CN103682117B - A kind of organic light emission lighting device - Google Patents

A kind of organic light emission lighting device Download PDF

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Publication number
CN103682117B
CN103682117B CN201310752715.8A CN201310752715A CN103682117B CN 103682117 B CN103682117 B CN 103682117B CN 201310752715 A CN201310752715 A CN 201310752715A CN 103682117 B CN103682117 B CN 103682117B
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layer
organic light
light emission
lighting device
electrode
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CN103682117A (en
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段炼
李曼
张国辉
刘嵩
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Tsinghua University
Beijing Visionox Technology Co Ltd
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Tsinghua University
Beijing Visionox Technology Co Ltd
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/10OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/11OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers
    • H10K50/125OLEDs or polymer light-emitting diodes [PLED] characterised by the electroluminescent [EL] layers specially adapted for multicolour light emission, e.g. for emitting white light
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/10OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/14Carrier transporting layers
    • H10K50/15Hole transporting layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/10OLEDs or polymer light-emitting diodes [PLED]
    • H10K50/14Carrier transporting layers
    • H10K50/16Electron transporting layers
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K2101/00Properties of the organic materials covered by group H10K85/00

Abstract

Organic light emission lighting device of the present invention, including first electrode layer, luminescent layer, the second electrode lay, successively decrease successively along the energy gap away from first electrode direction, each luminescent layer;When driving DC voltage is relatively low, the small luminescent layer luminous intensity of energy gap is big, and with the rise of driving voltage, the larger luminescent layer luminous intensity of energy gap gradually strengthens.With the rise of driving voltage, because the carrier mobility of electron transfer layer is more than the carrier mobility of hole transmission layer so that the complex centre in electronics and hole is close to hole transmission layer side so that glow color changes.Organic light emission lighting device is driven using pulse voltage, the regulation of color and brightness can be achieved by the amplitude and time that adjust pulse voltage.And on the basis of the device architecture of existing organic light emission lighting device, the adjustable of glow color just can be realized without increasing functional layer and preparation technology, not only preparation technology is simple but also light transmittance is high.

Description

A kind of organic light emission lighting device
Technical field
The present invention relates to field of organic electroluminescence, and in particular to a kind of organic light emission lighting device of Color tunable.
Background technology
Organic light emitting apparatus(English full name is Organic Light Emitting Device, referred to as OLED)As Lighting engineering of future generation, has the advantages that face luminous, low heat emission, low energy consumption, light, thin.Importantly, China illuminates use every year Electricity is about 600,000,000,000 degree, accounts for the 12% of national annual electricity, 5.98 hundred million tons of carbon dioxide of annual illumination discharge.According to OLED Lighting engineering replace existing lighting engineering, every year can 400,000,000,000 degree of using electricity wisely, reduction 3.99 hundred million tons of CO2 emission, have Important application value.
In the prior art, monochromatic illumination is used organic light emission lighting device, to realize that illuminating color is adjustable more, it will usually It is achieved using the Organic Light Emitting Diode for stacking multiple different glow colors.In the structure shown here, adjacent organic light-emitting diodes Need to set charge generation layer between the adjacent electrode of pipe, and the electrode of Organic Light Emitting Diode also needs to be connected to outside, Structure and preparation technology are complicated.In addition, the electrode of Organic Light Emitting Diode must possess the high grade of transparency and low sheet resistance, so And, both is conflicting demand;Therefore, half-way house is generally used in the prior art so that transparency and electric conductivity Can all it be short of, it is difficult to realize large area Color tunable organic light emission lighting device.
