CN103665497A - Anti-vibration rubber composition - Google Patents
Anti-vibration rubber composition Download PDFInfo
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- CN103665497A CN103665497A CN201310620433.2A CN201310620433A CN103665497A CN 103665497 A CN103665497 A CN 103665497A CN 201310620433 A CN201310620433 A CN 201310620433A CN 103665497 A CN103665497 A CN 103665497A
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- rubber composition
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Abstract
The invention belongs to the field of rubber, and particularly relates to anti-vibration rubber composition. The anti-vibration rubber comprises components of chloroprene rubber, butadiene styrene rubber, dibutyl phthalate, dicyandiamide, polyamide, epoxy resin, quartz powder, coumarone resin, microcrystalline wax, carbon black N100, styrene, dimethylaniline, a softening agent, an anti-aging agent, nano-zinc oxide and carbon nanofibers. Compared with other common rubber, on the basis of original features of rubber, the anti-vibration rubber has a good anti-vibration effect, can be used as an anti-vibration material of an engine support, a balancing pole bushing, a suspension bushing and the like of an automobile, and further can be used as a hard disk absorber of a computer, an absorber of common household appliance products such as a washing machine and the like, as well as a vibration absorbing wall, an absorber and the like in the building field; and besides the advantages, the anti-vibration rubber has good heat resistance and can realize compression deformation, and the spring characteristics further can be highly considered.
Description
Technical field
The invention belongs to elastomeric material technical field, be specifically related to a kind of vibration damping rubber composition.
background technology
In the vehicles such as automobile, in order to improve passenger's comfort level, conventional, attempted various vibration isolating materials being set as those parts places of vibration or noisemaker, suppress thus vibration or noise and penetrate compartment, for example, engine about the main source for vibration and noise, vibration-proof rubber forms member as torsional vvibration dampeer and engine support for this type of, be absorbed in thus the vibration during engine driven and suppress vibration or noise penetrate into compartment and noise diffusion to surrounding enviroment the two.
As fundamental property, this type of vibration-proof rubber need to have the heavy especially object of support as the vibrationproof performance of the strength characteristics of engine and absorption and inhibition vibration.In addition, for hot environment, not only need to have low the dynamic and stalic state modular ratio and good vibrationproof performance but also need to there is high heat resistance and weather resistance as the vibration-proof rubber of nacelle.Especially, in recent years, follow the thousands of of engine output and save nacelle space to guarantee wider space, compartment, starting the temperature in cabin to be tending towards rising.This trend impels vibration-proof rubber more in being usually used in harsh environment.As a result, expected that automobile meets about severe requirements such as thermotolerances with vibration-proof rubber.
Polymkeric substance as above-mentioned vibration damping rubber composition, can use various rubber in the past, wherein natural rubber is because inexpensive and vibrationproof characteristic is also excellent, so its applicable frequency is higher, but the Sulfur that is used as the vulcanizing agent of natural rubber can decompose under more than 100 ℃ hot conditionss, therefore, often easily there is physical property and reduce in the long-term thermal ageing that the natural rubber of usining causes for reasons such as weathers as the vibration damping rubber composition of polymkeric substance.
Neoprene adhesive is applicable to the bonding of flexibility object, can alleviate owing to expanding or shrinking the stress concentration causing, but traditional neoprene adhesive can not bonding artificial polyvinyl chloride leather, polyurethane synthetic leather, the ethylene-vinyl acetate co-polymer foamed end, at the bottom of styrene-butadiene rubber(SBR), at the bottom of synthetic rubber imitation leather containing RVA and PU, the materials such as thermoplastic elastomer, because in order to increase the flexibility of above-mentioned materials, the softening agent that need add small molecules amount, this class softening agent can infiltrate adhesive layer or on its interface, gathers and form weak boundary layer, the oil-proofness that chloroprene rubber is good like this reduces its bonding strength greatly.
In order to solve the above problems, by rubber in the past together, use multiple filler and auxiliary agent etc., by combination, thereby the vibrationproof performance of rubber is improved.
Summary of the invention
In order to solve above-mentioned technical problem, the invention provides the rubber that a kind of vibration-isolating effect is good.
Vibration-proof rubber of the present invention, this vibration-proof rubber comprises the component of following portions by weight:
Chloroprene rubber 50-120 styrene-butadiene rubber(SBR) 60-100
Dibutyl phthalate 1-9 Dyhard RU 100 2-8
Polymeric amide 1-6 epoxy resin 2-10
Silica powder 2-8 coumarone indene resin 1-6
Microcrystalline Wax 2-8 carbon black N100 1-8
Vinylbenzene 1-6 xylidene(s) 2-8
Tenderizer 1-5 anti-aging agent 2-8
Nano zine oxide 1-4 sodium rice carbon fiber 1-6.
