CN103665631B - A kind of Polyvinyl chloride wood-plastic composite material - Google Patents
A kind of Polyvinyl chloride wood-plastic composite material Download PDFInfo
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- CN103665631B CN103665631B CN201310532580.4A CN201310532580A CN103665631B CN 103665631 B CN103665631 B CN 103665631B CN 201310532580 A CN201310532580 A CN 201310532580A CN 103665631 B CN103665631 B CN 103665631B
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- 239000000463 material Substances 0.000 title claims abstract description 19
- 229920001587 Wood-plastic composite Polymers 0.000 title claims abstract description 18
- 239000011155 wood-plastic composite Substances 0.000 title claims abstract description 18
- 229920000915 polyvinyl chloride Polymers 0.000 title claims abstract description 17
- 239000004800 polyvinyl chloride Substances 0.000 title claims abstract description 17
- 239000000843 powder Substances 0.000 claims abstract description 16
- 239000000853 adhesive Substances 0.000 claims abstract description 13
- 230000001070 adhesive effect Effects 0.000 claims abstract description 13
- 239000002994 raw material Substances 0.000 claims abstract description 13
- 239000002023 wood Substances 0.000 claims abstract description 9
- UIIMBOGNXHQVGW-UHFFFAOYSA-M Sodium bicarbonate Chemical compound [Na+].OC([O-])=O UIIMBOGNXHQVGW-UHFFFAOYSA-M 0.000 claims abstract description 8
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 7
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 7
- 241001330002 Bambuseae Species 0.000 claims abstract description 7
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 7
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229960000892 attapulgite Drugs 0.000 claims abstract description 7
- 239000011425 bamboo Substances 0.000 claims abstract description 7
- 150000002148 esters Chemical class 0.000 claims abstract description 7
- 239000003365 glass fiber Substances 0.000 claims abstract description 7
- 229910052625 palygorskite Inorganic materials 0.000 claims abstract description 7
- 239000002245 particle Substances 0.000 claims abstract description 7
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims abstract description 7
- 229910052902 vermiculite Inorganic materials 0.000 claims abstract description 7
- 235000019354 vermiculite Nutrition 0.000 claims abstract description 7
- 239000010455 vermiculite Substances 0.000 claims abstract description 7
- CJZGTCYPCWQAJB-UHFFFAOYSA-L calcium stearate Chemical compound [Ca+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O CJZGTCYPCWQAJB-UHFFFAOYSA-L 0.000 claims abstract description 4
- 235000013539 calcium stearate Nutrition 0.000 claims abstract description 4
- 239000008116 calcium stearate Substances 0.000 claims abstract description 4
- 229910000030 sodium bicarbonate Inorganic materials 0.000 claims abstract description 4
- 235000017557 sodium bicarbonate Nutrition 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 12
- BNCADMBVWNPPIZ-UHFFFAOYSA-N 2-n,2-n,4-n,4-n,6-n,6-n-hexakis(methoxymethyl)-1,3,5-triazine-2,4,6-triamine Chemical compound COCN(COC)C1=NC(N(COC)COC)=NC(N(COC)COC)=N1 BNCADMBVWNPPIZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000004640 Melamine resin Substances 0.000 claims description 6
- 229920000877 Melamine resin Polymers 0.000 claims description 6
- 239000004952 Polyamide Substances 0.000 claims description 6
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- KOVKEDGZABFDPF-UHFFFAOYSA-N n-(triethoxysilylmethyl)aniline Chemical compound CCO[Si](OCC)(OCC)CNC1=CC=CC=C1 KOVKEDGZABFDPF-UHFFFAOYSA-N 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 6
- -1 turps Substances 0.000 claims description 5
- 229920002085 Dialdehyde starch Polymers 0.000 claims description 3
- UIIMBOGNXHQVGW-DEQYMQKBSA-M Sodium bicarbonate-14C Chemical compound [Na+].O[14C]([O-])=O UIIMBOGNXHQVGW-DEQYMQKBSA-M 0.000 claims description 3
- 238000001816 cooling Methods 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000009413 insulation Methods 0.000 claims description 3
- 229940119170 jojoba wax Drugs 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 238000007493 shaping process Methods 0.000 claims description 3
- 239000011159 matrix material Substances 0.000 abstract description 3
- 230000000694 effects Effects 0.000 abstract description 2
- 238000009434 installation Methods 0.000 abstract description 2
- 238000012423 maintenance Methods 0.000 abstract description 2
- 229920003023 plastic Polymers 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000011157 advanced composite material Substances 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000001192 hot extrusion Methods 0.000 description 1
- 239000010903 husk Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
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- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
The invention discloses a kind of Polyvinyl chloride wood-plastic composite material, it is made up of the raw material of following weight parts: igelite particle 94-100, wood powder 30-40, bamboo powder 20-30, attapulgite 10-15, vermiculite power 6-8, calcium stearate 3-4, glass fibre 2-3, phthalic ester 1-2, turps 2-3, propyl trimethoxy silicane 1-2, sodium bicarbonate 2-3, adhesive aid 3-4, Polyvinyl chloride wood-plastic composite material density of the present invention is low, installation and maintenance is convenient, water-fast, creep resistance, the superior performance such as incompressible, the adhesive aid added improves the bonding effect of each storeroom, further increase the mechanical property of matrix material.
