CN103653457B - Thermal radiation prevention and flame retardance knitted fabric and manufacturing method - Google Patents
Thermal radiation prevention and flame retardance knitted fabric and manufacturing method Download PDFInfo
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- CN103653457B CN103653457B CN201310655826.7A CN201310655826A CN103653457B CN 103653457 B CN103653457 B CN 103653457B CN 201310655826 A CN201310655826 A CN 201310655826A CN 103653457 B CN103653457 B CN 103653457B
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Abstract
The invention discloses a manufacturing method of a thermal radiation prevention and flame retardance knitted fabric. The method includes the steps of knitting a double-faced knitted gray fabric through silver-plated fiber filaments and Lenzing thermal protection fiber filaments so that one face of the gray fabric can be a silver-plated fiber face and the other face of the gray fabric can be a flame retardance fiber face, and then conducting dyeing and finishing on the gray fabric, wherein chinlon filaments serve as carriers for the silver-plated fiber face, silver is arranged on the surface layer of the silver-plated fiber face through an electrolytic method or a permeating and fixing method, the Lenzing thermal protection fiber filaments serve as carriers for the flame retardance fiber face, and a flame retardance medium is arranged on the surface of the flame retardance fiber face through a soaking method. The silver-plate fiber is reasonably combined and matched with the Lenzing thermal protection fiber, and therefore a fabric with a thermal radiation prevention function and a flame retardance function is produced.
Description
Technical field
The present invention relates to a kind of double knit fabric, particularly relate to the fire-retardant knit fabric of a kind of thermal radiation resistant and preparation method.
Background technology
At present, the operator before the inherent high temperature furnace in smeltery, wears thick canvas clothes with it, add the heat radiation generated in high temperature furnace, the heaviness of clothes of just seeming and backing hot, very uncomfortable, and infliction of body can be caused to operator for a long time in the past.
Summary of the invention
For the problems referred to above, the knit fabric that the object of the present invention is to provide a kind of thermal radiation resistant fire-retardant and preparation method.
For achieving the above object, the knit fabric that a kind of thermal radiation resistant of the present invention is fire-retardant, the one side of described fabric is that silver plated fiber long filament is weaved and formed, to form silver-colored fibrous face; Wherein, described silver plated fiber take chinlon filament as carrier, adopts electrolytic method or ooze solid method silver is arranged on its top layer; The another side of described fabric is that Lenzin thermal protection fiber filament is weaved and formed, and to form fire resistance fibre face, wherein, described fire resistance fibre face is with Lenzin thermal protection fiber filament for carrier, adopts to invade bubble mode and fire-retardant medium is arranged on its surface.
Preferably, the silver plated fiber of described fabric, the content of Lenzin thermal protection fiber are respectively 10%-40%, 60%-90%.
Preferably, described Lenzin thermal protection fiber filament is 9.7tex; Described silver plated fiber long filament is 77.8dtex/24F.
For achieving the above object, the preparation method of the knit fabric that a kind of thermal radiation resistant of the present invention is fire-retardant, the method is: use silver plated fiber long filament and Lenzin thermal protection fiber filament to weave described two-sided knit fabric grey cloth, to make the one side of described grey cloth for silver-colored fibrous face, and another side is fire resistance fibre face, then dyeing and finishing process is carried out to described grey cloth; Wherein, described silver plated fiber take chinlon filament as carrier, adopts electrolytic method or ooze solid method silver to be arranged on its top layer; Described fire resistance fibre face is with Lenzin thermal protection fiber filament for carrier, and employing is invaded bubble mode and fire-retardant medium is arranged on its surface.
Preferably, described dyeing and finishing step is followed successively by: oil removing, dyeing, one-step building, anti-oxidant treatment, top finish, secondary heat treatment.
