CN103694771A - Paint remover and preparation method thereof - Google Patents
Paint remover and preparation method thereof Download PDFInfo
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- CN103694771A CN103694771A CN201310657014.6A CN201310657014A CN103694771A CN 103694771 A CN103694771 A CN 103694771A CN 201310657014 A CN201310657014 A CN 201310657014A CN 103694771 A CN103694771 A CN 103694771A
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Abstract
The invention relates to a paint remover and a preparation method thereof. The paint remover comprises the following materials in parts by weight: 60-80 parts of N-2 methyl pyrrolidone, 15-30 parts of alkyl phosphonic acid 2- ethyl hexyl ester monoethanolamine salt, 1-5 parts of ethylene glycol butyl ether, 5-10 parts of N, N-dimethyl acrylamide, 5-10 parts of cyclohexanone, 5-10 parts of isopropanol, 3-5 parts of diethanol amine, 2-4 parts of deionized water and 1-2 parts of OP-101. The paint remover disclosed by the invention solves problems that the paint remover in the prior air is only suitable for removing epoxy primer and a polyurethane finish coating and high in volatility, and can be used for conveniently removing various paint layers, so that a plurality of steps for re-coating are reduced; moreover, the paint remover is low in volatility, low in toxicity, high in stability and free from corrosivity.
Description
Technical field
The present invention relates to a kind of paint remover and preparation method thereof, belong to field of polymer material preparing technology.
Background technology
It is good that now widely used multiple priming paint and finish paint have good enamelled coating over-all properties, such as preferably acid and alkali-resistance and solvent nature, strong etc. with basal body binding force.But in life-time service process, because paint film can be subject to the impact of multiple inherence and externalities, there is aging, be full of cracks, peeling and the phenomenon such as come off, cause paint film to lose protection decoration function.Need with this understanding former coating removal to carry out application again.Conventional stripping method has mechanical or manual removal method, paint remover to remove method, combustion method, strong oxidizer removal method etc.These methods not only waste time and energy, and easily matrix surface are caused to physical abuse, particularly more difficult to the parts of some geometrical shape more complicated.
It is CN102888141A that State Intellectual Property Office discloses a publication number in 2013.1.23, name is called the patent of invention of " paint remover of removing epoxy primer and polyurethane finish coating ", this patent relates to a kind of paint remover of removing epoxy primer and polyurethane finish coating, aim to provide a kind of low toxicity, potential of hydrogen is little, depainting efficiency is high, corrosion-free to metal substrate, paint remover that particularly can fast eliminating aircraft engine Profile For Compressor Stator straightening vanes lacquering.The present invention is achieved by following technical proposals: by weight percentage, said composition mainly contains, 45% ~ 55% N-Methyl pyrrolidone and 15% ~ 25% pimelinketone are as main solvent, 8% ~ 12% methyl alcohol or ethanol are as solubility promoter, in 8% ~ 12% ethanolamines, any does promotor, and 8% ~ 12% ethylene glycol ethyl ether is as tensio-active agent and a small amount of thickening material and resistance volatilizer.The present invention is rapid to the inefficacy ability of enamelled coating surface bonding power, sticking power, solvent resistance, and toxicity is low, to metal, plastic basis material non-corrosiveness, produces free from environmental pollutionly, has controlled preferably the corrosive nature to matrix.Can promptly remove stainless steel subassembly surface epoxy primer and polyurethane paint coating.
Removing epoxy primer in above-mentioned patent and the paint remover of polyurethane finish coating exist and are only applicable to remove epoxy primer and polyurethane finish coating, and the high problem of volatility.
Summary of the invention
The present invention is intended to solve paint remover existence of the prior art and is only applicable to remove epoxy primer and polyurethane finish coating, and the high problem of volatility, and a kind of paint remover is provided, and makes its range of application wider, and volatility is low.
To achieve these goals, concrete technical scheme of the present invention is as follows:
A paint remover, is characterized in that: comprise following according to the raw material of parts by weight meter:
N-2 methyl-2-pyrrolidone 60-80 part
Alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salt 15-30 part
Ethylene glycol monobutyl ether 1-5 part
N,N-DMAA 5-10 part
Pimelinketone 5-10 part
Virahol 5-10 part
Diethanolamine 3-5 part
Deionized water 2-4 part
OP-10 1-2 part.
