CN103692722A - Preparation method for BOPET high-imitation metal wiredrawing VCM film - Google Patents
Preparation method for BOPET high-imitation metal wiredrawing VCM film Download PDFInfo
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Abstract
The invention discloses a preparation method for a BOPET (biaxially oriented polyester) high-imitation metal wiredrawing VCM film. The method includes: conducting surface wiredrawing treatment on one side of a transparent BOPET film; coating one surface without surface wiredrawing treatment by a polyurethane UV curable paint, carrying out UV photo-curing and heat curing, and performing natural cooling to obtain a surface hardened coating; coating the surface subjected to surface wiredrawing treatment with a model SC-400 pre-aluminizing prime coat to obtain a fastness enhanced coating; conducting vacuum aluminizing processing on the fastness enhanced coating to obtain a vacuum aluminized layer; and coating the aluminized surface of the vacuum aluminized layer with a model SC-500 topcoat, thus obtaining an antioxidant protective coating. Single-layer BOPET is adopted as a film main material, thus reducing the dosage of a raw material film, saving the production cost, prolonging the product life and improving the tolerance to various adverse conditions. The film obtained by the method has the visual effects of an imitated metal wire drawing board, thus realizing the purpose of high simulation of different material wiredrawing metal boards.
Description
Technical field
The present invention relates to the preparation method of the high imitative metal wire-drawing VCM film of a kind of BOPET.
Background technology
Non-ferrous metal, nonmetal plate and non-ferrous metal and composite non-metal sheet material, owing to economizing on resources, being easy to processing, with low cost, the application in industry and life is more and more general.Particularly the application of thin plate is more extensive, and the furniture of automobile, refrigerator, washing machine, elevator wallboard and top grade and room division board etc. all will be used.Be all after the shape that sheet material is processed into requirement, print again or spray to obtain appearance attractive in appearance the earliest, but the appearance effect that this nonplanar printing and spray process obtain is limited, technology is complicated and not environmental protection of technical process.In recent years in household electrical appliance industry, rise gradually at surface of steel plate composite plastic film and substitute the sheet metal with special decoration appearance characteristics, can not only play protective action, also there is decoration function, there is good appearance effect, regrettably plastic foil, when producing multicolour and pattern, has also hidden the gloss of metal, has lost the peculiar texture of metal material.
At present, for the stainless steel wire drawing plate of family expenses panel, fine aluminium bushing, titanizing wire drawing steel plate etc., its material price is higher, has therefore restricted it and has applied.
Patent 201110365769.X discloses a kind of imitative aluminium wiredrawing composition membrane, comprises PET rete, adhesive phase, PVC rete and wire drawing aluminium foil layer.Another kind of technical scheme replaces PVC rete with PET rete.This imitative aluminium wiredrawing composition membrane, has metallic luster and the wire drawing texture of wire drawing aluminum, simultaneously because wire drawing paper tinsel layer is between PET rete and PVC rete, therefore, can starvation, anti-oxidation, realize permanent keep wire drawing aluminium foil metallic luster and wire-drawing effect; This imitative aluminium wiredrawing composition membrane can further be compound in flat cold-rolled sheet, aluminium sheet, galvanized sheet, building material surface, plays a part to decorate protection and attractive in appearance, and technique is simple, easy and simple to handle, cost is low.
Patent 201110357527.6 discloses a kind of artificial stainless steel composite membrane with wire-drawing effect, comprises metal aluminum foil layer, PET rete, PVC rete, printing color layer and the protective layer that process through wire drawing on surface.This artificial stainless steel composite membrane has very strong stainless steel wire drawing gloss, and artificial stainless steel degree is high, and metallic luster is lasting, is applied on household electrical appliances, cooking apparatus and makes it more attractive in appearance, improves product specification.