Description
Technical field
The present invention relates generally to a kind of matrix material, particularly relates to a kind of Polyvinyl chloride wood-plastic composite material.
Background technology
Wood plastic composite is the class advanced composite material be in recent years surging forward both at home and abroad, refer to utilize polyethylene, polypropylene and polyvinyl chloride etc., replace common resin adhesive, new wood materials is mixed into useless vegetable fibres such as the wood powder more than more than 50%, rice husk, stalks, again through plastic processings such as extruding, mold pressing, injection moldings, the sheet material produced or section bar.Be mainly used in the industries such as building materials, furniture, logistics packaging.Through the sheet material of hot extrusion molding after plastics and wooden powder are mixed by a certain percentage, be referred to as to extrude wood-plastic composite panel.
Summary of the invention
The object of the invention is just to provide a kind of Polyvinyl chloride wood-plastic composite material.
The present invention is achieved by the following technical solutions:
A kind of Polyvinyl chloride wood-plastic composite material, it is made up of the raw material of following weight parts:
Igelite particle 94-100, wood powder 30-40, bamboo powder 20-30, attapulgite 10-15, vermiculite power 6-8, calcium stearate 3-4, glass fibre 2-3, phthalic ester 1-2, turps 2-3, propyl trimethoxy silicane 1-2, sodium bicarbonate 2-3, adhesive aid 3-4;
Described adhesive aid is made up of the raw material of following weight parts:
Polyvinyl alcohol 15-20, hexamethoxymethyl melamine resin 3-4, polyamide wax micropowder 2-3, dialdehyde starch 4-5, Jojoba oil 1-2, anilinomethyl triethoxysilane 1-2;
Above-mentioned polyvinyl alcohol is joined in reactor, be heated to 70-80 DEG C, add polyamide wax micropowder, insulation reaction 4-5 minute, reduction temperature is 50-60 DEG C, adds hexamethoxymethyl melamine resin, anilinomethyl triethoxysilane, 600-700 rev/min of dispersed with stirring 10-15 minute, be cooled to normal temperature, add each raw material of residue, namely abundant mixing obtains described adhesive aid.
A preparation method for Polyvinyl chloride wood-plastic composite material, comprises the following steps:
By above-mentioned wood powder, bamboo powder, glass fibre mixes with attapulgite, pre-thermal response 10-15 minute at 100-130 DEG C, reduction temperature is 50-60 DEG C, add propyl trimethoxy silicane, 600-800 rev/min of dispersed with stirring 3-5 minute, add igelite particle, turps, vermiculite power, phthalic ester, stir, raised temperature is 105-120 DEG C, add sodium bicarbonate, normal temperature is reduced to after stirring, add each raw material of residue, forcing machine is sent into after abundant mixing, extrusion moulding, cooling and shaping, obtain described Polyvinyl chloride wood-plastic composite material.
Advantage of the present invention is:
Polyvinyl chloride wood-plastic composite material density of the present invention is low, and installation and maintenance is convenient, and water-fast, creep resistance, the superior performance such as incompressible, the adhesive aid added improves the bonding effect of each storeroom, further increases the mechanical property of matrix material.
Embodiment
Embodiment 1
A kind of Polyvinyl chloride wood-plastic composite material, it is made up of the raw material of following weight parts (kilogram):
Igelite particle 100, wood powder 40, bamboo powder 20, attapulgite 15, vermiculite power 8, calcium stearate 4, glass fibre 3, phthalic ester 1, turps 3, propyl trimethoxy silicane 1, sodium bicarbonate 2, adhesive aid 4;
Described adhesive aid is made up of the raw material of following weight parts:
Polyvinyl alcohol 20, hexamethoxymethyl melamine resin 4, polyamide wax micropowder 3, dialdehyde starch 5, Jojoba oil 2, anilinomethyl triethoxysilane 2;
Above-mentioned polyvinyl alcohol is joined in reactor, be heated to 80 DEG C, add polyamide wax micropowder, insulation reaction 5 minutes, reducing temperature is 60 DEG C, adds hexamethoxymethyl melamine resin, anilinomethyl triethoxysilane, 700 revs/min of dispersed with stirring 15 minutes, be cooled to normal temperature, add each raw material of residue, namely abundant mixing obtains described adhesive aid.