A paint remover, is characterized in that: comprise following according to the raw material of parts by weight meter:
N-2 methyl-2-pyrrolidone 75-78 part
Alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salt 20-26 part
Ethylene glycol monobutyl ether 2-4 part
N,N-DMAA 6-8 part
Pimelinketone 6-9 part
Virahol 6-9 part
Diethanolamine 4-5 part
Deionized water 3-3.5 part
OP-10 1-1.5 part.
A preparation method for paint remover, is characterized in that: comprise following processing step:
A, prior to adding successively N-2 methyl-2-pyrrolidone, pimelinketone, Virahol, diethanolamine in container, stirring and dissolving is even;
B, in the container in steps A, add alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salt, ethylene glycol monobutyl ether and N,N-DMAA again, stirring and dissolving is even;
C, in another container, add successively deionized water and OP-10, stirring and dissolving is even;
D, under agitation condition, the solution preparing in step C is slowly joined to the container in steps A;
E, fully stir and misciblely can discharging obtain paint remover of the present invention after evenly.
The useful technique effect that the present invention brings:
Paint remover of the present invention has solved paint remover existence of the prior art and has been only applicable to remove epoxy primer and polyurethane finish coating, and the problem that volatility is high, can make easily multiple enamelled coating come off, a plurality of steps of again covering with paint, lacquer, colour wash, etc. have been reduced, and volatility is low, toxicity is low, and stability is high, non-corrosiveness.
Embodiment
embodiment 1
A paint remover, comprises following according to the raw material of parts by weight meter:
60 parts of N-2 methyl-2-pyrrolidones
15 parts of alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salts
1 part of ethylene glycol monobutyl ether
5 parts of N,N-DMAAs
5 parts of pimelinketone
5 parts of Virahols
3 parts of diethanolamine
2 parts of deionized waters
1 part of OP-10.
embodiment 2
A paint remover, comprises following according to the raw material of parts by weight meter:
80 parts of N-2 methyl-2-pyrrolidones
30 parts of alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salts
5 parts of ethylene glycol monobutyl ethers
10 parts of N,N-DMAAs
10 parts of pimelinketone
10 parts of Virahols
5 parts of diethanolamine
4 parts of deionized waters
2 parts of OP-10.
embodiment 3
A paint remover, comprises following according to the raw material of parts by weight meter:
70 parts of N-2 methyl-2-pyrrolidones
22.5 parts of alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salts
3 parts of ethylene glycol monobutyl ethers
7.5 parts of N,N-DMAAs
7.5 parts of pimelinketone
7.5 parts of Virahols
4 parts of diethanolamine
3 parts of deionized waters
1.5 parts of OP-10.
embodiment 4
A paint remover, comprises following according to the raw material of parts by weight meter:
75 parts of N-2 methyl-2-pyrrolidones
20 parts of alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salts
2 parts of ethylene glycol monobutyl ethers
6 parts of N,N-DMAAs
6 parts of pimelinketone
6 parts of Virahols
4 parts of diethanolamine
3 parts of deionized waters
1 part of OP-10.
embodiment 5
A paint remover, comprises following according to the raw material of parts by weight meter:
78 parts of N-2 methyl-2-pyrrolidones
26 parts of alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salts
4 parts of ethylene glycol monobutyl ethers
8 parts of N,N-DMAAs
9 parts of pimelinketone
9 parts of Virahols
5 parts of diethanolamine
3.5 parts of deionized waters
1.5 parts of OP-10.
embodiment 6
A paint remover, comprises following according to the raw material of parts by weight meter:
76.5 parts of N-2 methyl-2-pyrrolidones
23 parts of alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salts
3 parts of ethylene glycol monobutyl ethers
7 parts of N,N-DMAAs
7.5 parts of pimelinketone
7.5 parts of Virahols
4.5 parts of diethanolamine
3.25 parts of deionized waters
1.25 parts of OP-10.
embodiment 7
A preparation method for paint remover, comprises following processing step:
A, prior to adding successively N-2 methyl-2-pyrrolidone, pimelinketone, Virahol, diethanolamine in container, stirring and dissolving is even;
B, in the container in steps A, add alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salt, ethylene glycol monobutyl ether and N,N-DMAA again, stirring and dissolving is even;
C, in another container, add successively deionized water and OP-10, stirring and dissolving is even;
D, under agitation condition, the solution preparing in step C is slowly joined to the container in steps A;
E, fully stir and misciblely can discharging obtain paint remover of the present invention after evenly.
