CN103665901A - Antibacterial wood-plastic composite material - Google Patents
Antibacterial wood-plastic composite material Download PDFInfo
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- CN103665901A CN103665901A CN201310532727.XA CN201310532727A CN103665901A CN 103665901 A CN103665901 A CN 103665901A CN 201310532727 A CN201310532727 A CN 201310532727A CN 103665901 A CN103665901 A CN 103665901A
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Abstract
The invention discloses an antibacterial wood-plastic composite material which is composed of the following raw materials in parts by weight: 50-60 parts of polyethylene resin particles, 70-80 parts of wood fiber, 6-8 parts of nano bauxite, 3-4 parts of tributyl citrate, 2-4 parts of methylisothiazolinone, 1-2 parts of zinc naphthenate, 2-3 parts of pentaerythritol, 1-2 parts of cetyl trimethyl ammonium bromide, 1-2 parts of aminopropyl triethoxysilane and 6-10 parts of a bonding aid. The antibacterial wood-plastic composite material disclosed by the invention is excellent in antibacterial property, moisture resistance and friction resistance, and the composite material disclosed by the invention can be sawed, planed and nailed and is good in processing performance, strong in dimension stability and wide in application range.
Description
Technical field
The present invention relates generally to a kind of matrix material, relates in particular to a kind of antimicrobial form wood plastic composite.
Background technology
Wood plastic composite is the class advanced composite material being in recent years surging forward both at home and abroad, refer to utilize polyethylene, polypropylene and polyvinyl chloride etc., replace common resin adhesive, be mixed into new wood materials with useless vegetable fibres such as surpassing more than 50% wood powder, rice husk, stalk, again through the plastic processings such as extruding, mold pressing, injection molding, the sheet material of producing or section bar.Be mainly used in the industries such as building materials, furniture, logistics packaging.Plastics and wooden powder are mixed to the sheet material by hot extrusion molding by a certain percentage, be referred to as to push wood-plastic composite panel.
Summary of the invention
The object of the invention is just to provide a kind of antimicrobial form wood plastic composite.
The present invention is achieved by the following technical solutions:
An antimicrobial form wood plastic composite, it is comprised of the raw material of following weight parts:
Polyvinyl resin particle 50-60, wood fibre 70-80, nano aluminum alumina 6-8, tributyl citrate 3-4, methylisothiazolinone 2-4, zinc naphthenate 1-2, tetramethylolmethane 2-3, cetyl trimethylammonium bromide 1-2, aminopropyltriethoxywerene werene 1-2, adhesive aid 6-10;
Described adhesive aid is comprised of the raw material of following weight parts:
Polyvinyl alcohol 15-20, hexamethoxymethyl melamine resin 3-4, polyamide wax micropowder 2-3, dialdehyde starch 4-5, Jojoba oil 1-2, anilinomethyl triethoxysilane 1-2;
Above-mentioned polyvinyl alcohol is joined in reactor, be heated to 70-80 ℃, add polyamide wax micropowder, insulation reaction 4-5 minute, reduction temperature is 50-60 ℃, adds hexamethoxymethyl melamine resin, anilinomethyl triethoxysilane, 600-700 rev/min of dispersed with stirring 10-15 minute, be cooled to normal temperature, add each raw material of residue, fully mixing obtains described adhesive aid.
A preparation method for antimicrobial form wood plastic composite, comprises the following steps:
By above-mentioned methylisothiazolinone, zinc naphthenate mixes, after being uniformly mixed, add wood fibre, at 70-80 ℃, heat 4-5 minute, reduction temperature is 50-60 ℃, add aminopropyltriethoxywerene werene, 400-500 rev/min of dispersed with stirring 3-4 minute, with polyvinyl resin particle, nano aluminum alumina, tetramethylolmethane, cetyl trimethylammonium bromide mixes, high-speed stirring 15-20 minute in high-speed mixer, add each raw material of residue, fully mix, send into twin screw extruder, extrusion moulding, cooling and shaping, obtain described antimicrobial form wood plastic composite.
Advantage of the present invention is:
Wood plastic composite of the present invention has excellent antibacterial, moisture resistant, crocking resistance, and matrix material of the present invention can be sawed, can dig, can follow closely, good processability, and dimensional stability is strong, applied widely.
