CN103663838A - Integrated and comprehensive water treatment equipment for electrochemical water - Google Patents

Integrated and comprehensive water treatment equipment for electrochemical water Download PDF

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Publication number
CN103663838A
CN103663838A CN201310664463.3A CN201310664463A CN103663838A CN 103663838 A CN103663838 A CN 103663838A CN 201310664463 A CN201310664463 A CN 201310664463A CN 103663838 A CN103663838 A CN 103663838A
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China
Prior art keywords
water
equipment
electrochemical
level
plate
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CN201310664463.3A
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Chinese (zh)
Inventor
刘汉元
梁勤朗
李�杰
吴宗文
欧群飞
蒋礼平
陈章
陈聪
黄平
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Chengdu Feichuang Technology Co Ltd
Tongwei Co Ltd
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Chengdu Feichuang Technology Co Ltd
Tongwei Co Ltd
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Priority to CN201310664463.3A priority Critical patent/CN103663838A/en
Publication of CN103663838A publication Critical patent/CN103663838A/en
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Abstract

The invention discloses integrated and comprehensive water treatment equipment for electrochemical water. The equipment comprises a first-level strong magnetizer, at least one second-level water electrolysis reactor, a third-level filter and a fourth-level ultraviolet sterilizer which are sequentially communicated through pipelines. The equipment disclosed by the invention belongs to the integrated innovation of physical sterilization and algae removal comprehensive techniques; viruses, bacteria and algae in the water are effectively killed after multilevel sterilization and algae removal treatment; the water quality is guaranteed to be healthy; the treated water has the functions of continuous sterilization, disinfection and algae removal due to the presence of a strong oxidant. The equipment is widely applied to the roe incubating rate increasing of aquaculture, the aquaculture wastewater treatment and the live fish clean culture as well as aquatic food processing, disinfecting and sterilizing; and the equipment has the advantages that the sustainable and healthy development of aquaculture industry is promoted, the aquatic food safety at the source is guaranteed and safe and pollution-free food for people is provided.

Description

A kind of electrochemical water integrated comprehensive water treating equipment
Technical field
The present invention relates to cultivation project equipment and food processing plant field, particularly a kind of employing physical method sterilizing, the polytechnic integrated innovation of algae, supporting assembling, the electrochemical water integrated comprehensive water treating equipment of realization " resources conservation, environment-friendly ".
Background technology
Electrification water is after the certain density electrochemical matter solution of electrification, to generate the acidity electrification water with oxidation capacity at anode in two groove diaphragm type electrification grooves, generates the alkalescence electrification water with reducing power at negative electrode.Acid electrochemical glassware for drinking water has wide spectrum, efficient, safe and harmless feature, can kill fast various pathogenic bacterias and sterilization effect is better than traditional sterilization mode.But acid electrochemical glassware for drinking water is corrosive, sour water equipment price is expensive, little its core component ion-exchange membrane of aquifer yield is running stores, when easily obstruction is serious in use procedure, causes diaphragm failures, needs periodic replacement and replacement cost high.Acid electrochemical water is deposited and is required strictly, and illumination, resistance to air loss etc. all can affect the validity of its germicidal action.Strongly-acid electrification glassware for drinking water has stronger corrodibility, in reflection process simultaneously, can produce the lower by product alkaline water of a large amount of utility values.
Summary of the invention
The object of the invention is to: for the technical problem of above-mentioned existence, provide a kind of MULTIPLE COMPOSITE sterilization, algae removal, make glassware for drinking water after processing have the electrochemical water integrated comprehensive water treating equipment of lasting sterilization and bacteria growing inhibiting effect.
Technical scheme of the present invention is achieved in that a kind of electrochemical water integrated comprehensive water treating equipment, it is characterized in that: comprise one-level strong magnetizer, at least one group of secondary brine electrolysis reactor, tertiary filter and level Four ultraviolet sterilizer, above-mentioned equipment at different levels is communicated with successively by pipeline.
