CN103689855B - A kind of deodorization and sterilization durable leather shoe - Google Patents
A kind of deodorization and sterilization durable leather shoe Download PDFInfo
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- CN103689855B CN103689855B CN201310737418.6A CN201310737418A CN103689855B CN 103689855 B CN103689855 B CN 103689855B CN 201310737418 A CN201310737418 A CN 201310737418A CN 103689855 B CN103689855 B CN 103689855B
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Abstract
The invention discloses a kind of deodorization and sterilization durable leather shoe, these leather shoes are made up of vamp and sole, and sole was made up of the large end and shoe-pad, and described vamp material is natural leather; Described insole material is that hypo is beautiful, and the ball area of shoe-pad and heel area are respectively embedded with the shrinkage pool of 4-6 uniform pore diameter, built-in Chinese medicine block in shrinkage pool; Described large bottom material is high-strength, high-anti-friction rubber expanded material; Be glued at described vamp and the large end or use suturing with thread management.Leather shoe structure of the present invention is simple, good permeability, and hygroscopic desiccation and deodorization and sterilization Be very effective are comfortable and easy to wear, economical and practical, with low cost, durable in use.
Description
Technical field
The present invention relates to a kind of leather shoes, be specifically related to a kind of deodorization and sterilization durable leather shoe.
Background technology
Leather shoes take natural leather as vamp, with leather or rubber, plastics, PU foaming, PVC etc. for sole, shaping through processes such as seam stitch the sole to the upper, gluing or injection mouldings.Because pin is the person position that above sweat gland is more flourishing, wherein the most easily perspire in ball area and heel area, and sweat fermentation produces foul smell, and serious words can develop into beriberi, not only affect surrounding environment, and self also very itches unbearably.For this reason, manufacture a kind of ventilative, moisture absorption, sterilization, deodorizing and have the leather shoes of good sanitation performance, be the object pursued in the industry always.But on market there is complex structure, cost is high, deodorization and sterilization effect is unsatisfactory deficiency in existing deodorization and sterilization leather shoes mostly, simultaneously, existing leather shoe sole also there is stretching and tearing strength low, the defect such as wear no resistance, and has a strong impact on the service life of leather shoes.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, provide that a kind of good permeability, hygroscopic desiccation and deodorization and sterilization are effective, structure is simple, economical and practical, comfortable and easy to wear, long-lived deodorization and sterilization durable leather shoe.
For achieving the above object, the technical solution used in the present invention is as follows:
A kind of deodorization and sterilization durable leather shoe of the present invention, be made up of vamp and sole, sole was made up of the large end and shoe-pad, it is characterized in that, described vamp material is natural leather; Described insole material is that hypo is beautiful, and the ball area of shoe-pad and heel area are respectively embedded with the shrinkage pool of 4-6 uniform pore diameter, built-in Chinese medicine block in hole; Described large bottom material is high-strength, high-anti-friction rubber expanded material; Be glued at described vamp and the large end or use suturing with thread management.
Wherein, described natural leather can be pigskin, ox-hide, sheepskin, horse skin or donkey hide.
