CN103666674A - Cold rolling lubricant for antimony and antimony alloy plate strip - Google Patents
Cold rolling lubricant for antimony and antimony alloy plate strip Download PDFInfo
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- CN103666674A CN103666674A CN201310585171.0A CN201310585171A CN103666674A CN 103666674 A CN103666674 A CN 103666674A CN 201310585171 A CN201310585171 A CN 201310585171A CN 103666674 A CN103666674 A CN 103666674A
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Abstract
The invention discloses a cold rolling lubricant for antimony and an antimony alloy plate strip. No. 32 oil for a total loss system is used as basic oil and multiple composite additives are mixed with the basic oil, wherein the composite additives include an anti-wear agent, an oily agent, an oxidation and corrosion prevention agent, an antioxidant, an anti-foaming agent, an auxiliary, a dispersant, a friction improver and the like. The cold rolling lubricant for the antimony and the antimony alloy plate strip can effectively perform lubricating, cleaning, cooling and reduce the phenomena of adherence between rollers and rolled pieces, so that the damage caused by adhesion of the surface of the plate strip is reduced.
Description
Technical field
The invention belongs to antimony and alloy plate strip cold-rolling lubricant field thereof.
Background technology
Antimony, silvery white is glossy hard and crisp metal.There is flakey crystalline structure.In damp atmosphere, tarnish gradually, heat-flash burns into the oxide compound of white antimony.Antimony is electricity and hot poor conductor, not oxidizable at normal temperatures, has corrosion resistance.Therefore, the Main Function of antimony in alloy is to increase hardness, is often called as the stiffening agent of metal or alloy.After the antimony that additional proportion does not wait in metal, the hardness of metal will strengthen, and can be used for manufacturing munitions, so antimony is called as strategy metal.First antimony and antimony compounds are used in wear resistant alloy, printing type metal and munitions industry, are important strategic materials.Along with scientific and technical development, antimony has been widely used in producing department's products such as various fire retardants, enamel, glass, rubber, coating, pigment, pottery, plastics, semiconductor element, fireworks, medicine and chemical industry now.
Antimony matter is hard and crisp, easily pulverizes, glossy, nil ductility and malleability.Alloy containing antimony, lead is corrosion-resistant, is the preferred material of producing battery plate, chemical pipeline, cable sheathing; The alloy strength of antimony and tin, lead, copper is high, extremely wear-resisting, is the good material of manufacturing bearing, gear, and the mixture of high purity antimony and other metal (as silver-colored antimony, gallium antimony) is the ideal material of producing semi-conductor and electric heating device.
Summary of the invention
The technical problem to be solved in the present invention is to provide and a kind ofly can be effectively lubricated, cleaning, cooling and reduce antimony and the alloy plate strip cold-rolling lubricant thereof that roll and rolled piece adherent phenomenon, minimizing strip surface adhering cause damage.
The present invention is usingd following technical scheme and is solved the problems of the technologies described above: adopt No. 32 total loss systems with oil as base oil, coordinate multiple composite additive, its each component and mass percent thereof are:
| Component | Content (mass percent) |
| Base oil | Surplus |
| Anti-wear agent | 4.0%～5.0% |
| Oiliness improver | 5.0%～8.0% |
| Antioxidant preservative | 0.5%～1.0% |
| Kilfoam | 0.001%～0.003% |
| Oxidation inhibitor | 0.3%～0.5% |
| Auxiliary agent | 3.0%～4.0% |
| Dispersion agent | 2.0%～3.0% |
| Friction improver | 3.0%～5.0% |
Base oil is No. 32 oil for total loss system.
Anti-wear agent is dibutyl dithiocaarbamate antimony.
Oiliness improver is that Methyl palmitoleinate and 60%～50% the hexadecanol of mass ratio 40%～50% is compound.
Antioxidant preservative is sulphur phosphorus fourth octyl group zinc salt.
Kilfoam is dimethyl silicone oil.
Oxidation inhibitor is that 2,6 ditertiary butyl p cresol and 40%～50% the 124 Triazole derivative of mass ratio 60%～50% is compound.
Auxiliary agent is Microcrystalline Wax.
Dispersion agent is polyisobutene succinimide.
Friction improver is oleic acid oxalic acid ester.
Antimony of the present invention and alloy plate strip cold-rolling lubricant thereof, adopt No. 32 total loss systems to use oil as base oil, coordinates multiple composite additive.Comprise anti-wear agent, oiliness improver, antioxidant preservative, oxidation inhibitor, kilfoam, auxiliary agent, dispersion agent, friction improver etc.This lubricant can effectively be lubricated, cleaning, cooling and reduce roll and rolled piece adherent phenomenon, the damage that minimizing strip surface adhering causes.
Embodiment
Embodiment 1:
Following component is in harmonious proportion and is formed by mass percentage:
| Component | Content (mass percent) |
| No. 32 oil for total loss system | 74.0% |
| Dibutyl dithiocaarbamate antimony | 5.0% |
| The Methyl palmitoleinate of mass ratio 40% and 60% hexadecanol are compound | 8.0% |
| Sulphur phosphorus fourth octyl group zinc salt | 0.5% |
| Dimethyl silicone oil | 0.003% |
| The 2,6 ditertiary butyl p cresol of mass ratio 60% and 40% 124 Triazole derivative are compound | 0.497% |
| Microcrystalline Wax | 4.0% |
| Polyisobutene succinimide | 3.0% |
| Oleic acid oxalic acid ester | 5.0% |
Above component summation is 100%.