Embodiment
Embodiment 1
An antimicrobial form wood plastic composite, it by following weight parts (kilogram) raw material form:
Polyvinyl resin particle 60, wood fibre 80, nano aluminum alumina 8, tributyl citrate 4, methylisothiazolinone 2, zinc naphthenate 2, tetramethylolmethane 2, cetyl trimethylammonium bromide 1, aminopropyltriethoxywerene werene 1, adhesive aid 10;
Described adhesive aid is comprised of the raw material of following weight parts:
Polyvinyl alcohol 20, hexamethoxymethyl melamine resin 4, polyamide wax micropowder 3, dialdehyde starch 5, Jojoba oil 2, anilinomethyl triethoxysilane 2;
Above-mentioned polyvinyl alcohol is joined in reactor, be heated to 80 ℃, add polyamide wax micropowder, insulation reaction 5 minutes, reducing temperature is 60 ℃, adds hexamethoxymethyl melamine resin, anilinomethyl triethoxysilane, 700 revs/min of dispersed with stirring 15 minutes, be cooled to normal temperature, add each raw material of residue, fully mixing obtains described adhesive aid.
A preparation method for antimicrobial form wood plastic composite, comprises the following steps:
Above-mentioned methylisothiazolinone, zinc naphthenate are mixed, after being uniformly mixed, add wood fibre, at 80 ℃, heat 5 minutes, reducing temperature is 60 ℃, add aminopropyltriethoxywerene werene, 500 revs/min of dispersed with stirring 4 minutes, mix with polyvinyl resin particle, nano aluminum alumina, tetramethylolmethane, cetyl trimethylammonium bromide, in high-speed mixer, high-speed stirring is 20 minutes, adds each raw material of residue, fully mixes, send into twin screw extruder, extrusion moulding, cooling and shaping, obtains described antimicrobial form wood plastic composite.
Performance test:
Flexural strength is 58.67MPa;
Modulus in flexure is 3.54GPa.
Claims (2)
1. an antimicrobial form wood plastic composite, is characterized in that it is comprised of the raw material of following weight parts:
Polyvinyl resin particle 50-60, wood fibre 70-80, nano aluminum alumina 6-8, tributyl citrate 3-4, methylisothiazolinone 2-4, zinc naphthenate 1-2, tetramethylolmethane 2-3, cetyl trimethylammonium bromide 1-2, aminopropyltriethoxywerene werene 1-2, adhesive aid 6-10;
Described adhesive aid is comprised of the raw material of following weight parts:
Polyvinyl alcohol 15-20, hexamethoxymethyl melamine resin 3-4, polyamide wax micropowder 2-3, dialdehyde starch 4-5, Jojoba oil 1-2, anilinomethyl triethoxysilane 1-2;
Above-mentioned polyvinyl alcohol is joined in reactor, be heated to 70-80 ℃, add polyamide wax micropowder, insulation reaction 4-5 minute, reduction temperature is 50-60 ℃, adds hexamethoxymethyl melamine resin, anilinomethyl triethoxysilane, 600-700 rev/min of dispersed with stirring 10-15 minute, be cooled to normal temperature, add each raw material of residue, fully mixing obtains described adhesive aid.
2. a preparation method for antimicrobial form wood plastic composite as claimed in claim 1, is characterized in that comprising the following steps:
By above-mentioned methylisothiazolinone, zinc naphthenate mixes, after being uniformly mixed, add wood fibre, at 70-80 ℃, heat 4-5 minute, reduction temperature is 50-60 ℃, add aminopropyltriethoxywerene werene, 400-500 rev/min of dispersed with stirring 3-4 minute, with polyvinyl resin particle, nano aluminum alumina, tetramethylolmethane, cetyl trimethylammonium bromide mixes, high-speed stirring 15-20 minute in high-speed mixer, add each raw material of residue, fully mix, send into twin screw extruder, extrusion moulding, cooling and shaping, obtain described antimicrobial form wood plastic composite.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310532727.XA CN103665901B (en) | 2013-11-01 | 2013-11-01 | A kind of Antibacterial wood-plastic composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310532727.XA CN103665901B (en) | 2013-11-01 | 2013-11-01 | A kind of Antibacterial wood-plastic composite material |
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| CN103665901A true CN103665901A (en) | 2014-03-26 |
| CN103665901B CN103665901B (en) | 2016-01-20 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877272A (en) * | 2015-06-12 | 2015-09-02 | 广东省微生物研究所 | Anti-algae wood-plastic composite material and preparation method thereof |
| CN105542498A (en) * | 2016-01-19 | 2016-05-04 | 普洱市思茅区康和木制品厂 | Modified wood-plastic composite material and preparation method thereof |
| CN107325382A (en) * | 2017-08-25 | 2017-11-07 | 安徽钰锦生态木材料有限公司 | A kind of Antibacterial wood-plastic composite material and preparation method thereof |
