CN103668619B - Yarn, textile material and the clothes containing it - Google Patents
Yarn, textile material and the clothes containing it Download PDFInfo
- Publication number
- CN103668619B CN103668619B CN201310296070.1A CN201310296070A CN103668619B CN 103668619 B CN103668619 B CN 103668619B CN 201310296070 A CN201310296070 A CN 201310296070A CN 103668619 B CN103668619 B CN 103668619B
- Authority
- CN
- China
- Prior art keywords
- yarn
- regenerated celulose
- celulose fibre
- fibre
- fiber
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Active
Links
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41D—OUTERWEAR; PROTECTIVE GARMENTS; ACCESSORIES
- A41D31/00—Materials specially adapted for outerwear
- A41D31/04—Materials specially adapted for outerwear characterised by special function or use
- A41D31/08—Heat resistant; Fire retardant
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/22—Yarns or threads characterised by constructional features, e.g. blending, filament/fibre
- D02G3/36—Cored or coated yarns or threads
-
- D—TEXTILES; PAPER
- D02—YARNS; MECHANICAL FINISHING OF YARNS OR ROPES; WARPING OR BEAMING
- D02G—CRIMPING OR CURLING FIBRES, FILAMENTS, THREADS, OR YARNS; YARNS OR THREADS
- D02G3/00—Yarns or threads, e.g. fancy yarns; Processes or apparatus for the production thereof, not otherwise provided for
- D02G3/44—Yarns or threads characterised by the purpose for which they are designed
- D02G3/443—Heat-resistant, fireproof or flame-retardant yarns or threads
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2201/00—Cellulose-based fibres, e.g. vegetable fibres
- D10B2201/20—Cellulose-derived artificial fibres
-
- D—TEXTILES; PAPER
- D10—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B—INDEXING SCHEME ASSOCIATED WITH SUBLASSES OF SECTION D, RELATING TO TEXTILES
- D10B2331/00—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products
- D10B2331/02—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides
- D10B2331/021—Fibres made from polymers obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds, e.g. polycondensation products polyamides aromatic polyamides, e.g. aramides
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/30—Woven fabric [i.e., woven strand or strip material]
- Y10T442/3976—Including strand which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous composition, water solubility, heat shrinkability, etc.]
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T442/00—Fabric [woven, knitted, or nonwoven textile or cloth, etc.]
- Y10T442/60—Nonwoven fabric [i.e., nonwoven strand or fiber material]
- Y10T442/696—Including strand or fiber material which is stated to have specific attributes [e.g., heat or fire resistance, chemical or solvent resistance, high absorption for aqueous compositions, water solubility, heat shrinkability, etc.]
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Woven Fabrics (AREA)
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
Yarn includes：A the regenerated celulose fibre of () about 45wt% to about 85wt%, the regenerated celulose fibre has the dry strength of about 27cN/tex or higher, the regenerated celulose fibre is included in the intrastitial flame-retardant compound；The para-aramid fiber of (b) about 5wt% to about 25wt%.The textile material of such as fabric includes this yarn of multiply.The clothes of such as shirt or trousers include this textile material.The method of the individual infra-red radiation from that can be produced during arc-flash of protection make use of this textile material.
Description
Technical field
The application is related to show yarn, textile material and the clothes of refractory properties.
Background technology
Fire-resistant fabric can be used for many purposes, including produce the clothes that the personnel of various industrial or occupations are worn, such as
Military field, electric field (being used for arc protection), petrochemical production and emergency response field.Cellulose or cellulose are mixed
Yarn fabric generally for these clothes be it is preferred, this be attributable to these fabrics can relatively easily be made fire resisting and
These fabrics relative comfort for wearer.
Although cellulose or cellulose blends fire-resistant fabric are commonly used, existing fabric is limited really.Many fibers
The combustibility of plain fire-resistant fabric is not enough to meet the strict demand of some industry.Therefore, it is still necessary to which energy is provided at lower cost
Meet the alternative fire-resistant fabric of existing refractory standard.
The content of the invention
In the first embodiment, the invention provides the yarn comprising following component：A () about 45wt% is to about 85wt%'s
Regenerated celulose fibre, the regenerated celulose fibre has the dry strength of about 27cN/tex or higher, the regenerated cellulose
Fiber is included in the intrastitial flame-retardant compound；(b) about 5wt% to about 25wt% para-aramid fibers.
In this second embodiment, the invention provides the textile material comprising multi-strand yarns, the yarn is included：
A the regenerated celulose fibre of () about 45wt% to about 85wt%, the regenerated celulose fibre has about 27cN/tex or higher
Dry strength, the regenerated celulose fibre is included in the intrastitial flame-retardant compound；(b) about 5wt% is to about 25wt%'s
Para-aramid fiber.
In the third embodiment, the invention provides including one piece or more the clothes of block fabric, the fabric
At least one piece in fabric includes multi-strand yarns, and the yarn is included：A the regenerated cellulose of () about 45wt% to about 85wt% is fine
Dimension, the regenerated celulose fibre has the dry strength of about 27cN/tex or higher, and the regenerated celulose fibre is included in institute
State intrastitial flame-retardant compound；The para-aramid fiber of (b) about 5wt% to about 25wt%.
In the 4th implementation method, the invention provides the shirt comprising polylith fabric, in the fabric
At least one piece at least two pieces defined in the body covering part and the fabric of the shirt are defined and the lining
The connected coat-sleeve of the body covering part of shirt, at least one piece in the fabric includes multi-strand yarns, and the yarn is included：
A the regenerated celulose fibre of () about 45wt% to about 85wt%, the regenerated celulose fibre has about 27cN/tex or higher
Dry strength, the regenerated celulose fibre is included in the intrastitial flame-retardant compound；(b) about 5wt% is to about 25wt%'s
Para-aramid fiber.
In the 5th implementation method, the invention provides the trousers comprising polylith fabric, in the fabric
At least two pieces leg covering parts for defining the trousers, at least one piece in the fabric includes multi-strand yarns, institute
Yarn is stated to include：A the regenerated celulose fibre of () about 45wt% to about 85wt%, the regenerated celulose fibre has about 27cN/
The dry strength of tex or higher, the regenerated celulose fibre is included in the intrastitial flame-retardant compound；(b) about 5wt%
To the para-aramid fiber of about 25wt%.