But above-mentioned two patents all adopt trilaminate material complex technique, technology is complicated, still very large to the energy and raw-material consumption demand, limited in the progress of the aspect such as energy-conservation, to economize on resources; And owing to having used aluminium foil, because aluminium foil belongs to non-feature of environmental protection composite, so product does not possess environment-friendly function.
Number of patent application 201020640194.9 discloses a kind of stainless steel wire drawing plate.This is a kind of PCM precoating plate, and base material adopts corrosion resistant plate, carries out wire drawing, surface roller coating finishing oil with wire-drawing equipment.Pencil hardness is greater than HB, and cupping performance can be rushed dark 8mm, and combination property reaches conventional precoating product requirement comprehensively.But; this patent is large to corrosion resistant plate consumption demand; not only cost of material is high; compare simultaneously and on plastic sheeting, carry out wire drawing processing; on corrosion resistant plate, carry out wire drawing intractability larger, protect more difficult realization; therefore cost is very high, its production technology neither energy-conservation, economize on resources, also not environmental protection.
Summary of the invention
Technical problem to be solved by this invention be to have overcome existing imitative metal wire-drawing composite film material consumption large, not energy-conservation, economize on resources, the also defect such as not environmental protection and production cost height, provides a kind of BOPET preparation method of high imitative metal wire-drawing VCM film.The present invention adopts individual layer BOPET as main film body material; compare existing by imitative metal wire-drawing film production technology two-layer or that plural layers are compound; the present invention has reduced the consumption of raw material film in a large number; thereby production and the manufacturing cost of film have been saved significantly; also extended the performance of life of product and all kinds of bad conditions of tolerance simultaneously; also there is excellent anti-ultraviolet function, fully protective film and metal level avoid ultraviolet long-time irradiation and cause aging, oxidation.The film that preparation method of the present invention obtains has best imitative metal wire-drawing plate visual effect, has really realized the high emulation object to unlike material wire drawing metallic plate.
The invention provides the preparation method of the high imitative metal wire-drawing VCM film of a kind of BOPET, it comprises the steps: that (1) carry out surperficial wire drawing processing to the one side of transparent BOPET film; (2) on a surface of not processing through surperficial wire drawing, be coated with polyurethane ultraviolet curing coating in described transparent BOPET film, carry out ultraviolet photo-curing and heat cure, the naturally cooling hard surface coating that obtains; (3) on the surface of processing through surperficial wire drawing in described transparent BOPET film, to be coated with model that Cong Haoshi international trade (Shanghai) Co., Ltd. buys be SC-400 aluminize before primary coat, must strengthen fastness coating; (4) in this enhancing fastness coating, carry out vacuum aluminum-coated processing, obtain vacuum aluminium coated layer; (5) face that the model of buying in the face of the aluminizing coating Cong Haoshi of this vacuum aluminium coated layer international trade (Shanghai) Co., Ltd. is SC-500 is coated with, and obtains anti-oxidation protection coating.
In the present invention, described " BOPET film " is art technology term, refers to biaxially oriented polyester film.
In the present invention, described " VCM " is art technology term, refers to colorful laminated film-covered colored steel, and the covering material of this colorful laminated film-covered colored steel is called " VCM film ".
In the present invention, the thickness of described transparent BOPET film is preferably 23～188 microns.The light transmittance of described transparent BOPET film is preferably that 80～92%, 45 ° of glossiness are preferably 80～160Gs, and mist degree is preferably 0.8～3.0%.
In the present invention, described surperficial wire drawing is processed and is adopted the surperficial Wire Drawing technique of this area routine to carry out, and the preparation method of the wire drawing decorative film of recording in the patent application that preferably publication number is CN101746203A carries out described surperficial wire drawing and processes.In the present invention, for quoting of this patent application, should be considered as quoting in full it.By described wire drawing, processing the wire drawing lines obtaining can obtain by this area conventional method, as changes the wire drawing roller of different lines and regulate the speed of wire drawing roller to control.
