CN103662190B - Seal container - Google Patents
Seal container Download PDFInfo
- Publication number
- CN103662190B CN103662190B CN201310393424.4A CN201310393424A CN103662190B CN 103662190 B CN103662190 B CN 103662190B CN 201310393424 A CN201310393424 A CN 201310393424A CN 103662190 B CN103662190 B CN 103662190B
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- Prior art keywords
- sealing
- barrier layer
- junction surface
- thermoplastic resin
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D75/00—Packages comprising articles or materials partially or wholly enclosed in strips, sheets, blanks, tubes, or webs of flexible sheet material, e.g. in folded wrappers
- B65D75/28—Articles or materials wholly enclosed in composite wrappers, i.e. wrappers formed by associating or interconnecting two or more sheets or blanks
- B65D75/30—Articles or materials enclosed between two opposed sheets or blanks having their margins united, e.g. by pressure-sensitive adhesive, crimping, heat-sealing, or welding
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/34—Electrical apparatus, e.g. sparking plugs or parts thereof
- B29L2031/3468—Batteries, accumulators or fuel cells
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B27/08—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B51/00—Devices for, or methods of, sealing or securing package folds or closures; Devices for gathering or twisting wrappers, or necks of bags
- B65B51/10—Applying or generating heat or pressure or combinations thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65D—CONTAINERS FOR STORAGE OR TRANSPORT OF ARTICLES OR MATERIALS, e.g. BAGS, BARRELS, BOTTLES, BOXES, CANS, CARTONS, CRATES, DRUMS, JARS, TANKS, HOPPERS, FORWARDING CONTAINERS; ACCESSORIES, CLOSURES, OR FITTINGS THEREFOR; PACKAGING ELEMENTS; PACKAGES
- B65D77/00—Packages formed by enclosing articles or materials in preformed containers, e.g. boxes, cartons, sacks or bags
- B65D77/10—Container closures formed after filling
- B65D77/20—Container closures formed after filling by applying separate lids or covers, i.e. flexible membrane or foil-like covers
Abstract
The present invention provides a kind of sealing container that can stably obtain high obstructing performance, the at least one side of barrier layer (13) is laminated with the laminate wrapping material (10a of thermoplastic resin (14), 10b), overlap in the way of thermoplastic resin (14) is placed in inner side, by overlapping laminate wrapping material (10a, periphery 10b) engages and seals, it is consequently formed resettlement section (16), wherein, the sealing (31) of described periphery has the heat-sealing portion (33) being deposited with thermoplastic resin (14), with the multiple barrier layer junction surfaces (34) making barrier layer (13) be engaged with each other, the plurality of barrier layer junction surface (34) in heat-sealing portion (33) discontinuously with mottled configuration.
Description
The application is willing to 2012-based on the Japanese patent application laid that on August 29th, 2012 submits to
No. 189015 and CLAIM OF PRIORITY, and the disclosure of which is directly constituted the part of the application.
Technical field
The present invention relates to use at the battery housings such as lithium rechargeable battery and various food
Sealing container in sealing bag (retort pouch) etc. and correlation technique thereof.
Background technology
Sealing container has been used for the packaging of the above-mentioned article not liking light, oxygen, moisture,
This sealing container uses and is laminated to thermoplastic resin interdict light, oxygen, the metal of moisture
Laminate wrapping material on barrier layer.As shown in Figures 1 and 2, above-mentioned sealing container 100
It is typically the thermoplastic resin 14 of laminate wrapping material 10a, 10b to be placed in inner side and weighs
Folded, and circumference is sealed and is manufactured into.As shown in figure 11, the method manufacture
Seal container 100 periphery sealing 101 by making thermoplastic resin 14 deposition each other
And formed.
Above-mentioned sealing container 100 by metal barrier 13 with outside light, oxygen gas and water
Separate absolutely.But, the sealing 101 of above-mentioned sealing container 100 from outer circumference end until inner circumferential
Hold and be communicated with thermoplastic resin 14, thus, worry the peripheral end face from sealing 101
The light of trace of intrusion, oxygen, moisture can invade collecting by thermoplastic resin 14
In portion 16.Even if their intrusion volume is trace, also can worry once to invade to resettlement section
16 can produce various problem.Such as, in sealing the containers for food use such as bag, once aerobic
Gas cut enters, and content will degenerate.If it addition, packed as lithium rechargeable battery
If electrolyte, then worry that once having moisture to invade will produce Fluohydric acid. and sealing property
Significantly reduce.
For the problems referred to above, patent documentation 1 proposes a kind of method, i.e. strength presses ballast
Folded laminate wrapping material so that barrier layer one another along peripheral direction with wire near to or in contact with
Mode seal.According to this encapsulating method, if making barrier layer closer to each other, then narrow
Thermoplastic resin can form narrow road, so that light etc. are difficult to invade.If it addition, intercepting
If layer contacts with each other, owing to thermoplastic resin interrupts at contact point, it is possible to stop
The intrusion (with reference to patent documentation 1) of light etc..
Patent documentation 1: Japanese Unexamined Patent Publication 2000-264313 publication
The method recorded by patent documentation 1 can make barrier improve.But, even if making
Barrier layer, close to forming narrow road, the most simply makes intrusion sectional area diminish, therefore cannot
Blocking light etc. completely.And, the transmission from the heat of hot sealing device can be due to outside air temperature
Deng and there is deviation, therefore, it is difficult to make intrusion sectional area stable, and then barrier property can not yet
Stable.It addition, resin can be pushed in order to make barrier layer contact with each other, but when wire-shaped contact
Only push up against resin in single shaft side, therefore the mobility of resin is very poor.Thus, in order to really
Push resin on the spot and barrier layer is engaged with each other, need to impose severe pressure.It addition,
If remaining resin if pushing amount is not enough on joint interface, then can be formed and invade from outside
The path entered.If if there is non-bonding part in the part in wire-shaped contact portion, then light etc.
Can pass through from which and invade to internal with beeline, therefore barrier property can become unstable
Fixed.