Wherein, the preparation method of described Chinese medicine block is as follows:
A, take the raw material of following weight portion: zeolite 10-15, attapulgite 5-10, medical stone 4-8, Nano silica sol 15-20, activated alumina 2-4, sodium carboxymethyl starch 1-3, coconut husk charcoal 3-5, aloe powder 2-3, jade powder 1-2, kuh-seng 2-3, luffa vine 1.5-2.5, rhizome of cyrtomium 1-2, rhizoma atractylodis 2-3, balsamine 3-4, golden cypress 0.5-1.5, camphortree leaf 1-2, Chinese gall 2-3, Chinese bulbul 2-3, wolf's milk 1-2, lemon peel 3-4, bunge pricklyash leaf 2-3;
B, get zeolite, attapulgite, medical stone mix, being placed in concentration is that the hydrochloric acid solution of 15-20% soaks 0.5-1h, and take out and be washed with distilled water to neutrality, dry, 720-750 DEG C of calcining 1-2h, is cooled to room temperature, pulverizes, cross 100-150 mesh sieve, stand-by;
C, get kuh-seng, luffa vine, rhizome of cyrtomium, rhizoma atractylodis, balsamine, golden cypress, camphortree leaf, Chinese gall, the Chinese bulbul, wolf's milk, lemon peel, bunge pricklyash leaf mix, add 4-8 times amount water boiling and extraction 1-2h, filter, filter residue adds 3-6 times of water gaging again, decoct and extract 0.5-1h, filter, merging filtrate, be concentrated into the thick paste that relative density is 1.35-1.40, stand-by;
D, the powder that above-mentioned obtained thick paste and step b are obtained to be stirred, stand-by; E, get Nano silica sol and activated alumina, sodium carboxymethyl starch, coconut husk charcoal, aloe powder, jade powder stir, then the mixture that above-mentioned steps c is obtained is added, 1000-1500rpm high-speed stirred 20-30min, briquetting, every block weight is 3-6g, dries.
Wherein, the solid content of described Nano silica sol is 40-45%.
Wherein, the preparation method of described high-strength, high-anti-friction rubber expanded material is as follows:
A, get the raw material of following weight portion: butadiene rubber 50-60, EVA 20-30, SEBS 10-15, Celogen Az 3-5, cumyl peroxide 2-4, sodium acid carbonate 4-8, blanc fixe 8-12, zinc oxide 2-3, stearic acid 1-2, calcined loess 10-15, nano-silicon nitride 5-10, high abrasion furnace carbon black N330 15-20, zinc stearate 1-2, calcium stearate 1-2, White Mineral Oil 20-30, isopropyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanate esters 1-3, accelerant N A-22 1-2, accelerant CZ 0.5-1.5, antioxidant NBC 2-3, antioxidant MB 1-2,
B, butadiene rubber is added in twin-roll plastic mixing mill, roller temperature is mixing 5-10min at 90-100 DEG C, add EVA again, SEBS, White Mineral Oil, nano-silicon nitride, high wear-resistant carbon black, blanc fixe and calcined loess, mixing 4-6min, then cumyl peroxide is added successively, Celogen Az, sodium acid carbonate, zinc oxide, stearic acid, zinc stearate, calcium stearate, isopropyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanate esters, accelerant N A-22, accelerant CZ, antioxidant NBC, antioxidant MB, discharging after mixing 8-12min, moulded from foam is carried out shaping after parking 12-24h, press temperature is 160-180 DEG C, press time is 10-15min, pressing pressure is 8-12MPa.
Beneficial effect of the present invention:
1, leather shoes shoe-pad ball area of the present invention and heel area are embedded with Chinese medicine block, and this Chinese medicine block has significant hygroscopic desiccation, deodorization and sterilization effect, effectively can prevent and treat the generation of beriberi, and without any side effects to human body, use safety;
2, leather shoe outsole of the present invention adopts the butadiene rubber of excellent in abrasion resistance to be major ingredient, and utilize SEBS, EVA, blanc fixe, nano-silicon nitride, calcined loess etc. to carry out modification to butadiene rubber, SEBS significantly can improve the processing fluidity of butadiene rubber; EVA can make the mechanical property of expanded material improve, and blanc fixe, nano-silicon nitride, calcined loess etc. add the tearing strength that can make material and hardness rises; Obtained expanded material flexibility is out good, and intensity is high, and resilience is good, has excellent wear-resisting, high-low temperature resistant, endurance, the performance such as ageing-resistant, durable in use, substantially increases the service life of leather shoes;
3, leather shoe structure of the present invention is simple, and good permeability is comfortable and easy to wear, economical and practical, with low cost, has a extensive future.
Accompanying drawing explanation
Fig. 1 is the shape figure of leather shoes of the present invention.