Therefore, a kind of electroluminescent device is disclosed in Chinese patent literature CN102414858A, including substrate, two electricity Pole and lamination, the lamination include at least two Electroluminescent emissives and be arranged at least two adjacent Electroluminescent emissives it Between at least one interlayer, wherein Electroluminescent emissive include electroluminescent molecules, wherein interlayer is undoped interlayer and tool Having allows the thickness to form interface zone, the interface zone be included at least two Electroluminescent emissives each in deposit Electroluminescent molecules.When driving the electroluminescent device, it is assumed that the hole mobility of interlayer is better than electron mobility, That is, hole is transmitted with higher speed in interlayer;At the lower voltage, the electroluminescence layer only close to negative electrode lights, with electricity The increase of pressure, influence of the electric field to electron mobility is bigger than hole mobility, and electronics is bigger than the transmission speed in hole so that lean on The electroluminescence layer of nearly anode starts to light;The glow color of multiple Organic Light Emitting Diodes is overlapped, and realizes glow color It is adjustable with brightness.But, the electroluminescent device is at least provided with an interlayer between emission layer, and preparation technology is complicated.
The content of the invention
Therefore, to be solved by this invention is that the el light emitting device preparation technology of Color tunable in the prior art is answered Miscellaneous the problem of, there is provided a kind of simple Color tunable organic light emission lighting device of preparation technology.
In order to solve the above technical problems, the technical solution adopted by the present invention is as follows:
A kind of organic light emission lighting device of the present invention, including first electrode layer and the second electrode lay, described first At least two luminescent layers are provided between electrode layer and the second electrode lay, along remote first electrode direction, each luminescent layer Energy gap is successively decreased successively;Hole transmission layer, the second electrode are provided between the first electrode layer and the luminescent layer Electron transfer layer is provided between layer and the luminescent layer.
The carrier mobility of the electron transfer layer is more than the carrier mobility of the hole transmission layer.
The first electrode layer and/or the second electrode lay are transparent or semitransparent film layer.
The glow color of each luminescent layer is different from each other.
The work function of the first electrode layer is higher than the work function of the second electrode lay.
Be additionally provided with hole injection layer between the first electrode layer and the hole transmission layer, the second electrode lay with Electron injecting layer is additionally provided between the electron transfer layer.
The organic light emission lighting device is driven by pulse voltage.
The waveform of the pulse voltage is combination one or more in square wave, sawtooth waveforms, sine wave.
The frequency of the pulse voltage is more than 25HZ.
The above-mentioned technical proposal of the present invention has advantages below compared with prior art:
Organic light emission lighting device of the present invention, including first electrode layer and the second electrode lay, the first electrode At least two luminescent layers are provided between layer and the second electrode lay, along away from first electrode direction, the forbidden band of each luminescent layer Width successively decreases successively, when driving DC voltage is relatively low, and the small luminescent layer luminous intensity of energy gap is big, with driving voltage Rise, the larger luminescent layer luminous intensity of energy gap gradually strengthens.Under low driving voltage, the electron transfer layer and described Influence of the carrier mobility of hole transmission layer to the organic light emission lighting device be not obvious;With the liter of driving voltage Height, because the carrier mobility of the electron transfer layer is more than the carrier mobility of the hole transmission layer so that electronics Complex centre with hole is close to hole transmission layer side so that glow color changes.Therefore, according to the principle of three primary colours Time mixing color method, the organic light emission lighting device is driven using pulse voltage, by adjust pulse voltage amplitude and when Between the regulation of the organic light emission lighting device color and brightness can be achieved.And the organic light emission lighting device is existing On the basis of the device architecture of organic light emission lighting device, glow color just can be realized without increasing functional layer and preparation technology Adjustable, not only preparation technology is simple but also light transmittance is high.