Electrochemical water integrated comprehensive water treating equipment of the present invention, described in it, secondary brine electrolysis reactor comprises reactor tank body and is placed in the electrode plate groups in reactor tank body, in described reactor tank body bottom, be provided with liquid inlet, its top is provided with liquid exit, on described reactor tank body top, be provided with supply lead access port, described electrode plate groups is comprised of at least two positive plates and at least two negative plates, described positive plate and negative plate alternative expression are arranged and are arranged in parallel, described positive plate is connected by corresponding screw rod respectively with negative plate, between adjacent positive plate and negative plate, spacing is 1~4cm.
Electrochemical water integrated comprehensive water treating equipment of the present invention, described in it, secondary brine electrolysis reactor is two groups and mutually by pipeline, connects, the reaction times of single secondary brine electrolysis reactor is 3 minutes, described reactor tank body is of a size of DN300 * 1200, described electrode plate groups is comprised of four positive plates and four negative plates, and between described adjacent positive plate and negative plate, spacing is 2cm.
Electrochemical water integrated comprehensive water treating equipment of the present invention, described in it, positive plate adopts titanium-based noble metal coated electrode plate, and negative plate adopts pure titanium sheet material matter.
Electrochemical water integrated comprehensive water treating equipment of the present invention, described in it, pipeline adopts food grade PVC water supply line.
Electrochemical water integrated comprehensive water treating equipment of the present invention, equal integrated being arranged on prying body of one-level strong magnetizer, secondary brine electrolysis reactor, tertiary filter and level Four ultraviolet sterilizer described in it.
Electrochemical water integrated comprehensive water treating equipment of the present invention, described in it, secondary brine electrolysis reactor is connected with housing respectively with level Four ultraviolet sterilizer, and described secondary brine electrolysis reactor required voltage, electric current are regulated by Controlling System.
The invention belongs to physical method sterilizing, the polytechnic integrated innovation of algae, water is effectively killed virus in water body and bacterium, algae after the multistage sterilization of equipment, algae removal are processed, guarantee water quality " health ", the water after processing is because the existence of strong oxidizer has guaranteed the function of its lasting sterilization, sterilization, algae removal.The hatch fish roe that equipment is widely used in aquaculture improves hatching rate, used for aquiculture water treatment and fresh and alive fish are supported and aquatic food processing sterilization aspect only, promoted aquaculture industry sustainable and healthy development, from source, start to guarantee aquatic food safety, for people provide the food of safety non-pollution.
Accompanying drawing explanation
Fig. 1 is structural representation of the present invention.
Fig. 2 is functional block diagram of the present invention.
Fig. 3 is electric control schematic diagram of the present invention.
Fig. 4 is the structural representation of secondary brine electrolysis reactor in the present invention.
Fig. 5 is the front view of electrode plate groups in secondary brine electrolysis reactor.
Fig. 6 is the side-view of Fig. 5.
Fig. 7 is the vertical view of Fig. 5.
Mark in figure: 1 is one-level strong magnetizer, 2 is secondary brine electrolysis reactor, 3 is tertiary filter, 4 is level Four ultraviolet sterilizer, and 5 is pipeline, and 6 is reactor tank body, 7 is positive plate, 8 is negative plate, and 9 is screw rod, and 10 is liquid inlet, 11 is liquid exit, 12 is supply lead access port, and 13 is prying body, and 14 is housing.
Embodiment
Below in conjunction with accompanying drawing, the present invention is described in detail.
In order to make object of the present invention, technical scheme and advantage clearer, below in conjunction with drawings and Examples, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
As Fig. 1, shown in 2 and 3, a kind of electrochemical water integrated comprehensive water treating equipment, comprise one-level strong magnetizer 1, two groups of secondary brine electrolysis reactors 2, tertiary filter 3 and level Four ultraviolet sterilizer 4, the pipeline 5 that above-mentioned equipment at different levels supplies water by food grade PVC is communicated with successively, described one-level strong magnetizer 1, secondary brine electrolysis reactor 2, tertiary filter 3 and level Four ultraviolet sterilizer 4 be integrated being arranged on prying body 13 all, described secondary brine electrolysis reactor 2 is connected with housing 14 respectively with level Four ultraviolet sterilizer 4, described secondary brine electrolysis reactor 2 required voltages, electric current is regulated by Controlling System.
