CN103661183B - A kind of automobile-used hybrid composite energy absorbing part and production method thereof - Google Patents

A kind of automobile-used hybrid composite energy absorbing part and production method thereof Download PDF

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Publication number
CN103661183B
CN103661183B CN201310680430.8A CN201310680430A CN103661183B CN 103661183 B CN103661183 B CN 103661183B CN 201310680430 A CN201310680430 A CN 201310680430A CN 103661183 B CN103661183 B CN 103661183B
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China
Prior art keywords
aramid fiber
fiber layer
energy absorbing
carbon fiber
hybrid composite
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CN103661183A (en
Inventor
阳玉球
马岩
张前锦
杨佳慧
于利超
刘夏慧
徐芝兰
孔徐洁
肖冰
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Donghua University
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Donghua University
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Abstract

The invention discloses a kind of automobile-used hybrid composite energy absorbing part and production method thereof.Described energy absorbing member is round tubular parts, including the first aramid fiber layer from the inside to the outside, carbon fiber layer, the second aramid fiber layer.Production method is: is wound around on core successively and has infiltrated the aramid fiber of substrate, carbon fiber, aramid fiber, forms the first aramid fiber layer, carbon fiber layer, the second aramid fiber layer respectively;Core is sloughed after being solidified by the energy absorbing member twined.The present invention meets automobile light weight and the demand for development of safety, and process route is reasonable, treatment technology and method is with low cost, cost performance is high, security performance is good, meets automobile low energy consumption, oligosaprobic developing direction, has complied with the development trend of energy-saving and emission-reduction, environmental protection.