Preferably, described dyeing and finishing step is specially:
Oil removing: knit fabric embryo cloth is put into closed overflow dyeing machine, adds the clever 1g/L and soda ash 2g/L that deoils in the pure water in overflow dyeing machine, be warming up to 75-80 DEG C and keep 20 minutes to it; Then add acetic acid 0.5ml/L, wash 10-15 minute water temperature 70-80 DEG C of overflow;
Dyeing: water filling again after the overflow dyeing machine carrying out the oil removing stage is discharged water, water temperature is 25-30 DEG C, adds glauber salt 8g/L, levelling agent 1ml/L, chelating agent 1ml/L successively; Embryo cloth adds dyestuff after soaking 10 minutes, and continues immersion 10 minutes; Then every 1 minute water temperature raises 1 DEG C, is warmed up to 85-90 DEG C and keeps 40 minutes; Wherein, dye colour composition accounts for the proportion of embryo cloth and is: yellow 4RFN0.714%, zhang blue or green B-EXF0.161%, black S-R6.071%;
And then every 1 minute water temperature reduces by 1 DEG C, cools to 40-45 DEG C and keeps 5-10 minute; After add soda ash 20g/L and carry out fixation; Then make every 1 minute of water temperature raise 1 DEG C, be warmed up to 55-60 DEG C and overflow is washed after keeping 35-40 minute; Then discharge water water filling, adds acetic acid 2ml/L and carry out overflow and wash; Then discharge water water filling, adds liquid of soaping, and keeps 15-20 minute, discharge water at water temperature 90-98 DEG C; The 70-80 DEG C of hot water that reinjects carries out hot water wash 20 minutes, discharges water; Water filling adds softening agent immersion again; Wherein, the proportion that the liquid component of liquid soaped described in accounts for total water level is: soap lye 2ml/L, chelating agent 1ml/L, deoil clever 1ml/L;
One-step building: the first Zha Shui of embryo cloth, then enter in the forming machine of temperature 110-120 DEG C, shape with the speed of 20-28 rice per minute;
Anti-oxidant treatment: form titanium diaphragm with the form of multi-arc ion coating on the surface of described silver-colored fibrous face;
Top finish: this step comprises allotment slurry, oven dry, washing, wherein,
The dosage of described slurry is as follows: waterproof and oilproof reinforcing agent HF0.02g/L, water and oil repellent agent KG-500A33g/L, thickener FS-80E35g/L, sunlight fastness promoting agent JR-TN0222g/L are carried out mixing preparation form slurry;
By above-mentioned slurry after printing machine starching, on baking oven nylon conduction band, 70-90 DEG C, speed of a motor vehicle 30-45m/min are dried; After oven dry, in overflow dyeing machine, carry out 70-90 DEG C, 30min, add moisture absorbing and sweat releasing agent 3g/L, washing; Then dewater, 75-80 DEG C of oven dry;
Secondary heat treatment: embryo cloth pads softening agent 10g/L, then enter in the forming machine of temperature 110-115 DEG C, carry out secondary sizing with the speed of 25-30 rice per minute.
Beneficial effect of the present invention is:
The present invention carries out rational combination collocation design by employing silver plated fiber, Lenzin thermal protection fiber, produces thermal radiation resistant fabric with flame retarding function.Lenzin thermal protection fiber is drawn materials from natural beech, makes fabric finally have softness and comfortableness.And add fire-retardant medium, reach flame retardant effect.Silver plated fiber adopts electrolysis mode that silver is plated in fiber surface, reaches radiation-proof effect.
Accompanying drawing explanation
Fig. 1 is the knitting schematic diagram of the fire-retardant fabric of thermal radiation resistant of the present invention.
Detailed description of the invention
Below in conjunction with Figure of description, the present invention will be further described.
The knit fabric that described in the embodiment of the present invention, a kind of thermal radiation resistant is fire-retardant, the one side of described fabric is that silver plated fiber long filament is weaved and formed, to form silver-colored fibrous face; Wherein, described silver plated fiber take chinlon filament as carrier, adopts electrolytic method or ooze solid method silver is arranged on its top layer; The another side of described fabric is that Lenzin thermal protection fiber filament is weaved and formed, and to form fire resistance fibre face, wherein, described fire resistance fibre face is with Lenzin thermal protection fiber filament for carrier, adopts to invade bubble mode and fire-retardant medium is arranged on its surface.Wherein, the silver plated fiber of described fabric, the content of Lenzin thermal protection fiber are respectively 10%-40%, 60%-90%.Described Lenzin thermal protection fiber filament is 9.7tex; Described silver plated fiber long filament is 77.8dtex/24F.
The braiding of described fabric adopts two-sided large circle machine, is illustrated in figure 1 the weaving figure of fabric.Wherein, upper dish full pin A, lower wall ABAC, wherein the first via is coiled the whole lopping of eedle, the lopping of lower wall second runway machine eedle, lower wall first and the 3rd runway machine eedle flotation line, the first via enters 77.8dtex/24F thermal radiation resistant silver plated fiber; Second tunnel is coiled the whole flotation line of eedle, lower wall second runway eedle flotation line, lower wall first and the 3rd runway machine eedle lopping, 9.7tex Lenzin thermal protection fiber is entered on the second tunnel; 3rd and the 5th tunnel weaves with the first via.4th and the 6th with the second tunnel braiding.7th tunnel is coiled the whole lopping of eedle, the lopping of lower wall the 3rd runway machine eedle, lower wall first and second runway machine eedle flotation line, 77.8dtex/24F heat release radiation silver plated fiber is entered on the 7th tunnel; The whole flotation line of 8th road lower wall eedle, lower wall the 3rd runway machine eedle flotation line, the lopping of lower wall first and second runway machine eedle, 9.7tex Lenzin thermal protection fiber is entered on the 8th tunnel; 9th and the 11 tunnel with the 7th tunnel braiding.Tenth and the 12 tunnel with the 8th tunnel braiding, upper and lower hand misplaces respectively.Yarn H forms the knit fabric of heat release radiation, permanent fire retardant under eedle G effect.