The present invention is divided into level Four, and MULTIPLE COMPOSITE sterilization, algae removal make water quality reach aseptic, algae water condition.Glassware for drinking water after processing has lasting sterilization and bacteria growing inhibiting effect.
Coagulation: first former water enter strong Management of magnetic water device, forms em polarization water, changes water clusters clustering architecture.Current, through the action of a magnetic field, change specific conductivity, osmotic pressure, electromagnetic environment, and microorganism cells breaks, and cell stops the effect that breeding reaches sterilizing, algae removal and suppresses the microbial reproduction in water.Molecular structure water generation series of physical changes, and hydrogen bond angle becomes 103 ° by 105 °, and water becomes subset by original macromolecular mass magnetic field intercepts.The seepage force of water, solubleness, surface tension strengthen.
Second-stage treatment: enter electro-chemical water treater after strong magnetic treatment, through heavy metal ion and calcium, magnesium ion in electricity flocculation removal water, electrochemical treatment is further killed bacterium, gemma, the algae in water again; Electro-chemical reaction anode adopts titanium-based noble metal coated electrode plate, and negative electrode adopts pure titanium sheet material matter, and research shows that in electrochemical effect, interelectrode distance does not change, and can guarantee that electrification operates in the stable situation of bath voltage to carry out; Operating voltage is low, power consumption is little, current efficiency is high; Can overcome graphite anode and lead anode problems of dissolution, avoid the pollution to electrochemical liquid and cathode product, improve the quality of product; Erosion resistance is strong, can be strong in much corrodibility, work in the electrochemical medium that has particular requirement, and the titanium anode working life-span is long; Electrode is lightweight, can reduce labor intensity, and the use of can regenerating of matrix titanium material.
When reaction water is chloride electro-chemical solution:
Main reaction: Cl --2e+H 20=HClO+H +
Side reaction: 2H 2o-4e=4H ++ O 2
O 2+2H ++2e=H 2O 2
3H 2O-6e=6H ++O 3
Generate strong oxidizer HClO, O 3, H 2o 2continue sterilization, algae removal.
When reaction water quality is during for chloride breeding water not:
By electrode, power delivery is inner to water body, make bacterium electric shock sterilization; Change solution and solute situation simultaneously, produce the multiple actions such as electronics modify-water, electro-flotation, ionization purification.Meanwhile, this device utilizes additional special electric energy to change by force the combining form of solvents, destroys bacteria live condition antibacterial.The highly active ion sterilization that coordinates electrode to discharge.
Tertiary treatment: hold back the impurity such as suspended substance in the above large granular impurity of 5 μ m and water, micelle by strainer, strainer must regularly replace filter core or back flushing quartz sand regularly again.
Level Four is processed: finally by the further sterilization and disinfection of ultraviolet sterilizer.Utilize the ultraviolet ray of high frequency C-band to produce destruction to the DNA of various microorganisms, kill bacterium and virus; Can produce a certain amount of ozone, keep continuing sterilizing ability.
As shown in Figure 4, described secondary brine electrolysis reactor 2 comprises reactor tank body 6 and is placed in the electrode plate groups in reactor tank body 6, the reaction times of single secondary brine electrolysis reactor is 3 minutes, described reactor tank body 6 is of a size of DN300 * 1200(mm), in described reactor tank body 6 bottoms, be provided with liquid inlet 10, its top is provided with liquid exit 11, on described reactor tank body 6 tops, be provided with supply lead access port 12, described electrode plate groups is comprised of four positive plates 7 and four negative plates 8, described positive plate 7 and negative plate 8 alternative expressions are arranged and are arranged in parallel, described positive plate 7 is connected by corresponding screw rod 9 respectively with negative plate 8, between adjacent positive plate 7 and negative plate 8, spacing is 2cm, wherein, described positive plate 7 adopts titanium-based noble metal coated electrode plate, negative plate 8 adopts pure titanium sheet material matter.