In the present invention, the thickness of described hard surface coating is preferably 0.8～1.2 micron.Described hard surface coating is polyurethane ultraviolet curing coating (polyurethane UV coating) layer, the dumb light UV coating that the light UV coating that the model that the preferred Shanghai of wherein said polyurethane ultraviolet curing coating Ying Jun packaging material Co., Ltd produces is UV6763-50 or model are UV6763M-BASE.
In the present invention, the uviol lamp that described ultraviolet photo-curing preferably adopts four groups of power to be all 250 milli Jiao carries out.The temperature of described heat cure is preferably 65～100 ℃.
In the present invention, the thickness of described enhancing fastness coating is preferably 0.8～1.2 micron.The fastness that transparent BOPET film surface is directly aluminized is generally 1～2.5N/15mm, and after being coated with this enhancing fastness coating, the attachment fastness of this vacuum aluminium coated layer and BOPET can be brought up to 6～10N/mm.
In the present invention, the thickness of described vacuum aluminium coated layer can be selected arbitrarily at the light transmittance that makes to have the BOPET film of this vacuum aluminium coated layer between 0.1%～50%, preferably to have the light transmittance of the BOPET film of this vacuum aluminium coated layer be 5～7% or 26～28% two kinds.When light transmittance is 5～7%, can realize the effect of high imitative wire drawing aluminium sheet, when light transmittance is 26～28%, can realize the effect of high imitative titanizing steel plate, high artificial stainless steel bushing.Described vacuum aluminum-coated processing can adopt the various vacuum aluminum-coated processing technology of this area routine to carry out, and preferably adopting publication number is that the aluminum plating method for plastic film of recording in the patent application of CN101503790A carries out.In the present invention, for quoting of this patent application, should be considered as quoting in full it.
In the present invention, the thickness of described anti-oxidation protection coating is preferably 0.8～1.2 micron.
The raw material that the present invention is used or reagent except special instruction, equal commercially available obtaining.
Meeting on the basis of this area general knowledge, above-mentioned each optimum condition, can be combined, and obtains the preferred embodiments of the invention.
Positive progressive effect of the present invention is:
1, the present invention adopts individual layer BOPET as main film body material, compares existingly by imitative metal wire-drawing film production technology two-layer or that plural layers are compound, has reduced the consumption of raw material film, production and the manufacturing cost of greatly having saved film.
2, in the coating of BOPET film wire-drawing surface, strengthen fastness coating, strengthened the attachment fastness of vacuum aluminium coated layer and BOPET film, extended the performance of life of product and all kinds of bad conditions of tolerance.More than the pencil hardness of hard surface coating reaches 2H, not only rub resistance, weather-resistant property are strong, also have excellent anti-ultraviolet function simultaneously, and protective film and metal level are avoided ultraviolet long-time irradiation and aging, the oxidation that cause fully.Accurately the vacuum aluminium coated layer of processing, has obtained best imitative metal wire-drawing plate visual effect, has really realized the high emulation object to unlike material wire drawing metallic plate.The protective finish of face of aluminizing has been realized the anti-oxidant, corrosion-resistant of aluminium coated, effectively guarantees and extended the life-span of integral product.
3, the high imitative metal wire-drawing VCM film of BOPET that preparation method of the present invention obtains, by adhesive and sheet metal (as corrosion resistant plate, galvanized sheet etc.), real core plank, plastic plate, glass etc., undertaken compound, the effect both with high imitative metal wire-drawing plate, lightweight, attractive in appearance, durable in, having again cheaper manufacturing cost, is existing by low cost two-layer or the imitative metal wire-drawing film production technology that plural layers the are compound production method that upgrades.
4, the high imitative metal wire-drawing VCM film of BOPET that preparation method of the present invention obtains, the sodium hydroxide solution 72 hours that drips respectively 10% hydrochloric acid and 10% at film surface is without significant change, hard surface coating face pencil hardness >=2H, can rush dark 8mm with the compound rear detection cupping performance of sheet metal, all reach or surpass the technical requirement of conventional precoating color steel product, therefore, there is high industrial value and application prospect.