Fig. 2 is the Shoe-pad structure figure of leather shoes of the present invention.
In figure:
1, vamp; 2, the large end; 3, shoe-pad; 4, ball area;
5, heel area; 6, shrinkage pool; 7, Chinese medicine block.
Detailed description of the invention
Embodiment 1: the preparation of Chinese medicine block:
(1) raw material of following weight (kg) is taken: zeolite 10, attapulgite 5, medical stone 4, Nano silica sol 15, activated alumina 24, sodium carboxymethyl starch 1, coconut husk charcoal 3, aloe powder 2, jade powder 1, kuh-seng 2, luffa vine 1.5, rhizome of cyrtomium 1, rhizoma atractylodis 2, balsamine 3, golden cypress 0.5, camphortree leaf 1, Chinese gall 2, the Chinese bulbul 2, wolf's milk 1, lemon peel 3, bunge pricklyash leaf 2;
(2) get zeolite, attapulgite, medical stone mix, be placed in concentration be 15% hydrochloric acid solution soak 1h, take out and be washed with distilled water to neutrality, dry, 720 DEG C of calcining 2h, are cooled to room temperature, pulverize, cross 100 mesh sieves, stand-by;
(3) get kuh-seng, luffa vine, rhizome of cyrtomium, rhizoma atractylodis, balsamine, golden cypress, camphortree leaf, Chinese gall, the Chinese bulbul, wolf's milk, lemon peel, bunge pricklyash leaf mix, add 4 times amount water boiling and extraction 1h, filter, filter residue adds 3 times of water gagings again, decoct and extract 0.5h, filter, merging filtrate, be concentrated into the thick paste that relative density is 1.35, stand-by;
(4) powder that above-mentioned obtained thick paste and step (2) obtain is stirred, stand-by;
(5) get Nano silica sol and activated alumina, sodium carboxymethyl starch, coconut husk charcoal, aloe powder, jade powder stir, then add the mixture that above-mentioned steps (4) is obtained, 1000rpm high-speed stirred 30min, briquetting, every block weight is 3g, dries.
The solid content of above-mentioned Nano silica sol is 40%.
Embodiment 2: the preparation of Chinese medicine block
(1) raw material of following weight (kg) is taken: zeolite 12, attapulgite 8, medical stone 6, Nano silica sol 18, activated alumina 3, sodium carboxymethyl starch 2, coconut husk charcoal 4, aloe powder 2.5, jade powder 1.5, kuh-seng 2.5, luffa vine 2, rhizome of cyrtomium 1.5, rhizoma atractylodis 2.5, balsamine 3.5, golden cypress 1, camphortree leaf 1.5, Chinese gall 2.5, the Chinese bulbul 2.5, wolf's milk 1.5, lemon peel 3.5, bunge pricklyash leaf 2.5;
(2) b gets zeolite, attapulgite, medical stone mix, be placed in concentration be 18% hydrochloric acid solution soak 0.5h, take out and be washed with distilled water to neutrality, dry, 740 DEG C of calcining 1h, are cooled to room temperature, pulverize, cross 120 mesh sieves, stand-by;
(3) get kuh-seng, luffa vine, rhizome of cyrtomium, rhizoma atractylodis, balsamine, golden cypress, camphortree leaf, Chinese gall, the Chinese bulbul, wolf's milk, lemon peel, bunge pricklyash leaf mix, add 6 times amount water boiling and extraction 1.5h, filter, filter residue adds 4 times of water gagings again, decoct and extract 0.5h, filter, merging filtrate, be concentrated into the thick paste that relative density is 1.38, stand-by;
(4) powder that above-mentioned obtained thick paste and step (2) obtain is stirred, stand-by;
(5) get Nano silica sol and activated alumina, sodium carboxymethyl starch, coconut husk charcoal, aloe powder, jade powder stir, then add the mixture that above-mentioned steps (4) is obtained, 1200rpm high-speed stirred 25min, briquetting, every block weight is 5g, dries.