Summary of the invention
The present invention is in view of above-mentioned technical background, to provide one can stably obtain high-barrier
For the purpose of the sealing container of performance and correlation technique thereof.
That is, the present invention has the structure that following [1]~[12] is recorded.
[1] a kind of sealing container, is laminated with thermoplastic resin at least one side of barrier layer
Laminate wrapping material, overlapping in the way of thermoplastic resin is placed on inner side, by overlap
Laminate wrapping material periphery engage and seal, be consequently formed resettlement section, it is characterised in that
The sealing of described periphery has and is deposited with the heat-sealing portion of thermoplastic resin and makes resistance
Multiple barrier layer junction surfaces that interlayer is engaged with each other, the plurality of barrier layer junction surface is in heat-sealing
Discontinuously with mottled configuration in portion.
[2] according to the sealing container described in preceding paragraph 1, it is characterised in that described barrier layer is by gold
Belong to and constituting.
[3] according to the sealing container described in preceding paragraph 1 or 2, it is characterised in that close with described
At least one barrier layer junction surface is there is on the arbitrary line that the periphery in envelope portion is orthogonal.
[4] according to the sealing container according to any one of preceding paragraph 1~3, it is characterised in that with
Be orthogonal to the periphery of described sealing straight line angled for the arbitrary line less than 45 °
On, there is at least one barrier layer junction surface.
[5] according to the sealing container according to any one of preceding paragraph 1~4, it is characterised in that described
The flat shape at barrier layer junction surface is rhombus.
[6] according to the sealing container described in preceding paragraph 5, it is characterised in that described barrier layer engages
The flat shape in portion is the rhombus that catercorner length is different, and this barrier layer junction surface is so that longer
Diagonal configure along the mode of the peripheral direction of sealing.
[7] according to the sealing container according to any one of preceding paragraph 1~6, it is characterised in that in institute
State and on the width of sealing, be configured with multiple row barrier layer junction surface.
[8] according to the sealing container according to any one of preceding paragraph 1~7, it is characterised in that in institute
Have in stating the region, inner circumferential side of sealing: there is no barrier layer junction surface and only by heat-sealing portion structure
The region become.
[9] according to the sealing container according to any one of preceding paragraph 1~8, it is characterised in that described
Sealing container is battery housing.
[10] a kind of battery, it is characterised in that battery main body is seated in the electricity described in preceding paragraph 9
In the housing of pond, it is drawn out to outside housing at the electrode lead-in wire being connected with described battery main body
State under, the periphery of this housing is formed sealing.
[11] a kind of manufacture method sealing container, it is characterised in that carry out following operation:
Thermoplastic resin will be laminated with at least one side of the barrier layer being made up of metal
Laminate wrapping material, operation overlapping in the way of making thermoplastic resin become inner side;
Heat by being clipped the periphery of the laminate wrapping material of overlap by pressing plate, and make
The heat-sealing portion formation process of thermoplastic resin deposition each other;With
On the periphery of overlapping laminate wrapping material, pressing is the most discontinuously
With the fixture of the mottled band projection being provided with multiple projection, grant ultrasonic activation,
By the front end face pushing thermoplastic resin of described projection so that barrier layer exposes, then will be revealed
The barrier layer junction surface formation process that the barrier layer gone out is engaged with each other,
On the periphery of overlapping laminate wrapping material, be formed in heat-sealing portion discontinuously with
The mottled sealing being configured with multiple barrier layer junction surface.
[12] according to the manufacture method sealing container described in preceding paragraph 11, it is characterised in that
After having carried out described heat-sealing portion formation process, it is in soft state at thermoplastic resin
Period carries out barrier layer junction surface formation process.
Invention effect
According to the hermetic container described in above-mentioned [1], owing to being intended to invade to appearance from the end face of sealing
The deteriorations such as light in device, water, oxygen promote that thing is blocked a layer junction surface blocking, so from resistance
Interlayer junction surface is roundabout and only advances in heat-sealing portion.This intrusion path is in adjacent resistance
The narrow road formed between interlayer junction surface, sectional area diminishes, and therefore deterioration promotes the intrusion of thing
Suppressed.Further, the distance making intrusion path by forming alternate path is elongated,
Thus deterioration promotes that the intrusion of thing is suppressed.
It addition, above-mentioned barrier layer junction surface in heat-sealing portion discontinuously with mottled formation,
Thus, the whole of barrier layer junction surface is around all heat-sealing portion, is all thermoplastic resin.Cause
This, in order to be engaged with each other by barrier layer, and push thermoplastic resin to make barrier layer expose
Time, it is possible to resin is pushed to all directions of the surrounding of barrier layer junction surface (reservations),
Thus, resin can flow well and easily make barrier layer expose.Thus, with little
Exert pressure and just can positively form barrier layer junction surface, and then be obtained in that stable barrier
Energy.
It addition, compared with the heat-sealing portion of resin deposition each other, make barrier layer junction surface
Adhesion become higher in the case of, sealing is relative to making resistance to from outside stress
Peel strength improves.
According to the sealing container described in above-mentioned [2], owing to the barrier layer of laminate wrapping material is gold
Belong to, so barrier property and intensity are the highest.
According to the sealing container described in above-mentioned [3], cross sealing owing to not existing with beeline
The intrusion path in portion, it is possible to positively extend the distance invading path.
According to the sealing container described in above-mentioned [4], orthogonal straight relative to the periphery of sealing
Line, the angle of inclination invading path of straight line is more than 45 °.Above-mentioned angle of inclination becomes more
Greatly, the distance invading path can become the longest, thus obtains corresponding with above-mentioned angle of inclination
Deterioration promotes the intrusion inhibition of thing.
According to the sealing container described in above-mentioned [5], it is possible to by linear cutter manufacture for
Form the fixture of the band projection at barrier layer junction surface, therefore, it is possible to manufacture fixture with low cost.
According to the sealing container described in above-mentioned [6], orthogonal straight relative to the periphery of sealing
Line, the angle of inclination invading path of straight line is more than 45 °.Above-mentioned angle of inclination becomes the biggest,
The distance invading path can become the longest, thus obtains deteriorate corresponding with above-mentioned angle of inclination
Promote the intrusion inhibition of thing.