Description

A kind of automobile-used hybrid composite energy absorbing part and production method thereof
Technical field
The present invention relates to a kind of automobile energy absorbing member, especially relate to a kind of carbon fiber, aramid fiber mixes type Strengthen three dimensional structure energy absorbing member.
Background technology
According to official statistics, since the later stage eighties 20th century, Road Traffic Accidents in China quantity, death toll, ten thousand cars Accident death rates etc. are all in world's umber one.China's automobile guarantee-quantity in 2009 accounts for the 3% of the world, and the death of vehicle accident Number but accounts for 16%, and the safety improving the vehicles is extremely the most urgent.
At present there is a two types for the parts of protection occupant during collision in vehicle: the high rigid frame high energy that eases up is inhaled Receive parts.High rigid material, such as bumper bar and body shell, mainly provides enough physics when vehicle collides for occupant Safe space, thus require that rigidity is strong, deforms little, but impact energy absorbability to external world is low, it is impossible to reduce external impact The power injury to occupant;On the other hand, for the high-energy absorption material of buffering, such as between the bumper bar and front longitudinal of vehicle Place one group of cast energy-absorbing element, can effectively be absorbed the energy of shock by the deformation of parts and the destruction of self, no Only reduce the impact to high rigidity car body, and slow down the too fast increase of deceleration, reduce the collision physiological damage to occupant.
As shown in Figure 1-2, generally rear side in vehicle front bumper 1 installs the energy-absorption box 2 of one group of metal material as energy Amount absorption piece, energy-absorption box 2 is fixed on front longitudinal by rivet, makes vehicle effectively absorb shock in collision process Energy, the life safety of the passenger that adequately protects.But generally self is heavier, mainly by the plasticity of metal material for ordinary metallic material Deformation carrys out energy-absorbing, and the most now by metallic material of aluminum, its specific energy absorption value (energy value that unit mass absorbs) is only 44.6kJ/ Kg, energy absorption is on the low side, can not meet the development trend of automotive light weight technology, low energy consumption and high security.
Carbon fiber has the characteristic of high-modulus, high intensity, and aramid fiber extension at break is up to 2.5-3% simultaneously, by rationally setting The structure of meter composite reduces the stretching, extension of Median cracks, can reach high bending, the purpose of multi-fiber fracture destruction, maximum limit The absorption failure energy of degree, delays impact velocity, reduces the harm to vehicle-mounted passenger.
Composite refers to, by two kinds or the two or more material with different physics, chemical property, with microcosmic, be situated between and see Or the different layer of structure such as macroscopic view, the material system formed through complicated spatial organization.By different size, In different levels, structure Design and optimization can obtain in performance and functionally new considerably beyond its simple substance component property and function Material, current composite is all widely used in fields such as Aeronautics and Astronautics, weapons, naval vessels.But as energy absorbing parts of automobiles Application has no Patents or report.
Summary of the invention
To be solved by this invention is that existing Vehicular metal energy-absorbing element energy absorption is undesirable, quality heavy, no The problems such as the requirement meeting safety, light weight, energy-conserving and environment-protective.
In order to solve above-mentioned technical problem, the invention provides a kind of automobile-used hybrid composite energy absorbing part, It is characterized in that, described energy absorbing member is round tubular parts, including the first aramid fiber layer from the inside to the outside, carbon fiber Layer, the second aramid fiber layer.
Preferably, described first aramid fiber layer, the second aramid fiber layer are with aramid fiber as reinforcement, asphalt mixtures modified by epoxy resin Fat, phenolic resin or unsaturated polyester resin are substrate;Described carbon fiber layer is with carbon fiber as reinforcement, epoxy resin, Phenolic resin or unsaturated polyester resin are substrate, and the first aramid fiber layer, carbon fiber layer, the second aramid fiber layer use Substrate identical.
Preferably, described first aramid fiber layer, carbon fiber layer, the second aramid fiber layer thickness than for 1:10:2.5; The pipe thickness of described energy absorbing member and diameter of inner pipe are than for 1:22.
The automobile-used hybrid composite energy absorbing part that the present invention provides can also be used with basalt fiber, carbon fiber Layer, glass layer substitute described first aramid fiber layer, the second aramid fiber layer, or/and by basalt fiber, glass fibers Dimension layer substitutes carbon fiber layer;Substitute the first aramid fiber layer, the second aramid fiber layer material identical, and with substitute carbon fiber layer Material different.
Present invention also offers the production method of above-mentioned automobile-used hybrid composite energy absorbing part, its feature exists In, comprise the following steps:
Step 1): by aramid fiber, carbon fiber infiltration substrate standby;
Step 2): winding step 1 on core successively) prepare aramid fiber, carbon fiber, aramid fiber, formed respectively First aramid fiber layer, carbon fiber layer, the second aramid fiber layer, make hybrid composite energy absorbing part;
Step 3): by step 2) prepare hybrid composite energy absorbing part solidification after slough core.
Preferably, described step 1) method that is wound around is: it is axially 0 ° with the pipe axle of mandrel, the winding angle of aramid fiber Being 75 °~90 °, the winding angle of carbon fiber is 5 °~20 °.
Further, described step 1) method that is wound around is: it is axially 0 ° with the pipe axle of mandrel, the winding angle of aramid fiber Degree is 88 °, and the winding angle of carbon fiber is 17.6 °.
Preferably, described step 1) in the first aramid fiber layer, carbon fiber layer, the thickness ratio of the second aramid fiber layer be 1:10:2.5;The pipe thickness of described energy absorbing member and diameter of inner pipe are than for 1:22.
Preferably, described step 3) in solidification method particularly includes: temperature be 20 ± 2 DEG C, relative humidity be 65 ± 5% Under conditions of solidify 24 hours.
The present invention uses complementary reinforcing fiber to be reinforcement, and carbon fiber has the characteristic of high intensity, high-modulus, when carbon is fine Dimension occurs to realize high energy-absorbing during fracture, although aramid fiber compression performance is significantly worse than tensile property, but extension at break Up to 2.5-3%, utilizes three interlayers every complementary winding arrangement so that aramid fiber compresses on 0 ° of direction in compression process, While being converted into stretching on 90 ° of directions, limit deformation and the extension of composite inner Median cracks of carbon fiber, the most greatly Degree improves the quantity of fibrous fracture, thus absorbs more substantial energy.Winding shaping process, the most Wrapping formed by fiber, The manufacture process damage to fiber need not be reduced largely through operations such as such as longitude and latitude intertexture, braidings, improves making of fiber Use performance.
The composite energy absorption mechanism of present invention offer is with the absorption mechanism of conventional metals energy absorbing member not With, traditional metal material carrys out energy-absorbing mainly by its plastic deformation, and its load the most significantly declines, its Amount of energy is on the low side;The present invention is tubular composite material, its mainly by fibrous fracture, bend, deform, the mode such as layering is inhaled Can, its load declines and keeps stable load the most by a small margin.This characteristic can reduce further Foreign impacts is to car body after energy absorbing component and the injury of occupant in car body, and the high frequency repeated stock i.e. with certain amplitude reduces Injury to occupant.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of front bumper on automobile;
Fig. 2 is the schematic diagram during energy-absorption box use of existing metal material;
Schematic diagram when Fig. 3 uses for the automobile-used hybrid composite energy absorbing part that the present invention provides;
The partial enlarged drawing of the automobile-used hybrid composite energy absorbing part that Fig. 4 provides for the present invention.
Detailed description of the invention
For making the present invention become apparent, hereby with preferred embodiment, and accompanying drawing is coordinated to be described in detail below.
Embodiment
1. raw material
Epoxy resin (Mitsubishi chemical Co., Ltd, 308A3801);Aramid fiber;Carbon fiber.
2. production method
2.1 by aramid fiber, carbon fiber infiltration epoxy matrix material standby;
2.2 aramid fibers that on core prepared by winding step 2.1 successively, carbon fiber, aramid fiber, form first respectively Aramid fiber layer 4, carbon fiber layer the 5, second aramid fiber layer 6, make hybrid composite energy absorbing part 2 ';With core Pipe axle be axially 0 °, control aramid fiber winding angle be 88 °, the winding angle of carbon fiber is 17.6 °;During winding, the One aramid fiber layer 4, carbon fiber layer the 5, second aramid fiber layer 6 thickness than for 1:10:2.5;The pipe of energy absorbing member 2 ' Wall thickness and diameter of inner pipe are than for 1:22.
2.3 hybrid composite energy absorbing parts 2 ' that step 2.2 is prepared temperature be 20 DEG C, relative humidity be Core is sloughed after solidifying 24 hours under conditions of 65%.
3. performance test
The hybrid composite energy absorbing part 2 ' that said method is prepared and the energy-absorbing of traditional metal materials aluminum matter Box 2 quasistatic compression test comparison, test uses model to be the electronic universal tester of WDW3100, and compression speed is: 5mm/ min.Comparing result is as shown in table 1:
Table 1
As shown in Table 1, it is multiple that the hybrid composite energy absorbing part 2 ' that embodiment prepares uses carbon/aramid fiber to mix type Condensation material, its specific energy absorption value is up to 100kJ/kg, be the energy-absorption box 2 of existing aluminum matter energy absorption twice with On;I.e. on the premise of absorbing identical energy, the weight that required carbon/aramid fiber mixes type composite is less than required metal aluminium The half of material.As can be seen here, present invention accomplishes automobile light weight and while the demand for development of safety, process route is reasonable, Treatment technology and method is with low cost, cost performance is high, security performance is good, meets automobile low energy consumption, oligosaprobic developing direction, also Comply with the development trend of energy-saving and emission-reduction, environmental protection greatly.
4. use and install
As it is shown on figure 3, the position of the energy-absorption box 2 of hybrid composite energy absorbing part 2 ' installation site and metal material Put identical, be arranged between front bumper 1 and front longitudinal 3, the metal cylinder identical with core shape can be installed on front longitudinal 3 Body, is enclosed within hybrid composite energy absorbing part 2 ' on this metal cylinder, or uses other existing connected modes to incite somebody to action Hybrid composite energy absorbing part 2 ' is arranged between front bumper 1 and front longitudinal 3.

