CN110341265A - A kind of energy-absorbing composite material - Google Patents

A kind of energy-absorbing composite material Download PDF

Info

Publication number
CN110341265A
CN110341265A CN201910619335.4A CN201910619335A CN110341265A CN 110341265 A CN110341265 A CN 110341265A CN 201910619335 A CN201910619335 A CN 201910619335A CN 110341265 A CN110341265 A CN 110341265A
Authority
CN
China
Prior art keywords
composite material
energy
fiber cloth
aryl fiber
absorbing composite
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201910619335.4A
Other languages
Chinese (zh)
Inventor
韩建秋
彭银钢
张超
葛晶
徐茂
潘军
杨晔
晏晨
沈燕
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JIANGSU HONGYUAN GFRP Co Ltd
JSTI Group Co Ltd
PowerChina Roadbridge Group Co Ltd
Original Assignee
JIANGSU HONGYUAN GFRP Co Ltd
JSTI Group Co Ltd
PowerChina Roadbridge Group Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by JIANGSU HONGYUAN GFRP Co Ltd, JSTI Group Co Ltd, PowerChina Roadbridge Group Co Ltd filed Critical JIANGSU HONGYUAN GFRP Co Ltd
Priority to CN201910619335.4A priority Critical patent/CN110341265A/en
Publication of CN110341265A publication Critical patent/CN110341265A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C70/00Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
    • B29C70/04Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
    • B29C70/28Shaping operations therefor
    • B29C70/30Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core
    • B29C70/34Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation
    • B29C70/342Shaping by lay-up, i.e. applying fibres, tape or broadsheet on a mould, former or core; Shaping by spray-up, i.e. spraying of fibres on a mould, former or core and shaping or impregnating by compression, i.e. combined with compressing after the lay-up operation using isostatic pressure
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B37/00Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
    • B32B37/10Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure
    • B32B37/1018Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding characterised by the pressing technique, e.g. using action of vacuum or fluid pressure using only vacuum
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/22Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed
    • B32B5/24Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer
    • B32B5/26Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by the presence of two or more layers which are next to each other and are fibrous, filamentary, formed of particles or foamed one layer being a fibrous or filamentary layer another layer next to it also being fibrous or filamentary
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0261Polyamide fibres
    • B32B2262/0269Aromatic polyamide fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10Inorganic fibres
    • B32B2262/101Glass fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/50Properties of the layers or laminate having particular mechanical properties
    • B32B2307/54Yield strength; Tensile strength

Abstract

The present invention relates to fibre reinforced composites field, specifically a kind of energy-absorbing composite material;Energy-absorbing composite material is layer structure;Upper epidermis is aryl fiber cloth;Layer is aryl fiber cloth;Interlayer is glass fabric;Matrix is aromatic resins;Aryl fiber cloth, glass fabric are the two-way fabric of plain weave;Upper epidermis, interlayer, layer volume ratio be 1:2:1;This energy-absorbing composite material energy-absorbing effect is good, cheap, and can promote tensile modulus of elasticity.