According to the sealing container described in above-mentioned [7], owing to invading the roundabout number of times of path according to row
Count and increase, it is possible to make the distance of intrusion path become longer.
According to the sealing container described in above-mentioned [8], owing to the region, inner circumferential side of sealing does not exists
Barrier layer junction surface and be only made up of heat-sealing portion, so content only connects with thermoplastic resin
Touch.This sealing container is for needing to avoid the packaging of the content contacted with barrier layer also can pacify
Full use.
According to the sealing container described in above-mentioned [9], battery housing is obtained in that above-mentioned effect
Really.
According to the battery described in above-mentioned [10], promoting thing relative to deterioration, barrier property is the highest,
And it is obtained in that stable barrier property.
According to the manufacture method sealing container described in above-mentioned [11], it is possible to using barrier layer is gold
The laminate wrapping material belonged to manufactures the sealing container that barrier property is stable.
According to the manufacture method sealing container described in above-mentioned [12], due to the heat by first carrying out
Envelope portion formation process can be flattened thermoplastic resin and make it thinning, so the resistance carried out after by
Even if ultrasonic bonding the pushed amount of resin of interlayer junction surface formation process tails off also may be used
With, therefore, barrier layer joint each other becomes easy.And, soft by being at resin
The period of change state carries out ultrasonic bonding, and the pushing of resin can be easy to, therefore barrier layer
The formation at junction surface is also easy to, it is possible to carry out encapsulation process efficiently.
Accompanying drawing explanation
Fig. 1 is the battery housing of an embodiment of the hermetic container representing the present invention
The axonometric chart of the state before encapsulation process.
Fig. 2 is the sectional view of the sealing circumference of the battery housing of Fig. 1.
Fig. 3 is the axonometric chart of the battery of the battery housing using Fig. 1.
Fig. 4 A is the top view of the sealing of battery housing.
Fig. 4 B is the sectional view of the sealing of battery housing.
Fig. 5 is other embodiments of the sealing on hermetic container.
Fig. 6 is the another embodiment of the sealing on hermetic container.
Fig. 7 is the another embodiment of the sealing on hermetic container.
Fig. 8 is the another embodiment of the sealing on hermetic container.
Fig. 9 is the another embodiment of the sealing on hermetic container.
Figure 10 is in the manufacture method of the hermetic container of the present invention, represents encapsulation process operation
Sectional view.
Figure 11 is the sectional view of the periphery sealing of existing sealing container.
Description of reference numerals
1-battery is with housing (sealing container)
2-battery
10a, 10b-case half bodies (laminate wrapping material)
11-recess
12-sealing circumference
13-barrier layer
14-thermoplastic resin
15-outer layer
16-resettlement section
20-positive pole goes between
21-negative pole goes between
30-periphery sealing
31-the first sealing (sealing)
33,41,46,51,56,61-heat-sealing portion
34,47,52,57,62-barrier layer junction surface
Region, 36-inner circumferential side
40,45,50,55,60-sealing
The diagonal that 63-is longer
70,71-heat-sealing pressing plate
72-projection
The fixture of 73-band projection
Detailed description of the invention
[sealing the summary of container]
Fig. 1 and Fig. 2 represents the battery housing 1 that constitutes based on laminate wrapping material
State before encapsulation process, represents in Fig. 3 and above-mentioned battery housing 1 is carried out encapsulation process
And the battery 2 manufactured.The battery housing 1 implementing encapsulation process is the airtight appearance of the present invention
One embodiment of device.It addition, in the following description, including from the outside sealing container
Invade and make, including light that content deteriorate, oxygen, moisture etc., to be referred to as " deterioration promotion thing ".
Battery housing 1 be will be formed with sealing circumference 12 two case half bodies 10a,
10b configures in the way of the peristome that makes recess 11 is relative, and by overlapping sealing periphery
Portion 12 engages, and is consequently formed the parts of resettlement section 16, this sealing with circumference 12 from vertical view
Opening periphery for the recess 11 of tetragon extends to the outside of general horizontal direction.Such as Fig. 2
Shown in, above-mentioned case half bodies 10a, 10b are shape to laminate wrapping material enforcement stretch process
Becoming to have the parts of recess 11, this laminate wrapping material is laminated with in the one side of barrier layer 13
Thermoplastic resin 14, and on another side, it is laminated with outer layer 15, housing after assembling
Halfbody 10a, 10b make thermoplastic resin 14 contact with each other in sealing circumference 12.
[laminate wrapping material]
In above-mentioned laminate wrapping material 10a, 10b, the preferred material of each layer is as follows.
As long as the material of barrier layer 13 can interdict deterioration promotes the material of thing, there is no
Limit.As the preferred material of barrier layer 13, with barrier height, bond strength this point high,
The metals such as aluminum, copper, ferrum can be recommended.Further, it is possible to by using these metals to make
It is suitable for ultrasonic bonding in encapsulation process described later for barrier material.
As long as the material becoming the thermoplastic resin 14 sealing inner surface of container can be by warm
Plastic resin carries out the material of deposition, it is possible to use any materials, particularly preferred CPP
(un-stretched polypropylene) and polyethylene.These thermoplastic resins easily soften, and are consequently adapted to
Push the encapsulation process that resin makes barrier layer 13 be engaged with each other.
The material of outer layer 15 preferably fusing point higher tree compared with thermoplastic resin 14
Fat, can recommend polyethylene terephthalate and polyamide.
The essential condition of the laminate wrapping material sealed in container being applicable to the present invention is,
The face facing container inside is thermoplastic resin, and compared with this thermoplastic resin 14
There is in outside barrier layer 13, as long as meet the material of this condition, the most also can be suitably used for it
The packaging material of his stepped construction.Although the presence or absence of the outer layer 15 of illustrated example is also any
, but in order to protect barrier layer 13, the laminate wrapping material with outer layer 15 is preferably used.