Wherein, for the decoration form of described positive plate and negative plate, carried out the simultaneous test of various structures design, according to test of many times result, electro-chemical reaction efficiency raises than increasing with battery lead plate useful area and container effective volume, therefore, select power consumption and the high parallel-plate electrode structure of electrochemical efficiency.At the test battery lead plate of selecting 6 kinds of different patterns, guarantee to process water same, by electric current, voltage modulated maximum, test-results is as follows:
Electrode form Voltage (V) Electric current (A) Sterilizing rate (%) Oxygen dissolving value (mg/L)
Parallel-plate electrode 60 6.5 94.5 8.3
Container (plate) formula 62 5.4 88.3 6.6
Press filter type 50 7.1 90.1 7.1
Heap disc type 57 5.2 83.2 6.6
Concentric drums 42 5.4 78.2 5.8
Flow type 71 5.2 91.7 7.8
For the electro-chemical reaction time, according to faraday's First Law, research shows, electrochemical efficiency is directly proportional to strength of current and conduction time.The many experiments proof electro-chemical reaction time is greater than 5min germ-killing efficiency and can reaches more than 99%, but the reaction times is long, and it is faint that sterilization promotes effect, and equipment reduces costs and guarantee aquifer yield 4m 3/ h electrification water retort size is set as DN300X1200, and now the single retort reaction times is 3min, therefore adopt the structure of two secondary brine electrolysis reactors in series in order to reach the best use of time.
Adopt a test electricity consumption water desalting plant, guarantee to process water identical, electric current, voltage are identical, test-results is as follows, conclusion (of pressure testing): after electrochemical 5min, sterilizing rate can reach more than 99%, therefore, the electrochemical water retort of DN300X1200 size of take is example, it is 6min that two tanks connect the use electrification time, and guarantees that aquifer yield is greater than 4m 3/ h.
For the spacing between positive plate and negative plate, too little reactor short circuit, the voltage increasing that the too large needs of distance apply, power consumption increase and the electro-chemical reaction Efficiency Decreasing of easily causing of battery lead plate spacing.Process many experiments result: reaching the best use of effect required voltage during d=2cm is 50V, and during d=3cm, the best use of voltage is 60V, and during d=4cm, the best use of voltage is 80V, therefore, is optimum distance while selecting spacing d=2cm in this equipment.Adopt a test electricity consumption water desalting plant, guarantee to process water identical, the time is 4min, and test-results is as follows:
Polar plate spacing (cm) Voltage (V) Electric current (A) Sterilizing rate (%) Power consumption
1 45 5.2 95.2 234
2 50 5.7 95.2 285
3 60 6.8 94.8 408
4 80 7.3 95.4 584
To sum up, at equipment, reduce costs and guarantee aquifer yield 4m 3/ h, electrochemical water retort size is set as DN300X1200, and the efficiency of electro-chemical reaction improves and equipment sterilization effect is directly proportional to electro-chemical reaction efficiency than increasing with the effective volume of battery lead plate useful area and container.Therefore in container useful volume one timing electro-chemical reaction efficiency, be directly proportional to the limited area of battery lead plate, cathode-anode plate spacing 2cm, electrode plate groups can not contact with electro-chemical reaction tank tube wall, arranges 8 electrode plate therefore maximum.Through repeatedly repeating experimental result, show, while adopting 2 pairs of 4 pole plates, sterilizing rate is 70%, while adopting 3 pairs of 6 pole plates, sterilizing rate is 96%, and while adopting 4 pairs of 8 pole plates, does not detect bacterium residual in the electrochemical water after processing, in marginal test, adopt 5 pairs of 10 pole plates, in the electrochemical water after processing, do not detect bacterium residual, but due to effect and 8 close, add the factors such as cost and electrochemical tank volume, be finally decided to be 8.
Wherein, the hard magnetization of one-level strong magnetizer is processed and is changed water clusters clustering architecture macromolecular structure, water becomes 5-6 subsets by 13-18 original macromolecular mass, and water body specific conductivity and electromagnetic environment change, and when microorganism is killed, also can improve electro-chemical reaction efficiency.