A preparation method for Polyvinyl chloride wood-plastic composite material, comprises the following steps:
Above-mentioned wood powder, bamboo powder, glass fibre are mixed with attapulgite, pre-thermal response 15 minutes at 130 DEG C, reducing temperature is 60 DEG C, add propyl trimethoxy silicane, 800 revs/min of dispersed with stirring 5 minutes, add igelite particle, turps, vermiculite power, phthalic ester, stir, raised temperature is 120 DEG C, adds sodium bicarbonate, normal temperature is reduced to after stirring, add each raw material of residue, fully send into forcing machine, extrusion moulding after mixing, cooling and shaping, obtains described Polyvinyl chloride wood-plastic composite material.
Performance test:
Freeze-thaw resistance: flexural failure load retention rate is 89%;
Flexural failure load: 3804N;
Normal temperature lands impact: pit diameter is 7.2mm;
Low temperature ball falling impact :-10 DEG C, flawless;
Thickness swelling rate (normal-temperature water soaks 1 hour): 0.79%;
Creep recovery rate: 77%.
Claims (1)
1. a Polyvinyl chloride wood-plastic composite material, is characterized in that it is made up of the raw material of following weight parts:
Igelite particle 94-100, wood powder 30-40, bamboo powder 20-30, attapulgite 10-15, vermiculite power 6-8, calcium stearate 3-4, glass fibre 2-3, phthalic ester 1-2, turps 2-3, propyl trimethoxy silicane 1-2, sodium bicarbonate 2-3, adhesive aid 3-4;
Described adhesive aid is made up of the raw material of following weight parts:
Polyvinyl alcohol 15-20, hexamethoxymethyl melamine resin 3-4, polyamide wax micropowder 2-3, dialdehyde starch 4-5, Jojoba oil 1-2, anilinomethyl triethoxysilane 1-2;
Above-mentioned polyvinyl alcohol is joined in reactor, be heated to 70-80 DEG C, add polyamide wax micropowder, insulation reaction 4-5 minute, reduction temperature is 50-60 DEG C, adds hexamethoxymethyl melamine resin, anilinomethyl triethoxysilane, 600-700 rev/min of dispersed with stirring 10-15 minute, be cooled to normal temperature, add each raw material of residue, namely abundant mixing obtains described adhesive aid;
The preparation method of described Polyvinyl chloride wood-plastic composite material, comprises the following steps:
By above-mentioned wood powder, bamboo powder, glass fibre mixes with attapulgite, pre-thermal response 10-15 minute at 100-130 DEG C, reduction temperature is 50-60 DEG C, add propyl trimethoxy silicane, 600-800 rev/min of dispersed with stirring 3-5 minute, add igelite particle, turps, vermiculite power, phthalic ester, stir, raised temperature is 105-120 DEG C, add sodium bicarbonate, normal temperature is reduced to after stirring, add each raw material of residue, forcing machine is sent into after abundant mixing, extrusion moulding, cooling and shaping, obtain described Polyvinyl chloride wood-plastic composite material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310532580.4A CN103665631B (en) | 2013-11-01 | 2013-11-01 | A kind of Polyvinyl chloride wood-plastic composite material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310532580.4A CN103665631B (en) | 2013-11-01 | 2013-11-01 | A kind of Polyvinyl chloride wood-plastic composite material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103665631A CN103665631A (en) | 2014-03-26 |
| CN103665631B true CN103665631B (en) | 2016-03-09 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310532580.4A Active CN103665631B (en) | 2013-11-01 | 2013-11-01 | A kind of Polyvinyl chloride wood-plastic composite material |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108547425A (en) * | 2018-04-26 | 2018-09-18 | 合肥慧林建材有限公司 | A kind of environment-friendlyweather-proof weather-proof wood moulding floor tile and preparation method thereof |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104356545A (en) * | 2014-11-06 | 2015-02-18 | 安徽省三乐门窗幕墙工程有限公司 | High-weather-tolerance PVC wood-plastic composite material and preparation method thereof |
| CN104387696A (en) * | 2014-11-06 | 2015-03-04 | 安徽省三乐门窗幕墙工程有限公司 | Energy-saving PVC (polyvinyl chloride) wood-plastic composite material and preparation method thereof |