It addition, in encapsulation process described later, if there being outer layer 15, be the most also avoided that with sealing use
Fixture clips the damage of the barrier layer 13 in the case of pressurizeing.Alternatively, it is also possible to be,
There is between barrier layer 13 and thermoplastic resin 14 or outer layer 15 stacking in intermediate layer
Structure.
Although the thickness constituting each layer of above-mentioned laminate wrapping material 10a, 10b is not defined yet,
But make barrier layer 13 owing to carrying out in the present invention pushing the resin of thermoplastic resin 14
The encapsulation process being engaged with each other, as long as so being able to ensure that bond strength, thermoplastic resin
14 is the most relatively thin.From this viewpoint, the thickness of thermoplastic resin 14 is 10~100 μm,
Especially preferably 20~40 μm.It addition, the thickness of above-mentioned barrier layer 13 is preferably thermoplastic resin
More than the 1/3 of the thickness of lipid layer 14.In encapsulation process, clip laminate packaging material with fixture
Material 10a, 10b push resin, therefore, in order to not make barrier layer 13 break in this operation
Split, the thickness of the most above-mentioned scope.The thickness of especially preferred outer layer 15 is
10~80 μm.
[using the battery sealing container]
As it is shown on figure 3, in using the manufacture of battery 2 of above-mentioned battery housing 1,
In the recess 11 of the case half bodies 10b of one side house battery main body, and will respectively with battery master
Positive pole that the positive pole of body is connected with negative pole lead-in wire 20 and negative pole go between 21 be drawn out to outside
Portion, in this case, covers the case half bodies 10a of the opposing party and by sealing circumference 12
Overlap carries out encapsulation process.Above-mentioned positive pole lead-in wire 20 and negative pole lead-in wire 21 are respectively
By tab film (tab film) 22,23 clamping state under be arranged in sealing circumference 12,
Between 12.Therefore, if carrying out the encapsulation process of sealing circumference 12,12, then it is formed at
The first sealing 31 in lead-in wire 20,21 the most derivative parts, is directly bonded to upper and lower
Seal and use circumference 12,12, and be formed at second in the parts of 20,21 extractions that will go between
Sealing 32 is bonded to upper and lower sealing and uses via lead-in wire 20,21 and lead-in wire film 22,23
Circumference 12,12.Above-mentioned battery housing 1 is formed by two first sealings on all-round
The periphery sealing 30 that portion 31 and two the second sealings 32 are constituted, and at lead-in wire 20,21
The state lower seal being drawn out to outside housing.
[sealing the sealing of container]
On above-mentioned periphery sealing 30, it is formed at the most derivative part of lead-in wire 20,21
On the first sealing 31 corresponding with the sealing of the present invention, it is by heat-sealing portion and barrier layer
Junction surface and constitute.
As shown in fig. 4 a and fig. 4b, the first sealing 31 by by thermoplastic resin 14,
The deposition of 14 and the heat-sealing portion 33 that formed and the resin pushing thermoplastic resin 14 and make
Multiple barrier layer junction surfaces 34 that barrier layer 13,13 is engaged with each other and formed.Above-mentioned heat-sealing
In the whole region of the width that portion 33 is formed at the first sealing 31, in contrast,
In the zone line 35 that barrier layer junction surface 34 is made only on width, inner circumferential lateral areas
There is not barrier layer junction surface 34 in territory 36 and outer circumferential side region 37, and only exist heat-sealing
Portion 33.
Above-mentioned heat-sealing portion 33 is uninterrupted in the whole region of the first sealing 31, but even
Continue, in contrast, multiple barrier layer junction surface 34 is the most discontinuous, and in heat-sealing portion 33
In with mottled existence.It addition, each barrier layer junction surface 34 be shaped as two cornerwise
The rhombus (square) that length is equal, two diagonal are along the periphery of the first sealing 31
Direction and width and configure.It addition, these barrier layer junction surfaces 34 are at sealing 30
Width on be configured to multiple row, and relative to peripheral direction and width the two side
To with zigzag arranged askew with staggered configuration.The configuration at this barrier layer junction surface 34
For the closeest configuration of rhombus, the heat-sealing portion 33 in zone line 35 is by barrier layer junction surface
The closeest configuration of 34 and form oblique grille-like.
The deterioration come from container external belt promotes that thing is interdicted completely by barrier layer 13, but has
There may be trace to enter in thermoplastic resin 14.Therefore, shown in Fig. 4 A
In the vertical view of one sealing 31, the deterioration entered from peripheral end face promotes that thing is only along heat-sealing portion
33 arrive in container, and heat-sealing portion 33 becomes intrusion path.Above-mentioned heat-sealing portion 33 is blocked layer
Junction surface 34 clips and forms narrow road, and the sectional area invading path diminishes, and thus deteriorates promotion
The intrusion of thing is inhibited.Further, since above-mentioned heat-sealing portion 33 is from the first sealing 31
Outer circumference end be connected in the zone line 35 of inner side as oblique grille-like, so deterioration promotes
The intrusion path 38,39 of thing can become roundabout and avoid the jagged of barrier layer junction surface 34
Route 38 or become angled straight lines 39.Jagged intrusion path 38 and angled straight lines
Intrusion path 39 and route S-phase longer than distance, this route S be by with the first sealing
The route of the beeline represented by straight line that the periphery of 31 is orthogonal, invades path by extending
Distance suppress deterioration promote thing intrusion.As it has been described above, present embodiment is first close
Envelope portion 31 promotes the sectional area invading path of thing by reducing deterioration, and extends intrusion path,
And synthetically suppress to invade, improve barrier.
It addition, barrier layer junction surface 34 and heat-sealing portion 33 phase making resin deposition each other
More higher than adhesion.Thus, by formation barrier layer junction surface 34 in heat-sealing portion 33
Peel resistant strength is improved relative to from outside stress.