Description

A kind of energy-absorbing composite material
Technical field
The present invention relates to fibre reinforced composites field, specifically a kind of energy-absorbing composite material.
Background technique
In recent years, fibre reinforced composites are quickly grown, from aerospace field and electronics industry gradually to each row Each industry development and application;Fibre reinforced composites have lightweight, and high-strength material property can replace traditional metal materials well Status in engineering;However, single fibre reinforced composites also have certain limitation, such as carbon fibre fabric tool There is very strong tensile property, but elongation at break is lower, shear strength is low, is not very useful in by curved member in shear; Aramid fiber toughness is extremely strong, but rigidity is too low, and expensive;For this purpose, the research and development of assorted fibre are multiple at current fiber reinforcement The research hotspot of condensation material;Researcher's door discovery, enhances basis material after different fibrous materials is mixed, can highlight different fibres Respective superiority is tieed up, stronger comprehensive performance is obtained;In research followed by, researchers are by changing different preparation works Skill, different fiber types, different matrix resins have studied the superiority and inferiority of the properties of assorted fibre under different arrangement modes Property, it proposes and mixes law theory, analyze its damage and failure mode, pushed the application of assorted fibre;The two-way fiber of plain weave Fabric is widely used reinforcing fiber in recent years, and compared to the fabric unidirectionally arranged, intensity is slightly reduced, but greatly enhances Mechanical property in vertical direction, researchers are to the research of such hybrid materials less.
To sum up, it since aramid fiber energy-absorbing effect is good, but involves great expense, it is good how to develop energy-absorbing effect, price Cheaply, and the fibrous composite of tensile modulus of elasticity can be promoted become that our company researcher is urgently to be solved to ask body.
Summary of the invention
The technical problem to be solved by the present invention is it is good how to develop energy-absorbing effect, it is cheap, and drawing can be promoted Stretch the fibrous composite of elasticity modulus.
In order to achieve the above object, the invention is realized by the following technical scheme:
The present invention is a kind of energy-absorbing composite material, and energy-absorbing composite material is layer structure;Upper epidermis is aryl fiber cloth;Following table Layer is aryl fiber cloth;Interlayer is glass fabric;Matrix is aromatic resins;Aryl fiber cloth, glass fabric are flat The two-way fabric of line;
Further, the gram weight (g/m2) of aryl fiber cloth is 200, and thickness (mm) is 0.28;The glass fabric Gram weight (g/m2) is 120, and thickness (mm) is 0.32.
Beneficial effects of the present invention: the present invention is a kind of energy-absorbing composite material, passes through aryl fiber cloth and glass fabric Mix, can either effectively promote the energy-absorbing of composite material, and can promote tensile modulus of elasticity, and the cost expense that degraded With.
Detailed description of the invention
Present invention will be further explained below with reference to the attached drawings and examples.
Fig. 1 is structural schematic diagram of the invention;
Fig. 2 is the structural schematic diagram of production method of the present invention;
Fig. 3 is the load-displacement experimental data curve of five embodiments of the invention;
1- aryl fiber cloth, 2- glass fabric, 3- fiber hybrid composite material, 4- vacuum bag, 5- diversion pipe, 6- demoulding Cloth, 7- soak drift net, the first conduit of 8-, 9- aspiration pump, the second conduit of 10-, 11- aryl fiber cloth.
Specific embodiment
In conjunction with the accompanying drawings, the present invention is further explained in detail.These attached drawings are simplified schematic diagram, only with Illustration illustrates basic structure of the invention, therefore it only shows the composition relevant to the invention.
Embodiment 1
Such as Fig. 1, the present invention is a kind of energy-absorbing composite material, and upper epidermis takes two layers of aryl fiber cloth 1, layer to take two layers of virtue Synthetic fibre fiber cloth 1, interlayer are four-layer glass fiber cloth 2;
S1: aryl fiber cloth, glass fabric are neatly stacked into pressing in order, and are put into vacuum bag 4;
S2: fixing a circle diversion pipe 5 in aryl fiber cloth, glass fabric periphery, by release cloth 6 and soaks drift net 7 successively It is laid on fiber hybrid composite material 3, finally seals up vacuum bag 4;
S3: one end of the first conduit 8 being inserted into vacuum bag 4, and is adhesively fixed with glass cement, the other end and aspiration pump 9 It is connected, for evacuating air in vacuum bag 4;
S4: one end of the second conduit 10 is connected and is fixed with diversion pipe 5, the other end imports the aromatic resins now adjusted;
S5: preparation process lasts about 30 minutes, to the complete heat release of resin after, pull out the first conduit 8, it is cooling under room temperature After 2 hours, fiber hybrid composite material is made in stripping forming.
Size of materialsing is 25x250mm2, using universal testing machine carry out uniaxial tensile test, acceleration 2mm/min, The data obtained is exported by the system that testing machine carries;Measuring tensile modulus of elasticity (GPa) is 14.032.
Comparative example 2
Embodiment 2 is eight layers of glass fabric;
Glass fabric: neatly being stacked pressing by S1 in order, and is put into vacuum bag 4;