Adopt equipment of the present invention to process respectively Spawning water or breeding water and certain density NaCl solution, be specially:
One, utilize it to process Spawning water or breeding water.As shown in Figure 2, the first step strong magnetizer that pending water (Spawning water or breeding water) is sent into electrochemical water integrated comprehensive water treating equipment through water pump extraction carries out hard magnetization processing, specific conductivity, penetration degree are changed, microorganism cells breaks, cell stops breeding and reaches the microbial reproduction in sterilizing, algae removal, inhibition water, water is cut into subset by macromolecular mass, and hydrogen bond angle becomes 103 ° by 105 °.The seepage force of water, solubleness, surface tension strengthen, and prevent fouling; After strong magnetic treatment, send into secondary brine electrolysis reactor, heavy metal ion and calcium, magnesium ion, impurity in electricity flocculation, electro-flotation removal water, electrochemical treatment is further killed bacterium, gemma, the algae in water, and electrification increases dissolved oxygen amount in water body; After secondary brine electrolysis reactor for treatment, through tertiary filter, filtering is greater than suspended solid, the colloid in the above large granular impurity of 5 μ m and water again; Finally again through the further disinfection of level Four ultraviolet sterilizer.
Hatching and aquaculture water water are after equipment complex is processed, produce that dissolved oxygen is high, aseptic, the aseptic electrochemical water of neutrality of algae, insect pest and suspended particle, and this neutrality electrification water also possesses certain characteristic that continues sterilizing ability, support temporarily and consume live fish fill, improve tolerance and effectively kill body surface bacterium simultaneously, make fish body " totally " more, improve and support temporarily and transportation survival rate, and to fish body without injury, for fish bulk-growth has been created a good water body environment, effectively prevent fish disease, reduce cultivation risk, improved Safety of Aquatic Products.
Two, utilize it to process certain density NaCl solution.As shown in Figure 2, the first step strong magnetizer that pending water (certain density NaCl solution) is sent into electrochemical water integrated comprehensive water treatment complete equipment through water pump extraction is processed through row hard magnetization, specific conductivity, penetration degree are changed, microorganism cells breaks, cell stops breeding and reaches the microbial reproduction in sterilizing, algae removal, inhibition water, water is cut into subset by macromolecular mass, and hydrogen bond angle becomes 103 ° by 105 °.The seepage force of water, solubleness, surface tension strengthen, and prevent fouling; After strong magnetic treatment, send into secondary brine electrolysis reactor, heavy metal ion and calcium, magnesium ion, impurity in electricity flocculation, electro-flotation removal water, electrochemical treatment is further killed bacterium, gemma, the algae in water, and strong electro-chemical reaction occurs,
Wherein, anodic reaction is:
Cl --2e+H 20=HClO+H +
2H 2O-4e=4H ++O 2
3H 2O-6e=6H ++O 3
Cathodic reaction is:
O 2+2H ++2e=H 2O 2
2H ++2e=H 2
Thereby generate strong oxidizer HClO, O 3, H 2o 2continue sterilization, algae removal; And then filtering is greater than the above large granular impurity of 5 μ m through tertiary filter, finally again through the further disinfection of level Four ultraviolet sterilizer.
The neutral sterilization electrification water generating through device processes, its pH value 6.5-8.0, available chlorine ACC concentration (50mg/L-150mg/L), redox potential 800mV-1300mV, do not have corrodibility; This water sample action time≤1min, can effectively quantitatively kill intestinal bacteria, streptococcus aureus, Candida albicans, subtilis, concentration logarithmic value >=5; Action time≤5min, can quantitatively kill aquatic products common bacteria: Aeromonas hydrophila, Aeromonas caviae, Aeromonas veronii, acinetobacter calcoaceticus, concentration logarithmic value >=7.Equipment replaces on pharmaceutical chemicals sterilization algae removal, having wide spectrum in the processing of aquaculture hatching and aquatic food, the characteristic of efficient, non-secondary pollution, has a extensive future.
The foregoing is only preferred embodiment of the present invention, not in order to limit the present invention, all any modifications of doing within the spirit and principles in the present invention, be equal to and replace and improvement etc., within all should being included in protection scope of the present invention.

Claims (7)

1. electrochemical water integrated comprehensive water treating equipment, it is characterized in that: comprise one-level strong magnetizer (1), at least one group of secondary brine electrolysis reactor (2), tertiary filter (3) and level Four ultraviolet sterilizer (4), above-mentioned equipment at different levels is communicated with successively by pipeline (5).