Brief description of the drawings
In order that present disclosure is more likely to be clearly understood, specific embodiment and combination below according to the present invention Accompanying drawing, the present invention is further detailed explanation, wherein
Fig. 1 is the structural representation of organic light emission lighting device described in the embodiment of the present invention 1;
Fig. 2 is the spectrogram under different driving voltage of organic light emission lighting device described in the embodiment of the present invention 1;
Fig. 3 is the chromaticity coordinates figure under different driving voltage of organic light emission lighting device described in the embodiment of the present invention 1;
Fig. 4 is the luminance graph under different driving voltage of organic light emission lighting device described in the embodiment of the present invention 1;
Fig. 5 is the driving voltage scheme of organic light emission lighting device described in the embodiment of the present invention 1;
Fig. 6 is organic light emission lighting device described in the embodiment of the present invention 1 in pulse voltage(VL=0)Lower chromaticity coordinates figure (CIE-x);
Fig. 7 is organic light emission lighting device described in the embodiment of the present invention 1 in pulse voltage(VL=0)Lower chromaticity coordinates figure (CIE-y);
Fig. 8 is organic light emission lighting device described in the embodiment of the present invention 1 in pulse voltage(VL=0)Lower luminance graph;
Fig. 9 is organic light emission lighting device described in the embodiment of the present invention 1 in pulse voltage(VL> 0)Lower chromaticity coordinates figure (CIE-x, CIE-y);
Figure 10 is organic light emission lighting device described in the embodiment of the present invention 1 in pulse voltage(VL> 0)Lower luminance graph.
Embodiment
In order that the object, technical solutions and advantages of the present invention are clearer, below in conjunction with reality of the accompanying drawing to the present invention The mode of applying is described in further detail.
The present invention can be embodied in many different forms, and should not be construed as limited to embodiment set forth herein. Opposite there is provided these embodiments so that the disclosure will be thorough and complete, and the design of the present invention will be fully conveyed to Those skilled in the art, the present invention will only be defined by the appended claims.In the accompanying drawings, for clarity, Ceng He areas can be exaggerated The size and relative size in domain.
Embodiment 1
The present embodiment provides a kind of organic light emission lighting device, as shown in figure 1, including first electrode layer and second electrode Layer, stack gradually in the first electrode layer be provided with hole injection layer, hole transmission layer, the first luminescent layer, the second luminescent layer, Electron transfer layer, electron injecting layer and the second electrode lay, along away from first electrode direction, the energy gap of each luminescent layer Successively decrease successively, the energy gap of first luminescent layer is 2.65eV, and the energy gap of second luminescent layer is 2.18eV.
The concrete structure of the organic light emission lighting device is:
ITO(180nm)/HAT-CN(5nm)/NPB(30nm)/Bepp2(10nm):BD(4%)/TCTA(12nm):Bepp2 (100%):TBRb(3%)/DPyPA(15nm)/LiF(0.5nm)/Al(150nm).
Wherein, ITO(Indium tin oxide)Layer is first electrode layer;HAT-CN layers are hole injection layer;NPB layers are that hole is passed Defeated layer;Material of main part Bepp2 and guest materials BD, which adulterates, constitutes the first luminescent layer of transmitting blue light;Material of main part TCTA, Bepp2 Adulterated with guest materials TBRb and constitute the second luminescent layer of transmitting orange light;DPyPA layers are electron transfer layer;LiF layers are electronics Implanted layer;Al layers are the second electrode lay;Each layer preparation method is compared with technology in the organic light emission lighting device.
It is 1.0 × 10 as the carrier mobility of the DPyPA layers of the present embodiment electron transfer layer-3cm2/ Vs, hole The carrier mobility that NPB layers of transport layer is 1.63 × 10-5cm2/V·s。
As the other embodiment of the present invention, the hole mobility of the hole transport layer material is 10-5~10-4cm2/ Between Vs, NPB, TCTA, TAPC, CBP etc. are selected from, but not limited to,;The electron mobility of the electron transport layer materials is 10-4 ~10-3cm2/ Vs, is selected from, but not limited to, Bepp2, Bebq2, Bphen, DPyPA, Tm3PyPb etc., can realize the present invention Purpose, belong to protection scope of the present invention.
Organic light emission lighting device spectrogram, chromaticity coordinates figure and the luminance graph under different direct voltage drives point Not as shown in Figure 2, Figure 3, Figure 4.