S2: fixing a circle diversion pipe 5 in glass fabric periphery, and release cloth 6 and leaching drift net 7 are successively laid on fiber and are mixed On miscellaneous composite material 3, vacuum bag 4 is finally sealed up;
S3: one end of the first conduit 8 being inserted into vacuum bag 4, and is adhesively fixed with glass cement, the other end and aspiration pump 9 It is connected, for evacuating air in vacuum bag 4;
S4: one end of the second conduit 10 is connected and is fixed with diversion pipe 5, the other end imports the aromatic resins now adjusted;
S5: preparation process lasts about 30 minutes, to the complete heat release of resin after, pull out the first conduit 8, it is cooling under room temperature After 2 hours, fiber hybrid composite material is made in stripping forming.
Size of materialsing is 25x250mm2, using universal testing machine carry out uniaxial tensile test, acceleration 2mm/min, The data obtained is exported by the system that testing machine carries;Measuring tensile modulus of elasticity (GPa) is 15.264.
Comparative example 3
Embodiment 3 is eight layers of aryl fiber cloth;
Aryl fiber cloth: neatly being stacked pressing by S1 in order, and is put into vacuum bag 4;
S2: fixing a circle diversion pipe 5 in aryl fiber cloth periphery, and release cloth 6 and leaching drift net 7 are successively laid on fiber and are mixed On miscellaneous composite material 3, vacuum bag 4 is finally sealed up;
S3: one end of the first conduit 8 being inserted into vacuum bag 4, and is adhesively fixed with glass cement, the other end and aspiration pump 9 It is connected, for evacuating air in vacuum bag 4;
S4: one end of the second conduit 10 is connected and is fixed with diversion pipe 5, the other end imports the aromatic resins now adjusted;
S5: preparation process lasts about 30 minutes, to the complete heat release of resin after, pull out the first conduit 8, it is cooling under room temperature After 2 hours, fiber hybrid composite material is made in stripping forming.
Size of materialsing is 25x250mm2, using universal testing machine carry out uniaxial tensile test, acceleration 2mm/min, The data obtained is exported by the system that testing machine carries;Measuring tensile modulus of elasticity (GPa) is 12.871.
Comparative example 4
Embodiment 4 is that upper epidermis takes layer glass fiber cloth, layer to take layer glass fiber cloth, and interlayer is four layers of aramid fiber Fiber cloth;S1: aryl fiber cloth, glass fabric are neatly stacked into pressing in order, and are put into vacuum bag 4;
S2: fixing a circle diversion pipe 5 in aryl fiber cloth, glass fabric periphery, by release cloth 6 and soaks drift net 7 successively It is laid on fiber hybrid composite material 3, finally seals up vacuum bag 4;
S3: one end of the first conduit 8 being inserted into vacuum bag 4, and is adhesively fixed with glass cement, the other end and aspiration pump 9 It is connected, for evacuating air in vacuum bag 4;
S4: one end of the second conduit 10 is connected and is fixed with diversion pipe 5, the other end imports the aromatic resins now adjusted;
S5: preparation process lasts about 30 minutes, to the complete heat release of resin after, pull out the first conduit 8, it is cooling under room temperature After 2 hours, fiber hybrid composite material is made in stripping forming.
Size of materialsing is 25x250mm2, using universal testing machine carry out uniaxial tensile test, acceleration 2mm/min, The data obtained is exported by the system that testing machine carries;Measuring tensile modulus of elasticity (GPa) is 13.331.
Comparative example 5
Embodiment 5 is four-layer glass fiber cloth, four layers of aryl fiber cloth are staggered;
S1: aryl fiber cloth, glass fabric are neatly stacked into pressing in order, and are put into vacuum bag 4;
S2: fixing a circle diversion pipe 5 in aryl fiber cloth, glass fabric periphery, by release cloth 6 and soaks drift net 7 successively It is laid on fiber hybrid composite material 3, finally seals up vacuum bag 4;
S3: one end of the first conduit 8 being inserted into vacuum bag 4, and is adhesively fixed with glass cement, the other end and aspiration pump 9 It is connected, for evacuating air in vacuum bag 4;
S4: one end of the second conduit 10 is connected and is fixed with diversion pipe 5, the other end imports the aromatic resins now adjusted;
S5: preparation process lasts about 30 minutes, to the complete heat release of resin after, pull out the first conduit 8, it is cooling under room temperature After 2 hours, fiber hybrid composite material is made in stripping forming.
Size of materialsing is 25x250mm2, using universal testing machine carry out uniaxial tensile test, acceleration 2mm/min, The data obtained is exported by the system that testing machine carries;Measuring tensile modulus of elasticity (GPa) is 18.807.
As shown in figure 3, the load-displacement curve of above-mentioned five embodiments of observation, eight layers of aryl fiber cloth envelope of curve Area is bigger, and energy-absorbing effect is best;It secondly is embodiment 1.
To sum up, upper epidermis takes two layers of aryl fiber cloth, layer to take two layers of aryl fiber cloth, and interlayer is four-layer glass fiber The energy-absorbing effect of cloth is preferable, and low cost, and tensile modulus of elasticity is also strengthened.
Taking the above-mentioned ideal embodiment according to the present invention as inspiration, through the above description, relevant staff is complete Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.The technology of this invention Property range is not limited to the contents of the specification, it is necessary to which the technical scope thereof is determined according to the scope of the claim.