It is individual infrared from what can be produced during arc-flash the invention provides protection in the 6th implementation method
The method of radiation, the described method comprises the following steps：Textile material is placed in the individual equipment with that can produce arc-flash
Between, the textile material includes multi-strand yarns, and the yarn is included：The regenerated cellulose of (a) about 45wt% to about 85wt%
Fiber, the regenerated celulose fibre has the dry strength of about 27cN/tex or higher, and the regenerated celulose fibre is included in
The intrastitial flame-retardant compound；The para-aramid fiber of (b) about 5wt% to about 25wt%.
Specific embodiment
As described above, the invention provides fire resistant textile material.As used herein, term " fire resisting " refers in removal
The material of smoulder or self-extinguish after outside Ignition sources.The fire resistance of textile material can be by any suitable inspection
Survey method is measured, those for such as describing in the following：National Fire Protection Association(NFPA)
701, entitled " Standard Methods of Fire Tests for Flame Propagation of Textiles and
Films”；ASTM D6413, entitled " Standard Test Method for Flame Resistance of Textiles
(vertical test)”；NFPA2112, entitled " Standard on Flame Resistant clothes for Protection
of Industrial Personnel Against Flash Fire”；ASTM F1506, entitled " The Standard
Performance Specification for Flame Resistant Textile Materials for Wearing
Apparel for Use by Electrical Workers Exposed to Momentary Electric Arc and
Related Thermal Hazards”；And ASTM F1930, entitled " Standard Test Method for
Evaluation of Flame Resistant Clothing for Protection Against Flash Fire
Simulations Using an Instrumented Manikin”。
In the first embodiment, the invention provides the yarn comprising regenerated celulose fibre and para-aramid fiber
Line.The yarn can be the yarn of any suitable type.Preferably, the regenerated celulose fibre and para-aramid are fine
Dimension is chopped fiber, and the yarn is spun yarn.Such spun yarn can be formed by any suitable spinning process, such as ring
Ingot spinning, air-jet spinning or open-end-spinning.In some embodiments, the yarn is spun into using ring spinning process
(that is, described yarn is ring spinning).
Yarn of the invention includes regenerated celulose fibre.Term " regenerated celulose fibre " in this article refer to by with
The fiber that under type is made：By cellulose dissolution in a suitable solvent, then the solution spinned in suitable medium or
Person extrudes, so that cellulose is precipitated or condensed out in the form of long filament or fiber.There is several different types of regenerated fiber
Cellulose fiber can use.Suitable regenerated celulose fibre includes but is not limited to viscose rayon (for example, viscose rayon fibre, high humidity mould
Amount viscose rayon, Modal fibre and polynoise fiber), Lyocell fibre (lyocell fiber), and they
Mixture.In a preferred embodiment, the regenerated celulose fibre be selected from viscose rayon, Lyocell fibre and they
Mixture.In preferred implementation method, the regenerated celulose fibre is Lyocell fibre.
The pliability and regain of regenerated celulose fibre generally display cause that the regenerated celulose fibre especially can use
In manufacture when wearing comfortable textile material.However, some regenerated celulose fibres are involved in relatively low intensity (especially
It is wet strength).The fragility of such regenerated celulose fibre mean they can not be largely used in textile material and
The durability of textile material will not be sacrificed.Therefore, regenerated celulose fibre used in embodiments of the present invention is preferred
Intensity relatively high is shown when drying and in moistening.More specifically, the regenerated celulose fibre is preferred shows about
The dry strength of 27cN/tex or higher, more preferably from about 30cN/tex or higher, most preferably from about 35cN/tex or higher.The regeneration
Cellulose fibre further preferably shows the wet strength of about 20cN/tex or higher or about 25cN/tex or higher.
Regenerated celulose fibre can be present in yarn with any suitable amount.When regenerated celulose fibre has institute above
During the intensity relatively high stated, during the regenerated celulose fibre can be added into yarn (and yarn is added to textile
In material) without sacrificing the durability of any textile material that yarn and the yarn are added thereto.Preferred
In implementation method, regenerated celulose fibre is present in yarn with following amount：Pact based on total weight of fibers present in yarn
40wt% or more, about 45wt% or more, about 50wt% or more, about 55wt% or more, about 60wt% or more or about
65wt% or more (e.g., from about 70wt%).Although the regenerated celulose fibre with relative high intensity recited above can be relative
Amount high is used, yarn of the invention can include other the required properties for producing and/or improving yarn other fibers (for example,
Para-aramid fiber).Therefore, regenerated celulose fibre is preferably present in yarn with following amount：Based on existing in yarn
Total weight of fibers about 85wt% or less (for example, about 80wt% or less or about 75wt% or less).Therefore, a series of
In preferred embodiment, regenerated celulose fibre is preferably present in yarn with following amount：It is total based on fiber present in yarn
About 45wt% to about 85wt%, the about 50wt% of weight are to about 85wt%, about 55wt% to about 85wt%, about 60wt% to about 85wt% or about
65wt% to about 85wt% (for example, about 65wt% to about 80wt% or about 65wt% to about 75wt%).
Regenerated celulose fibre preferably is contained in the flame-retardant compound in the fiber.This flame-retardant compound is preferably with such as
Under type is added into regenerated celulose fibre：It will not significantly reduce original regenerated celulose fibre (that is, without fire retardant
Regenerated celulose fibre) intensity.In fact, regenerated cellulose is fine after even in flame-retardant compound is added into fiber
Intensity in the preferred display above range of dimension.This causes that regenerated celulose fibre used in the present invention is different from such as FR viscose glues
Etc other fire-retardant regenerated cellulose fibers, the latter because add flame-retardant compound show significant intensity decreases.Regeneration is fine
Cellulose fiber can include any suitable flame retardant compound.Preferably, regenerated celulose fibre includes phosphorous flame-retardant compound.
Phosphor-containing flame-proof compound can be any suitable phosphor-containing flame-proof compound.Preferably, phosphor-containing flame-proof compound is
The compound being prepared as follows：First by (i) four methylol phosphonium salt, four methylol phosphonium salt condensation products or theirs is mixed
Compound reacts with (ii) crosslinking agent.Then the condensation product of gained is aoxidized, it is believed that this is by least a portion in condensation product
Phosphorus atoms are converted into more stable pentavalent form by trivalent form.Condensation product can be used it is any suitable oxidizing, it is all
Such as hydrogen peroxide, sodium perborate or sodium hypochlorite.