Owing to the sealing 31 of the present invention there are multiple resistance with mottled in heat-sealing portion 33
Interlayer junction surface 34, so the width in heat-sealing portion 33 has essentially become the width of sealing 31
Degree W1 (with reference to Fig. 4 A).The present invention is not limiting as the width W1 of sealing 31, but is
Guarantee bond strength relative to the intrinsic pressure of container, be preferably formed as width W1 be 1mm with
On sealing 31.If it addition, width W1 is 10mm, then can sufficiently be connect
Close intensity.Accordingly, it is preferred that the width W1 of sealing 31 is 1~20mm.On it addition,
The preferred value of the width W1 stating sealing 31 also can be by the thickness of thermoplastic resin 14
With the impact of the MFR value of resin, therefore, it is preferably according to these situations, suitably sets
In the range of 1~20mm.The width W1 of especially preferred sealing 31 is 3~10mm.
Further, since the inner peripheral side end portion of sealing 31 can contact content, so it is excellent
Elect as and only formed by the material of thermoplastic resin 14.Some content must avoid or
The material with barrier layer 13 (such as metal) is preferably avoided to contact.Such as, if battery
If, it is necessary for avoiding electrolyte to contact with metal barrier layer 13.It is thus preferable that
In the region, inner circumferential side 36 of sealing 31, it is not provided with barrier layer junction surface 34, and is only formed
There are the region in heat-sealing portion 33, said structure also be able to use safely needs avoid with
In the packaging of the content of barrier layer contact.The width W2 in region, above-mentioned inner circumferential side 36 is preferred
It is 3~15mm, especially preferably 5~10mm.On the other hand, sealing 31 is not limited
No barrier layer junction surface 34 is had in outer circumferential side region 37.
As illustrated by according to above-mentioned embodiment, on sealing 31, by reducing deterioration
Promote thing invade path sectional area, or make further intrusion path roundabout extend away from
From, can suppress to invade deterioration and promote the intrusion of thing.
As long as reducing of the sectional area of above-mentioned intrusion path invades the width of path i.e.
Can, as long as invade path width reduce be discontinuously formed in heat-sealing portion 33 multiple
Barrier layer junction surface 34, just can with the shape at barrier layer junction surface 34 and forming position independently
Realize.The width invading path is the interval D between barrier layer junction surface 34, therefore, logical
Crossing constriction interval D can suppress deterioration to promote the intrusion (with reference to Fig. 4 A) of thing.On the other hand,
In order to so that the amount that reduces of interval D between barrier layer junction surface 34 is to push resin, lead
Cause to need the processing conditionss such as bigger pressure to become strict, and, in the feelings that resin is not pushed out
Under condition, it is impossible to make barrier layer 13 contact with each other, thus barrier layer junction surface 34 cannot be formed.
From this viewpoint, being preferably, the interval D between barrier layer junction surface 34 is set in
In the range of 0.2~3mm, especially preferably 0.5~1.5mm.
It addition, about the size at each barrier layer junction surface 34, preferably its circumscribed circle is a diameter of
0.2~5mm, especially preferably 0.5~1.5mm.
It addition, invade the expanding by the shape at barrier layer junction surface 34 or shape of the distance of path
Position or combinations thereof is become to be capable of.As shown in Figure 4 A, the shortest intrusion is led to
Road is positioned on the straight line S orthogonal with the periphery of sealing 31, with beeline cross this first
Distance in the case of sealing 31 is the size of the width W1 of sealing 31, therefore,
As long as there is at least one barrier layer junction surface 34 on above-mentioned straight line S, then just can lead to
Cross by roundabout for this barrier layer junction surface 34 and extend invade path distance.Therefore, if with
Make to there is at least one barrier layer on the arbitrary line S orthogonal with the periphery of sealing 31 to connect
The mode in conjunction portion 34 configures barrier layer junction surface 34, and the intrusion path of above-mentioned beeline will
Becoming not exist, invading path will be elongated compared with the width W1 of sealing 31.It addition,
As shown in Figure 4 A, if forming multiple row barrier layer junction surface on the width of sealing 31
34, the most roundabout number of times will increase, therefore, it is possible to make the distance of intrusion path become longer.
But, if increasing columns in limited width W1, then between barrier layer junction surface 34
Interval also can narrow, and the flowing of the resin pushed easily is retarded by silt, and thus, columns is preferably
Below 20 row.
The sealing 40 of Fig. 5, in heat-sealing portion 41, makes and the barrier layer of Fig. 4 A same shape
Junction surface 34 is not with staggered and configure in column.In the case of this configuration in column, along outward
The straight line 42 passed through between the barrier layer junction surface 34 that circumferential direction is adjacent is, beeline
Invading path, this straight line is the shortest by represented by the straight line orthogonal with the periphery of sealing 40
The route S of distance, therefore, it is impossible to extend the distance invading path.Additionally, due to it is above-mentioned close
Envelope portion 40 has been discontinuously formed multiple barrier layer junction surface 34, has by reducing intrusion logical
The sectional area on road suppresses the effect of the intrusion of deterioration promotion thing, so comprising in the present invention.
[other shape examples at barrier layer junction surface and configuration example]
Sealing 45,50,55,60 shown in Fig. 6~Fig. 9 is its of the sealing of the present invention
His embodiment.
(1) Fig. 6
Sealing 45 is in heat-sealing portion 46, by parallel in the width of sealing 45
Multiple barrier layer junction surfaces 47 of tetragon are configured to the example of string.Even if being configured to string,
According to and the adjacent barrier layer junction surface 47 of the interior angle of parallelogram between the setting at interval
Value, also can make to there is at least one resistance on the arbitrary line S orthogonal with the periphery of sealing 45
Interlayer junction surface 47.In figure, 48 is the shortest intrusion path.
(2) Fig. 7
Sealing 50 is in heat-sealing portion 51, by the barrier layer junction surface 52 of triangle close
Be configured to multiple row on the width in envelope portion 50, and so that vertex of a triangle towards each
The example that the mode that row all mutually reverse configures.This sealing 50 is not only orthogonal with periphery
There is at least one barrier layer junction surface 52 on arbitrary line S, and there is not invading of straight line
Enter path, invade path 53 and be zigzag.