Claims (2)

1. a kind of energy-absorbing composite material, it is characterised in that: the energy-absorbing composite material is layer structure;
Upper epidermis is aryl fiber cloth;
Layer is aryl fiber cloth;
Interlayer is glass fabric;
Matrix is aromatic resins;
The aryl fiber cloth, glass fabric are the two-way fabric of plain weave;
The upper epidermis, interlayer, layer volume ratio be 1:2:1.
2. a kind of energy-absorbing composite material according to claim 1, it is characterised in that: the gram weight of the aryl fiber cloth It (g/m2) is 200, thickness (mm) is 0.28;The gram weight (g/m2) of the glass fabric is 120, and thickness (mm) is 0.32.
CN201910619335.4A 2019-07-10 2019-07-10 A kind of energy-absorbing composite material Pending CN110341265A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910619335.4A CN110341265A (en) 2019-07-10 2019-07-10 A kind of energy-absorbing composite material

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910619335.4A CN110341265A (en) 2019-07-10 2019-07-10 A kind of energy-absorbing composite material

Publications (1)

Publication Number Publication Date
CN110341265A true CN110341265A (en) 2019-10-18

Family

ID=68176937

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910619335.4A Pending CN110341265A (en) 2019-07-10 2019-07-10 A kind of energy-absorbing composite material

Country Status (1)

Country Link
CN (1) CN110341265A (en)

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103661183A (en) * 2013-12-12 2014-03-26 东华大学 Hybrid composite energy absorbing part for automobile and manufacturing method thereof
CN207156605U (en) * 2017-05-27 2018-03-30 咸宁海威复合材料制品有限公司 A kind of warship lightweight armor composite fibre hybrid structure

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103661183A (en) * 2013-12-12 2014-03-26 东华大学 Hybrid composite energy absorbing part for automobile and manufacturing method thereof
CN207156605U (en) * 2017-05-27 2018-03-30 咸宁海威复合材料制品有限公司 A kind of warship lightweight armor composite fibre hybrid structure

Similar Documents

Publication Publication Date Title
Kazemi et al. Mechanical properties and failure modes of hybrid fiber reinforced polymer composites with a novel liquid thermoplastic resin, Elium®
El-Dessouky et al. Ultra-lightweight carbon fibre/thermoplastic composite material using spread tow technology
An et al. Static strength of RTM composite joint with I-fiber stitching process
Li et al. Enhancing the fracture toughness of laminated composites through carbon nanotube belt stitching
Liu et al. Experimental investigation of carbon fiber reinforced poly (phenylene sulfide) composites prepared using a double-belt press
Rahmani et al. Elastic properties of carbon fibre-reinforced epoxy composites
Wu et al. Effect of matrix modification on interlaminar shear strength of glass fibre reinforced epoxy composites at cryogenic temperature
Abdurohman et al. Kajian eksperimental tensile properties komposit poliester berpenguat serat karbon searah hasil manufaktur vacuum infusion sebagai material struktur Lsu
CN111890701A (en) 2.5D fiber woven reinforced resin matrix composite material and preparation method thereof
Ikbal et al. Effect of hybrid ratio and laminate geometry on compressive properties of carbon/glass hybrid composites
Zachariah et al. Experimental analysis of the effect of the woven aramid fabric on the strain to failure behavior of plain weaved carbon/aramid hybrid laminates
Abot et al. On the mechanical response of carbon nanotube array laminated composite materials
CN106626436A (en) Hybrid fiber woven roving composite material automobile battery box and manufacturing method thereof
CN110341204A (en) A kind of fiber hybrid composite material and preparation method thereof
CN113292822A (en) Aramid fiber-epoxy resin based composite material and preparation method and application thereof
Saidi et al. Tensile strength of natural fiber in different type of matrix
CN110341265A (en) A kind of energy-absorbing composite material
Dan et al. Tensile properties of Z-pins reinforced laminates
Daelemans et al. Effect of interleaved polymer nanofibers on the properties of glass and carbon fiber composites
Shinde et al. Flexural behavior of fiberglass polymer composite with and without TEOS electrospun nanofibers
Jain et al. Effect of through-thickness stitching on the fatigue life of composite single-lap joints
Ikbal et al. GF/CF hybrid laminates made through intra-tow hybridization for automobile applications
Abdelal et al. The effect of nylon and Kevlar stitching on the mode I fracture of carbon/epoxy composites
CN111993680A (en) Composite material and processing device thereof
Shinde et al. Short beam strength of laminated fiberglass composite with and without electospun teos nanofibers

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WD01 Invention patent application deemed withdrawn after publication

Application publication date: 20191018

WD01 Invention patent application deemed withdrawn after publication