Term " four methylol phosphonium salts " refers to the salt containing four methylol phosphoniums (THP) cation with following structure：
Including but not limited to hydrochloride, sulfate, acetate, carbonate, borate and phosphate.As used herein,
Term " four methylol phosphonium salt condensation products " (THP condensate) refers to the product for obtaining in the following way：By four methylol phosphonium salts
(such as those above) is reacted to give following compound with limited amount crosslinking agent (such as urea, guanazole or biguanides)：
At least some its methylol groups that passed through wherein in each Si methylol phosphonium cation are connected.As being made using urea
The structure of condensation product is as illustrated below：
The synthesis of this condensation product is described in such as documents below：(the Textile Research such as Frank
Journal, November1982, pages678-693) and Frank etc. (Textile Research Journal,
December1982,pages738-750).These THPS condensation products can also be obtained by commercial channel, for example, conductCFR derives from Emerald Performance Materials.
Crosslinking agent is any suitable compound that THP can be crosslinked and/or be solidified.Suitable crosslinking agent is included for example
Urea, guanidine (that is, guanidine, its salt or guanidine derivatives), dicyandiamidines, glycoluril, ammonia, ammonia-formaldehyde adducts, ammonia-acetaldehyde adduct, ammonia-fourth
Aldehyde adducts, ammonia-chloral adduct, aminoglucose, polyamine are (for example, polyethyleneimine, polyvinylamine, polyimide, polyethylene
Amine, polyacrylamide, shitosan, glycosaminoglycan), glycidol ether, isocyanates, blocked isocyanate and their group
Close.Preferably, crosslinking agent is urea or ammonia, and urea is preferred crosslinking agent.
Flame-retardant compound can be added in regenerated celulose fibre in any suitable manner.For example, can be by fire-retardant chemical combination
Thing is added thereto in the solvent for having dissolved cellulose or added it in cellulosic material.When so done, will be fire-retardant
Compound is added thereto when fiber is extruded.Or alternatively, technology as known in the art can be used by fiber or yarn
Line (or by the thread textile material of the yarn) is post-processed with flame-retardant compound.
When fire retardant being applied on fiber or yarn (or by the thread textile material of the yarn), can be with any
Suitable amount applies THP or THP condensate.Typically, THP salt or THP condensate are applied with following amount：The amount is provided and is based on
At least 0.5wt% of the weight of untreated fiber or yarn (or by the thread textile material of the yarn) is (for example, at least
1wt%, at least 1.5wt%, at least 2wt%, at least 2.5wt%, at least 3wt%, at least 3.5wt%, at least 4wt% or at least
Element phosphor 4.5wt%).THP salt or THP condensate are also typically applied with following amount：The amount is provided and is based on untreated fibre
Dimension or yarn (or by the thread textile material of the yarn) weight less than 5wt% (for example, less than 4.5wt%, be less than
4wt%, less than 3.5wt%, less than 3wt%, less than 2.5wt%, less than 2wt%, less than 1.5wt% or less than 1wt%) element phosphor.It is excellent
Selection of land, THP salt or THP condensate are applied with following amount：The amount is provided based on untreated fiber or yarn (or by the yarn
Thread textile material) weight about 1wt% to about 4wt% (for example, about 1wt% to about 3wt% or about 2wt% are to about
Element phosphor 3wt%).Crosslinking agent can be applied to fiber or yarn (or by the thread textile of the yarn with any suitable amount
Material) on.Typically, crosslinking agent is applied with following amount：Based on untreated fiber or yarn (or by the thread spinning of the yarn
Fabric material) weight at least 0.1wt% (for example, at least 1wt%, at least 2wt%, at least 3wt%, at least 5wt%, at least
7wt%, at least 10wt%, at least 15wt%, at least 18wt% or at least 20wt%).Crosslinking agent is also typically applied with following amount：
Weight based on untreated fiber or yarn (or by the thread textile material of the yarn) less than 25wt% (for example, few
In 20wt%, less than 18wt%, less than 15wt%, less than 10wt%, less than 7wt%, less than 5wt%, less than 3wt% or be less than
1wt%).May preferred embodiment in, crosslinking agent is applied with following amount：Based on untreated fiber or yarn (or by
The thread textile material of the yarn) weight about 2wt% to about 7wt%.
Yarn of the invention also includes para-aramid fiber.These fibers are in order to following many in being comprised in yarn
Reason is planted, yarn and the intensity and durability by the thread any textile material of the yarn is such as improved.Para-aramid
Fiber can be present in yarn with any suitable amount.Preferably, para-aramid fiber is present in yarn with following amount：
Based on about 5wt% or more of total weight of fibers present in yarn, about 10wt% or more or about 15wt% or more.Although right
Aramid fibre can be used to improve the intensity and durability of yarn, have the yarn of the para-aramid fiber of a large amount
The uncomfortable textile material when wearing can be produced.Therefore, para-aramid fiber is preferably present in yarn with following amount
In：About 30wt% or less, about 25wt% or less or about 20wt% or less based on total weight of fibers present in yarn.Cause
This, in series of preferred embodiments, para-aramid fiber is present in yarn with following amount：Based on existing in yarn
Total weight of fibers about 5wt% to about 25wt%, about 10wt% to about 25wt% or about 15wt% to about 25wt%.
Yarn of the invention can also include other fibers, such as other synthetic fibers.These other synthetic fibers can be
Any suitable synthetic fibers, and can for a variety of reasons and by comprising.For example, described other synthetic fibers can be thermoplastic
Property synthetic fibers.These thermoplastic synthetic fibers can generally be comprised in yarn to improve it to such as industrial washing condition
Durability.Particularly, thermoplastic synthetic fiber tends to the abrasion to being used in industrial laundry facilities and harsh wash conditions spy
There is not durability, and add it to that the yarn can be improved to the resistance to of this kind of condition in the spun yarn of such as containing cellulose fiber
Long property.And the yarn durability of this raising causes to be improved by the durability of the thread textile material of the yarn.Suitably
Thermoplastic synthetic fiber includes but is not necessarily limited by polyester fiber (for example, poly- (ethylene glycol terephthalate) fiber, poly- (right
Benzene dicarboxylic acid 1,2-propylene glycol ester) fiber, poly- (terephthalic acid (TPA) 1,3- propylene glycol esters) fiber), poly- (terephthalic acid (TPA) fourth two
Alcohol) fiber and its blending), Fypro is (for example, nylon 6 fiber, the fiber of nylon 6,6, the fiber of nylon 4,6 and nylon 12 are fine
Dimension), vinal and combinations thereof, mixture or blending.In a preferred embodiment, yarn also includes polyamide
Fiber (for example, nylon 6 fiber, the fiber of nylon 6,6, the fiber of nylon 4,6 and the fiber of nylon 12), preferably nylon 6,6 fibers.