The solid content of above-mentioned Nano silica sol is 42%.
Embodiment 3: the preparation of Chinese medicine block
(1) raw material of following weight (kg) is taken: zeolite 15, attapulgite 10, medical stone 8, Nano silica sol 20, activated alumina 4, sodium carboxymethyl starch 3, coconut husk charcoal 5, aloe powder 3, jade powder 2, kuh-seng 3, luffa vine 2.5, rhizome of cyrtomium 2, rhizoma atractylodis 3, balsamine 4, golden cypress 1.5, camphortree leaf 2, Chinese gall 3, the Chinese bulbul 3, wolf's milk 2, lemon peel 4, bunge pricklyash leaf 3;
(2) get zeolite, attapulgite, medical stone mix, be placed in concentration be 20% hydrochloric acid solution soak 0.5h, take out and be washed with distilled water to neutrality, dry, 750 DEG C of calcining 1h, are cooled to room temperature, pulverize, cross 150 mesh sieves, stand-by;
(3) get kuh-seng, luffa vine, rhizome of cyrtomium, rhizoma atractylodis, balsamine, golden cypress, camphortree leaf, Chinese gall, the Chinese bulbul, wolf's milk, lemon peel, bunge pricklyash leaf mix, add 8 times amount water boiling and extraction 2h, filter, filter residue adds 6 times of water gagings again, decoct and extract 1h, filter, merging filtrate, be concentrated into the thick paste that relative density is 1.40, stand-by;
(3) powder that above-mentioned obtained thick paste and step (2) obtain is stirred, stand-by;
(4) get Nano silica sol and activated alumina, sodium carboxymethyl starch, coconut husk charcoal, aloe powder, jade powder stir, then add the mixture that above-mentioned steps (4) is obtained, 1500rpm high-speed stirred 20min, briquetting, every block weight is 6g, dries.
The solid content of above-mentioned Nano silica sol is 45%.
In embodiment 1-3, zeolite, attapulgite and medical stone mix, after pickling, calcination processing, greatly can improve absorption property, mix with the thick paste of the Chinese herbal medicine decocting liquid such as kuh-seng, luffa vine, rhizome of cyrtomium, rhizoma atractylodis, balsamine again, have bactericidal effect, last Nano silica sol, activated alumina, sodium carboxymethyl starch, coconut husk charcoal, aloe powder, the composite modified said mixture of jade powder, can significantly strengthen hygroscopic desiccation, sterilizing and deodorizing function; Obtained Chinese medicine block hygroscopic desiccation performance is good, can remove stink fast, kill harmful bacteria and fungi, suppress the breeding of harmful bacteria and fungi, and use safety, without any side effects to human body.
Embodiment 4: the leather shoe outsole preparation of high-strength, high-anti-friction rubber expanded material
(1) raw material of following weight (kg) is got: butadiene rubber 50, EVA 20, SEBS 10, Celogen Az 3, cumyl peroxide 2, sodium acid carbonate 4, blanc fixe 8, zinc oxide 2, stearic acid 1, calcined loess 10, nano-silicon nitride 5, high abrasion furnace carbon black N330 15, zinc stearate 1, calcium stearate 1, White Mineral Oil 20, isopropyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanate esters 1, accelerant N A-22 1, accelerant CZ 0.5, antioxidant NBC 2, antioxidant MB 1,
(2) butadiene rubber is added in twin-roll plastic mixing mill, roller temperature is mixing 10min at 90 DEG C, add EVA again, SEBS, White Mineral Oil, nano-silicon nitride, high wear-resistant carbon black, blanc fixe and calcined loess, mixing 6min, then cumyl peroxide is added successively, Celogen Az, sodium acid carbonate, zinc oxide, stearic acid, zinc stearate, calcium stearate, isopropyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanate esters, accelerant N A-22, accelerant CZ, antioxidant NBC, antioxidant MB, discharging after mixing 12min, moulded from foam is carried out shaping after parking 24h, press temperature is 160 DEG C, press time is 15min, pressing pressure is 8MPa.