| CN107446318A (en) * | 2017-08-22 | 2017-12-08 | 桐城市钰锦塑料包装有限公司 | A kind of cyclic polyester CBT wood plastic composites |
| CN108927878A (en) * | 2018-08-04 | 2018-12-04 | 滁州晶田新型装饰材料有限公司 | A kind of anti-skidding easy construction WPC floor producing technology |
| CN117488588A (en) * | 2023-10-12 | 2024-02-02 | 浙江金龙再生资源科技股份有限公司 | Special core paper for compounding high-grade gray paperboard and production process thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001113583A (en) * | 1999-10-19 | 2001-04-24 | Okura Ind Co Ltd | Round bar of two-layer polyolefin resin and method of manufacturing the same |
| CN1944539A (en) * | 2006-10-09 | 2007-04-11 | 华明扬 | Flame-retardant and water-proof bactericidal plant fibre powder/high molecule plastic ocmposite tower tube and its preparing method |
| CN102618052A (en) * | 2012-03-30 | 2012-08-01 | 常熟市常福有机复合肥有限公司 | Environmental-protection high-performance wood-plastic composite |
| KR101204469B1 (en) * | 2012-06-26 | 2012-11-30 | (주)한국폴리우드 | Method for manufacturing wood plastic composite |
| CN103205042A (en) * | 2013-03-19 | 2013-07-17 | 马立波 | Polyolefin wood-plastic composite material with high thermal deformation temperature and preparation method thereof |
| CN103232720A (en) * | 2013-05-09 | 2013-08-07 | 南京荣仕景复合材料有限公司 | Mildewing resistant plastic-wood composite material |
-
2013
- 2013-11-01 CN CN201310532727.XA patent/CN103665901B/en active Active
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2001113583A (en) * | 1999-10-19 | 2001-04-24 | Okura Ind Co Ltd | Round bar of two-layer polyolefin resin and method of manufacturing the same |
| CN1944539A (en) * | 2006-10-09 | 2007-04-11 | 华明扬 | Flame-retardant and water-proof bactericidal plant fibre powder/high molecule plastic ocmposite tower tube and its preparing method |
| CN102618052A (en) * | 2012-03-30 | 2012-08-01 | 常熟市常福有机复合肥有限公司 | Environmental-protection high-performance wood-plastic composite |
| KR101204469B1 (en) * | 2012-06-26 | 2012-11-30 | (주)한국폴리우드 | Method for manufacturing wood plastic composite |
| CN103205042A (en) * | 2013-03-19 | 2013-07-17 | 马立波 | Polyolefin wood-plastic composite material with high thermal deformation temperature and preparation method thereof |
| CN103232720A (en) * | 2013-05-09 | 2013-08-07 | 南京荣仕景复合材料有限公司 | Mildewing resistant plastic-wood composite material |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104877272A (en) * | 2015-06-12 | 2015-09-02 | 广东省微生物研究所 | Anti-algae wood-plastic composite material and preparation method thereof |
| CN105542498A (en) * | 2016-01-19 | 2016-05-04 | 普洱市思茅区康和木制品厂 | Modified wood-plastic composite material and preparation method thereof |
| CN105542498B (en) * | 2016-01-19 | 2018-07-10 | 普洱市思茅区康和木制品厂 | A kind of modified composite material of woods and plastics and preparation method thereof |
| CN107446318A (en) * | 2017-08-22 | 2017-12-08 | 桐城市钰锦塑料包装有限公司 | A kind of cyclic polyester CBT wood plastic composites |
| CN107325382A (en) * | 2017-08-25 | 2017-11-07 | 安徽钰锦生态木材料有限公司 | A kind of Antibacterial wood-plastic composite material and preparation method thereof |
| CN108927878A (en) * | 2018-08-04 | 2018-12-04 | 滁州晶田新型装饰材料有限公司 | A kind of anti-skidding easy construction WPC floor producing technology |
| CN117488588A (en) * | 2023-10-12 | 2024-02-02 | 浙江金龙再生资源科技股份有限公司 | Special core paper for compounding high-grade gray paperboard and production process thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103665901B (en) | 2016-01-20 |
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Effective date of registration: 20170328 Address after: 236500 Anhui city of Fuyang Province Jieshou Guangwu Pansum industrial zone four Road No. B16 Patentee after: Jieshou City Yu Zesu industry company limited Address before: 236500 Anhui city of Fuyang Province Jieshou Guangwu Industrial Park Patentee before: JIESHOU JIATONG PLASTIC PRODUCT CO., LTD. |
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Address after: 236500 No. four, No. four, Guang Wu industrial zone, Jieshou City, Fuyang, Anhui. Patentee after: Anhui Yu Ze plastic industry Polytron Technologies Inc Address before: 236500 No. four, No. four, Guang Wu industrial zone, Jieshou City, Fuyang, Anhui. Patentee before: Jieshou City Yu Zesu industry company limited |
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Address after: 236500 No. four, No. four, Guang Wu industrial zone, Jieshou City, Fuyang, Anhui. Patentee after: Anhui Yuze Plastic Technology Co.,Ltd. Address before: 236500 No. four, No. four, Guang Wu industrial zone, Jieshou City, Fuyang, Anhui. Patentee before: Anhui Yu Ze plastic industry Polytron Technologies Inc. |
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