Other synthetic fibers can also be intrinsic refractory fibre.As used herein, term " intrinsic refractory fibre " refers to
Following synthetic fibers：The synthetic fibers show anti-flammability due to being made the chemical composition of its material and without extra fire-retardant place
Reason.In such implementation method, intrinsic refractory fibre can be any suitable intrinsic refractory fibre, and such as polyoxadiazole is fine
Dimension, polysulfonamide fibre, poly- (benzimidazole) fiber, poly- (benzene sulphur) fiber, meta-aramid fibre, polypyridine and two
Imidazoles fiber, poly- benzyl thiazole fiber, poly- Bian Ji oxazoles fiber, carbamide polymer fiber, P-F polymerization
Fibres, oxidation polyacrylonitrile fiber, polyamide-imide fiber and combinations thereof, mixture and blending.Preferred real
In applying mode, yarn also Bao Han polyoxadiazole fibers.
In a preferred embodiment, synthetic fibers be selected from Fypro, polyester fiber, meta-aramid fibre,
Modified polyacrylonitrile (modacrylic) fiber, polyoxadiazole fibers, acrylic fiber, vinal and they
Mixture.
These other synthetic fibers can be present in yarn with any suitable amount.When they are present in yarn, this
A little other synthetic fibers preferably exist with following amount：About 0.1wt% or more based on total weight of fibers present in yarn, about
0.5wt% or more, about 1wt% or more, about 2wt% or more, about 3wt% or more, about 4wt% or more, about 5wt% or more
Many, about 6wt% or more, about 7wt% or more, about 8wt% or more, about 9wt% or more or about 10wt% or more.When it
When being present in yarn, these other synthetic fibers preferably exist with following amount：Based on total weight of fibers present in yarn
About 40wt% or less, about 35wt% or less, about 30wt% or less, about 25wt% or less or about 20wt% or less.Cause
This, in series of preferred embodiments, these other synthetic fibers exist with following amount：It is total based on fiber present in yarn
The about 0.1wt% to about 30wt% of weight is (for example, about 0.5wt% to about 30wt%, about 1wt% are to about 30wt% or about 5wt% to about
30wt%) or about 5wt% to about 25wt% (for example, about 5wt% to about 20wt%).Certainly, the optimum weight of other synthetic fibers will
The particular type of other synthetic fibers being at least partially dependent on included in yarn.Thus, for example, when other synthetic fibers are
During Fypro, the Fypro is preferably present in yarn with following amount：About 5wt% based on total weight of fibers in yarn
To about 20wt% or about 5wt% to about 15wt% (for example, about 10wt%).In another example, such as when other synthetic fibers
During Shi polyoxadiazole fibers, the polyoxadiazole fibers are preferably present in yarn with following amount：Based on total weight of fibers in yarn
About 5wt% to about 25wt% or about 10wt% to about 20wt% (for example, about 15wt%).
In another embodiment, the invention provides the textile material comprising the above-mentioned yarn of multiply.It is of the invention
Textile material can have any suitable structure.In other words, the yarn for forming the textile material can produce fabric
Any suitable pattern spread configuration.Preferably, textile material with machine-knitted structure set, such as plain weave, matted weave,
Twill-weave, satin weave or sateen tissue.Suitable plain weave includes but is not limited to obtained anti-in the following way
Rupture (ripstop) tissue：In forming process, in the warp-wise, broadwise or warp-wise and broadwise in the textile material with
Fixed intervals introduce extra yarn or enhancing yarn.Suitable twill-weave is included through face and twilled warp-back cloth, such as 2/
1st, 3/1,3/2,4/1,1/2,1/3 or 1/4 twill-weave.
Textile material of the invention can be provided with any suitable weight (that is, the weight of per unit area).Textile
The approrpiate wts of material will depend on a number of factors, and such as textile material will be supplied to the required degree of protection of wearer.Under
The preferred instruction of weight range that face is provided has carried out any treatment (such as chemical treatment and/or machine on textile material
Tool treatment) after textile material weight.Preferably, textile material shows following weight：About 135g/m2Or more,
About 140g/m2Or more, about 145g/m2Or more, about 150g/m2Or more, about 155g/m2Or more, about 160g/m2Or more
Many, about 165g/m2Or more, about 170g/m2Or more, about 175g/m2Or more, about 180g/m2Or more or about 185g/m2
Or more.Preferably, textile material shows following weight：About 305g/m2Or less, about 300g/m2Or less, about 295g/m2
Or less, about 290g/m2Or less, about 285g/m2Or less, about 280g/m2Or less, about 275g/m2Or less, about 270g/
m2Or less, about 265g/m2Or less, about 260g/m2Or less or about 255g/m2Or it is less.Therefore, a series of preferred
In implementation method, textile material shows following weight：About 135g/m2To about 305g/m2Or about 170g/m2To about 255g/
m2。
Further to improve the feel of textile material, the textile material optionally uses one or more stem-winder
Face processes to process.Mechanical surface treatment generally makes to assign stress relaxation, the destruction of fabric in solidification and fabric process
The tearing resistance of fabric of the yarn knot and raising for being formed in the curing process through processing.The example of suitable mechanical surface treatment
Attached bag is included and processed with high pressure air flow or current (such as in United States Patent (USP) 4,918,795, the and of United States Patent (USP) 5,033,143
Those described in United States Patent (USP) 6,546,605), processed with steam jet, acupuncture, microparticle bombardment, spray ice (ice-
Blasting), roller reversion, granite-wash, the contraction by nozzle and with mechanical oscillation, sharp bend, shearing or compression processed.
One or more in the alternative above-mentioned technique of shrink-proof process uses feel to improve fabric and control to knit outside it
The contraction of thing.Can be used to be at the other machinery that assign flexibility and can also be carried out before shrink-proof process through the fabric for the treatment of
Reason includes brushing, brushing is carried out with the brushing line for being covered with diamond, carrying out pattern mill without particle frosted, to the surface with embossment
Sand, bead, sandblasting, scrub, immersion brush roll, sonic oscillation, napping, engraving or pattern roller denude and relative to or use it
Its material (such as identical or different fabric, abrasion matrix, steel wool, Buddha's warrior attendant sand roller, tungsten carbide roller, etching or scar or
Sand paper roller) impact.