The present invention carries out rational combination collocation design by employing silver plated fiber, Lenzin thermal protection fiber, produces thermal radiation resistant fabric with flame retarding function.Lenzin thermal protection fiber is drawn materials from natural beech, makes fabric finally have softness and comfortableness.And add fire-retardant medium, reach flame retardant effect.Silver plated fiber adopts electrolysis mode that silver is plated in fiber surface, reaches radiation-proof effect.
For the making of above-mentioned fabric, the invention provides the preparation method of the fire-retardant knit fabric of a kind of thermal radiation resistant, the method is: use silver plated fiber long filament and Lenzin thermal protection fiber filament to weave described two-sided knit fabric grey cloth, to make the one side of described grey cloth for silver-colored fibrous face, and another side is fire resistance fibre face, then dyeing and finishing process is carried out to described grey cloth; Wherein, described silver plated fiber take chinlon filament as carrier, adopts electrolytic method or ooze solid method silver to be arranged on its top layer; Described fire resistance fibre face is with Lenzin thermal protection fiber filament for carrier, and employing is invaded bubble mode and fire-retardant medium is arranged on its surface.
Described dyeing and finishing step is followed successively by: oil removing, dyeing, one-step building, anti-oxidant treatment, top finish, secondary heat treatment.
Described dyeing and finishing step is specially:
Oil removing: knit fabric embryo cloth is put into closed overflow dyeing machine, adds the clever 1g/L and soda ash 2g/L that deoils in the pure water in overflow dyeing machine, be warming up to 75-80 DEG C and keep 20 minutes to it; Then add acetic acid 0.5ml/L, wash 10-15 minute water temperature 70-80 DEG C of overflow;
Dyeing: water filling again after the overflow dyeing machine carrying out the oil removing stage is discharged water, water temperature is 25-30 DEG C, adds glauber salt 8g/L, levelling agent 1ml/L, chelating agent 1ml/L successively; Embryo cloth adds dyestuff after soaking 10 minutes, and continues immersion 10 minutes; Then every 1 minute water temperature raises 1 DEG C, is warmed up to 85-90 DEG C and keeps 40 minutes; Wherein, dye colour composition accounts for the proportion of embryo cloth and is: yellow 4RFN0.714%, zhang blue or green B-EXF0.161%, black S-R6.071%;
And then every 1 minute water temperature reduces by 1 DEG C, cools to 40-45 DEG C and keeps 5-10 minute; After add soda ash 20g/L and carry out fixation; Then make every 1 minute of water temperature raise 1 DEG C, be warmed up to 55-60 DEG C and overflow is washed after keeping 35-40 minute; Then discharge water water filling, adds acetic acid 2ml/L and carry out overflow and wash; Then discharge water water filling, adds liquid of soaping, and keeps 15-20 minute, discharge water at water temperature 90-98 DEG C; The 70-80 DEG C of hot water that reinjects carries out hot water wash 20 minutes, discharges water; Water filling adds softening agent immersion again; Wherein, the proportion that the liquid component of liquid soaped described in accounts for total water level is: soap lye 2ml/L, chelating agent 1ml/L, deoil clever 1ml/L;
One-step building: the first Zha Shui of embryo cloth, then enter in the forming machine of temperature 110-120 DEG C, shape with the speed of 20-28 rice per minute;
Anti-oxidant treatment: form titanium diaphragm with the form of multi-arc ion coating on the surface of described silver-colored fibrous face;
Top finish: this step comprises allotment slurry, oven dry, washing, wherein,
The dosage of described slurry is as follows: waterproof and oilproof reinforcing agent HF0.02g/L, water and oil repellent agent KG-500A33g/L, thickener FS-80E35g/L, sunlight fastness promoting agent JR-TN02 22g/L are carried out mixing preparation form slurry;
By above-mentioned slurry after printing machine starching, on baking oven nylon conduction band, 70-90 DEG C, speed of a motor vehicle 30-45m/min are dried; After oven dry, in overflow dyeing machine, carry out 70-90 DEG C, 30min, add moisture absorbing and sweat releasing agent 3g/L, washing; Then dewater, 75-80 DEG C of oven dry;
Secondary heat treatment: embryo cloth pads softening agent 10g/L, then enter in the forming machine of temperature 110-115 DEG C, carry out secondary sizing with the speed of 25-30 rice per minute.
Above; be only preferred embodiment of the present invention, but protection scope of the present invention is not limited thereto, is anyly familiar with those skilled in the art in the technical scope that the present invention discloses; the change that can expect easily or replacement, all should be encompassed within protection scope of the present invention.Therefore, the protection domain that protection scope of the present invention should define with claim is as the criterion.