Claims (8)

1. an automobile-used hybrid composite energy absorbing part, it is characterised in that described energy absorbing member (2 ') is circle Shape tubular part, including the first aramid fiber layer (4) from the inside to the outside, carbon fiber layer (5), the second aramid fiber layer (6);Described First aramid fiber layer (4), carbon fiber layer (5), the second aramid fiber layer (6) thickness than for 1:10:2.5;Described energy is inhaled Receive pipe thickness and the diameter of inner pipe of parts (2 ') ratio for 1:22;The system of described automobile-used hybrid composite energy absorbing part Standby step is:
Step 1): by aramid fiber, carbon fiber infiltration substrate standby;
Step 2): winding step 1 on core successively) prepare aramid fiber, carbon fiber, aramid fiber, form first respectively Aramid fiber layer, carbon fiber layer, the second aramid fiber layer, make hybrid composite energy absorbing part;The method being wound around For: being axially 0 ° with the pipe axle of mandrel, the winding angle of aramid fiber is 75 °~90 °, the winding angle of carbon fiber be 5 °~ 20°;
Step 3): by step 2) prepare hybrid composite energy absorbing part solidification after slough core.
Automobile-used hybrid composite energy absorbing part the most as claimed in claim 1, it is characterised in that described first aramid fiber Fibrous layer (4), the second aramid fiber layer (6) are with aramid fiber as reinforcement, epoxy resin, phenolic resin or unsaturated polyester Ester resin is substrate;Described carbon fiber layer (5) is with carbon fiber as reinforcement, epoxy resin, phenolic resin or unsaturated polyester Ester resin is substrate, and the substrate that the first aramid fiber layer (4), carbon fiber layer (5), the second aramid fiber layer (6) use is identical.
3. the automobile-used hybrid composite energy absorbing part described in claim 1, it is characterised in that use basalt fibre Layer, carbon fiber layer, glass layer substitute described first aramid fiber layer (4), the second aramid fiber layer (6), or/and use the Black Warrior Rock fibrous layer, glass layer substitute carbon fiber layer (5);Substitute the first aramid fiber layer (4), the second aramid fiber layer (6) Material is identical, and different from the material substituting carbon fiber layer (5).
4. the production method of the automobile-used hybrid composite energy absorbing part described in claim 1, it is characterised in that include Following steps:
Step 1): by aramid fiber, carbon fiber infiltration substrate standby;
Step 2): winding step 1 on core successively) prepare aramid fiber, carbon fiber, aramid fiber, form first respectively Aramid fiber layer (4), carbon fiber layer (5), the second aramid fiber layer (6), make hybrid composite energy absorbing part (2’);
Step 3): by step 2) prepare hybrid composite energy absorbing part (2 ') solidification after slough core.
The production method of automobile-used hybrid composite energy absorbing part the most as claimed in claim 4, it is characterised in that institute State step 1) method that is wound around is: being axially 0 ° with the pipe axle of mandrel, the winding angle of aramid fiber is 75 °~90 °, carbon fiber Winding angle be 5 °~20 °.
The production method of automobile-used hybrid composite energy absorbing part the most as claimed in claim 4, it is characterised in that institute State step 1) method that is wound around is: being axially 0 ° with the pipe axle of mandrel, the winding angle of aramid fiber is 88 °, twining of carbon fiber It it is 17.6 ° around angle.
The production method of automobile-used hybrid composite energy absorbing part the most as claimed in claim 4, it is characterised in that institute State step 1) in the first aramid fiber layer (4), carbon fiber layer (5), the second aramid fiber layer (6) thickness than for 1:10: 2.5;The pipe thickness of described energy absorbing member and diameter of inner pipe are than for 1:22.
The production method of automobile-used hybrid composite energy absorbing part the most as claimed in claim 4, it is characterised in that institute State step 3) in solidification method particularly includes: temperature be 20 ± 2 DEG C, relative humidity be that to solidify 24 under conditions of 65 ± 5% little Time.
CN201310680430.8A 2013-12-12 2013-12-12 A kind of automobile-used hybrid composite energy absorbing part and production method thereof Expired - Fee Related CN103661183B (en)