(3) Fig. 8
Sealing 55 is in heat-sealing portion 56, is being sealed at circular barrier layer junction surface 57
Be configured to multiple row on the width in portion 55, and with relative to peripheral direction and width this
Both direction in the way of zigzag oblique arrangement with the example of staggered configuration.This sealing
55 not only exist at least one barrier layer junction surface on the arbitrary line S orthogonal with periphery
57, and there is not the intrusion path of straight line, invade path 58 and be roundabout barrier layer joint
Portion 57 and form sinuate serpentine shape.
(4) Fig. 9
Sealing 60 is in heat-sealing portion 61, is being sealed at the barrier layer junction surface 62 of rhombus
Be configured to multiple row on the width in portion 60, and with relative to peripheral direction and width this
Both direction in the way of zigzag oblique arrangement with the example of staggered configuration.This sealing
62 is the rhombus that two cornerwise length is different, and longer diagonal 63 is along peripheral direction
And configure.That is, above-mentioned barrier layer junction surface 62 is rhombus longer in peripheral direction.
Make the inclination angle invading path 64 of straight line in the sealing 60 of the closeest configuration of rhombus
Spend α, i.e. by the road of the beeline represented by the straight line orthogonal with the periphery of this sealing 60
Line S and straight line invade path 64 the angled interior angle being this rhombus 1/2.In above-mentioned
Angle is in two pairs of interior angles, be positioned on the straight line S orthogonal with the periphery of sealing 60 a pair
Interior angle.Therefore, above-mentioned interior angle 2 α becomes the biggest, just invades the tilt angle alpha of path 64
Becoming the biggest, distance just becomes the longest, and deterioration promotes that the intrusion inhibition of thing just becomes more
Greatly.Above-mentioned interior angle 2 α is determined by two cornerwise length, in two diagonal of rhombus
Longer diagonal 63 along peripheral direction, and the difference of cornerwise length becomes the biggest,
The distance then invading path 64 becomes the longest, thus obtains invade corresponding with distance and suppress effect
Really.
Owing to interior angle 2 α of the rhombus shown in Fig. 9 is obtuse angle, so invading inclining of path 64
Rake angle α is more than 45 °.Therefore, in the sealing making the closeest configuration of rhombus, if by Pedicellus et Pericarpium Trapae
Shape to make longer diagonal configure in the way of peripheral direction, then the intrusion path of straight line
The tilt angle alpha of 64 is more than 45 °.On the other hand, due to the resistance of sealing 31 of Fig. 4 A
Interlayer junction surface 34 is the rhombus (square) that two cornerwise length is equal, so invading
The tilt angle alpha entering path is 45 °.In other words, be orthogonal to above-mentioned sealing 31
Periphery straight line angled on the arbitrary line less than 45 °, there is at least one resistance
, there is not the intrusion path of the tilt angle alpha straight line less than 45 ° in interlayer junction surface 34.
As it has been described above, in the case of the closeest configuration in barrier layer junction surface making rhombus, preferably
For giving difference to two cornerwise length, by longer diagonal configuration along periphery
On the direction in direction, cornerwise length difference becomes the biggest, then deterioration promotes that the intrusion of thing presses down
Effect processed becomes the biggest.It addition, the preferred size of rhombus is, the size of long-diagonal be 0.05~
20mm, the size of short diagonal is 0.02~10mm, and especially preferred size is, long diagonal angle
The size of line is 0.5~3mm, and the size of short diagonal is 0.2~1.2mm.
It addition, the distance invading path of straight line is along with orthogonal relative to the periphery with sealing
Straight line invade path angle of inclination become the biggest and become the longest, this situation does not limit
It is the situation of rhombus due to above-mentioned barrier layer junction surface, is all common in any shape.
Therefore, if with the straight line of the periphery being orthogonal to sealing angled any for less than 45 °
On straight line, there is at least one barrier layer junction surface, the most there is not angle of inclination less than 45 °
The intrusion path of straight line, the angle of inclination invading path of straight line becomes more than at 45 °,
To the intrusion inhibition that deteriorate promotion thing corresponding with above-mentioned angle.
[sealing the purposes of container]
The sealing container of the present invention can not like light, oxygen, moisture as battery, food etc.
The packing container of article and extensively apply.It addition, seal the shape of container, the layer of lamellar
The presence or absence (recess shape presence or absence) of the shaping of pressure packaging material, the size sealing container are equal
It doesn't matter.But, since needing the periphery to container to implement encapsulation process, the most applicable
In planar dimension be 10mm × more than 20mm, thickness be the container of more than 3mm.It addition,
Be also applied for planar dimension be 300mm × below 300mm, thickness be the appearance of below 50mm
Device.
It addition, the present invention seal container condition be, periphery at least some of on shape
Become to have and be formed with the sealing at multiple barrier layer junction surface in a discontinuous manner (hereinafter referred to as
For " sealing of the present invention "), a part for periphery is formed without the close of the present invention
The container in envelope portion is also contained in the present invention.For example, referring to Fig. 3, it is being applicable to battery shell
In the case of body, electrode lead-in wire is drawn out to outside container, thus drawing at electrode lead-in wire
Go out to be formed without in portion the sealing of the present invention, but formed on the periphery in addition to lead division.
It addition, the content of tubular container is not how, although there is the periphery at container and leave content
Filling peristome, and carrying out encapsulation process and filling the situation of rear enclosed peristome, but
It is that the container leaving peristome to fill with is also contained in the present invention.
[sealing the manufacture method of container]
Hereinafter, as a example by enumerating the encapsulation process of sealing 31 of Fig. 4 A and Fig. 4 B, reference
It is to seal container in the case of metal that Figure 10 illustrates the barrier layer of laminate wrapping material
Manufacture method.