Preferably, vibration-proof rubber of the present invention, this vibration-proof rubber comprises the component of following portions by weight:
Chloroprene rubber 60-110 styrene-butadiene rubber(SBR) 70-90
Dibutyl phthalate 1-8 Dyhard RU 100 2-7
Polymeric amide 1-6 epoxy resin 2-9
Silica powder 2-7 coumarone indene resin 1-5
Microcrystalline Wax 2-7 carbon black N100 1-7
Vinylbenzene 1-5 xylidene(s) 2-7
Tenderizer 1-5 anti-aging agent 2-7
Nano zine oxide 1-4 sodium rice carbon fiber 1-5.
Preferred, vibration-proof rubber of the present invention, this vibration-proof rubber comprises the component of following portions by weight:
Chloroprene rubber 90 styrene-butadiene rubber(SBR) 80
Dibutyl phthalate 5 Dyhard RU 100s 4
Kymene epoxy resin 6
Silica powder 4 coumarone indene resins 3
Microcrystalline Wax 5 carbon black N100 4
Vinylbenzene 3 xylidene(s)s 5
Tenderizer 3 anti-aging agent 4
Nano zine oxide 2 sodium rice carbon fibers 3.
Above-mentioned anti-aging agent is 6-oxyethyl group-2,2,4-trimethylammonium-1,2 dihyaroquinolines, 2,2,4-trimethylammonium 1, at least one in 2-dihydro quinoline polymer, diaryl secondary amine antioxidant, Ursol D class.
Above-mentioned anti-aging agent is at least one of N-phenyl-α-aniline, N-phenyl-N '-sec.-propyl-Ursol D, N-N '-phenylbenzene-Ursol D, antioxidant 4020.
Above-mentioned anti-aging agent is N-phenyl-α-aniline, N-N '-phenylbenzene-Ursol D, and both ratios of weight and number are 1-3:1.
Above-mentioned tenderizer is at least one in ointment, stearic acid, oleic acid.
Above-mentioned composition also comprises promotor, its parts by weight are 2-8, and described promotor is any in dibenzothiazyl disulfide, tetramethyl-thiuram disulfide, zinc diethyldithiocarbamate, 2-thiol group tetrahydroglyoxaline, two butyl disulfide amido acid zinc, the N-tertiary butyl-2 benzothiazole sulphenamide.
The parts by weight of above-mentioned softening agent are 5 parts.
Beneficial effect of the present invention is, vibration-proof rubber of the present invention, compare with other General Purpose Rubber, keeping on the basis of rubber primary characteristic, its vibration-isolating effect is good, can be used as the vibration isolating material of engine bearer that automobile etc. uses, rock arm lining, suspension lining etc., can also be as the vibroshock of conventional family's electrical article of the hard disk anti-vibration of computer, washing machine etc., vibration-damping wall in building field, vibroshock etc.; Except thering is above-mentioned advantage, and its good heat resistance, beyond compression set, can also highly take into account spring characteristic.
Embodiment
Below in conjunction with specific embodiment, the present invention is further described, so that those skilled in the art more understands the present invention, but does not therefore limit the present invention.
Embodiment 1
Chloroprene rubber 90 styrene-butadiene rubber(SBR) 80
Dibutyl phthalate 5 Dyhard RU 100s 4
Kymene epoxy resin 6
Silica powder 4 coumarone indene resins 3
Microcrystalline Wax 5 carbon black N100 4
Vinylbenzene 3 xylidene(s)s 5
Tenderizer 3 anti-aging agent 4
Nano zine oxide 2 sodium rice carbon fibers 3.
Above-mentioned anti-aging agent is N-phenyl-α-aniline, N-N '-phenylbenzene-Ursol D, and the weight ratio of N-phenyl-α-aniline, N-N '-phenylbenzene-Ursol D is 1:2.
Above-mentioned tenderizer is oleic acid.
Promotor is dibenzothiazyl disulfide, and its parts by weight are 5.
Embodiment 2
Chloroprene rubber 50 styrene-butadiene rubber(SBR) 60
Dibutyl phthalate 1 Dyhard RU 100 2
Polymeric amide 1 epoxy resin 2
Silica powder 2 coumarone indene resins 1
Microcrystalline Wax 2 carbon black N100 1
Vinylbenzene 1 xylidene(s) 2
Tenderizer 1 anti-aging agent 2
Nano zine oxide 1 sodium rice carbon fiber 1.
Above-mentioned anti-aging agent is 6-oxyethyl group-2,2,4-trimethylammonium-1,2 dihyaroquinolines.