Embodiment 5: the leather shoe outsole preparation of high-strength, high-anti-friction rubber expanded material
(1) raw material of following weight (kg) is got: butadiene rubber 55, EVA 25, SEBS 12, Celogen Az 4, cumyl peroxide 3, sodium acid carbonate 6, blanc fixe 10, zinc oxide 2.5, stearic acid 1.5, calcined loess 12, nano-silicon nitride 7, high abrasion furnace carbon black N330 18, zinc stearate 1.5, calcium stearate 1.5, White Mineral Oil 25, isopropyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanate esters 2, accelerant N A-22 1.5, accelerant CZ 1, antioxidant NBC 2.5, antioxidant MB 1.5,
(2) butadiene rubber is added in twin-roll plastic mixing mill, roller temperature is mixing 8min at 95 DEG C, add EVA again, SEBS, White Mineral Oil, nano-silicon nitride, high wear-resistant carbon black, blanc fixe and calcined loess, mixing 5min, then cumyl peroxide is added successively, Celogen Az, sodium acid carbonate, zinc oxide, stearic acid, zinc stearate, calcium stearate, isopropyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanate esters, accelerant N A-22, accelerant CZ, antioxidant NBC, antioxidant MB, discharging after mixing 10min, moulded from foam is carried out shaping after parking 24h, press temperature is 170 DEG C, press time is 12min, pressing pressure is 10MPa.
Embodiment 6: the leather shoe outsole preparation of high-strength, high-anti-friction rubber expanded material
(1) raw material of following weight (kg) is got: butadiene rubber 60, EVA 30, SEBS 15, Celogen Az 5, cumyl peroxide 4, sodium acid carbonate 8, blanc fixe 12, zinc oxide 3, stearic acid 2, calcined loess 15, nano-silicon nitride 10, high abrasion furnace carbon black N330 20, zinc stearate 2, calcium stearate 2, White Mineral Oil 30, isopropyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanate esters 3, accelerant N A-22 2, accelerant CZ 1.5, antioxidant NBC 3, antioxidant MB 2,
(2) butadiene rubber is added in twin-roll plastic mixing mill, roller temperature is mixing 5min at 100 DEG C, add EVA again, SEBS, White Mineral Oil, nano-silicon nitride, high wear-resistant carbon black, blanc fixe and calcined loess, mixing 4min, then cumyl peroxide is added successively, Celogen Az, sodium acid carbonate, zinc oxide, stearic acid, zinc stearate, calcium stearate, isopropyl two oleic acid acyloxy (dioctyl phosphoric acid acyloxy) titanate esters, accelerant N A-22, accelerant CZ, antioxidant NBC, antioxidant MB, discharging after mixing 8min, moulded from foam is carried out shaping after parking 24h, press temperature is 180 DEG C, press time is 10min, pressing pressure is 12MPa.
In embodiment 4-6, expanded material adopts the butadiene rubber of excellent in abrasion resistance to be major ingredient, and utilize SEBS, EVA, blanc fixe, nano-silicon nitride, calcined loess etc. to carry out modification to butadiene rubber, SEBS significantly can improve the processing fluidity of butadiene rubber; EVA can make the mechanical property of expanded material improve, and blanc fixe, nano-silicon nitride, calcined loess etc. add the tearing strength that can make material and hardness rises; Obtained expanded material flexibility is out good, and intensity is high, and resilience is good, has excellent wear-resisting, high-low temperature resistant, endurance, the performance such as ageing-resistant, durable in use, substantially increases the service life of leather shoes.