Owing to heat-sealing portion 33 is thermoplastic resin 14 joint each other, it is possible to pass through
The pressing plate 70,71 of heat-sealing clips the sealing circumference 12 of overlap and heats, thus
Formed (heat-sealing portion formation process).While with the shape at barrier layer junction surface 34 and configuration phase
The fixture 73 of the band projection that pressing is formed with multiple projection 72 pressurizes accordingly, and one
While grant ultrasonic activation, the front end face of projection 72 push resin and make barrier layer 13 exist
Expose on joint interface, and make exposed barrier layer 13 be engaged with each other, thus, form resistance
Interlayer junction surface 34 (barrier layer junction surface formation process).By the pressing of projection 72 and super
Acoustic vibration and the resin that is pushed out flows to be present in the whole recess around of projection 72
In 74, barrier layer 13 is the most easily made to expose.Therefore, just can be really with less exerting pressure
Ground forms barrier layer junction surface 34, and then is obtained in that stable barrier property.
If above-mentioned encapsulating method being described from sealing container side, then engage due to above-mentioned barrier layer
Portion 34 in heat-sealing portion 33 discontinuously with mottled formation, so barrier layer junction surface 34
Whole be around all heat-sealing portion 33, be all thermoplastic resin.Therefore, in order to by barrier layer
13 are engaged with each other, when pushing thermoplastic resin and making barrier layer 13 expose, it is possible to by resin
All directions of the surrounding to barrier layer junction surface 34 (reservations) are pushed, thus, and resin
Can flow well, and easily make barrier layer expose.
By carrying out above-mentioned heat-sealing portion formation process and barrier layer junction surface formation process, energy
Enough sealings 31 forming the present invention on the periphery of laminate wrapping material.These operations are permissible
Carry out, it is also possible to carry out successively simultaneously.
In the case of carrying out two operations by an operation, as shown in Figure 10, simultaneously
Pressing plate 71 is installed the fixture 73 of band projection, clips sealing circumference 12 and carry out
Heating pressurization, grants ultrasonic activation to the fixture 73 of band projection.
In the case of carrying out two operations successively, pressing plate 70,71 is the most only used to be formed
Heat-sealing portion 33 (heat-sealing portion formation process), the fixture 73 re-using band projection afterwards is formed
Barrier layer junction surface 34 (barrier layer junction surface formation process).If entering with being divided into two operations
If row encapsulation process, then can flatten thermoplastic due to the heat-sealing portion formation process by first carrying out
Property resin bed 14 and make it thinning, so the barrier layer junction surface formation process carried out after by
The amount of resin of ultrasonic bonding pushing seldom can also, thus, barrier layer 13 joint each other
Become easy.It addition, barrier layer junction surface formation process is preferably, carrying out heat-sealing portion
After formation process, it is carried out continuously when resin temperature does not also reduce.If at resin temperature very
High and resin be in period of soft state carry out ultrasonic bonding if, the pushing meeting of resin
Being easy to, therefore the formation at barrier layer junction surface 34 is also easy to.By ultrasonic activation also
Resin can be softened, but by utilizing heat during heat-sealing, it is possible to more efficiently form barrier layer
Junction surface 34, and then more efficiently carry out encapsulation process.
Above-mentioned heat-sealing and ultrasonic bonding do not have restriction with good conditionsi, can be according to laminate packaging material
The thermoplastic resin of material and the purposes etc. of the material of barrier layer and thickness, sealing container are fitted
Local setting.
Such as, about the temperature of heat-sealing, if thermoplastic resin 14 is LLDPE (straight chain
Shape Low Density Polyethylene) if, the most preferably more than 140 DEG C, if CPP is (non-stretched poly-
Propylene) if, the most preferably more than 160 DEG C.If it addition, outside having and being made up of resin
If the laminate wrapping material of side layer 15, then condition is that temperature is relatively low compared with the fusing point of resin.
If if constituting the resin PET of above-mentioned outer layer, the most preferably less than 250 DEG C, if
If nylon, the most preferably less than 230 DEG C.It addition, exerting pressure preferably during heat-sealing
0.2~1.0MPa, it is preferably 2~5 seconds heat time heating time.
It addition, as ultrasonic bonding condition, it is preferably, frequency is 15~40kHz,
To exert pressure be 5~20MPa, energy is 0.5~100J, the ultrasonic irradiation time is 0.1~2 second.
In the fixture 73 of ultrasonic bonding band projection, the front end face shape of projection 72
And the shape at configuration and the barrier layer junction surface 34 of sealing 31 and configure corresponding.Above-mentioned
The manufacture method of the fixture with projection does not limit, it is possible to use according to shape with any means
The fixture of the band projection manufactured.For instance, it is possible to excised by linear cutter and adjacent barrier
The corresponding part in heat-sealing portion 33,61,46 between layer junction surface 34,62,47, by
This manufactures for joining the closeest for the barrier layer junction surface 34,62 of the rhombus of Fig. 4 A, Fig. 9
The fixture of the band projection put and for making the barrier layer junction surface 47 of the parallelogram of Fig. 6
The fixture of the band projection configured in column.Can be defined to the fixture of linear cutter manufacture
There is not the shape at barrier layer junction surface on cutting line, but owing to being processed into desired shape be
Easily, so having the advantage that can manufacture with low cost.
It addition, with reference to Fig. 4 A, Fig. 9, Fig. 6, although it is based on linear cutter system
The fixture of the band projection made and the sealing 31,60,45 that formed, the intrusion with straight line is led to
Road 39,64,48, but by so that invading the elongated side of distance of path 39,64,48
Formula increases their tilt angle alpha, it is possible to increases deterioration and promotes the intrusion inhibition of thing.Example
As, in the closeest configuration at rhombus barrier layer junction surface, it is longer right to make in two diagonal
Linea angulata is along peripheral direction, and along with more increasing the difference of cornerwise length, makes tilt angle alpha
Become the biggest.
The present invention can be suitable as the sealing bag of lithium rechargeable battery housing and food etc.
With.
Claims (12)
1. a sealing container, is laminated with thermoplastic resin at least one side of barrier layer
Laminate wrapping material overlapping in the way of thermoplastic resin is placed on inner side, by overlapping
The periphery of laminate wrapping material engages and seals, and is consequently formed resettlement section, it is characterised in that
The sealing of described periphery has and is deposited with the heat-sealing portion of thermoplastic resin and makes obstruct
Multiple barrier layer junction surfaces that layer is engaged with each other, the plurality of barrier layer junction surface is in heat-sealing portion
In discontinuously with mottled configuration.