Accompanying drawing explanation
The structural representation of the VCM film that Fig. 1 obtains for the preparation method by the high imitative metal wire-drawing VCM film of BOPET of the present invention.
The specific embodiment
Mode below by embodiment further illustrates the present invention, but does not therefore limit the present invention among described scope of embodiments.The experimental technique of unreceipted actual conditions in the following example, according to conventional method and condition, or selects according to catalogue.
Embodiment 1
One, the high imitative metal wire-drawing VCM membrane structure of BOPET:
As shown in Figure 1, the present embodiment is produced BOPET is high, and imitative metal wire-drawing VCM film comprises successively: a hard surface coating 12, an one side carried out transparent BOPET film 13, that surperficial wire drawing processes and strengthen vacuum aluminium coated layer 15 and the anti-oxidation protection coating 16 that fastness coating 14, a light transmittance are 26～28%; The one side that BOPET processes through surperficial wire drawing is connected with this enhancing fastness coating 14.
Wherein, the thickness of BOPET film before carrying out wire drawing processing is 188 microns, and 90.2%, 45 ° of glossiness of former film light transmittance is 138Gs, mist degree 1.96%, other physical performance indexs meet State Standard of the People's Republic of China GB/T16958-2008[packing biaxially oriented polyester film].
The light UV coating that the model that surface cured coating selects buying to produce from Shanghai Ying Jun packaging material Co., Ltd is UV6763-50, is stirred rear standby.
Strengthen aluminium coated fastness coating and select the product of buying Zi Haoshi international trade (Shanghai) Co., Ltd., name of product: primary coat before aluminizing, model: SC-400, is stirred rear standby.
Anti-oxidation protection coating is selected the product of buying Zi Haoshi international trade (Shanghai) Co., Ltd., name of product: face is coated with, and model: SC-500, is stirred rear standby.
Two, the preparation method of the high imitative metal wire-drawing VCM film of BOPET:
(1) transparent BOPET film is carried out to surperficial wire drawing processing, this processing entrusts Guangdong Yong Sheng packaging material Co., Ltd to carry out, and processing line number is No. 1 line.
(2) coating of surperficial cured coating layer: adopt Zhongshan City Songde Coating Machine Co., Ltd, model: the coating apparatus of ST1650-21 type, utilize the applicator roll of roller H2, it is the coating (coating complete after the thickness of coating be 1 ± 0.2 micron) of 2 ± 0.2 grams/m that the non-wire-drawing surface of transparent BOPET film is coated with to dry measure, adopt dry the two drying proposal combining of heat cure and UV lamp, 65～100 ℃ of physical dryness Temperature Settings, UV is dry adopts four groups of power to be all the burnt UV lamp of 250 milli, naturally cooling standby after coating.
(3) strengthen the coating of fastness coating: adopt Zhongshan City Songde Coating Machine Co., Ltd, model: the coating apparatus of ST1650-21 type, utilize the applicator roll of roller H2, it is the coating (coating complete after 1 ± 0.2 micron of the thickness of coating) of 4 grams/m that the wire-drawing surface of transparent BOPET film is coated with to wet amount, naturally cooling standby after coating.