As shown in Fig. 2 the organic light emission lighting device there are two emission peaks of 460nm and 575nm, the first hair is corresponded to respectively Photosphere and the second luminescent layer.Under different driving DC voltages, the emissive porwer of the first luminescent layer is constant, the second luminescent layer Emissive porwer is gradually reduced with the rise of driving voltage.In the present embodiment, the first electrode layer is euphotic electrode, described Second electrode is reflecting electrode, and the energy gap of first luminescent layer is more than the energy gap of second luminescent layer.When straight When stream driving voltage is relatively low, the second small luminescent layer luminous intensity of energy gap is big, with the rise of driving voltage, energy gap The first larger luminescent layer luminous intensity gradually strengthens.Under low driving voltage, the electron transfer layer and the hole transport Influence of the carrier mobility of layer to the organic light emission lighting device be not obvious(That is the first luminescent layer is in low-voltage in Fig. 2 Under driving, luminous intensity is constant);With the rise of driving voltage, because the carrier mobility of the electron transfer layer is more than The carrier mobility of the hole transmission layer so that the complex centre in electronics and hole is close to hole transmission layer side, makes Glow color is obtained to change.
With the rise of driving voltage it can be seen from data in Fig. 2, the glow color of the organic light emission lighting device Gradually change;The change of specific chromaticity coordinates can be as seen from Figure 3.
The brightness of the organic light emission lighting device is with the rise of voltage it can be seen from the test data in Fig. 4 Rise.
As shown in figure 5, driving the organic light emission lighting device by square wave pulse voltage;Dutycycle D=T1/(T1+ T2);It is DC voltage V as D=0HChromaticity coordinates and brightness during driving;During D=1, device is closed.Due to human eye Visual lag sensing speed be >=40ms, so the frequency of the pulse voltage needs to be more than 25HZ, preferably greater than or equal to 50Hz and less than or equal to 4KHz, the present embodiment is more preferably higher than equal to 1KHz and less than or equal to 2KHz.
Work as VLDuring=0V, fixed VH, as shown in Figure 6 and Figure 7, regulation dutycycle D=T1/(T1+T2), the organic light emission photograph The chromaticity coordinates of bright device(CIE-x, CIE-y)Do not change with the change of D and voltage.
As shown in figure 8, the brightness of the organic light emission lighting device reduces with D increase.
, can be by adjusting V in the case of brightness identicalHThe tune of the organic light emission lighting device color is realized with D Section;In the case of color identical, pass through fixed VH, only by dutycycle D regulation, just can show that the organic light emission shines The brightness regulation of bright device.
Work as VL>During 0V, with VLExemplified by=4.5V, as shown in Figure 9 and Figure 10, the chromaticity coordinates of the organic light emission lighting device and Brightness is to dutycycle D and VHUniform dependence is, it is necessary to adjust V simultaneouslyHIt could be realized to the organic light emission lighting device with D Chromaticity coordinates and brightness regulation.
As D=0, VH=VL, with VHConstant pressure drives;As D=1, VH=VL, with VLConstant pressure drives.
To sum up, VLDuring > 0V, by changing VL、VHWith D collocation, can equally realize fixed chromaticity coordinates, change described in have The brightness of machine litillumination devices;Or brightness is fixed, change the chromaticity coordinates of the organic light emission lighting device.
Organic light emission lighting device described in the present embodiment, the organic light emission lighting device is driven using pulse voltage, The regulation of the organic light emission lighting device color and brightness can be achieved by the amplitude and time that adjust pulse voltage.And The organic light emission lighting device is on the basis of the device architecture of existing organic light emission lighting device, without increasing other functional layers And preparation technology just can realize the adjustable of glow color, not only preparation technology is simple but also light transmittance is high.