Sealing container the most according to claim 1, it is characterised in that described barrier layer
It is made up of metal.
Sealing container the most according to claim 1, it is characterised in that close with described
At least one barrier layer junction surface is there is on the arbitrary line that the periphery in envelope portion is orthogonal.
Sealing container the most according to claim 1, it is characterised in that be orthogonal to
The straight line of the periphery of described sealing angled for, on the arbitrary line less than 45 °, existing
At least one barrier layer junction surface.
Sealing container the most according to claim 1, it is characterised in that described barrier layer
The flat shape at junction surface is rhombus.
Sealing container the most according to claim 5, it is characterised in that described barrier layer
The flat shape at junction surface is the rhombus that catercorner length is different, this barrier layer junction surface so that
Longer diagonal configures along the mode of the peripheral direction of sealing.
Sealing container the most according to claim 1, it is characterised in that in described sealing
Multiple row barrier layer junction surface it is configured with on the width in portion.
Sealing container the most according to claim 1, it is characterised in that in described sealing
Have in the region, inner circumferential side in portion: there is no barrier layer junction surface and the district that is only made up of heat-sealing portion
Territory.
9. according to the sealing container according to any one of claim 1~8, it is characterised in that
Described sealing container is battery housing.
10. a battery, it is characterised in that battery main body is seated in described in claim 9
Battery housing in, be drawn out to shell at the electrode lead-in wire being connected with described battery main body
Under external state, the periphery of this housing is formed with sealing.
11. 1 kinds of manufacture methods sealing container, it is characterised in that carry out following operation:
Thermoplastic resin will be laminated with at least one side of the barrier layer being made up of metal
Laminate wrapping material, operation overlapping in the way of making thermoplastic resin become inner side;
Heat by being clipped the periphery of the laminate wrapping material of overlap by pressing plate, and make
The heat-sealing portion formation process of thermoplastic resin deposition each other;With
On the periphery of overlapping laminate wrapping material, pressing is the most discontinuously
With the fixture of the mottled band projection being provided with multiple projection, grant ultrasonic activation,
By the front end face pushing thermoplastic resin of described projection so that barrier layer exposes, then will be revealed
The barrier layer junction surface formation process that the barrier layer gone out is engaged with each other,
On the periphery of overlapping laminate wrapping material, be formed in heat-sealing portion discontinuously with
The mottled sealing being configured with multiple barrier layer junction surface.
The manufacture method of 12. sealing containers according to claim 11, it is characterised in that
After having carried out described heat-sealing portion formation process, it is in soft state at thermoplastic resin
Period carry out barrier layer junction surface formation process.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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JP2012-189015 | 2012-08-29 | ||
JP2012189015A JP5985930B2 (en) | 2012-08-29 | 2012-08-29 | Sealed container |
Publications (2)
Publication Number | Publication Date |
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CN103662190A CN103662190A (en) | 2014-03-26 |
CN103662190B true CN103662190B (en) | 2016-11-23 |
Family
ID=50301184
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
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CN201310393424.4A Active CN103662190B (en) | 2012-08-29 | 2013-08-28 | Seal container |
CN201320538058.2U Expired - Fee Related CN203544483U (en) | 2012-08-29 | 2013-08-28 | Sealed container |
Family Applications After (1)
Application Number | Title | Priority Date | Filing Date |
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CN201320538058.2U Expired - Fee Related CN203544483U (en) | 2012-08-29 | 2013-08-28 | Sealed container |
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JP (1) | JP5985930B2 (en) |
KR (1) | KR102051683B1 (en) |
CN (2) | CN103662190B (en) |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
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JP5985930B2 (en) * | 2012-08-29 | 2016-09-06 | 昭和電工パッケージング株式会社 | Sealed container |
JP6558810B2 (en) * | 2017-10-16 | 2019-08-14 | セイコーインスツル株式会社 | Electrochemical cell and method for producing electrochemical cell |
JP6996421B2 (en) * | 2018-05-28 | 2022-02-21 | 大日本印刷株式会社 | Batteries, heat seal devices, and battery manufacturing methods |
DE102019104379A1 (en) | 2019-02-21 | 2020-08-27 | Krones Ag | Device and method for producing filled containers |
DE102019104387A1 (en) * | 2019-02-21 | 2020-08-27 | Krones Ag | Device and method for producing filled containers |
US11535439B2 (en) | 2019-10-18 | 2022-12-27 | Sonoco Development, Inc. | Pasteurization pouch with barrier |
WO2022018948A1 (en) * | 2020-07-20 | 2022-01-27 | トタニ技研工業株式会社 | Bag making method and welding method |
KR102305454B1 (en) * | 2021-03-23 | 2021-10-01 | 쓰리애플즈코스메틱스 주식회사 | Cosmetic airtight container |
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2013
- 2013-08-28 CN CN201310393424.4A patent/CN103662190B/en active Active
- 2013-08-28 CN CN201320538058.2U patent/CN203544483U/en not_active Expired - Fee Related
- 2013-08-28 KR KR1020130102238A patent/KR102051683B1/en active IP Right Grant
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CN1189246A (en) * | 1995-06-26 | 1998-07-29 | 摩托罗拉公司 | Packaging for an electrochemical device and device using same |
CN1426121A (en) * | 2001-09-04 | 2003-06-25 | 日本电气株式会社 | High reliability and durability cell and its producing process |
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CN203544483U (en) * | 2012-08-29 | 2014-04-16 | 昭和电工包装株式会社 | Sealed container |
Also Published As
Publication number | Publication date |
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CN103662190A (en) | 2014-03-26 |
JP5985930B2 (en) | 2016-09-06 |
KR20140029258A (en) | 2014-03-10 |
CN203544483U (en) | 2014-04-16 |
KR102051683B1 (en) | 2019-12-03 |
JP2014049197A (en) | 2014-03-17 |
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