| CN104387695A (en) * | 2014-11-06 | 2015-03-04 | 安徽省三乐门窗幕墙工程有限公司 | High-strength PVC (polyvinyl chloride) wood-plastic composite material and preparation method thereof |
| CN104387698B (en) * | 2014-11-06 | 2016-03-30 | 安徽省三乐门窗幕墙工程有限公司 | PVC wood plastic composite material that a kind of plant waste is produced and preparation method thereof |
| CN106633493A (en) * | 2016-11-15 | 2017-05-10 | 安徽冠金绿可木业有限公司 | High-strength wood-plastic decorative sheet |
| CN106633518B (en) * | 2016-12-13 | 2018-07-24 | 安徽梦谷纤维材料科技有限公司 | A kind of wood plastic composite of basalt fibre enhancing |
| CN106928743A (en) * | 2017-05-04 | 2017-07-07 | 冯志容 | A kind of Environmental-protechigh-performance high-performance wood-plastic composite |
| CN109467950B (en) * | 2018-10-26 | 2021-06-29 | 深圳市德勤装饰工程有限公司 | Environment-friendly composite material for building and preparation method thereof |
| CN110903672A (en) * | 2019-11-29 | 2020-03-24 | 陕西速源节能科技有限公司 | Environment-friendly plate and preparation method thereof |
| CN117701023B (en) * | 2024-02-05 | 2024-04-16 | 河北润尔新材料科技股份有限公司 | High-strength wood-plastic composite material and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020091178A1 (en) * | 2001-01-05 | 2002-07-11 | Hossein Amin-Javaheri | Polyvinyl chloride composition |
| CN101955614A (en) * | 2010-02-22 | 2011-01-26 | 成都奥金希斯科技股份有限公司 | Novel wood plastic composite decorative building material and manufacturing method thereof |
| CN102604560A (en) * | 2012-02-24 | 2012-07-25 | 江南大学 | Preparation method of starch adhesive used for artificial board production |
| CN103044820A (en) * | 2013-01-10 | 2013-04-17 | 郑州大学 | Novel flame-retardant wood-plastic technology formula |
-
2013
- 2013-11-01 CN CN201310532580.4A patent/CN103665631B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20020091178A1 (en) * | 2001-01-05 | 2002-07-11 | Hossein Amin-Javaheri | Polyvinyl chloride composition |
| CN101955614A (en) * | 2010-02-22 | 2011-01-26 | 成都奥金希斯科技股份有限公司 | Novel wood plastic composite decorative building material and manufacturing method thereof |
| CN102604560A (en) * | 2012-02-24 | 2012-07-25 | 江南大学 | Preparation method of starch adhesive used for artificial board production |
| CN103044820A (en) * | 2013-01-10 | 2013-04-17 | 郑州大学 | Novel flame-retardant wood-plastic technology formula |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108547425A (en) * | 2018-04-26 | 2018-09-18 | 合肥慧林建材有限公司 | A kind of environment-friendlyweather-proof weather-proof wood moulding floor tile and preparation method thereof |
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| CN103665631A (en) | 2014-03-26 |
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Effective date of registration: 20170328 Address after: 236500 Anhui city of Fuyang Province Jieshou Guangwu Pansum industrial zone four Road No. B16 Patentee after: Jieshou City Yu Zesu industry company limited Address before: 236500 Anhui city of Fuyang Province Jieshou Guangwu Industrial Park Patentee before: JIESHOU JIATONG PLASTIC PRODUCT CO., LTD. |
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Address after: 236500 No. four, No. four, Guang Wu industrial zone, Jieshou City, Fuyang, Anhui. Patentee after: Anhui Yu Ze plastic industry Polytron Technologies Inc Address before: 236500 No. four, No. four, Guang Wu industrial zone, Jieshou City, Fuyang, Anhui. Patentee before: Jieshou City Yu Zesu industry company limited |
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Address after: 236500 No. four, No. four, Guang Wu industrial zone, Jieshou City, Fuyang, Anhui. Patentee after: Anhui Yuze Plastic Technology Co.,Ltd. Address before: 236500 No. four, No. four, Guang Wu industrial zone, Jieshou City, Fuyang, Anhui. Patentee before: Anhui Yu Ze plastic industry Polytron Technologies Inc. |
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Denomination of invention: Polyvinyl chloride wood plastic composite material Effective date of registration: 20210902 Granted publication date: 20160309 Pledgee: The development of small and medium-sized enterprises financing Company Limited by Guarantee Jieshou City Pledgor: Anhui Yuze Plastic Technology Co.,Ltd. Registration number: Y2021980008687 |
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