The performance test of the expanded material that embodiment 4-6 obtains is as shown in table 1:
The expanded material that table 1 embodiment 4-6 obtains and prior art performance test contrast
| Test item | Embodiment 4 | Embodiment 5 | Embodiment 6 | Prior art |
| Hot strength (MPa) | 8.2 | 8.8 | 7.8 | 6.4 |
| Tearing strength (kNm -1） | 25.6 | 26.2 | 24.5 | 19.7 |
| Hardness (A) | 89.3 | 90.6 | 87.7 | 82.9 |
| Elongation at break (%) | 211.8 | 218.4 | 204.2 | 183.9 |
| Compression set (%) | 18.2 | 17.4 | 19.5 | 22.6 |
| AKRON weares and teares (cc/1000) | 0.18 | 0.16 | 0.22 | 0.31 |
Embodiment 7: by reference to the accompanying drawings leather shoes of the present invention are described in detail
These leather shoes are made up of vamp 1 and sole, and sole was made up of the large end 2 and shoe-pad 3, and described vamp 1 material is ox-hide leather; Described shoe-pad 3 material is that hypo is beautiful, and shoe-pad ball area 4 is embedded with the shrinkage pool 6 of 6 uniform pore diameter, and heel area 5 is embedded with the shrinkage pool 6 of 4 uniform pore diameter, the Chinese medicine block 7 that in shrinkage pool 6, built-in embodiment 2 is obtained; Described material of the large end 2 is the high-strength, high-anti-friction rubber expanded material that embodiment 5 obtains; Be glued at described vamp 1 and the large end 2 or use suturing with thread management.
Above-mentioned obtained leather shoe structure is simple, good permeability, and hygroscopic desiccation and deodorization and sterilization Be very effective are comfortable and easy to wear, economical and practical, with low cost, durable in use.
Claims (2)
1. a deodorization and sterilization durable leather shoe, is made up of vamp (1) and sole, and sole is made up of the large end (2) and shoe-pad (3), it is characterized in that, described vamp (1) material is natural leather; Described shoe-pad (3) material is that hypo is beautiful, and the ball area (4) of shoe-pad (3) and heel area (5) are respectively embedded with the shrinkage pool (6) of 4-6 uniform pore diameter, built-in Chinese medicine block (7) in shrinkage pool (6); The described large end (2) material is high-strength, high-anti-friction rubber expanded material; To be glued between described vamp (1) and the large end (2) or with suturing with thread management; Described natural leather can be pigskin, ox-hide, sheepskin, horse skin or donkey hide;
The preparation method of described Chinese medicine block (7) is as follows:
A, take the raw material of following weight portion: zeolite 10-15, attapulgite 5-10, medical stone 4-8, Nano silica sol 15-20, activated alumina 2-4, sodium carboxymethyl starch 1-3, coconut husk charcoal 3-5, aloe powder 2-3, jade powder 1-2, kuh-seng 2-3, luffa vine 1.5-2.5, rhizome of cyrtomium 1-2, rhizoma atractylodis 2-3, balsamine 3-4, golden cypress 0.5-1.5, camphortree leaf 1-2, Chinese gall 2-3, Chinese bulbul 2-3, wolf's milk 1-2, lemon peel 3-4, bunge pricklyash leaf 2-3;
B, get zeolite, attapulgite, medical stone mix, being placed in concentration is that the hydrochloric acid solution of 15-20% soaks 0.5-1h, and be washed with distilled water to neutrality after taking-up, dry, 720-750 DEG C of calcining 1-2h, is cooled to room temperature, pulverizes, cross 100-150 mesh sieve, stand-by;
C, get kuh-seng, luffa vine, rhizome of cyrtomium, rhizoma atractylodis, balsamine, golden cypress, camphortree leaf, Chinese gall, the Chinese bulbul, wolf's milk, lemon peel, bunge pricklyash leaf mix, add 4-8 times amount water boiling and extraction 1-2h, filter, filter residue adds 3-6 times of water gaging again, decoct and extract 0.5-1h, filter, merging filtrate, be concentrated into the thick paste that relative density is 1.35-1.40, stand-by;
D, the powder that above-mentioned obtained thick paste and step b are obtained to be stirred, stand-by;
E, get Nano silica sol and activated alumina, sodium carboxymethyl starch, coconut husk charcoal, aloe powder, jade powder stir, then the mixture that above-mentioned steps d is obtained is added, 1000-1500rpm high-speed stirred 20-30min, briquetting, every block weight is 3-6g, dries.