(4) processing of vacuum aluminium coated layer: vacuum aluminum-plating equipment adopts the photoelectricity technology corporation, Ltd. purchased from German Lai Bao, and PRO-M2100 type packaging material web coating system, vacuumizes and reach high vacuum levels (10
-4～10
-5between mba), evaporation boat is preheated to 65%～80%(equipment and sets) between, aluminium wire transfer rate is controlled at 160～250mm/min, during device start winding speed>=3.5m/s, the equipment baffle plate of opening starts evaporation, and aluminium steam-condensation does not stop to cooling main hub surface on the enhancing fastness coating surface of the transparent BOPET film of reeling; The measured aluminum layer thickness of on-line measurement instrument of the on-line determination metallized film aluminum layer thickness measure of the change of providing for oneself according to aluminum-spraying machine in process is adjusted winding speed (speed is controlled between 5.0～10.0m/s).By this processing technology, finally can obtain light transmittance is 26～28% the BOPET film with vacuum aluminium coated layer, has the corrosion resistant plate surface wire-drawing effect of high emulation.After the transparent BOPET aluminium coated film of entire volume is produced, shutdowns, cooling evaporation boat, vacuum pumping, open a position and unload film, detection aluminum layer thickness, product evaporation finishes, and concrete operations condition can be referring to CN101503790A.
(5) coating of anti-oxidation protection coating: adopt Zhongshan City Songde Coating Machine Co., Ltd; model: the coating apparatus of ST1650-21 type; utilize the applicator roll of roller H2; it is the coating (coating complete after 1 ± 0.2 micron of the thickness of coating) of 4 grams/m that vacuum aluminium coated layer is coated with to wet amount, naturally coolingly after coating can make the high metal wire-drawing VCM film of imitating of BOPET.
Three, the performance test of the high imitative metal wire-drawing VCM film of BOPET:
The high imitative metal wire-drawing VCM film of the BOPET of the present embodiment is cut to test piece, on its hard surface coating, drips respectively after the sodium hydroxide solution 72h of 10% hydrochloric acid and 10%, rinse well, check dropping liquid film surface place, and with the not test piece surface contrast of dropping liquid.Result shows: surface is without significant change, and product is qualified;
By GB/T6739-1996 < < hardness of film pencil determination method > > (eqv JIS K5400-90-8.4), test and record its hard surface coating and reach pencil hardness 2H, without obviously scratch or breakage, product is qualified;
By the high imitative metal wire-drawing VCM film of BOPET and the thick galvanized steel plain sheet of 0.8mm pass through EAA PUR compound after, by GB4156-84 < < cupping test of metal method > >, test, record cupping performance and can rush dark 8.3mm, product is qualified;
Above emphasis detects the technical requirement that index all meets or exceeds conventional precoating color steel product.
Embodiment 2
One, the high imitative metal wire-drawing VCM membrane structure of BOPET:
As shown in Figure 1, the present embodiment is produced BOPET is high, and imitative metal wire-drawing VCM film comprises successively: a hard surface coating 12, an one side carried out transparent BOPET film 13, that surperficial wire drawing processes and strengthen vacuum aluminium coated layer 15 and the anti-oxidation protection coating 16 that fastness coating 14, a light transmittance are 5～7%; The one side that BOPET processes through surperficial wire drawing is connected with this enhancing fastness coating 14.
Wherein, the thickness of BOPET film before carrying out wire drawing processing is 23 microns, and 91%, 45 ° of glossiness of former film light transmittance is 139Gs, mist degree 1.92%, other physical performance indexs meet State Standard of the People's Republic of China GB/T16958-2008[packing biaxially oriented polyester film].
The dumb light UV coating that the model that surface cured coating selects buying to produce from Shanghai Ying Jun packaging material Co., Ltd is UV6763M-BASE, is stirred rear standby.
Strengthen aluminium coated fastness coating and select the product of buying Zi Haoshi international trade (Shanghai) Co., Ltd., name of product: primary coat before aluminizing, model: SC-400, is stirred rear standby.
Anti-oxidation protection coating is selected the product of buying Zi Haoshi international trade (Shanghai) Co., Ltd., name of product: face is coated with, and model: SC-500, is stirred rear standby.
Two, the preparation method of the high imitative metal wire-drawing VCM film of BOPET:
(1) transparent BOPET film is carried out to surperficial wire drawing processing, concrete operations are with embodiment 1.
(2) coating of surperficial cured coating layer: concrete operations are with embodiment 1.