Above-mentioned tenderizer is oleic acid.
Promotor is dibenzothiazyl disulfide, and its parts by weight are 5.
Embodiment 3
Chloroprene rubber 120 styrene-butadiene rubber(SBR) 100
Dibutyl phthalate 9 Dyhard RU 100s 8
Polyamide 6 epoxy resin 10
Silica powder 8 coumarone indene resins 6
Microcrystalline Wax 8 carbon black N100 8
Vinylbenzene 6 xylidene(s)s 8
Tenderizer 5 anti-aging agent 8
Nano zine oxide 4 sodium rice carbon fibers 6.
Above-mentioned anti-aging agent is N-phenyl-N '-sec.-propyl-Ursol D.
Above-mentioned tenderizer is stearic acid.
Promotor is dibenzothiazyl disulfide, and its parts by weight are 5.
Embodiment 4
Chloroprene rubber 770 styrene-butadiene rubber(SBR) 70
Dibutyl phthalate 3 Dyhard RU 100s 4
Kymene epoxy resin 4
Silica powder 3 coumarone indene resins 2
Microcrystalline Wax 4 carbon black N100 2
Vinylbenzene 2 xylidene(s)s 3
Tenderizer 2 anti-aging agent 3
Nano zine oxide 2 sodium rice carbon fibers 2.
Above-mentioned anti-aging agent is N-phenyl-α-aniline, N-N '-phenylbenzene-Ursol D, and the weight ratio of N-phenyl-α-aniline, N-N '-phenylbenzene-Ursol D is 1:2.
Above-mentioned tenderizer is oleic acid.
Promotor is the N-tertiary butyl-2 benzothiazole sulphenamides, and its parts by weight are 5.
Embodiment 5
Chloroprene rubber 100 styrene-butadiene rubber(SBR) 90
Dibutyl phthalate 8 Dyhard RU 100s 6
Polymeric amide 5 epoxy resin 8
Silica powder 6 coumarone indene resins 4
Microcrystalline Wax 6 carbon black N100 6
Vinylbenzene 5 xylidene(s)s 6
Tenderizer 4 anti-aging agent 6
Nano zine oxide 3 sodium rice carbon fibers 5.
Above-mentioned anti-aging agent is N-phenyl-α-aniline, N-N '-phenylbenzene-Ursol D, and the weight ratio of N-phenyl-α-aniline, N-N '-phenylbenzene-Ursol D is 1:2.
Above-mentioned tenderizer is oleic acid.
Promotor is two butyl disulfide amido acid zinc, and its parts by weight are 5.
Claims (9)
1. a vibration damping rubber composition, is characterized in that, described vibration damping rubber composition comprises the component of following parts by weight:
Chloroprene rubber 50-120 styrene-butadiene rubber(SBR) 60-100
Dibutyl phthalate 1-9 Dyhard RU 100 2-8
Polymeric amide 1-6 epoxy resin 2-10
Silica powder 2-8 coumarone indene resin 1-6
Microcrystalline Wax 2-8 carbon black N100 1-8
Vinylbenzene 1-6 xylidene(s) 2-8
Tenderizer 1-5 anti-aging agent 2-8
Nano zine oxide 1-4 sodium rice carbon fiber 1-6.
2. a kind of vibration damping rubber composition as claimed in claim 1, is characterized in that, described vibration-proof rubber comprises the component of following portions by weight:
Chloroprene rubber 60-110 styrene-butadiene rubber(SBR) 70-90
Dibutyl phthalate 1-8 Dyhard RU 100 2-7
Polymeric amide 1-6 epoxy resin 2-9
Silica powder 2-7 coumarone indene resin 1-5
Microcrystalline Wax 2-7 carbon black N100 1-7
Vinylbenzene 1-5 xylidene(s) 2-7
Tenderizer 1-5 anti-aging agent 2-7
Nano zine oxide 1-4 sodium rice carbon fiber 1-5.
3. a kind of vibration damping rubber composition as claimed in claim 1, is characterized in that, described vibration-proof rubber comprises the component of following portions by weight:
Chloroprene rubber 90 styrene-butadiene rubber(SBR) 80
Dibutyl phthalate 5 Dyhard RU 100s 4
Kymene epoxy resin 6
Silica powder 4 coumarone indene resins 3
Microcrystalline Wax 5 carbon black N100 4
Vinylbenzene 3 xylidene(s)s 5
Tenderizer 3 anti-aging agent 4
Nano zine oxide 2 sodium rice carbon fibers 3.
4. a kind of vibration damping rubber composition as claimed in claim 1, is characterized in that, described anti-aging agent is 6-oxyethyl group-2,2,4-trimethylammonium-1,2 dihyaroquinolines, 2,2,4-trimethylammonium 1, at least one in 2-dihydro quinoline polymer, diaryl secondary amine antioxidant, Ursol D class.
