaning handles and carry out pickling processes, remove surface of aluminum plate dust, dirt, impurity, adopt nature oven dry 4h again, guarantee the substrate surface clean dried.
2) the configuration quality percentage concentration is 2.5% epoxy resin suspension, evenly sprays with the substrate surface of spray gun in clean dried, and quantity for spray is controlled at 0. 2L/m
2, air dry was 90 minutes after spraying was finished, and formed confining bed.
3) according to the nano phase ag_2 o 1.5kg(1.5% of weight percent proportioning with film forming agent silane resin 8kg (8%), coalescents low-molecular-weight wax class dispersant 1.5 kg (1.5%), 5nm), the nano silicon oxide 3kg(3% of 5nm), ethylene glycol 40kg(40%), deionized water 46kg(46%), to make antistatic material stoste after stirring standby.
4) will configure antistatic material stoste and inject the chemosynthesis reaction still, rotating speed is controlled at 600 rev/mins, and temperature is controlled at 70 ℃, stirs 8 hours, stirs;
5) will stir the ageing 5 hours under 30 ℃ of conditions of liquid after finishing, naturally cool to room temperature, namely get antistatic material;
6) adopt above-mentioned antistatic material, utilize the automatic air spray gun of bore 1, gun slot is apart from substrate surface 15cm, laterally, vertically evenly spray 4 times, examine the substrate surface that is sprayed after the spraying, guarantee not have obvious became uneven, no sag, no bubble, no decorative pattern, do not have and omit, spraying finishes to form antistatic backing.
7) treating that substrate surface forms was positioned under the normal temperature maintenance behind the anti-static coating 1 hour, made filmogen generation condensation reaction, formed hardened coating film.
8) the configuration quality percentage concentration is 2% visible light photocatalyst suspension, evenly sprays with the substrate surface of spray gun after being coated with anti-static coating, and quantity for spray is controlled at 0.05L/m
2, air dry was 60 minutes after spraying was finished, and formed the self-cleaning coat of photocatalysis and antistatic complex function.
Case study on implementation 4:
1) needs is carried out the ceramic surface that automatically cleaning handles and wash processing, remove ceramic surface dust, dirt, impurity, adopt forced air drying 1h again, guarantee the substrate surface clean dried.
2) the configuration quality percentage concentration is 5% acrylic acid suspension, evenly sprays with the substrate surface of spray gun in clean dried, and quantity for spray is controlled at 0. 05L/m
2, forced air drying was 10 minutes after spraying was finished, and formed confining bed.
3) according to the weight percent proportioning with film forming agent acrylic resin 1kg (1%), become mould auxiliary agent ether alcohol class high polymer 1kg(1%), the nano tin dioxide 1kg(1% of 10nm), the nano silicon oxide 2kg(2% of 6nm), glycerine 35kg(35%), deionized water 60kg(60%), to make antistatic material stoste after stirring standby.
4) will configure antistatic material stoste and inject the chemosynthesis reaction still, rotating speed is controlled at 400 rev/mins, and temperature is controlled at 80 ℃, stirs 8 hours, stirs;
5) will stir the ageing 5 hours under 40 ℃ of conditions of liquid after finishing, naturally cool to room temperature, namely get antistatic material;
6) adopt above-mentioned antistatic material, utilize the automatic air spray gun of bore 1, gun slot is apart from substrate surface 10cm, laterally, vertically evenly spray 2 times, examine the substrate surface that is sprayed after the spraying, guarantee not have obvious became uneven, no sag, no bubble, no decorative pattern, do not have and omit, spraying finishes to form antistatic backing.
7) treating that substrate surface forms was positioned under the normal temperature maintenance behind the anti-static coating 48 hours, made filmogen generation condensation reaction, formed hardened coating film.
8) the configuration quality percentage concentration is 0.5% visible light photocatalyst suspension, evenly sprays with the substrate surface of spray gun after being coated with anti-static coating, and quantity for spray is controlled at 0.02L/m
2, spraying was finished the back air-dry 5 minutes, the self-cleaning coat of formation photocatalysis and antistatic complex function.