(3) strengthen the coating of fastness coating: concrete operations are with embodiment 1.
(4) processing of vacuum aluminium coated layer: vacuum aluminum-plating equipment adopts the photoelectricity technology corporation, Ltd. purchased from German Lai Bao, and PRO-M2100 type packaging material web coating system, vacuumizes and reach high vacuum levels (10
-4～10
-5between mba), evaporation boat is preheated to 65%～80%(equipment and sets) between, aluminium wire transfer rate is controlled at 250～350mm/min, during device start winding speed>=3.5m/s, the equipment baffle plate of opening starts evaporation, and aluminium steam-condensation does not stop to cooling main hub surface on the enhancing fastness coating surface of the transparent BOPET film of reeling; The measured aluminum layer thickness of on-line measurement instrument of the on-line determination metallized film aluminum layer thickness measure of the change of providing for oneself according to aluminum-spraying machine in process is adjusted winding speed (speed is controlled at 5.0～8.5m/s).By this processing technology, finally can obtain light transmittance is 5～7% the BOPET film with vacuum aluminium coated layer, has the surface of aluminum plate wire-drawing effect of high emulation.After the transparent BOPET aluminium coated film of entire volume is produced, shutdowns, cooling evaporation boat, vacuum pumping, open a position and unload film, detection aluminum layer thickness, product evaporation finishes, and concrete operations condition can be referring to CN101503790A.
(5) coating of anti-oxidation protection coating: concrete operations are with embodiment 1.
Three, the performance test of the high imitative metal wire-drawing VCM film of BOPET:
The high imitative metal wire-drawing VCM film of the BOPET of the present embodiment is cut to test piece, on its hard surface coating, drips respectively after the sodium hydroxide solution 72h of 10% hydrochloric acid and 10%, rinse well, check dropping liquid film surface place, and with the not test piece surface contrast of dropping liquid.Result shows: surface is without significant change, and product is qualified;
By GB/T6739-1996 < < hardness of film pencil determination method > > (eqv JIS K5400-90-8.4), test and record its hard surface coating and reach pencil hardness 2H, without obviously scratch or breakage, product is qualified;
By the high imitative metal wire-drawing VCM film of BOPET and the thick galvanized steel plain sheet of 0.8mm pass through EAA PUR compound after, by GB 4156-84 < < cupping test of metal method > >, test, record cupping performance and can rush dark 8.5mm, product is qualified;
Above emphasis detects the technical requirement that index all meets or exceeds conventional precoating color steel product.
Although more than described the specific embodiment of the present invention, it will be understood by those of skill in the art that these only illustrate, do not deviating under the prerequisite of principle of the present invention and essence, can make various changes or modifications to these embodiments.Therefore, protection scope of the present invention is limited by appended claims.
Claims (9)
1. a preparation method for the high imitative metal wire-drawing VCM film of BOPET, it comprises the steps: that (1) carry out surperficial wire drawing processing to the one side of transparent BOPET film; (2) on a surface of not processing through surperficial wire drawing, be coated with polyurethane ultraviolet curing coating in described transparent BOPET film, carry out ultraviolet photo-curing and heat cure, the naturally cooling hard surface coating that obtains; (3) primary coat before being coated with model on the surface of processing through surperficial wire drawing being aluminizing of SC-400 in described transparent BOPET film, must strengthen fastness coating; (4) in this enhancing fastness coating, carry out vacuum aluminum-coated processing, obtain vacuum aluminium coated layer; (5) face of aluminizing at this vacuum aluminium coated layer is coated with the face painting that model is SC-500, obtains anti-oxidation protection coating.
2. preparation method as claimed in claim 1, is characterized in that: the thickness of described transparent BOPET film is 23～188 microns.
3. preparation method as claimed in claim 1 or 2, is characterized in that: the light transmittance of described transparent BOPET film is that 80～92%, 45 ° of glossiness are 80～160Gs, and mist degree is 0.8～3.0%.