Claims (1)
1. the preparation method of the knit fabric that a thermal radiation resistant is fire-retardant, it is characterized in that, the method is: use silver plated fiber long filament and Lenzin thermal protection fiber filament to weave two-sided knit fabric grey cloth, to make the one side of described grey cloth for silver-colored fibrous face, and another side is fire resistance fibre face, then dyeing and finishing process is carried out to described grey cloth; Wherein, described silver plated fiber take chinlon filament as carrier, adopts electrolytic method or ooze solid method silver to be arranged on its top layer; Described fire resistance fibre face is with Lenzin thermal protection fiber filament for carrier, and employing is invaded bubble mode and fire-retardant medium is arranged on its surface;
Described dyeing and finishing step is followed successively by: oil removing, dyeing, one-step building, anti-oxidant treatment, top finish, secondary heat treatment;
Described dyeing and finishing step is specially:
Oil removing: knit fabric embryo cloth is put into closed overflow dyeing machine, adds the clever 1g/L and soda ash 2g/L that deoils in the pure water in overflow dyeing machine, be warming up to 75-80 DEG C and keep 20 minutes to it; Then add acetic acid 0.5ml/L, wash 10-15 minute water temperature 70-80 DEG C of overflow;
Dyeing: water filling again after the overflow dyeing machine carrying out the oil removing stage is discharged water, water temperature is 25-30 DEG C, adds glauber salt 8g/L, levelling agent 1ml/L, chelating agent 1ml/L successively; Embryo cloth adds dyestuff after soaking 10 minutes, and continues immersion 10 minutes; Then every 1 minute water temperature raises 1 DEG C, is warmed up to 85-90 DEG C and keeps 40 minutes; Wherein, dye colour composition accounts for the proportion of embryo cloth and is: yellow 4RFN 0.714%, zhang blue or green B-EXF0.161%, black S-R 6.071%;
And then every 1 minute water temperature reduces by 1 DEG C, cools to 40-45 DEG C and keeps 5-10 minute; After add soda ash 20g/L and carry out fixation; Then make every 1 minute of water temperature raise 1 DEG C, be warmed up to 55-60 DEG C and overflow is washed after keeping 35-40 minute; Then discharge water water filling, adds acetic acid 2ml/L and carry out overflow and wash; Then discharge water water filling, adds liquid of soaping, and keeps 15-20 minute, discharge water at water temperature 90-98 DEG C; The 70-80 DEG C of hot water that reinjects carries out hot water wash 20 minutes, discharges water; Water filling adds softening agent immersion again; Wherein, the proportion that the liquid component of liquid soaped described in accounts for total water level is: soap lye 2ml/L, chelating agent 1ml/L, deoil clever 1ml/L;
One-step building: the first Zha Shui of embryo cloth, then enter in the forming machine of temperature 110-120 DEG C, shape with the speed of 20-28 rice per minute;
Anti-oxidant treatment: form titanium diaphragm with the form of multi-arc ion coating on the surface of described silver-colored fibrous face;
Top finish: this step comprises allotment slurry, oven dry, washing, wherein,
The dosage of described slurry is as follows: waterproof and oilproof reinforcing agent HF 0.02g/L, water and oil repellent agent KG-500A 33g/L, thickener FS-80E 35g/L, sunlight fastness promoting agent JR-TN0222g/L are carried out mixing preparation form slurry;
By above-mentioned slurry after printing machine starching, on baking oven nylon conduction band, 70-90 DEG C, speed of a motor vehicle 30-45m/min are dried; After oven dry, in overflow dyeing machine, carry out 70-90 DEG C, 30min, add moisture absorbing and sweat releasing agent 3g/L, washing; Then dewater, 75-80 DEG C of oven dry;
Secondary heat treatment: embryo cloth pads softening agent 10g/L, then enter in the forming machine of temperature 110-115 DEG C, carry out secondary sizing with the speed of 25-30 rice per minute.
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| CN104957811A (en) * | 2015-06-06 | 2015-10-07 | 朱卫东 | Electricity-proof and flame-retardant shell fabric |
| CN105951283B (en) * | 2016-06-21 | 2018-07-20 | 际华三五四三针织服饰有限公司 | The preparation method of the unidirectional water guide antibiosis knitting face fabric of Chinese fiber crops |
| CN111020828B (en) * | 2019-12-06 | 2021-02-26 | 江苏东源纺织科技实业有限公司 | Production process of radiation-proof temperature-sensitive color-changing fabric |
| CN114347622A (en) * | 2022-01-11 | 2022-04-15 | 泉州禾伦织造有限公司 | Skin-friendly nylon double-sided knitted fabric and preparation method thereof |
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