Case study on implementation 5:
1) needs is carried out the artificial stone surface that automatically cleaning handles and carry out pickling processes, remove artificial stone surface dirt, dirt, impurity, adopt forced air drying 2h again, guarantee the substrate surface clean dried.
2) the configuration quality percentage concentration is 1% waterproofing agent of organosilicon suspension, evenly sprays with the substrate surface of spray gun in clean dried, and quantity for spray is controlled at 0. 1L/m
2, forced air drying was 30 minutes after spraying was finished, and formed confining bed.
3) according to the weight percent proportioning with polyurethane film-forming agent 8kg (8%), become mould auxiliary agent alcohol ester 12 0.5kg(0.5%), the nano tin dioxide 1kg(1% of 6nm), the nano phase ag_2 o 1kg(1% of 10nm), propyl alcohol 55kg(55%), deionized water 35kg(35%) to make antistatic material stoste after stirring standby.
4) will configure antistatic material stoste and inject the chemosynthesis reaction still, rotating speed is controlled at 300 rev/mins, and temperature is controlled at 60 ℃, stirs 5 hours, stirs;
5) will stir the ageing 4 hours under 40 ℃ of conditions of liquid after finishing, naturally cool to room temperature, namely get antistatic material;
6) adopt above-mentioned antistatic material, utilize the automatic air spray gun of bore 1, gun slot is apart from substrate surface 20cm, laterally, vertically evenly spray 3 times, examine the substrate surface that is sprayed after the spraying, guarantee not have obvious became uneven, no sag, no bubble, no decorative pattern, do not have and omit, spraying finishes to form antistatic backing.
7) treating that substrate surface forms was positioned under the normal temperature maintenance behind the anti-static coating 12 hours, made filmogen generation condensation reaction, formed hardened coating film.
8) the configuration quality percentage concentration is 1% visible light photocatalyst suspension, evenly sprays with the substrate surface of spray gun after being coated with anti-static coating, and quantity for spray is controlled at 0.04L/m
2, spraying was finished the back air-dry 20 minutes, the self-cleaning coat of formation photocatalysis and antistatic complex function.
Case study on implementation 6:
1) needs is carried out the marble surface that automatically cleaning handles and wash processing, remove marble surface dust, dirt, impurity, adopt forced air drying 4h again, guarantee the substrate surface clean dried.
2) the configuration quality percentage concentration is 2% waterproofing agent of organosilicon suspension, evenly sprays with the substrate surface of spray gun in clean dried, and quantity for spray is controlled at 0. 02L/m
2, forced air drying was 60 minutes after spraying was finished, and formed confining bed.
3) according to the nano tin dioxide 1.5kg(1.5% of weight percent proportioning with poly-hexylene glycol 0.5 kg (0.5%), 9nm of cellulose nitrate film forming agent 5kg (5%), coalescents), the nano phase ag_2 o 1kg(1% of 7nm), the nano silicon oxide 3kg(3% of 7nm), methyl alcohol 40kg(40%), deionized water 49kg(49%), to make antistatic material stoste after stirring standby.
4) will configure antistatic material stoste and inject the chemosynthesis reaction still, rotating speed is controlled at 600 rev/mins, and temperature is controlled at 80 ℃, stirs 5 hours, stirs;
5) will stir the ageing 4 hours under 40 ℃ of conditions of liquid after finishing, naturally cool to room temperature, namely get antistatic material;
6) adopt above-mentioned antistatic material, utilize the automatic air spray gun of bore 1, gun slot is apart from substrate surface 15cm, laterally, vertically evenly spray 4 times, examine the substrate surface that is sprayed after the spraying, guarantee not have obvious became uneven, no sag, no bubble, no decorative pattern, do not have and omit, spraying finishes to form antistatic backing.
7) treating that substrate surface forms was positioned under the normal temperature maintenance behind the anti-static coating 24 hours, made filmogen generation condensation reaction, formed hardened coating film.