Believe that textile material of the invention is shown to scintillation and the dangerous good protection of arc-flash.It is therefore believed that
The textile material is particularly suitable for manufacturing protective garment, is such as in the industry being exposed under scintillation and arc-flash danger
Workman worn those.When according to entitled " Standard Test Method for Flame Resistance of
When the ASTM D6413 of Textiles (vertical test) " are detected, textile material of the invention typically show extremely short
Char length and without afterflame.Typical char length shown by the textile material is for about 1 inch (2.5cm) to about
2.5 inches (6.4cm), this represents the textile material or even mechanical strength relatively high is still shown after flame is exposed to.
Further, since relatively high with the intensity of fiber under moisture state drying, the textile material is resistant to repeated
Family and/or industrial washing.This with the textile material being made of conventional viscose glue or FR viscose glues conversely, the latter's fiber have compared with
Low intensity and produce the display textile material relatively low to the durability of repeated washing.Except mechanical endurance it
Outward, the fire-resistance property of textile material also has durability to repeated washing.For example, textile material of the invention typically (and
And preferably) show that above-mentioned fire resisting is special after repeatedly (for example, 50 times or more, or 100 times) family and/or industrial washing
Property.
In another series of embodiments, the invention provides the clothes comprising one or more fabric.Described one
The mode that block or polylith fabric can surround internal volume engages (for example, sewing) together, and the internal volume is intended to
Occupied by wearer or wearer at least a portion anatomically.The suitable example of this clothes includes but is not limited to lining
Shirt, jacket, vest, trousers, blouse, coverall, hood and gloves.Or alternatively, the clothes need not be configured to
It is set to surround inner space.But, it is his or her that the clothes can be configured such that wearer can be fixedly secured to
So that it covers and protects at least a portion of his or she body on body.The suitable example of this clothes includes but is not limited to enclose
Skirt, bib, legging and spats.
In the embodiment of the invention, at least one piece fabric of the clothes includes weaving recited above
Product material (that is, including the textile material of multiply yarn recited above).Preferably, if the clothes include polylith fabric
Fabric, then all fabrics are comprising textile material recited above.In specific clothes implementation method, the clothes
It is the shirt for including polylith fabric.At least one piece in the fabric body covering part for defining shirt, and fabric
At least two pieces in fabric define the coat-sleeve being connected with the body covering part of the shirt.As described above, the shirt
At least one piece fabric includes textile material recited above.In the another embodiment of this shirt, institute
It is the trousers for including polylith fabric to state clothes.At least two pieces in the fabric leg covering parts for defining trousers.
As described above, at least one piece in the fabric includes textile material recited above.
In another embodiment, it is individual red from what can be produced during arc-flash the invention provides protection
The method of external radiation.In this embodiment, the described method comprises the following steps：Textile material is placed in individual and can
Between the equipment of generation arc-flash.The textile material is preferably textile material of the invention (that is, including multiply
The textile material of above-mentioned yarn).
In this method implementation method of the invention, what the textile material can be placed between individuality and equipment appoints
What appropriate point.However, to ensure that textile material is placed as providing farthest protection, the textile material to individuality
It is preferably formed as by the clothing section of the individual dress.Suitable clothes include but is not limited to shirt, trousers, jacket, hood, enclose
Skirt and gloves.In a preferred embodiment, by the textile part on the outside of the direction of the clothes of individual dress (that is, when the clothes
Those clothing sections of ancillary equipment when being worn by individuality) it is basic by (or even more preferably by) weaving of the invention
Product material is constituted.
Methods described above can be used to protect individuality from the arc-flash produced by any equipment.Typically, it is described
Equipment is electrical equipment part.Preferably, the equipment can be produced with about 1.2 calories/cm at individual present position2Or
More (about 5J/cm2Or more) incident energy arc-flash.It is highly preferred that the equipment can be at individual present position
Producing has about 4 calories/cm2Or more (about 17J/cm2Or more) incident energy arc-flash.The equipment preferably can
Enough generation at individual present position has about 8 calories/cm2Or more (about 33J/cm2Or more) incident energy electric arc dodge
Light.Arc-flash with such as those above incident energy is (especially with about 4 calories/cm2Or more or about
8 calories/cm2Or more incident energy arc-flash) can be to being exposed to the individual unprotected of the arc-flash or protecting
Not enough skin is protected to cause significantly to injure (for example, second-degree burn).
It is protection individual from such as 25 calories/cm2(105J/cm2) to 60 calories/cm2(250J/cm2) high energy
Amount arc-flash exposes to the open air, and multilayer textile material as described above can be used, or the textile material can be with other weavings
Product material or insulating barrier are applied in combination.For example, in such implementation method, textile material recited above can by with
Make outer layer, and other arc protection changeants and/or insulating materials are then below the textile material (that is, in textile material
And wearer between).In such implementation method, it is believed that anti-destructive high (the high break- of textile material of the present invention
Open resistance) following sandwich construction will be provided：The arc-flash that it provides required level is protected and is being exposed to
Its mechanical integrity is kept after arc-flash or flame.
Following examples further illustrate theme recited above, but are not necessarily to be construed as limiting by any way certainly
Its scope.
Embodiment 1
This method demonstrates the production of yarn of the invention and textile material.Using ring spinning processes be spun into containing
The uniform fiber of about 70wt% Lyocell fibres, about 20wt% para-aramids fiber and about 10wt% nylon 6,6 fibers is mixed
Thing is spun yarn is obtained.Then by gained yarn, for producing sateen tissue fabric, (yarn is used as the woven fabric simultaneously
Warp thread and weft yarn).By textile dyeing and arrangement be added to inside Lyocell fibre with by phosphor-containing flame-proof compound.Gained is knitted
The weight of thing is about 5.6oz/yd2(190g/m2)。
Then gained fabric is detected to determine its fire-resistance property.The fabric shows about 1.4 in warp-wise and broadwise
The char length of inch (3.6cm).By the fabric according to ASTM F1959-" Standard Test Method for
Determining the Arc Thermal Performance Value of Materials for Clothing " are carried out
Test.The fabric shows about 14.3 calories/cm2(59.8J/cm2) destruction threshold energy (Ebt).Through comparing, with commercially available ammonia process
The 5.5oz/yd of fire retardant treatment2(190g/m2) 88wt% cottons/12wt% RIPSTOPs are reported with about 10 calories/cm2
(40J/cm2) destruction threshold energy, and 6oz/yd2(200g/m2) nomex fabric is reported with about 13 calories/cm2
(54J/cm2) destruction threshold energy.
