CN103665526A - 一种功能性透明薄膜填充母料及其制备方法 - Google Patents
一种功能性透明薄膜填充母料及其制备方法 Download PDFInfo
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- CN103665526A CN103665526A CN201310747464.4A CN201310747464A CN103665526A CN 103665526 A CN103665526 A CN 103665526A CN 201310747464 A CN201310747464 A CN 201310747464A CN 103665526 A CN103665526 A CN 103665526A
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- hollow glass
- master batch
- glass micropearl
- filling master
- transparent film
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- 239000004594 Masterbatch (MB) Substances 0.000 title claims abstract description 41
- 238000011049 filling Methods 0.000 title claims abstract description 26
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- 239000011521 glass Substances 0.000 claims abstract description 50
- 238000012986 modification Methods 0.000 claims abstract description 17
- 230000004048 modification Effects 0.000 claims abstract description 17
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 21
- 238000007599 discharging Methods 0.000 claims description 15
- 238000005469 granulation Methods 0.000 claims description 14
- 230000003179 granulation Effects 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 13
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 10
- 239000011806 microball Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 239000006185 dispersion Substances 0.000 claims description 7
- 239000000463 material Substances 0.000 claims description 7
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 claims description 3
- BTBUEUYNUDRHOZ-UHFFFAOYSA-N Borate Chemical compound [O-]B([O-])[O-] BTBUEUYNUDRHOZ-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- 239000012190 activator Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 239000002270 dispersing agent Substances 0.000 abstract description 2
- 238000009413 insulation Methods 0.000 abstract 2
- 239000011325 microbead Substances 0.000 abstract 2
- 229920003023 plastic Polymers 0.000 description 34
- 239000004033 plastic Substances 0.000 description 31
- -1 can form gap Substances 0.000 description 18
- 239000004698 Polyethylene Substances 0.000 description 16
- 229920000573 polyethylene Polymers 0.000 description 16
- 239000000843 powder Substances 0.000 description 11
- 238000012545 processing Methods 0.000 description 6
- 238000002834 transmittance Methods 0.000 description 5
- 239000001993 wax Substances 0.000 description 5
- 230000005540 biological transmission Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 239000011159 matrix material Substances 0.000 description 4
- 238000001514 detection method Methods 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 239000003595 mist Substances 0.000 description 3
- 238000002156 mixing Methods 0.000 description 3
- 230000003287 optical effect Effects 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000007822 coupling agent Substances 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 229920001903 high density polyethylene Polymers 0.000 description 2
- 239000004700 high-density polyethylene Substances 0.000 description 2
- 229920001684 low density polyethylene Polymers 0.000 description 2
- 239000004702 low-density polyethylene Substances 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 229910052938 sodium sulfate Inorganic materials 0.000 description 2
- 235000011152 sodium sulphate Nutrition 0.000 description 2
- 229920003002 synthetic resin Polymers 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- 239000012780 transparent material Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 1
- 235000008429 bread Nutrition 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 1
- 230000002708 enhancing effect Effects 0.000 description 1
- 238000007306 functionalization reaction Methods 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 229920000092 linear low density polyethylene Polymers 0.000 description 1
- 239000004707 linear low-density polyethylene Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000005453 pelletization Methods 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 238000002203 pretreatment Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000010257 thawing Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J3/00—Processes of treating or compounding macromolecular substances
- C08J3/20—Compounding polymers with additives, e.g. colouring
- C08J3/22—Compounding polymers with additives, e.g. colouring using masterbatch techniques
- C08J3/226—Compounding polymers with additives, e.g. colouring using masterbatch techniques using a polymer as a carrier