Embodiment 2
The present embodiment provides a kind of organic light emission lighting device, including first electrode layer and the second electrode lay, described first Stacked gradually on electrode layer be provided with hole injection layer, hole transmission layer, the first luminescent layer, bipolarity barrier layer, second light Layer, electron transfer layer, electron injecting layer and the second electrode lay, along away from first electrode direction, the forbidden band of each luminescent layer Width successively decreases successively, and the energy gap of first luminescent layer is 2.65eV, and the energy gap of second luminescent layer is 2.21eV。
The concrete structure of the organic light emission lighting device is:
ITO(180nm)/HAT-CN(5nm)/NPB(30nm)/Bepp2(10nm):BD(4%)/TCTA(4nm):Bepp2 (100%)/TCTA(12nm):PO-01(10%)/DPyPA(15nm)/LiF(0.5nm)/Al(150nm).
Wherein, ITO(Indium tin oxide)Layer is first electrode layer;HAT-CN layers are hole injection layer;NPB layers are that hole is passed Defeated layer;Material of main part Bepp2 and guest materials BD, which adulterates, constitutes the first luminescent layer of transmitting blue light;Material of main part TCTA and Bepp2 adulterates to form bipolarity barrier layer;Material of main part TCTA and guest materials PO-01, which adulterates, constitutes the second of transmitting orange light Luminescent layer;DPyPA layers are electron transfer layer;LiF layers are electron injecting layer;Al layers are the second electrode lay;The organic light emission shines Each layer preparation method is compared with technology in bright device.
In the present embodiment, first luminescent layer is that fluorescent light-emitting layer, second luminescent layer are phosphorescence luminescent layer, in order to Prevent the triplet excitons of phosphorescence doping in second luminescent layer are diffused into first luminescent layer from producing Exciton quenching, it is special One layer of bipolarity barrier layer is set between first luminescent layer and second luminescent layer, shone improving the organic light emission While bright unit efficiency, the life-span of device is improved.
Embodiment 3
The present embodiment provides a kind of organic light emission lighting device, including first electrode layer and the second electrode lay, described first Stacked gradually on electrode layer be provided with hole injection layer, hole transmission layer, the first luminescent layer, bipolarity barrier layer, second light Layer, electron transfer layer, electron injecting layer and the second electrode lay, along away from first electrode direction, the forbidden band of each luminescent layer Width successively decreases successively, and the energy gap of first luminescent layer is 2.65eV, and the energy gap of second luminescent layer is 2.15eV。
The concrete structure of the organic light emission lighting device is:
ITO(180nm)/HAT-CN(5nm)/NPB(30nm)/Bepp2(10nm):BD(4%)/TCTA(4nm):Bepp2 (100%)/TCTA(12nm):Ir(ppy)3(15%):Ir(piq)3(1%)/DPyPA(15nm)/LiF(0.5nm)/Al(150nm).
Wherein, ITO(Indium tin oxide)Layer is first electrode layer;HAT-CN layers are hole injection layer;NPB layers are that hole is passed Defeated layer;Material of main part Bepp2 and guest materials BD, which adulterates, constitutes the first luminescent layer of transmitting blue light;Material of main part TCTA and Bepp2 adulterates to form bipolarity barrier layer;Material of main part TCTA and guest materials Ir (ppy)3、Ir(piq)3Doping constitutes transmitting Second luminescent layer of orange light;DPyPA layers are electron transfer layer;LiF layers are electron injecting layer;Al layers are the second electrode lay;Institute Each layer preparation method is stated in organic light emission lighting device compared with technology.
Equally, in the present embodiment, first luminescent layer is that fluorescent light-emitting layer, second luminescent layer are that phosphorescence lights Layer, exciton is produced in order to prevent the triplet excitons of phosphorescence doping in second luminescent layer to be diffused into first luminescent layer It is quenched, spy sets one layer of bipolarity barrier layer between first luminescent layer and second luminescent layer, has described in raising While machine litillumination devices efficiency, the life-span of device is improved.
Embodiment 4
The present embodiment provides a kind of organic light emission lighting device, including first electrode layer and the second electrode lay, described first Stacked gradually on electrode layer be provided with hole injection layer, hole transmission layer, the first luminescent layer, the second luminescent layer, electron transfer layer, Electron injecting layer and the second electrode lay, successively decrease successively along the energy gap away from first electrode direction, each luminescent layer, institute The energy gap for stating the first luminescent layer is 2.60eV, and the energy gap of second luminescent layer is 2.21eV.