2. electrochemical water integrated comprehensive water treating equipment according to claim 1, it is characterized in that: described secondary brine electrolysis reactor (2) comprises reactor tank body (6) and is placed in the electrode plate groups in reactor tank body (6), in described reactor tank body (6) bottom, be provided with liquid inlet (10), its top is provided with liquid exit (11), on described reactor tank body (6) top, be provided with supply lead access port (12), described electrode plate groups is comprised of at least two positive plates (7) and at least two negative plates (8), described positive plate (7) and negative plate (8) alternative expression are arranged and are arranged in parallel, described positive plate (7) is connected by corresponding screw rod (9) respectively with negative plate (8), between adjacent positive plate (7) and negative plate (8), spacing is 1~4cm.
3. electrochemical water integrated comprehensive water treating equipment according to claim 2, it is characterized in that: described secondary brine electrolysis reactor (2) is two groups and mutually by pipeline (5), connects, the reaction times of single secondary brine electrolysis reactor is 3 minutes, described reactor tank body (6) is of a size of DN300 * 1200, described electrode plate groups is comprised of four positive plates (7) and four negative plates (8), and between described adjacent positive plate (7) and negative plate (8), spacing is 2 cm.
4. electrochemical water integrated comprehensive water treating equipment according to claim 3, is characterized in that: described positive plate (7) adopts titanium-based noble metal coated electrode plate, and negative plate (8) adopts pure titanium sheet material matter.
5. electrochemical water integrated comprehensive water treating equipment according to claim 4, is characterized in that: described pipeline (5) adopts food grade PVC water supply line.
6. according to the electrochemical water integrated comprehensive water treating equipment described in any one in claim 1 to 5, it is characterized in that: described one-level strong magnetizer (1), secondary brine electrolysis reactor (2), tertiary filter (3) and level Four ultraviolet sterilizer (4) be integrated being arranged on prying body (13) all.
7. electrochemical water integrated comprehensive water treating equipment according to claim 6, it is characterized in that: described secondary brine electrolysis reactor (2) is connected with housing (14) respectively with level Four ultraviolet sterilizer (4), and described secondary brine electrolysis reactor (2) required voltage, electric current are regulated by Controlling System.
CN201310664463.3A 2013-12-10 2013-12-10 Integrated and comprehensive water treatment equipment for electrochemical water Pending CN103663838A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104098218A (en) * 2014-07-31 2014-10-15 合肥一言图文设计有限责任公司 Water-purifying process and water-purifying equipment thereof
CN105254079A (en) * 2014-06-19 2016-01-20 徐才浚 Pool water purification apparatus
CN106542683A (en) * 2016-12-09 2017-03-29 通威股份有限公司 A kind of utilization magnetic field and electric field prepare the technique that small water molecule rolls into a ball water

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1104184A (en) * 1993-12-26 1995-06-28 于忠辅 Electrochemical water-purifying device
CN2491449Y (en) * 2001-06-29 2002-05-15 任晓柱 High power rare-earth magnetizing ion water equipment
CN101033105A (en) * 2007-02-01 2007-09-12 彭云龙 Photoelectromagnetism integrated waste water advanced oxidization method and device thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1104184A (en) * 1993-12-26 1995-06-28 于忠辅 Electrochemical water-purifying device
CN2491449Y (en) * 2001-06-29 2002-05-15 任晓柱 High power rare-earth magnetizing ion water equipment
CN101033105A (en) * 2007-02-01 2007-09-12 彭云龙 Photoelectromagnetism integrated waste water advanced oxidization method and device thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105254079A (en) * 2014-06-19 2016-01-20 徐才浚 Pool water purification apparatus
CN105254079B (en) * 2014-06-19 2018-06-26 徐才浚 Purifying pool water device
CN104098218A (en) * 2014-07-31 2014-10-15 合肥一言图文设计有限责任公司 Water-purifying process and water-purifying equipment thereof
CN104098218B (en) * 2014-07-31 2016-01-06 合肥一言图文设计有限责任公司 Water-purifying process and water purifying plant thereof
CN106542683A (en) * 2016-12-09 2017-03-29 通威股份有限公司 A kind of utilization magnetic field and electric field prepare the technique that small water molecule rolls into a ball water

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Application publication date: 20140326