8) the configuration quality percentage concentration is 1% visible light photocatalyst suspension, evenly sprays with the substrate surface of spray gun after being coated with anti-static coating, and quantity for spray is controlled at 0.1L/m
2, air dry was 40 minutes after spraying was finished, and formed the self-cleaning coat of photocatalysis and antistatic complex function.
The self-cleaning coat of a kind of photocatalysis of the utility model and antistatic complex function and production method thereof have taken full advantage of the complex effect of the catalysis material of antistatic material and visible light effect, adopt the method for spraying to form the Nano self-cleaning coating at substrate surface, realize a kind of both possessed good antifouling, dust reduction capability, had the novel green material of photo-catalysis function again.The utility model is conducive to the application in large-scale terrestrial reference engineering, can each landmark all be designed to permanent, characteristics of personality is arranged, have environmental protection, an artistic work attractive in appearance.
The self-cleaning coat of a kind of photocatalysis of the utility model and antistatic complex function is primarily aimed at the reality in traditional self-cleaning material field poor performance, develops a kind of coating product of novel self-cleaning function.Product has overcome defectives such as poor, the self-cleaning effect of traditional self-cleaning material workability is not remarkable, is applied to external wall and can keeps combination with decorative surfaces to have good self-cleaning performance.
The product that the self-cleaning coat of a kind of photocatalysis of the utility model and antistatic complex function and production method thereof are made reaches following technical indicator through detecting: photocatalysis coating adhesive force 0-1 level; Photocatalysis performance: self-cleaning function is characterized by minimum water contact angle<10 °; Stain resistance can be reflectance factor rate of descent<10%;
Claims (2)
1. the self-cleaning coat of a photocatalysis and antistatic complex function is characterized in that: comprise confining bed (2), antistatic backing (3), photocatalysis layer (4); Confining bed (2) is coated in base material (1) surface, goes up compounded antistatic layer (3) at confining bed (2), goes up composite photocatalyst layer (4) at antistatic backing (3) at last.
2. the self-cleaning coat of photocatalysis according to claim 1 and antistatic complex function is characterized in that: described base material (1) is selected a kind of in cement plate, glass, aluminium sheet, marble, artificial stone, the pottery for use.
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CN 201320094031 CN203126083U (en) | 2013-03-01 | 2013-03-01 | Self-cleaning coating with photocatalysis and antistatic composite functions |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103112231A (en) * | 2013-03-01 | 2013-05-22 | 南京倍立达新材料系统工程股份有限公司 | Self-cleaning layer with photocatalysis and anti-static compounding functions and production method thereof |
CN107574768A (en) * | 2017-09-07 | 2018-01-12 | 广州市泰宇科技发展有限公司 | A kind of self-clean type sound barrier |
CN108941419A (en) * | 2018-08-04 | 2018-12-07 | 芜湖金光汽车配件有限责任公司 | A kind of braking automobile adjustment press forging |
CN109042353A (en) * | 2018-08-03 | 2018-12-21 | 安徽省强家庄生态农业有限公司 | A kind of dry clear formula excrement storage and handling facility of one-storey house formula pig house |
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2013
- 2013-03-01 CN CN 201320094031 patent/CN203126083U/en not_active Expired - Fee Related
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN103112231A (en) * | 2013-03-01 | 2013-05-22 | 南京倍立达新材料系统工程股份有限公司 | Self-cleaning layer with photocatalysis and anti-static compounding functions and production method thereof |
CN103112231B (en) * | 2013-03-01 | 2015-09-02 | 南京倍立达新材料系统工程股份有限公司 | A kind of self-cleaning coat and production method thereof with photocatalysis and antistatic complex function |
CN107574768A (en) * | 2017-09-07 | 2018-01-12 | 广州市泰宇科技发展有限公司 | A kind of self-clean type sound barrier |
CN109042353A (en) * | 2018-08-03 | 2018-12-21 | 安徽省强家庄生态农业有限公司 | A kind of dry clear formula excrement storage and handling facility of one-storey house formula pig house |
CN108941419A (en) * | 2018-08-04 | 2018-12-07 | 芜湖金光汽车配件有限责任公司 | A kind of braking automobile adjustment press forging |
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