Embodiment 2
This method demonstrates the production of yarn of the invention and textile material.Using ring spinning processes be spun into containing
The uniform fiber of about 75wt% Lyocell fibres, about 15wt% para-aramids fiber and about 10wt% polyoxadiazole fibers
Blend is being made yarn.Then by gained yarn, for producing sateen tissue fabric, (yarn is used as the woven fabric simultaneously
Warp thread and weft yarn).By textile dyeing and arrangement be added to inside Lyocell fibre with by phosphor-containing flame-proof compound.Gained
The weight of fabric is about 7.2oz/yd2(240g/m2)。
Then gained fabric is detected to determine its fire-resistance property.The fabric shows about 1.2 in warp-wise and broadwise
The char length of inch (3cm).It is being exposed to 2 calories/cm2Second (8.4J/cm2Second) flame after 10 seconds, the fabric
Maintain good flexibility and mechanical integrity.Believe that the fabric is suitable in arc-flash and scintillation protection clothes, at these
It is required that resistance is exposed to the destruction caused after the heat energy high from flame and electric arc in protective garment.
Embodiment 3
This method demonstrates the production of yarn of the invention and textile material.In following uniform fiber blend
High intensity Lyocell fibre of the middle use containing phosphor-containing flame-proof compound：About 70wt% Lyocell fibres, about 20wt%
Para-aramid fiber and about 10wt% polyoxadiazole fibers.The intimate blend fiber is made into ring spinning yarn, and the yarn
Line is woven to twill-weave fabric (yarn is used as the warp thread and weft yarn of the woven fabric simultaneously).Then fabric is rinsed,
Dyeing and arrangement.The fabric can be made into weight for about 5.6oz/yd2(190g/m2) and about 7.5oz/yd2(250g/m2).Expect
These fabrics show good flexibility and mechanical integrity after high energy arc and/or flame is exposed to.
All documents incorporated herein, including public publication, patent application and patent are incorporated by reference into, its journey
Degree is individually and specifically shown to be incorporated by reference into and overall statement together such as every document.
Unless shown in addition herein or within a context clearly conversely, in the context of description subject matter
The use of (especially in the context of the claim below) term "// a kind of " and " described/to be somebody's turn to do " is interpreted
Cover odd number and plural number simultaneously.Unless otherwise stated, term "comprising", " having ", " including " and " containing " be interpreted open
Formula term (that is, is represented " including but not limited to ").Unless shown in addition herein, it is intended merely to when addressing number range herein
As be independently related to fall into the range of this each individually value write a Chinese character in simplified form anti-loud, high-pitched sound hair, and each independent value is each added to explanation
In book, as it by independently addressing herein.Unless shown in addition herein or clear and definite phase within a context
Instead, all methods described herein can be implemented in any suitable order.Unless the context requires otherwise, it is provided in this article any and all
The use of example or exemplary language (for example, " such as ") is intended merely to preferably explain the theme of application, and will not be to theme
Scope make any limitation.Not having any language in specification should be interpreted to show any unasked key element to implementing
It is important for theme described herein.
It is described herein the preferred embodiment of subject matter, including known for inventor implements claimed
Theme best mode.When specification above is read, the variant of those preferred embodiments is to those skilled in the art
For can become obvious.Inventor is expected those skilled in the art can rightly use this variant, and inventor to be expected
Theme described herein can be implemented in the specific different mode of the person herein.Therefore, present disclosure includes applicable law institute
The all modifications and the equivalent form of value of theme described in this paper appended claims allowed.In addition, unless table in addition herein
It is bright or clear and definite conversely, any combination of its above-mentioned key element being possible in variant can covered in the disclosure within a context
In content.
Claims (41)
1. yarn, including：
A the regenerated celulose fibre of () 45wt% to 85wt%, the regenerated celulose fibre has 27cN/tex or higher
Dry strength, the regenerated celulose fibre is included in the intrastitial flame-retardant compound；With
The para-aramid fiber of (b) 5wt% to 25wt%,
Wherein described flame-retardant compound is by making (i) four methylol phosphonium salt, four methylol phosphonium salt condensation products or theirs is mixed
The phosphor-containing flame-proof compound that compound is prepared with the reaction of (ii) crosslinking agent.
2. yarn as claimed in claim 1, wherein the regenerated celulose fibre and the para-aramid fiber are short
Fiber, and intimate blend in the yarn.
3. yarn as claimed in claim 1, wherein the wet strength of the regenerated celulose fibre is 20cN/tex or higher.
4. yarn as claimed in claim 1, wherein the regenerated celulose fibre is selected from viscose rayon, Lyocell fibre
And their mixture.
5. yarn as claimed in claim 1, wherein the regenerated celulose fibre is Lyocell fibre.
6. yarn as claimed in claim 1, wherein the regenerated celulose fibre accounts for 65wt% to the 85wt% of the yarn.
7. yarn as claimed in claim 1, wherein the 15wt% that the para-aramid fiber accounts for the yarn is arrived
25wt%.
8. yarn as claimed in claim 1, wherein the yarn includes other synthetic fibers.
9. yarn as claimed in claim 8, wherein the synthetic fibers are selected from Fypro, polyester fiber, meta aromatics
Fypro, modified acrylic fibre, polyoxadiazole fibers, acrylic fiber, vinal and they
Mixture.
10. yarn as claimed in claim 8, wherein described other synthetic fibers account for 0.1wt% to the 30wt% of the yarn.
11. textile materials comprising multi-strand yarns, the yarn includes：
A the regenerated celulose fibre of () 45wt% to 85wt%, the regenerated celulose fibre has 27cN/tex or higher
Dry strength, the regenerated celulose fibre is included in the intrastitial flame-retardant compound；With
The para-aramid fiber of (b) 5wt% to 25wt%,
Wherein described flame-retardant compound is by making (i) four methylol phosphonium salt, four methylol phosphonium salt condensation products or theirs is mixed
The phosphor-containing flame-proof compound that compound is prepared with the reaction of (ii) crosslinking agent.
12. textile materials as claimed in claim 11, wherein the regenerated celulose fibre and the para-aramid
Fiber is chopped fiber, and the intimate blend in the yarn.
13. textile materials as claimed in claim 11, wherein the wet strength of the regenerated celulose fibre is 20cN/tex
Or it is higher.
14. textile materials as claimed in claim 11, wherein the regenerated celulose fibre is selected from viscose rayon, solvent-spun fibre
Cellulose fiber and their mixture.
15. textile materials as claimed in claim 11, wherein the regenerated celulose fibre is Lyocell fibre.