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103950418B (en) * 2014-05-05 2015-12-09 上海交通大学 Automobile carbon fiber composite material bumper
CN104590178A (en) * 2014-12-24 2015-05-06 芜湖市汽车产业技术研究院有限公司 Automobile energy absorption box
CN105065393B (en) * 2015-07-07 2019-01-01 奇瑞汽车股份有限公司 A kind of automobile carbon fiber component assembling structure and mode
CN106240502B (en) * 2016-08-26 2019-03-29 东华大学 A kind of automobile-used energy absorbing member of composite material and its processing method
CN108340937B (en) * 2018-03-21 2023-06-09 深圳市乾行达科技有限公司 Composite material anti-creeping energy-absorbing device
CN112141036A (en) * 2019-06-28 2020-12-29 北京新能源汽车股份有限公司 Energy absorption box for anti-collision beam and manufacturing method of energy absorption box
CN110341265A (en) * 2019-07-10 2019-10-18 中电建路桥集团有限公司 A kind of energy-absorbing composite material

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EP0361343A1 (en) * 1988-09-29 1990-04-04 Bayerische Motoren Werke Aktiengesellschaft, Patentabteilung AJ-3 Bumpers for motor vehicles, in particular passenger ones
US6601886B1 (en) * 2002-05-31 2003-08-05 Hexcel Corporation Energy absorbing composite tube
CN102563062A (en) * 2010-10-14 2012-07-11 韦特柯格雷公司 Thick walled composite tubular and method of making
CN102786776A (en) * 2012-08-03 2012-11-21 南通南京大学材料工程技术研究院 Carbon fiber/aramid fiber reinforced resin base composite material and vehicle front anticollision beam prepared from same
CN102785443A (en) * 2012-07-19 2012-11-21 马道平 Buffer laminate compounded layer structure composite material bumper and its preparation method
WO2013064859A1 (en) * 2011-10-31 2013-05-10 Industrialesud S.P.A. Article made of a multilayer composite material and preparation method thereof

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0361343A1 (en) * 1988-09-29 1990-04-04 Bayerische Motoren Werke Aktiengesellschaft, Patentabteilung AJ-3 Bumpers for motor vehicles, in particular passenger ones
US6601886B1 (en) * 2002-05-31 2003-08-05 Hexcel Corporation Energy absorbing composite tube
CN102563062A (en) * 2010-10-14 2012-07-11 韦特柯格雷公司 Thick walled composite tubular and method of making
WO2013064859A1 (en) * 2011-10-31 2013-05-10 Industrialesud S.P.A. Article made of a multilayer composite material and preparation method thereof
CN102785443A (en) * 2012-07-19 2012-11-21 马道平 Buffer laminate compounded layer structure composite material bumper and its preparation method
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