4. preparation method as claimed in claim 1, is characterized in that: the thickness of described hard surface coating is 0.8～1.2 micron.
5. the preparation method as described in claim 1 or 4, is characterized in that: described polyurethane ultraviolet curing coating is that model is the light UV coating of UV6763-50 or the dumb light UV coating that model is UV6763M-BASE.
6. preparation method as claimed in claim 1, is characterized in that: the uviol lamp that described ultraviolet photo-curing adopts four groups of power to be all 250 milli Jiao carries out; And/or the temperature of described heat cure is 65～100 ℃.
7. preparation method as claimed in claim 1, is characterized in that: the thickness of described enhancing fastness coating is 0.8～1.2 micron.
8. preparation method as claimed in claim 1, is characterized in that: the thickness of described vacuum aluminium coated layer, so that the light transmittance of the BOPET film of the vacuum aluminium coated layer described in having is 0.1～50.0%, is preferably 5～7% or 26～28%.
9. preparation method as claimed in claim 1, is characterized in that: the thickness of described anti-oxidation protection coating is 0.8～1.2 micron.
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|---|---|---|---|
| CN201210375529.2A CN103692722B (en) | 2012-09-27 | 2012-09-27 | A kind of preparation method of BOPET high metal wiredrawing VCM film |
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|---|---|---|---|
| CN201210375529.2A CN103692722B (en) | 2012-09-27 | 2012-09-27 | A kind of preparation method of BOPET high metal wiredrawing VCM film |
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| CN103692722B CN103692722B (en) | 2016-07-13 |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106111496A (en) * | 2016-08-16 | 2016-11-16 | 常州华威新材料有限公司 | A kind of 3D sense of touch artificial stainless steel drawing film and preparation method thereof |
| CN107399177A (en) * | 2016-05-19 | 2017-11-28 | 嘉兴艾森压烫科技有限公司 | One kind reversion wire drawing blocking film and preparation method thereof |
| CN109836602A (en) * | 2019-01-21 | 2019-06-04 | 浙江浙东建设有限公司 | Plate anti-pollution film and preparation method thereof is built in a kind of room |
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| CN2907504Y (en) * | 2006-05-15 | 2007-06-06 | 毛昱峰 | Shell coated with film of saucepan using slow fire |
| CN201456892U (en) * | 2009-08-19 | 2010-05-12 | 苏州禾盛新型材料股份有限公司 | PET real wiredrawing complex steel plate |
| CN102642439A (en) * | 2011-12-22 | 2012-08-22 | 东莞市国鼎光电膜材科技有限公司 | Manufacture process of imitation stainless steel metal drawbench film |
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| JP2005015819A (en) * | 2003-06-24 | 2005-01-20 | Chuo Motor Wheel Co Ltd | Surface treatment method for molded part having base material surface subjected to plating treatment |
| JP2005296841A (en) * | 2004-04-13 | 2005-10-27 | Fukuda Corporation:Kk | Decoration method of resin base material or metal base material |
| CN2907504Y (en) * | 2006-05-15 | 2007-06-06 | 毛昱峰 | Shell coated with film of saucepan using slow fire |
| CN201456892U (en) * | 2009-08-19 | 2010-05-12 | 苏州禾盛新型材料股份有限公司 | PET real wiredrawing complex steel plate |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107399177A (en) * | 2016-05-19 | 2017-11-28 | 嘉兴艾森压烫科技有限公司 | One kind reversion wire drawing blocking film and preparation method thereof |
| CN106111496A (en) * | 2016-08-16 | 2016-11-16 | 常州华威新材料有限公司 | A kind of 3D sense of touch artificial stainless steel drawing film and preparation method thereof |
| CN109836602A (en) * | 2019-01-21 | 2019-06-04 | 浙江浙东建设有限公司 | Plate anti-pollution film and preparation method thereof is built in a kind of room |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103692722B (en) | 2016-07-13 |
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