16. textile materials as claimed in claim 11, wherein the regenerated celulose fibre accounts for the 65wt% of the yarn
To 85wt%.
17. textile materials as claimed in claim 11, wherein the para-aramid fiber accounts for the yarn
15wt% to 25wt%.
18. textile materials as claimed in claim 11, wherein the yarn includes other synthetic fibers.
19. textile materials as claimed in claim 18, wherein the synthetic fibers be selected from Fypro, polyester fiber,
Meta-aramid fiber, modified acrylic fibre, polyoxadiazole fibers, acrylic fiber, vinal
And their mixture.
20. textile materials as claimed in claim 18, wherein the 0.1wt% that described other synthetic fibers account for the yarn is arrived
30wt%.
21. textile materials as claimed in claim 11, wherein the textile material is Woven textiles material.
22. textile materials as claimed in claim 21, wherein the multi-strand yarns are weaved with twill pattern.
23. textile materials as claimed in claim 11, wherein the weight of the textile material is 135g/m2To 305g/
m2。
24. textile materials as claimed in claim 23, wherein the weight of the textile material is 170g/m2To 255g/
m2。
25. clothes for including one or more fabric, at least one piece in the fabric includes multi-strand yarns, described
Yarn includes：
A the regenerated celulose fibre of () 45wt% to 85wt%, the regenerated celulose fibre has 27cN/tex or higher
Dry strength, the regenerated celulose fibre is included in the intrastitial flame-retardant compound；With
The para-aramid fiber of (b) 5wt% to 25wt%,
Wherein described flame-retardant compound is by making (i) four methylol phosphonium salt, four methylol phosphonium salt condensation products or theirs is mixed
The phosphor-containing flame-proof compound that compound is prepared with the reaction of (ii) crosslinking agent.
26. clothes as claimed in claim 25, wherein the regenerated celulose fibre and the para-aramid fiber are
Chopped fiber, and the intimate blend in the yarn.
27. clothes as claimed in claim 25, wherein the wet strength of the regenerated celulose fibre is 20cN/tex or higher.
28. clothes as claimed in claim 25, wherein the regenerated celulose fibre is selected from viscose rayon, solvent-spun cellulose fibre
Dimension and their mixture.
29. clothes as claimed in claim 28, wherein the regenerated celulose fibre is Lyocell fibre.
30. clothes as claimed in claim 25, wherein the 65wt% that the regenerated celulose fibre accounts for the yarn is arrived
85wt%.
31. clothes as claimed in claim 25, wherein the 15wt% that the para-aramid fiber accounts for the yarn is arrived
25wt%.
32. clothes as claimed in claim 25, wherein the yarn includes other synthetic fibers.
33. clothes as claimed in claim 32, wherein the synthetic fibers are selected from Fypro, polyester fiber, meta-virtue
Polyamide fiber, modified acrylic fibre, polyoxadiazole fibers, acrylic fiber, vinal and it
Mixture.
34. clothes as claimed in claim 33, wherein the 0.1wt% that described other synthetic fibers account for the yarn is arrived
30wt%.
35. clothes as claimed in claim 25, wherein the fabric is Woven textiles material.
36. clothes as claimed in claim 35, wherein the multi-strand yarns are weaved with twill pattern.
37. clothes as claimed in claim 25, wherein the weight of the fabric is 135g/m2To 305g/m2。
38. clothes as claimed in claim 37, wherein the weight of the fabric is 170g/m2To 255g/m2。
39. shirts for including polylith fabric, at least one piece body for defining the shirt in the fabric covers
At least two pieces in cover and the fabric define the coat-sleeve being connected with the body covering part of the shirt, described
At least one piece in fabric includes multi-strand yarns, and the yarn includes：
A the regenerated celulose fibre of () 45wt% to 85wt%, the regenerated celulose fibre has 27cN/tex or higher
Dry strength, the regenerated celulose fibre is included in the intrastitial flame-retardant compound；With
The para-aramid fiber of (b) 5wt% to 25wt%,
Wherein described flame-retardant compound is by making (i) four methylol phosphonium salt, four methylol phosphonium salt condensation products or theirs is mixed
The phosphor-containing flame-proof compound that compound is prepared with the reaction of (ii) crosslinking agent.
40. trousers for including polylith fabric, at least two pieces legs for defining the trousers in the fabric are covered
Cover, at least one piece in the fabric includes multi-strand yarns, and the yarn includes：
A the regenerated celulose fibre of () 45wt% to 85wt%, the regenerated celulose fibre has 27cN/tex or higher
Dry strength, the regenerated celulose fibre is included in the intrastitial flame-retardant compound；With
The para-aramid fiber of (b) 5wt% to 25wt%,
Wherein described flame-retardant compound is by making (i) four methylol phosphonium salt, four methylol phosphonium salt condensation products or theirs is mixed
The phosphor-containing flame-proof compound that compound is prepared with the reaction of (ii) crosslinking agent.