Claims (3)
1. a paint remover, is characterized in that: comprise following according to the raw material of parts by weight meter:
N-2 methyl-2-pyrrolidone 60-80 part
Alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salt 15-30 part
Ethylene glycol monobutyl ether 1-5 part
N,N-DMAA 5-10 part
Pimelinketone 5-10 part
Virahol 5-10 part
Diethanolamine 3-5 part
Deionized water 2-4 part
OP-10 1-2 part.
2. a kind of paint remover according to claim 1, is characterized in that: comprise following according to the raw material of parts by weight meter:
N-2 methyl-2-pyrrolidone 75-78 part
Alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salt 20-26 part
Ethylene glycol monobutyl ether 2-4 part
N,N-DMAA 6-8 part
Pimelinketone 6-9 part
Virahol 6-9 part
Diethanolamine 4-5 part
Deionized water 3-3.5 part
OP-10 1-1.5 part.
3. the preparation method of a kind of paint remover according to claim 1 and 2, is characterized in that: comprise following processing step:
A, prior to adding successively N-2 methyl-2-pyrrolidone, pimelinketone, Virahol, diethanolamine in container, stirring and dissolving is even;
B, in the container in steps A, add alkylphosphonic acid carboxylic acid 2-ethylhexyl monoethanolamine salt, ethylene glycol monobutyl ether and N,N-DMAA again, stirring and dissolving is even;
C, in another container, add successively deionized water and OP-10, stirring and dissolving is even;
D, under agitation condition, the solution preparing in step C is slowly joined to the container in steps A;
E, fully stir and misciblely can discharging obtain paint remover of the present invention after evenly.
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CN201310657014.6A CN103694771B (en) | 2013-12-09 | 2013-12-09 | Paint remover and preparation method thereof |
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CN201310657014.6A CN103694771B (en) | 2013-12-09 | 2013-12-09 | Paint remover and preparation method thereof |
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CN103694771A true CN103694771A (en) | 2014-04-02 |
CN103694771B CN103694771B (en) | 2015-07-15 |
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CN201310657014.6A Expired - Fee Related CN103694771B (en) | 2013-12-09 | 2013-12-09 | Paint remover and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106118213A (en) * | 2016-09-23 | 2016-11-16 | 重庆理工大学 | A kind of water-based plastic paint stripper and its preparation method and application |
CN106752282A (en) * | 2017-01-17 | 2017-05-31 | 中冶建筑研究总院有限公司 | A kind of method of fast eliminating Coil Coating Products paint film |
CN109694606A (en) * | 2017-10-20 | 2019-04-30 | 中蓝晨光化工研究设计院有限公司 | A kind of environmental protection paint remover and preparation method thereof |
Citations (3)
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US5049300A (en) * | 1990-10-01 | 1991-09-17 | Creativity Technologies Group, Inc. | Method of activating acidified NMP to provide an effective paint remover composition |
CN100999627A (en) * | 2007-01-12 | 2007-07-18 | 大连三达奥克化学有限公司 | Water-base depainting agent |
CN102888141A (en) * | 2012-09-24 | 2013-01-23 | 中国人民解放军第五七一九工厂 | Paint remover for removing epoxy primer and polyurethane finish coating |
-
2013
- 2013-12-09 CN CN201310657014.6A patent/CN103694771B/en not_active Expired - Fee Related
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5049300A (en) * | 1990-10-01 | 1991-09-17 | Creativity Technologies Group, Inc. | Method of activating acidified NMP to provide an effective paint remover composition |
CN100999627A (en) * | 2007-01-12 | 2007-07-18 | 大连三达奥克化学有限公司 | Water-base depainting agent |
CN102888141A (en) * | 2012-09-24 | 2013-01-23 | 中国人民解放军第五七一九工厂 | Paint remover for removing epoxy primer and polyurethane finish coating |
Non-Patent Citations (1)
Title |
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黄志超、许栋强: "《精细化工应用配方3000例》", 31 March 1990, 广东科技出版社 * |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106118213A (en) * | 2016-09-23 | 2016-11-16 | 重庆理工大学 | A kind of water-based plastic paint stripper and its preparation method and application |
CN106752282A (en) * | 2017-01-17 | 2017-05-31 | 中冶建筑研究总院有限公司 | A kind of method of fast eliminating Coil Coating Products paint film |
CN106752282B (en) * | 2017-01-17 | 2020-08-11 | 中冶建筑研究总院有限公司 | Method for quickly removing paint film of color-coated sheet |
CN109694606A (en) * | 2017-10-20 | 2019-04-30 | 中蓝晨光化工研究设计院有限公司 | A kind of environmental protection paint remover and preparation method thereof |
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CN103694771B (en) | 2015-07-15 |
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