Embodiment 2:
Following component is in harmonious proportion and is formed by mass percentage:
| Component | Content (mass percent) |
| No. 32 oil for total loss system | 78.0% |
| Dibutyl dithiocaarbamate antimony | 4.5% |
| The Methyl palmitoleinate of mass ratio 45% and 55% hexadecanol are compound | 6.5% |
| Sulphur phosphorus fourth octyl group zinc salt | 0.6% |
| Dimethyl silicone oil | 0.002% |
| The 2,6 ditertiary butyl p cresol of mass ratio 55% and 45% 124 Triazole derivative are compound | 0.398% |
| Microcrystalline Wax | 3.5% |
| Polyisobutene succinimide | 2.5% |
| Oleic acid oxalic acid ester | 4.0% |
Above component summation is 100%.
Embodiment 3:
Following component is in harmonious proportion and is formed by mass percentage:
| Component | Content (mass percent) |
| No. 32 oil for total loss system | 82.0% |
| Dibutyl dithiocaarbamate antimony | 4.0% |
| The Methyl palmitoleinate of mass ratio 50% and 50% hexadecanol are compound | 5.0% |
| Sulphur phosphorus fourth octyl group zinc salt | 0.7% |
| Dimethyl silicone oil | 0.001% |
| The 2,6 ditertiary butyl p cresol of mass ratio 50% and 50% 124 Triazole derivative are compound | 0.299% |
| Microcrystalline Wax | 3.0% |
| Polyisobutene succinimide | 2.0% |
| Oleic acid oxalic acid ester | 3.0% |
Above component summation is 100%.
Below the main physical and chemical index of embodiment 1 product:
| Project | Quality index |
| Moisture, % is not more than | Vestige |
| 40 ℃ of kinematic viscosity mm 2/s | 31.2 |
| Flash-point (opening) ℃, is greater than | 160 |
| Mechanical impurity, % is not more than | Nothing |
| Last non seizure load (Pb), Kg is not less than | 90 |
| Pour point, ℃, not higher than | -10 |
| Water soluble acid or alkali | Nothing |
| Corrosion test (copper sheet, 100 ℃, 3h), level | 1 |
| Viscosity index, is not less than | 90 |
Claims (10)
1. antimony and an alloy plate strip cold-rolling lubricant thereof, is characterized in that adopting No. 32 total loss systems as base oil, to coordinate multiple composite additive with oily, and its each component and mass percent thereof are:
2. antimony as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that base oil is No. 32 oil for total loss system.
3. antimony as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that anti-wear agent is dibutyl dithiocaarbamate antimony.
4. antimony as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that oiliness improver is that Methyl palmitoleinate and 60%～50% the hexadecanol of mass ratio 40%～50% is compound.
5. antimony as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that antioxidant preservative is sulphur phosphorus fourth octyl group zinc salt.
6. antimony as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that kilfoam is dimethyl silicone oil.
7. antimony as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that oxidation inhibitor is that 2,6 ditertiary butyl p cresol and 40%～50% the 124 Triazole derivative of mass ratio 60%～50% is compound.
8. antimony as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that auxiliary agent is Microcrystalline Wax.
9. antimony as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that dispersion agent is polyisobutene succinimide.
10. antimony as claimed in claim 1 and alloy plate strip cold-rolling lubricant thereof, is characterized in that friction improver is oleic acid oxalic acid ester.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310585171.0A CN103666674B (en) | 2013-11-19 | 2013-11-19 | Cold rolling lubricant for antimony and antimony alloy plate strip |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310585171.0A CN103666674B (en) | 2013-11-19 | 2013-11-19 | Cold rolling lubricant for antimony and antimony alloy plate strip |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103666674A true CN103666674A (en) | 2014-03-26 |
| CN103666674B CN103666674B (en) | 2015-04-29 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310585171.0A Active CN103666674B (en) | 2013-11-19 | 2013-11-19 | Cold rolling lubricant for antimony and antimony alloy plate strip |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106544088A (en) * | 2016-11-04 | 2017-03-29 | 广西大学 | A kind of Kazakhstan C series alloy cold heading technique lubricant compositions |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004263087A (en) * | 2003-03-03 | 2004-09-24 | Kao Corp | Lubricating oil for use in hot rolling oil for aluminum plate |
| CN101705144A (en) * | 2009-11-20 | 2010-05-12 | 王恩臣 | Lubricating oil for methanol fuel engine and preparation method thereof |
| CN102229843A (en) * | 2011-05-30 | 2011-11-02 | 石家庄新泰特种油有限公司 | Aluminum rolling oil additive composition |
-
2013
- 2013-11-19 CN CN201310585171.0A patent/CN103666674B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2004263087A (en) * | 2003-03-03 | 2004-09-24 | Kao Corp | Lubricating oil for use in hot rolling oil for aluminum plate |
| CN101705144A (en) * | 2009-11-20 | 2010-05-12 | 王恩臣 | Lubricating oil for methanol fuel engine and preparation method thereof |
| CN102229843A (en) * | 2011-05-30 | 2011-11-02 | 石家庄新泰特种油有限公司 | Aluminum rolling oil additive composition |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106544088A (en) * | 2016-11-04 | 2017-03-29 | 广西大学 | A kind of Kazakhstan C series alloy cold heading technique lubricant compositions |
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| CN103666674B (en) | 2015-04-29 |
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