The concrete structure of the organic light emission lighting device is:
ITO(180nm)/HAT-CN(5nm)/CBP(30nm)/CBP(30nm):Firpic(10%)/CBP(12nm):PO- 01(10%)/Tm3PyPb(15nm)/LiF(0.5nm)/Al(150nm).
Wherein, ITO(Indium tin oxide)Layer is first electrode layer;HAT-CN layers are hole injection layer;CBP layers are that hole is passed Defeated layer;Material of main part CBP and guest materials Firpic, which adulterates, constitutes the first luminescent layer of transmitting blue emitting phosphor;Material of main part CBP Adulterated with guest materials PO-01 and constitute the second luminescent layer of transmitting orange light;Tm3PyPb layers are electron transfer layer;LiF layers are electricity Sub- implanted layer;Al layers are the second electrode lay;Each layer preparation method is compared with technology in the organic light emission lighting device.
The structural formula of material used is in above-described embodiment:
Above-mentioned material is made all in accordance with prior art by testing synthesis.
Obviously, above-described embodiment is only intended to clearly illustrate example, and the not restriction to embodiment.It is right For those of ordinary skill in the art, can also make on the basis of the above description it is other it is various forms of change or Change.There is no necessity and possibility to exhaust all the enbodiments.And the obvious change thus extended out or Among changing still in protection scope of the present invention.

Claims (7)

1. a kind of organic light emission lighting device, including first electrode layer and the second electrode lay, it is characterised in that the first electrode At least two luminescent layers are provided between layer and the second electrode lay, along away from first electrode direction, the forbidden band of each luminescent layer Width successively decreases successively;Be provided with hole transmission layer between the first electrode layer and the luminescent layer, the second electrode lay with Electron transfer layer is provided between the luminescent layer;The carrier mobility of the electron transfer layer is more than the hole transmission layer Carrier mobility;The organic light emission lighting device is driven by pulse voltage.
2. organic light emission lighting device according to claim 1, it is characterised in that the first electrode layer and/or described The second electrode lay is transparent or semitransparent film layer.
3. organic light emission lighting device according to claim 1, it is characterised in that the glow color of each luminescent layer that This is different.
4. organic light emission lighting device according to claim 1, it is characterised in that the work function of the first electrode layer is high In the work function of the second electrode lay.
5. organic light emission lighting device according to claim 1, it is characterised in that the first electrode layer and the hole Hole injection layer is additionally provided between transport layer, electronics note is additionally provided between the second electrode lay and the electron transfer layer Enter layer.
6. organic light emission lighting device according to claim 1, it is characterised in that the waveform of the pulse voltage is rectangle One or more combination in ripple, sawtooth waveforms, sine wave.
7. organic light emission lighting device according to claim 1, it is characterised in that the frequency of the pulse voltage is more than 25HZ。
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CN106255277A (en) * 2016-09-30 2016-12-21 福州大学 The method improving OLED luminous efficiency based on drive circuit
CN109244255A (en) * 2018-07-31 2019-01-18 华南理工大学 Organic planar heterojunction white light parts and its dimmer application suitable for pulsed drive
CN109686853B (en) * 2018-12-26 2020-12-01 上海晶合光电科技有限公司 Color-adjustable organic electroluminescent device
CN111554819B (en) * 2020-04-27 2023-06-23 南方科技大学 Light-emitting device, light-emitting color adjusting method thereof and display device

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CN1729725A (en) * 2002-11-18 2006-02-01 出光兴产株式会社 Organic electroluminescent element
CN201466065U (en) * 2009-06-19 2010-05-12 深圳大学 Organic electroluminescent device
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CN1729725A (en) * 2002-11-18 2006-02-01 出光兴产株式会社 Organic electroluminescent element
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