5. a kind of vibration damping rubber composition as claimed in claim 3, is characterized in that, described anti-aging agent is at least one of N-phenyl-α-aniline, N-phenyl-N '-sec.-propyl-Ursol D, N-N '-phenylbenzene-Ursol D, antioxidant 4020.
6. a kind of vibration damping rubber composition as claimed in claim 3, is characterized in that, described anti-aging agent is N-phenyl-α-aniline, N-N '-phenylbenzene-Ursol D, and both ratios of weight and number are 1-3:1.
7. a kind of vibration damping rubber composition as claimed in claim 6, is characterized in that, described tenderizer is at least one in ointment, stearic acid, oleic acid.
8. a kind of vibration damping rubber composition as claimed in claim 6, it is characterized in that, described composition also comprises promotor, its parts by weight are 2-8, and described promotor is any in dibenzothiazyl disulfide, tetramethyl-thiuram disulfide, zinc diethyldithiocarbamate, 2-thiol group tetrahydroglyoxaline, two butyl disulfide amido acid zinc, the N-tertiary butyl-2 benzothiazole sulphenamide.
9. a kind of vibration damping rubber composition as claimed in claim 6, is characterized in that, the parts by weight of described softening agent are 5 parts.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310620433.2A CN103665497B (en) | 2013-11-29 | 2013-11-29 | vibration damping rubber composition |
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|---|---|---|---|
| CN201310620433.2A CN103665497B (en) | 2013-11-29 | 2013-11-29 | vibration damping rubber composition |
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| CN103665497A true CN103665497A (en) | 2014-03-26 |
| CN103665497B CN103665497B (en) | 2015-09-09 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861236A (en) * | 2015-04-28 | 2015-08-26 | 安徽同丰橡塑工业有限公司 | Neoprene and styrene butadiene rubber nanocomposite |
| CN113631850A (en) * | 2019-03-28 | 2021-11-09 | 株式会社电装 | Vibration-proof device |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306030A (en) * | 2000-01-18 | 2001-08-01 | 江西省励远化工科技实业公司 | Shock-damping rubber pad and its preparing process |
| CN1428366A (en) * | 2001-12-28 | 2003-07-09 | Jsr株式会社 | Rubber composition and shockproof rubber and shockproof fittings |
| CN101560311A (en) * | 2009-02-13 | 2009-10-21 | 青岛四方车辆研究所有限公司 | Railway vehicle vibration damping and anti-flaming rubber product and preparation method thereof |
| JP2012092193A (en) * | 2010-10-26 | 2012-05-17 | Tokai Rubber Ind Ltd | Rubber composition and vibration-proof rubber using the same |
-
2013
- 2013-11-29 CN CN201310620433.2A patent/CN103665497B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1306030A (en) * | 2000-01-18 | 2001-08-01 | 江西省励远化工科技实业公司 | Shock-damping rubber pad and its preparing process |
| CN1428366A (en) * | 2001-12-28 | 2003-07-09 | Jsr株式会社 | Rubber composition and shockproof rubber and shockproof fittings |
| CN101560311A (en) * | 2009-02-13 | 2009-10-21 | 青岛四方车辆研究所有限公司 | Railway vehicle vibration damping and anti-flaming rubber product and preparation method thereof |
| JP2012092193A (en) * | 2010-10-26 | 2012-05-17 | Tokai Rubber Ind Ltd | Rubber composition and vibration-proof rubber using the same |
Non-Patent Citations (1)
| Title |
|---|
| 任庆海等: ""杜仲胶/氯丁橡胶共混及其隔音性能研究", 《陕西科技大学学报（自然科学版）》, vol. 29, no. 1, 25 February 2011 (2011-02-25), pages 35 - 37 * |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104861236A (en) * | 2015-04-28 | 2015-08-26 | 安徽同丰橡塑工业有限公司 | Neoprene and styrene butadiene rubber nanocomposite |
| CN113631850A (en) * | 2019-03-28 | 2021-11-09 | 株式会社电装 | Vibration-proof device |
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| Publication number | Publication date |
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| CN103665497B (en) | 2015-09-09 |
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Effective date of registration: 20160708 Address after: 510800, No. 38-8, first floor, west side, No. 38, Sau Sau Road, Xinhua Street, Huadu District, Guangdong, Guangzhou (can be used as workshop) Patentee after: Guangzhou welline Mstar Technology Ltd Address before: 257335 Guangrao City, Dongying Province town of Rubber Industrial Park Patentee before: Shandong Yongtai Chemical Co., Ltd. |