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms
- C08L23/0815—Copolymers of ethene with unsaturated hydrocarbons only containing four or more carbon atoms with aliphatic 1-olefins containing one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
- C08J2323/04—Homopolymers or copolymers of ethene
- C08J2323/06—Polyethene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/003—Additives being defined by their diameter
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/10—Transparent films; Clear coatings; Transparent materials
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/16—Applications used for films
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2207/00—Properties characterising the ingredient of the composition
- C08L2207/06—Properties of polyethylene
- C08L2207/066—LDPE (radical process)
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Processes Of Treating Macromolecular Substances (AREA)
Abstract
Description
检测项目 | 纯聚乙烯薄膜 | 其他透明母料薄膜 | 本产品薄膜 | 检测标准 |
拉伸强度(MPa) | 31 | 28 | 32 | GB/T528-1998 |
断裂伸长率(%) | 386 | 138 | 176 | GB/T 6672-2001 |
透光率(%) | 92.1 | 82.7 | 88.3 | GB/T 2410-2008 |
密度(g/m3) | 0.915 | 1.158 | 0.908 | GB1033—1998 |
雾度 | 10.21 | 54.1 | 51.5 | GB/T 2410-2008 |
导热系数 | 0.03 | 0.05 | 0.01 | GB/T 3399-1982 |
薄膜两侧温度差(℃) | 3.5 | 2.0 | 5.0 |
检测项目 | 纯聚乙烯薄膜 | 其他透明母料薄膜 | 本产品薄膜 | 检测标准 |
拉伸强度(MPa) | 31 | 28 | 32 | GB/T528-1998 |
断裂伸长率(%) | 386 | 135 | 179 | GB/T 6672-2001 |
透光率(%) | 92.1 | 82.5 | 89.0 | GB/T 2410-2008 |
密度(g/m3) | 0.915 | 1.168 | 0.910 | GB1033—1998 |
雾度 | 10.21 | 53.1 | 51.9 | GB/T 2410-2008 |
导热系数 | 0.03 | 0.05 | 0.01 | GB/T 3399-1982 |
薄膜两侧温度差(℃) | 3.5 | 2.0 | 5.3 |
检测项目 | 纯聚乙烯薄膜 | 其他透明母料薄膜 | 本产品薄膜 | 检测标准 |
拉伸强度(MPa) | 31 | 28 | 33 | GB/T528-1998 |
断裂伸长率(%) | 386 | 142 | 169 | GB/T 6672-2001 |
透光率(%) | 92.1 | 81.3 | 88.5 | GB/T 2410-2008 |
密度(g/m3) | 0.915 | 1.149 | 0.914 | GB1033—1998 |
雾度 | 10.21 | 54.5 | 51.8 | GB/T 2410-2008 |
导热系数 | 0.03 | 0.05 | 0.01 | GB/T 3399-1982 |
薄膜两侧温度差(℃) | 3.5 | 2.0 | 5.5 |
Claims (3)
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CN201310747464.4A CN103665526B (zh) | 2013-12-31 | 2013-12-31 | 一种功能性透明薄膜填充母料及其制备方法 |
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CN201310747464.4A CN103665526B (zh) | 2013-12-31 | 2013-12-31 | 一种功能性透明薄膜填充母料及其制备方法 |
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CN103665526A true CN103665526A (zh) | 2014-03-26 |
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Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104045961A (zh) * | 2014-06-27 | 2014-09-17 | 成都新柯力化工科技有限公司 | 一种塑料散热散光母料及其制备方法 |
CN104810111A (zh) * | 2015-04-23 | 2015-07-29 | 德州学院 | 信号传输用电缆线芯 |
CN105566828A (zh) * | 2014-09-05 | 2016-05-11 | 韩国科学技术研究院 | 包含高分子胶囊的透明绝热材料及其制造方法 |
CN113581650A (zh) * | 2021-07-01 | 2021-11-02 | 徐建军 | 一种用于农产品保鲜包装的透明透气膜及其制造工艺 |
CN115044140A (zh) * | 2022-07-01 | 2022-09-13 | 安徽卡洛塑业科技有限公司 | 一种环保阻燃聚苯乙烯材料的制备工艺 |
CN118165391A (zh) * | 2024-03-01 | 2024-06-11 | 深圳市金广利薄膜材料有限公司 | 一种塑料薄膜及其制备工艺 |
CN118725385A (zh) * | 2024-06-12 | 2024-10-01 | 广东瑞捷新材料股份有限公司 | 一种耐高温发泡扩散板及其制备方法 |
CN120209663A (zh) * | 2025-03-31 | 2025-06-27 | 中铁五局集团有限公司 | 一种隧道用疏水增亮涂料组合物及其制备方法 |
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Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104045961A (zh) * | 2014-06-27 | 2014-09-17 | 成都新柯力化工科技有限公司 | 一种塑料散热散光母料及其制备方法 |
CN104045961B (zh) * | 2014-06-27 | 2016-04-06 | 成都新柯力化工科技有限公司 | 一种塑料散热散光母料及其制备方法 |
CN105566828A (zh) * | 2014-09-05 | 2016-05-11 | 韩国科学技术研究院 | 包含高分子胶囊的透明绝热材料及其制造方法 |
US9950340B2 (en) | 2014-09-05 | 2018-04-24 | Korea Institute Of Science And Technology | Transparent and heat-insulating material including polymer capsule and method for preparing the same |
CN105566828B (zh) * | 2014-09-05 | 2018-09-14 | 韩国科学技术研究院 | 包含高分子胶囊的透明绝热材料及其制造方法 |
CN104810111A (zh) * | 2015-04-23 | 2015-07-29 | 德州学院 | 信号传输用电缆线芯 |
CN113581650A (zh) * | 2021-07-01 | 2021-11-02 | 徐建军 | 一种用于农产品保鲜包装的透明透气膜及其制造工艺 |
CN115044140A (zh) * | 2022-07-01 | 2022-09-13 | 安徽卡洛塑业科技有限公司 | 一种环保阻燃聚苯乙烯材料的制备工艺 |
CN115044140B (zh) * | 2022-07-01 | 2024-02-02 | 安徽卡洛塑业科技有限公司 | 一种环保阻燃聚苯乙烯材料的制备工艺 |
CN118165391A (zh) * | 2024-03-01 | 2024-06-11 | 深圳市金广利薄膜材料有限公司 | 一种塑料薄膜及其制备工艺 |
CN118165391B (zh) * | 2024-03-01 | 2024-09-20 | 深圳市金广利薄膜材料有限公司 | 一种塑料薄膜及其制备工艺 |
CN118725385A (zh) * | 2024-06-12 | 2024-10-01 | 广东瑞捷新材料股份有限公司 | 一种耐高温发泡扩散板及其制备方法 |
CN118725385B (zh) * | 2024-06-12 | 2025-03-28 | 广东瑞捷新材料股份有限公司 | 一种耐高温发泡扩散板及其制备方法 |
CN120209663A (zh) * | 2025-03-31 | 2025-06-27 | 中铁五局集团有限公司 | 一种隧道用疏水增亮涂料组合物及其制备方法 |
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