2. deodorization and sterilization durable leather shoe according to claim 1, is characterized in that, the solid content of described Nano silica sol is 40-45%.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
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| CN201510323105.5A CN104983117B (en) | 2013-12-27 | 2013-12-27 | A kind of deodorization and sterilization leather shoes |
| CN201310737418.6A CN103689855B (en) | 2013-12-27 | 2013-12-27 | A kind of deodorization and sterilization durable leather shoe |
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| CN201310737418.6A CN103689855B (en) | 2013-12-27 | 2013-12-27 | A kind of deodorization and sterilization durable leather shoe |
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| CN105196587B (en) * | 2015-08-17 | 2017-08-25 | 林棉棉 | A kind of manufacture craft of sport shoe sole material |
| CN106073010A (en) * | 2016-08-12 | 2016-11-09 | 南京中脉科技发展有限公司 | A kind of multifunctional shoe for health care |
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| CN107467784A (en) * | 2017-09-25 | 2017-12-15 | 于鹏 | A kind of composite multi-functional shoe-pad and its production method |
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| TW202000779A (en) | 2018-06-13 | 2020-01-01 | 巴西商布拉斯科股份公司 | EVA thermoplastic compounds, methods thereof, and articles therefrom |
| CN108783752A (en) * | 2018-07-06 | 2018-11-13 | 王培奇 | A kind of production method of health insoles |
| CN110144065A (en) * | 2019-05-14 | 2019-08-20 | 林建辉 | A kind of antibacterial foamed shoe sole and preparation method thereof |
| CN110301716A (en) * | 2019-07-04 | 2019-10-08 | 邳州市尕星医药技术服务有限公司 | A kind of insole for preventing and treating tinea pedis |
| CN111802748B (en) * | 2020-07-30 | 2022-08-23 | 浙江奥康鞋业股份有限公司 | Formal dress shoes |
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| CN101649077B (en) * | 2009-06-22 | 2012-08-22 | 泰亚鞋业股份有限公司 | Ultralight rubber formulation for sport sole |
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| CN202680729U (en) * | 2012-06-20 | 2013-01-23 | 赵纯青 | Novel traditional Chinese medicine antibacterial deodorant sweat absorbent ventilate massage shoe pad |
| CN103012981B (en) * | 2012-12-13 | 2014-07-02 | 福建永悦科技有限公司 | Material for rubber forming shoes and preparation method of material |
| CN103012871B (en) * | 2012-12-25 | 2014-07-09 | 国家复合改性聚合物材料工程技术研究中心 | Natural rubber foam material and preparation method thereof |
| CN103205026B (en) * | 2013-04-02 | 2015-11-25 | 刘培珠 | A kind of Ultralight high-elastic rubber sole material and preparation method thereof |
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2013
- 2013-12-27 CN CN201310737418.6A patent/CN103689855B/en not_active Expired - Fee Related
- 2013-12-27 CN CN201510323105.5A patent/CN104983117B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20040031414A (en) * | 2002-10-05 | 2004-04-13 | 손영석 | Shoe insole made of paper, wood, etc. |
| TW200534805A (en) * | 2004-04-28 | 2005-11-01 | Chong-Kang Lee | Manufacturing method of shoe pad with Chinese herbal medicine |
| JP2007330726A (en) * | 2006-06-12 | 2007-12-27 | Yoitsu Otsuka | Aloe chip insole |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104983117A (en) | 2015-10-21 |
| CN104983117B (en) | 2016-08-31 |
| CN103689855A (en) | 2014-04-02 |
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