The method of the 41. individual infra-red radiations from being produced during arc-flash of protection, the described method comprises the following steps：Will
Textile material is placed between equipment that is individual and can producing arc-flash, and the textile material includes multi-strand yarns, institute
Stating yarn includes：
A the regenerated celulose fibre of () 45wt% to 85wt%, the regenerated celulose fibre has 27cN/tex or higher
Dry strength, the regenerated celulose fibre is included in the intrastitial flame-retardant compound；With
The para-aramid fiber of (b) 5wt% to 25wt%,
Wherein described flame-retardant compound is by making (i) four methylol phosphonium salt, four methylol phosphonium salt condensation products or theirs is mixed
The phosphor-containing flame-proof compound that compound is prepared with the reaction of (ii) crosslinking agent.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201261701270P | 2012-09-14 | 2012-09-14 | |
| US61/701,270 | 2012-09-14 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103668619A CN103668619A (en) | 2014-03-26 |
| CN103668619B true CN103668619B (en) | 2017-06-09 |
Family
ID=49223898
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310296070.1A Active CN103668619B (en) | 2012-09-14 | 2013-07-15 | Yarn, textile material and the clothes containing it |
Country Status (6)
| Country | Link |
|---|---|
| US (2) | US20140075659A1 (en) |
| CN (1) | CN103668619B (en) |
| BR (1) | BR112015005463A2 (en) |
| CA (1) | CA2882854A1 (en) |
| MX (1) | MX356878B (en) |
| WO (1) | WO2014043097A2 (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US9920474B2 (en) * | 2013-03-13 | 2018-03-20 | Milliken & Company | Flame-resistant fiber blend, yarn, and fabric, and method for making same |
| US20150329997A1 (en) * | 2014-05-15 | 2015-11-19 | Stephen Switzer | Antimicrobial fire-retardant yarn and method of manufacturing same |
| CN104674416A (en) * | 2015-03-06 | 2015-06-03 | 陕西元丰纺织技术研究有限公司 | Preparation method for modified acrylic fiber flame-retardant fabric |
| WO2016194766A1 (en) * | 2015-06-01 | 2016-12-08 | 株式会社カネカ | Flame-retardant fabric and protective clothing in which same is used |
| US20170159214A1 (en) * | 2015-12-02 | 2017-06-08 | L.S. Mills Limited | Lyocell-Polyester Fabric and Methods of Manufacture |
| CN106400266A (en) * | 2016-08-25 | 2017-02-15 | 康帝雅高档面料（苏州）有限公司 | Multi-component low-cost permanent inflaming retarding fabric and preparation method for same |
| CN106835841B (en) * | 2016-12-30 | 2019-01-29 | 赣州华劲纸业有限公司 | A kind of manufacturing method of fuzzy hand paper for daily use |
| AU2018346452B2 (en) * | 2017-10-06 | 2020-10-15 | Lenzing Aktiengesellschaft | Flame retardant Lyocell filament |
| CA3127070A1 (en) * | 2019-01-16 | 2020-07-23 | Hologenix, Llc | Cellulose and semi-cellulose based fibers and yarns embedded with mineral particles and methods of making the same |
| CN110042565A (en) * | 2019-04-26 | 2019-07-23 | 中科国联劳动防护技术研究院(北京)有限公司 | A kind of fire-retardant arc protection blend based on fire extinguishing type fire-retardant regenerated cellulose fiber |
| CA3141479A1 (en) | 2019-05-24 | 2020-12-03 | Southern Mills, Inc. | Flame resistant finished fabrics exhibiting water repellency and methods for making the same |
| US12104291B1 (en) * | 2020-12-02 | 2024-10-01 | Kaneka Corporation | Flame-retardant fabric and protective clothing made of the same |
| US11761124B1 (en) | 2021-09-09 | 2023-09-19 | Milliken & Company | Elastic flame-resistant fabric |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5690874A (en) * | 1993-05-11 | 1997-11-25 | Courtaulds Fibres (Holdings) Limited | Fiber production process |
| CN102482800A (en) * | 2009-09-01 | 2012-05-30 | 连津格股份公司 | Fire-retardant cellulose fiber, use thereof, and method for the production thereof |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US8898821B2 (en) * | 2009-05-19 | 2014-12-02 | Southern Mills, Inc. | Flame resistant fabric with anisotropic properties |
| AT511288B1 (en) * | 2010-11-24 | 2013-01-15 | Chemiefaser Lenzing Ag | Flame resistant fabric for protective clothing |
| US20130045653A1 (en) * | 2011-01-27 | 2013-02-21 | Sabic Innovative Plastics Ip B.V. | Protective suit fabric and spun yarn used for the same |
-
2013
- 2013-07-15 CN CN201310296070.1A patent/CN103668619B/en active Active
- 2013-09-10 US US14/022,883 patent/US20140075659A1/en not_active Abandoned
- 2013-09-10 MX MX2015003025A patent/MX356878B/en active IP Right Grant
- 2013-09-10 BR BR112015005463A patent/BR112015005463A2/en not_active IP Right Cessation
- 2013-09-10 CA CA2882854A patent/CA2882854A1/en not_active Abandoned
- 2013-09-10 WO PCT/US2013/058973 patent/WO2014043097A2/en active Application Filing
-
2019
- 2019-11-21 US US16/691,084 patent/US20200085122A1/en not_active Abandoned
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5690874A (en) * | 1993-05-11 | 1997-11-25 | Courtaulds Fibres (Holdings) Limited | Fiber production process |
| CN102482800A (en) * | 2009-09-01 | 2012-05-30 | 连津格股份公司 | Fire-retardant cellulose fiber, use thereof, and method for the production thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| US20140075659A1 (en) | 2014-03-20 |
| CN103668619A (en) | 2014-03-26 |
| CA2882854A1 (en) | 2014-03-20 |
| US20200085122A1 (en) | 2020-03-19 |
| MX356878B (en) | 2018-06-19 |
| BR112015005463A2 (en) | 2017-07-04 |
| WO2014043097A3 (en) | 2014-05-08 |
| WO2014043097A2 (en) | 2014-03-20 |
| MX2015003025A (en) | 2015-06-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103668619B (en) | Yarn, textile material and the clothes containing it | |
| JP6505798B2 (en) | Flame retardant fabric with improved surface abrasion resistance or pilling resistance and method of making them | |
| JP6388659B2 (en) | Fabrics and textile products | |
| KR102041835B1 (en) | Fiber blends, yarns, fabrics, and garments for arc and flame protection | |
| US10450679B2 (en) | Flame-retardant fabric, method for producing same and fireprotective clothes comprising same | |
| CA2798457C (en) | Flame resistant textile materials | |
| JP6839999B2 (en) | Textiles and textiles | |
| BR112015028571B1 (en) | CLOTH | |
| JP6975531B2 (en) | Fabrics and textiles | |
| JP2018021275A (en) | Laminated cloth and fiber product | |
| JP6832742B2 (en) | Fiber products | |
| AU2019293146B2 (en) | Fire-resistant cabled yarn and textile | |
| KR20170104539A (en) | Flame retardant fabrics | |
| JP6185302B2 (en) | Fabrics and textile products | |
| CN115210421A (en) | Flame resistant fabrics formed from long staple yarns and filament yarns | |
| JP6934226B2 (en) | Anti-wear cloth and clothing for clothing | |
| KR101460939B1 (en) | Flame-resistant fabrics comprising Cotton/Polyester mixed yarn and method for manufacturing thereof | |
| JP6666129B2 (en) | Fabrics and textile products | |
| JP2020026598A (en) | Fabric and protection product | |
| KR20230155116A (en) | A fireproof wristlet and manufacturing method thereof | |
| JP2022045049A (en) | Fabric and protective equipment | |
| JP2015229805A (en) | Fabric and textiles | |
| JP2021181646A (en) | Fabric and textile product | |
| BR122023008956B1 (en) | FLAME RESISTANT FABRICS THAT EXHIBIT WATER REPELLENCE |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |