CN103651461A - Ultra-low volume liquid containing cycloxaprid and carbamate pesticide - Google Patents
Ultra-low volume liquid containing cycloxaprid and carbamate pesticide Download PDFInfo
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Abstract
The invention belongs to the technical field of pesticides, and particularly relates to an ultra-low volume liquid containing cycloxaprid and a carbamate pesticide. According to the ultra-low volume liquid, cycloxaprid and the carbamate pesticide are compounded to form an active component, and other components are a surface active agent and a solvent; and the carbamate pesticide is one of carbosulfan, fenobucarb, triazamate, tsumacide, methomyl and thiodicarb. The ultra-low volume liquid is convenient to process and has long duration of efficacy and high work efficiency, a target has low probability of drug resistance, the environment pollution is little, pesticide and water are saved, the pesticide utilization rate is increased, and through ultra-low volume spray, low volume spray or ultra-low volume electrostatic spray, various pests of rice, wheat, corn, vegetable, tobacco, tea trees, fruit trees and sugar canes can be controlled.
Description
Technical field
The invention belongs to technical field of pesticide, particularly relate to a kind of ultra low volume liquids containing cycloxaprid and carbamate insecticide.
Background technology
Cycloxaprid is super-active of new generation, the special hypotoxic agricultural insecticide of East China University of Science's research and development.Chemical name: 9-((6-chloropyridine-3-yl) methyl)-4-nitro-8-oxa--10,11-glyoxalidine also (2,3-a) dicyclo (3,2,1) pungent-3-alkene, English common name: cycloxaprid, chemical molecular formula C14H15ClN4O3, chemical structural formula is:
Cycloxaprid has interior suction, stomach toxicity and contact toxicity to insect, can be used for preventing and treating Homoptera, coleoptera, lepidoptera pest on crops.The cycloxaprid mechanism of action is novel, research shows: cycloxaprid consumption is during lower than 10uM, nAChR is not shown to the reaction of activator, and show as unique antagonist feature, completely different from the mechanism of action of the anabasine receptor stimulating agent of current commercial anabasine insecticide variety, therefore with other anabasine insecticides without cross resistance.This product using dosage is low, environmentally safe, to beneficial organism without harm or endanger minimum.The aphid of the crops such as wheat, cotton, paddy rice, fruit tree, vegetables, rice leaf roller, plant hopper, aleyrodid, leafhopper, thrips, flea beetle, cotton bollworm, diamond-back moth, cabbage caterpillar, prodenia litura, mythimna separata etc. are had to higher insecticidal activity.
Carbamate insecticide have effect rapidly, high, the majority of selectivity have interior absorption, low to warm blooded animal toxicity, there is no the advantages such as residual hazard, especially leafhopper and plant hopper are had to special efficacy.But some kind insecticidal spectrum is wideless, has limited the scope of application, and minority kind is very high to person poultry toxicity, use not too safe; Some insect can produce resistance to carbamate chemicals for agriculture, and rational mixture can overcome above shortcoming, and in the present invention, the chemical name of the related carbamate insecticide of active component II is as follows:
The chemical name of carbosulfan is 2,3-dihydro-2,2-dimethyl benzofuran-7-base (dibutylamino sulphur) methyl carbamate;
The chemical name of Bassa is 2-2-phenylbutane base-N-methyl carbamate;
The chemical name of triaguron is (3-tertiary butyl-1-dimethylamino formyl-1H-1,2,4-triazole-5-base sulphur) ethyl acetate;
The chemical name of meta-tolyl-N-methylcarbamate (MTMC) is m-tolyl-N-methyl carbamate
The chemical name of Methomyl is 1-(methyl mercapto) ethylidene ammonia-N-methyl carbamate;
The chemical name of UC-51762 is 3,7,9,13-tetramethyl-5,11-dioxa-2,8,14-, tri-thia-4,7,9,12-, tetra--azepine pentadecane-3,12-diene-6,10-diketone;
Ultra low volume liquids is a kind of high-efficiency low-toxicity, the agricultural chemicals novel formulation of low-residual, this formulation can reduce usage amount and the frequency of utilization of medicament, delay the generation of pest resistance to insecticide, environmentally friendly, to non-target safety such as people and animals, can save dispenser water consumption, improving and prevent and treat work efficiency, can meet the various requirement of agricultural sustainable development, is the ideal chose of green agricultural product drug formulation.The solvent that ultra low volume liquids is low by screening volatility, flash-point is high, good to former medicine dissolubility, low to chemical injury of crops, viscosity is low, during dispenser, be not watered, but directly use with ultra low volume sprayer tool, low-gallonage spraying apparatus or ultra low volume electrostatic spray apparatus.Ultra low volume spraying is owing to not containing high volatile volatile composition in droplet, and its size does not have significant change with quality from leave spraying apparatus arrival target process, has reduced and has volatilized with elegant.Droplet is tiny and even, meets " biological best granula " requirement, has significantly improved deposition.Owing to using without being watered, ultra low volume liquids is suitable for water scarcity, damage by disease and insect fulminant large area occurs and the occasion of dispenser on a large scale in the palpus short time, and ultra low volume spraying simultaneously reduces operator's labour intensity greatly.
In the real process of agricultural production, using chemical agent is the most effectively means of control plant pest, but the problem the most easily producing by chemical control insect is the generation of pest resistance to insecticide.And long-term use single chemical insecticide continuously high dose, easily cause the series of problems such as residual, environmental pollution of medicament.Reasonably chemical insecticide is composite or be mixed and have expansion insecticidal spectrum, improve control efficiency, extend the optimum period for applying fertilizer, reduce dosage, reduce poisoning, reduce residual, delay pest resistance and the positive feature such as drug-fast generation and development, pesticide compositional or to be mixed be one of the effective method the most addressing the above problem.
The inventor is by studies have shown that, the ultra low volume liquids that the arbitrary pesticide active ingredient in cycloxaprid and carbosulfan, Bassa, triaguron, meta-tolyl-N-methylcarbamate (MTMC), Methomyl, UC-51762 is re-dubbed has extremely strong synergistic effect to target pest.
Summary of the invention
Based on above situation, the object of the present invention is to provide a kind of component reasonable, significantly synergy, the ultra low volume liquids preparation containing cycloxaprid and carbamate insecticide of good disinsection effect, and the preparation method of described ultra low volume liquids is provided.
Technical scheme of the present invention realizes by following measures:
Containing a ultra low volume liquids for cycloxaprid and carbamate insecticide, the active component of described ultra low volume liquids is cycloxaprid and carbamate insecticide, and all the other are surfactant and solvent; The weight ratio of described active component cycloxaprid and carbamate insecticide is 1:20～20:1, is preferably 1:10～10:1, is preferably 1:5～5:1.
Described carbamate insecticide is any one of carbosulfan, Bassa, triaguron, meta-tolyl-N-methylcarbamate (MTMC), Methomyl, UC-51762.
Further, the weight content sum of cycloxaprid and carbamate insecticide is 0.2%～50%, and wherein the weight content of cycloxaprid is 0.1%～20%, and the weight content of carbamate insecticide is 0.1%～30%; Surfactant weight content is 1%～10%.
Preferably, the weight content sum of cycloxaprid and carbamate insecticide is 6%～25%, and wherein the weight content of cycloxaprid is 1%～10%, and the weight content of carbamate insecticide is 5%～15%.
Applicable surfactant is selected from fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, the combination of one or more in calcium dodecyl benzene sulfonate, preferred fat alcohol APEO, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate.
Applicable solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and polar solvent; Aromatic hydrocarbon solvent comprises trimethylbenzene, o-dichlorohenzene, durene, diethylbenzene, methyl-propyl benzene, butylbenzene, methyl naphthalene, two wires oil; Plant oil solvent comprises soybean oil, cottonseed oil, corn oil, rapeseed oil, castor oil, turpentine oil, methyl oleate, ethyl oleate; Polar solvent comprises acetophenone, phenmethylol, methyl-sulfoxide, 1-METHYLPYRROLIDONE, DMF, DMA, n-hexyl alcohol, n-octyl alcohol, terpineol.
The preparation method of ultra low volume liquids of the present invention is, in the reaction vessel stirring at band, first with solvent by after active component stirring and dissolving, then add auxiliary component, fully be uniformly mixed, obtain the ultra low volume liquids containing cycloxaprid and carbamate insecticide; Technological parameter is: it is 60～150 revs/min that mixing speed is controlled, and mixing time is 15～60 minutes, and temperature is normal temperature, and pressure is normal pressure.
Applicable target crop is the cereal crops such as paddy rice, wheat, the economic crops such as sugarcane, banana, rubber, cotton, tea tree, oranges and tangerines, apple, hawthorn, peach, the vegetable crops such as tomato, eggplant, capsicum, lettuce, celery, wild cabbage, Kidney bean, broad bean, cowpea, pea, the ground family crops such as cucumber, pumpkin, watermelon.
Ultra low volume liquids of the present invention is applicable to control rice fulgorid, rice leaf roller, brown planthopper, white-backed planthopper, small brown rice planthopper, striped rice borer, rice thrips, rice gall midge, rice leafhopper, rice leafhopper, rice spider rafter stinkbug, star stinkbug, green rice bug resembles, red palpus fleahopper, the negative mixed worm of rice, rice cylinder water snout moth's larva, oryza chinensis, Phytophthira, aleyrodid class, a red-spotted lizard class, unaspis shield kuwana, the green stinkbug of Zhu, peach fruit borer, tangerine lyonetid, the thin moth of tea, striped flea-beetle, the beans fly of diving, cured a red-spotted lizard, diamond-back moth, two secret notes are chrysomelid, tea golden thistle horse, onion thrips, golden thistle horse, oranges and tangerines golden thistle horse, soybean pod gall-midge, tomato Liriomyza.
The method for optimizing of using ultra low volume liquids of the present invention is ultra low volume spraying, is secondly low-gallonage spraying and ultra low volume electrostatic spray, and according to controlling object, a situation arises determines suitable dosage, and formulation rate is 75～150g a.i./hm conventionally
2.
Ultra low volume liquids component of the present invention is reasonable, good disinsection effect, and drug cost is low, and its activity and insecticidal effect are not the simple superposition of each composition activity, but have significant synergistic effect, and good to crop safety, meet the security requirement of pesticidal preparations.
Embodiment
Below in conjunction with embodiment, the present invention is further described, but do not limit the scope of the invention.Reagent and the medicine in embodiment, used are commercially available prod, and content adds after calculating by folding hundred.If no special instructions, the ratio of below mentioning is all ratio of quality and the number of copies.
Embodiment 1 21% cycloxaprid carbosulfan ultra low volume liquids (1:20)
Cycloxaprid 1kg, carbosulfan 20.0kg, N, dinethylformamide 13.0kg, methyl naphthalene 5.0kg, o-dichlorohenzene 3.0kg, castor oil polyoxyethylene ether 1.0kg, two wires oil complement to 100kg, mix and make 20.1% cycloxaprid carbosulfan ultra low volume liquids.
Preparation technology: in the reaction vessel stirring at band, first with solvent by after cycloxaprid and carbosulfan stirring and dissolving, then add auxiliary component, be fully uniformly mixed, obtain 20.1% cycloxaprid carbosulfan ultra low volume liquids; Technological parameter is: it is 60～150 revs/min that mixing speed is controlled, and mixing time is 15～60 minutes, and temperature is normal temperature, and pressure is normal pressure.
According to the step of preparation process identical with embodiment 1, can prepare following examples.
Embodiment 2 22% cycloxaprid carbosulfan ultra low volume liquids (1:10)
Cycloxaprid 2.0kg, carbosulfan 20.0kg, N, N-dimethylacetylamide 10.0kg, 1-METHYLPYRROLIDONE 9.0kg, n-hexyl alcohol 5.0kg, turpentine oil 4.0kg, methyl-propyl benzene 10.0kg, alkylphenol polyoxyethylene 3.0kg, alkylaryl polyoxyethylene polyoxypropylene ether phosphate 3.5kg alkylaryl polyoxyethylene polyoxypropylene ether 3.5kg, cottonseed oil complement to 100kg, mix and make 22% cycloxaprid carbosulfan ultra low volume liquids.
Embodiment 3 30% cycloxaprid carbosulfan ultra low volume liquids (1:5)
Cycloxaprid 5.0kg, carbosulfan 25.0kg, N, dinethylformamide 5.0kg, 1-METHYLPYRROLIDONE 4.0kg, acetophenone 10.0kg, methyl oleate 8.0kg, calcium dodecyl benzene sulfonate 2.0kg, phenethyl phenol polyethenoxy ether phosphate 3.0kg, fatty alcohol-polyoxyethylene ether 2.0kg, soybean oil complement to 100kg, mix and make 30% cycloxaprid carbosulfan ultra low volume liquids
Embodiment 4 12% cycloxaprid carbosulfan ultra low volume liquids (1:3)
Cycloxaprid 3kg, carbosulfan 9kg, 1-METHYLPYRROLIDONE 15.0kg, phenmethylol 5.0kg, methyl-sulfoxide 4.0kg, ethyl oleate 4.0kg, terpineol 2.0kg, calcium dodecyl benzene sulfonate 3.2kg phenethyl phenol polyethenoxy ether 4.8kg, aliphatic alcohol polyoxyvinethene phosphate 2.0kg, castor oil complement to 100kg, mix and make 12% cycloxaprid carbosulfan ultra low volume liquids
Embodiment 5 0.2% cycloxaprid carbosulfan ultra low volume liquids (1:1)
Cycloxaprid 0.1kg, carbosulfan 0.1kg, N, dinethylformamide 5.0kg, methyl naphthalene 2.0kg castor oil polyoxyethylene ether 3.0kg, calcium dodecyl benzene sulfonate 2.0kg, methyl oleate complement to 100kg, mix and make 0.2% cycloxaprid carbosulfan ultra low volume liquids.
Embodiment 6 6.0% cycloxaprid carbosulfan ultra low volume liquids (5:1)
Cycloxaprid 5.0kg, carbosulfan 1.0kg, 1-METHYLPYRROLIDONE 8.0kg, n-octyl alcohol 5.5kg, methyl naphthalene 4.0kg, calcium dodecyl benzene sulfonate 2.0kg, OPEO 2.3kg, alkylphenol polyoxyethylene phosphate 3.7kg, ethyl oleate complement to 100kg, mix and make 6.0% cycloxaprid carbosulfan ultra low volume liquids.
Embodiment 7 11.0% cycloxaprid carbosulfan ultra low volume liquids (10:1)
Cycloxaprid 10.0kg, carbosulfan 1.0kg, alkylphenol polyoxyethylene 2.6kg, aliphatic alcohol polyoxyvinethene phosphate 5.4kg, methyl naphthalene 2.3kg, N, N-dimethylacetylamide 10.7kg, soybean oil are supplied 100kg, mix preparation 11.0% cycloxaprid carbosulfan ultra low volume liquids.
Embodiment 8 14.7% cycloxaprid carbosulfan ultra low volume liquids (14:0.7 is 20:1)
Cycloxaprid 14.0kg, carbosulfan 0.7kg, N, N-dimethylacetylamide 8.3kg, 1-METHYLPYRROLIDONE 10.0kg, n-hexyl alcohol 3.0kg, methyl-propyl benzene 10.0kg, alkylphenol polyoxyethylene 3.8kg, fatty alcohol-polyoxyethylene ether 5.2kg, two wires oil subsidy foot 100kg, mix preparation 14.7% cycloxaprid carbosulfan ultra low volume liquids.
Embodiment 9 26% cycloxaprid Bassa ultra low volume liquids (12:1)
Cycloxaprid 24.0kg, Bassa 2.0kg, 1-METHYLPYRROLIDONE 7.5kg, butylbenzene 8.0kg, ethyl oleate 7.0kg, calcium dodecyl benzene sulfonate 1.0kg, OPEO 2.5kg, alkylphenol polyoxyethylene phosphate 2.0kg, corn oil complement to 100kg, mix and make 26% cycloxaprid Bassa ultra low volume liquids.
Embodiment 10 7% cycloxaprid Bassa ultra low volume liquids (6:1)
Cycloxaprid 6.0kg, Bassa 1.0kg, N, N-dimethylacetylamide 10.0kg, 1-METHYLPYRROLIDONE 9.0kg, n-hexyl alcohol 5.0kg, turpentine oil 4.0kg, methyl-propyl benzene 10.0kg, alkylphenol polyoxyethylene 3.0kg, alkylaryl polyoxyethylene polyoxypropylene ether phosphate 1.5kg, alkylaryl polyoxyethylene polyoxypropylene ether 3.0kg, cottonseed oil complement to 100kg, mix and make 7% cycloxaprid Bassa ultra low volume liquids.
Embodiment 11 10% cycloxaprid Bassa ultra low volume liquids (1:1)
Cycloxaprid 5.0kg, Bassa 5.0kg, N, dinethylformamide 5.0kg, 1-METHYLPYRROLIDONE 4.0kg, acetophenone 10.0kg, methyl oleate 8.0kg, calcium dodecyl benzene sulfonate 2.0kg, phenethyl phenol polyethenoxy ether phosphate 3.0kg, fatty alcohol-polyoxyethylene ether 2.0kg, soybean oil complement to 100kg, mix and make 10% cycloxaprid Bassa ultra low volume liquids.
Embodiment 12 20% cycloxaprid Bassa ultra low volume liquids (1:9)
Cycloxaprid 2.0kg, Bassa 18.0kg, N, N-dimethylacetylamide 10.0kg, 1-METHYLPYRROLIDONE 9.0kg, n-hexyl alcohol 5.0kg, trimethylbenzene 4.0kg, methyl-propyl benzene 10.0kg, alkylphenol polyoxyethylene 3.0kg, alkylaryl polyoxyethylene polyoxypropylene ether phosphate 1.5kg, alkylaryl polyoxyethylene polyoxypropylene ether 3.0kg, cottonseed oil complement to 100kg, mix and make 20% cycloxaprid Bassa ultra low volume liquids.
Embodiment 13 38.0% cycloxaprid Bassa ultra low volume liquids (1:18)
Cycloxaprid 2.0kg, Bassa 36.0kg, 1-METHYLPYRROLIDONE 6.0kg, N, dinethylformamide 5.0kg, n-octyl alcohol 5.5kg, durene 5.0kg, calcium dodecyl benzene sulfonate 2.0kg, OPEO 1.5kg, castor oil polyoxyethylene ether 2.0kg, rapeseed oil complement to 100kg, mix and make 38% cycloxaprid Bassa ultra low volume liquids.
Embodiment 14 32% cycloxaprid triaguron ultra low volume liquids (15:1)
Cycloxaprid 30.0kg, triaguron 2.0kg, 1-METHYLPYRROLIDONE 12.0kg, N, dinethylformamide 10.0kg, n-octyl alcohol 5.5kg, diethylbenzene 5.0kg, terpineol 3.0kg, calcium dodecyl benzene sulfonate 2.0kg, OPEO 1.5kg, castor oil polyoxyethylene ether 2.0kg, rapeseed oil complement to 100kg, mix and make 32% cycloxaprid triaguron ultra low volume liquids.
Embodiment 15 18% cycloxaprid triaguron ultra low volume liquids (8:1)
Cycloxaprid 16kg, triaguron 2.0kg, 1-METHYLPYRROLIDONE 6.0kg, N, dinethylformamide 5.0kg, methyl naphthalene 5.5kg, phenmethylol 4.3kg, alkylphenol polyoxyethylene 3.9kg, OPEO 2.1kg, castor oil polyoxyethylene ether 2.0kg, ethyl oleate complement to 100kg, mix and make 18% cycloxaprid triaguron ultra low volume liquids.
Embodiment 16 25.0% cycloxaprid triaguron ultra low volume liquids (4:1)
Cycloxaprid 20.0kg, triaguron 5.0kg, 1-METHYLPYRROLIDONE 7.5kg, durene 8.0kg, phenmethylol 2.0kg, ethyl oleate 5.0kg, calcium dodecyl benzene sulfonate 1.0kg, aliphatic alcohol polyoxyvinethene phosphate 2.5kg, alkylphenol polyoxyethylene phosphate 2.0kg, corn oil complement to 100kg, mix and make 25.0% cycloxaprid triaguron ultra low volume liquids.
Embodiment 17 9% cycloxaprid triaguron ultra low volume liquids (2:1)
Cycloxaprid 6.0kg, triaguron 3.0kg, N, N-dimethylacetylamide 10.0kg, n-hexyl alcohol 5.0kg, trimethylbenzene 4.0kg, alkylphenol polyoxyethylene 3.0kg, alkylaryl polyoxyethylene polyoxypropylene ether phosphate 1.5kg, alkylaryl polyoxyethylene polyoxypropylene ether 3.0kg, cottonseed oil complement to 100kg, mix and make 9% cycloxaprid triaguron ultra low volume liquids.
Embodiment 18 12% cycloxaprid triaguron ultra low volume liquids (6:6)
Cycloxaprid 6.0kg, triaguron 6.0kg, 1-METHYLPYRROLIDONE 4.0kg, methyl naphthalene 5.0kg, methyl oleate 8.0kg, calcium dodecyl benzene sulfonate 3.4kg, phenethyl phenol polyethenoxy ether phosphate 2.6kg, fatty alcohol-polyoxyethylene ether 2.0kg, two wires oil complement to 100kg, mix and make 12% cycloxaprid Bassa ultra low volume liquids.
Embodiment 19 16% cycloxaprid triaguron ultra low volume liquids (1:2)
Cycloxaprid 4.0kg, triaguron 12.0kg, 1-METHYLPYRROLIDONE 8.5kg, methyl-sulfoxide 6.0kg, n-octyl alcohol 5.0kg, methyl oleate 8.0kg, calcium dodecyl benzene sulfonate 2.0kg, phenethyl phenol polyethenoxy ether phosphate 3.0kg, fatty alcohol-polyoxyethylene ether 2.0kg, turpentine oil complement to 100kg, mix and make 16% cycloxaprid triaguron ultra low volume liquids
Embodiment 20 27% cycloxaprid triaguron ultra low volume liquids (1:8)
Cycloxaprid 3.0kg, triaguron 24.0kg, 1-METHYLPYRROLIDONE 7.3kg, N, N-dimethylacetylamide 2.7kg, terpineol 5.5kg, calcium dodecyl benzene sulfonate 2.2kg, OPEO 1.5kg, castor oil polyoxyethylene ether 2.3kg, methyl oleate complement to 100kg, mix and make 27% cycloxaprid triaguron ultra low volume liquids.
Embodiment 21 34% cycloxaprid triaguron ultra low volume liquids (1:16)
Cycloxaprid 2.0kg, triaguron 32.0kg, 1-METHYLPYRROLIDONE 6.3kg, ethyl oleate 4.7kg, calcium dodecyl benzene sulfonate 2.5kg, phenethyl phenol polyethenoxy ether phosphate 1.5kg, fatty alcohol-polyoxyethylene ether 2.3kg, soybean oil complement to 100kg, mix and make 34% cycloxaprid triaguron ultra low volume liquids.
Embodiment 22 16% cycloxaprid meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids (15:1)
Cycloxaprid 15.0kg, meta-tolyl-N-methylcarbamate (MTMC) 1.0kg, 1-METHYLPYRROLIDONE 7.5kg, durene 8.0kg ethyl oleate 7.0kg, calcium dodecyl benzene sulfonate 1.0kg, phenethyl phenol polyethenoxy ether phosphate 6.5kg alkylphenol polyoxyethylene phosphate 2.5kg, two wires oil complement to 100kg, mix and make 16% cycloxaprid meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids.
Embodiment 23 8% cycloxaprid meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids (3:1)
Cycloxaprid 6.0kg, meta-tolyl-N-methylcarbamate (MTMC) 2.0kg, dinethylformamide 3.5kg, N, N-dimethylacetylamide 10.0kg, trimethylbenzene 2.0kg, DBSA 2.8kg, fatty alcohol-polyoxyethylene ether 2.7kg, turpentine oil complement to 100kg, mix and make 24.5% cycloxaprid meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids.
Embodiment 24 20% cycloxaprid meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids (10:10)
Cycloxaprid 10kg, meta-tolyl-N-methylcarbamate (MTMC) 10kg, 1-METHYLPYRROLIDONE 6.0kg, N, N-dimethylacetylamide 5.0kg, terpineol 5.5kg, durene 5.0kg, calcium dodecyl benzene sulfonate 2.0kg, OPEO 1.5kg, castor oil polyoxyethylene ether 2.0kg, rapeseed oil complement to 100kg, mix and make 20% cycloxaprid meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids.
Embodiment 25 12% cycloxaprid meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids (1:5)
Cycloxaprid 2.0kg, meta-tolyl-N-methylcarbamate (MTMC) 10.0kg, N, N-dimethylacetylamide 10.0kg, n-hexyl alcohol 5.0kg, trimethylbenzene 4.0kg, methyl-propyl benzene 10.0kg, alkylphenol polyoxyethylene 3.0kg, castor oil polyoxyethylene ether 1.5kg, aliphatic alcohol polyoxyvinethene phosphate 3.0kg, two wires oil complement to 100kg, mix and make 12% cycloxaprid meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids.
Embodiment 26 32% cycloxaprid meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids (1:15)
Cycloxaprid 2.0kg, meta-tolyl-N-methylcarbamate (MTMC) 30.0kg, N, dinethylformamide 5.0kg, 1-METHYLPYRROLIDONE 4.0kg, acetophenone 10.0kg, durene 8.0kg, DBSA 2.0kg, fatty alcohol-polyoxyethylene ether 2.0kg, turpentine oil complement to 100kg, mix and make 32% cycloxaprid meta-tolyl-N-methylcarbamate (MTMC) ultra low volume liquids
Embodiment 27 22.0% cycloxaprid Methomyl ultra low volume liquids (10:1)
Cycloxaprid 20.0kg, Methomyl 2.0kg, 1-METHYLPYRROLIDONE 7.5kg, trimethylbenzene 8.0kg, n-octyl alcohol 2.0kg, ethyl oleate 5.0kg, calcium dodecyl benzene sulfonate 1.0kg, aliphatic alcohol polyoxyvinethene phosphate 2.5kg, castor oil polyoxyethylene ether 6.5kg, corn oil complement to 100kg, mix and make 22.0% cycloxaprid Methomyl ultra low volume liquids.
Embodiment 28 50% cycloxaprid Methomyl ultra low volume liquids (2:3)
Cycloxaprid 20.0kg, Methomyl 30.0kg, N, N-dimethylacetylamide 10.0kg, n-hexyl alcohol 5.0kg, trimethylbenzene 15.0kg, methyl-propyl benzene 10.0kg, alkylphenol polyoxyethylene 3.0kg, alkylaryl polyoxyethylene polyoxypropylene ether 1.5kg, alkylaryl polyoxyethylene polyoxypropylene ether 3.0kg, cottonseed oil complement to 100kg, mix and make 50% cycloxaprid Methomyl ultra low volume liquids.
Embodiment 29 35.0% cycloxaprid Methomyl ultra low volume liquids (1:6)
Cycloxaprid 5.0kg, Methomyl 30.0kg, 1-METHYLPYRROLIDONE 6.0kg, n-octyl alcohol 5.5kg, diethylbenzene 5.0kg, terpineol 3.0kg, calcium dodecyl benzene sulfonate 2.0kg, OPEO 1.5kg, castor oil polyoxyethylene ether 2.0kg, two wires oil complement to 100kg, mix and make 35.0% cycloxaprid Methomyl ultra low volume liquids
Embodiment 30 13% cycloxaprid Methomyl ultra low volume liquids (1:12)
Cycloxaprid 1.0kg, Methomyl 12.0kg, 1-METHYLPYRROLIDONE 7.3kg, n-octyl alcohol 5.2kg, methyl naphthalene 5.4kg, phenmethylol 3.0kg, alkylphenol polyoxyethylene 2.2kg, OPEO 1.5kg, phenethyl phenol polyethenoxy ether phosphate 2.3kg, two wires oil complement to 100kg, mix and make 13% cycloxaprid Methomyl ultra low volume liquids
Embodiment 31 10.1% cycloxaprid UC-51762 ultra low volume liquids (0.1:10)
Cycloxaprid 0.1kg, UC-51762 10.0kg, 1-METHYLPYRROLIDONE 6.0kg, o-dichlorohenzene 5.5kg, diethylbenzene 5.0kg, terpineol, 3.0kg, calcium dodecyl benzene sulfonate 2.0kg, OPEO 1.5kg, alkylaryl polyoxyethylene polyoxypropylene ether 2.0kg, cottonseed oil complement to 100kg, mix and make 10.1% cycloxaprid UC-51762 ultra low volume liquids.
Embodiment 32 15% cycloxaprid UC-51762 ultra low volume liquids (14:1)
Cycloxaprid 14.0kg, UC-51762 1.0kg, N, N-dimethylacetylamide 2.7kg, terpineol 4.2kg, calcium dodecyl benzene sulfonate 2.2kg, OPEO 1.5kg, aliphatic alcohol polyoxyvinethene phosphate 1.3kg, two wires oil 15kg, castor oil polyoxyethylene ether 2.3kg, methyl oleate complement to 100kg, mix and make 27% cycloxaprid triaguron ultra low volume liquids.
Embodiment 33 10% cycloxaprid UC-51762 ultra low volume liquids (4:6)
Cycloxaprid 4.0kg, UC-51762 6.0kg, 1-METHYLPYRROLIDONE 5.0kg, methyl-sulfoxide 6.0kg, acetophenone 10.0kg, methyl oleate 8.0kg, calcium dodecyl benzene sulfonate 2.0kg fatty alcohol-polyoxyethylene ether 3.0kg, fatty alcohol-polyoxyethylene ether 2.0kg, soybean oil complement to 100kg, mix and make 10% cycloxaprid UC-51762 ultra low volume liquids.
Embodiment 34 24% cycloxaprid UC-51762 ultra low volume liquids (1:5)
Cycloxaprid 4.0kg, UC-51762 20.0kg, N, N-dimethylacetylamide 10.0kg, 1-METHYLPYRROLIDONE 9.0kg, n-hexyl alcohol 5.0kg, durene 4.0kg, methyl-propyl benzene 10.0kg, alkylphenol polyoxyethylene 3.0kg, phenethyl phenol polyethenoxy ether phosphate 5.5kg, DBSA 1.5kg corn oil complement to 100kg, mix and make 24% cycloxaprid UC-51762 ultra low volume liquids.
Embodiment 35 30% cycloxaprid UC-51762 ultra low volume liquids (1:14)
Cycloxaprid 2.0kg, carbosulfan 28.0kg, 1-METHYLPYRROLIDONE 12.0kg, n-octyl alcohol 5.3kg, trimethylbenzene 4.3kg, calcium dodecyl benzene sulfonate 3.2kg, OPEO 1.7kg, alkylphenol polyoxyethylene phosphate 2.6kg, ethyl oleate complement to 100kg, mix and make 30.0% cycloxaprid UC-51762 ultra low volume liquids.
Control Example 1
Cycloxaprid 30.0kg, 1-METHYLPYRROLIDONE 12.0kg, N, dinethylformamide 10.0kg, n-octyl alcohol 5.5kg, diethylbenzene 5.0kg, terpineol 3.0kg, calcium dodecyl benzene sulfonate 2.0kg, OPEO 1.5kg, castor oil polyoxyethylene ether 2.0kg, rapeseed oil complement to 100kg, mix and make 30% cycloxaprid ultra low volume liquids.
The prepared ultra low volume liquids outward appearance containing cycloxaprid and carbamate insecticide is homogeneous oily liquids; Under 5 ℃ of conditions of the good ， of low-temperature phase capacitive –, refrigeration 7d is crystallization and suspension not; Volatility is low, and filter paper hangs sends out measurement result, and volatility is lower than 30%; To plant safety, without poisoning; The employing method of remaining silent is measured, and flash-point is greater than 70 ℃; Viscosity is less than 30mPas; Conductance is 1 * 10
-6～1 * 10
-10within the scope of s/cm.
The furthermore bright beneficial effect of the present invention of field efficacy measurement result carrying out in conjunction with the application embodiment of the present invention more below.
Application Example of the present invention is the method that adopts Toxicity Determination and field control effectiveness test to combine.First pass through Toxicity Determination, co-toxicity coefficient (CTC) after clear and definite two kinds of medicaments are composite by a certain percentage, CTC < 80 is antagonism, 80 < CTC < 120 are summation action, and CTC > 120 is synergistic effect; On the basis of Toxicity Determination, determine co-toxicity coefficient (CTC) be greater than 80 two kinds of medicaments be mixed and reach after phase additive synergism, then carry out the effect that field control effectiveness test is verified its addition or synergy.
Application Example 1
The indoor joint toxicity measuring test of cycloxaprid and carbosulfan
Cycloxaprid and carbosulfan are pressed to active ingredient part by weight 1:20, 1:10, 1:5, 1:3, 1:1, 5:1, 10:1, 20:1 mixing is made into binary built agent, test method is with reference to the agricultural industry criteria NY/T 1154.1-2006 > > of the < < People's Republic of China (PRC), the agricultural industry criteria NY/T 1154.7-2006 > > of the < < People's Republic of China (PRC), adopt drop method, take brown planthopper nymph in 3 age as examination worm, within after medicine 24 hours, check dead borer population, calculate lethality.Blank drop equivalent clear water.General each processing arranges 5 concentration gradients.With SPSS statistical analysis software, carry out statistical analysis, calculate the LC of each medicament
50, evaluate according to this activity of reagent agent to examination worm, according to the abundant calculating co-toxicity coefficient of Sun Yun (CTC).
The indoor joint toxicity measuring result of table 1 cycloxaprid and carbosulfan (24 hours)
Measurement result is in Table 1, measurement result shows: cycloxaprid and carbosulfan are hybridly prepared into binary built agent by active ingredient part by weight 1:20,1:10,1:5,1:3,1:1,5:1,10:1,20:1, co-toxicity coefficient to brown planthopper nymph in 3 age is respectively 129.0,133.3,138.3,141.1,137.9,129.7,136.6,134.6, shows that cycloxaprid and carbosulfan all have synergistic effect to brown planthopper afterwards in 20:1～1:20 ratio is composite.
Application Example 2
The indoor joint toxicity measuring test of cycloxaprid and Bassa
Cycloxaprid and Bassa are pressed to active ingredient part by weight 12:1, 6:1, 1:1, 1:9, 1:18, mix and be made into binary built agent, test method is with reference to the agricultural industry criteria NY/T 1154.1-2006 > > of the < < People's Republic of China (PRC), the agricultural industry criteria NY/T 1154.7-2006 > > of the < < People's Republic of China (PRC), adopt drop method, take brown planthopper nymph in 3 age as examination worm, within after medicine 24 hours, check dead borer population, calculate lethality.Blank drop equivalent clear water.General each processing arranges 5 concentration gradients.With SPSS statistical analysis software, carry out statistical analysis, calculate the LC of each medicament
50, evaluate according to this activity of reagent agent to examination worm, according to the abundant calculating co-toxicity coefficient of Sun Yun (CTC).
The indoor joint toxicity measuring result of table 2 cycloxaprid and Bassa (24 hours)
Measurement result is in Table 2, measurement result shows: cycloxaprid and Bassa are hybridly prepared into binary built agent by active ingredient part by weight 12:1,6:1,1:1,1:9,1:18, co-toxicity coefficient to brown planthopper nymph in 3 age is respectively 143.0,135.8,145.8,135.5,130.6, shows that cycloxaprid and Bassa all have synergistic effect to brown planthopper afterwards in 12:1～1:18 ratio is composite.
Application Example 3
The indoor joint toxicity measuring test of cycloxaprid and triaguron
Cycloxaprid and triaguron are pressed to active ingredient part by weight 15:1, 8:1, 2:1, 1:1, 1:2, 1:8, 1:16 mixing is made into binary built agent, test method is with reference to the agricultural industry criteria NY/T 1154.1-2006 > > of the < < People's Republic of China (PRC), the agricultural industry criteria NY/T 1154.7-2006 > > of the < < People's Republic of China (PRC), adopt drop method, take sugarcane aphid nymph in 3 age as examination worm, within after medicine 24 hours, check dead borer population, calculate lethality.Blank drop equivalent clear water.General each processing arranges 5 concentration gradients.With SPSS statistical analysis software, carry out statistical analysis, calculate the LC of each medicament
50, evaluate according to this activity of reagent agent to examination worm, according to the abundant calculating co-toxicity coefficient of Sun Yun (CTC).
The indoor joint toxicity measuring result of table 3 cycloxaprid and triaguron (24 hours)
Measurement result is in Table 3, measurement result shows: cycloxaprid and triaguron are hybridly prepared into binary built agent by active ingredient part by weight 15:1,8:1,2:1,1:1,1:2,1:8,1:16, co-toxicity coefficient to sugarcane aphid nymph in 3 age is respectively 123.8,138.0,148.1,148.3,144.8,136.3,138.8,138.2, show that cycloxaprid and triaguron all have synergistic effect to sugarcane aphid afterwards in 15:1～1:16 ratio is composite, wherein particularly remarkable to the synergistic effect of brown planthopper after the two is composite in 4:1～1:1 ratio.
Application Example 4
The indoor joint toxicity measuring test of cycloxaprid and meta-tolyl-N-methylcarbamate (MTMC)
Cycloxaprid and meta-tolyl-N-methylcarbamate (MTMC) are pressed to active ingredient part by weight 15:1, 3:1, 1:1, 1:5, 1:15 mixing is made into binary built agent, test method is with reference to the agricultural industry criteria NY/T 1154.1-2006 > > of the < < People's Republic of China (PRC), the agricultural industry criteria NY/T 1154.7-2006 > > of the < < People's Republic of China (PRC), adopt drop method, take brown planthopper nymph in 3 age as examination worm, within after medicine 24 hours, check dead borer population, calculate lethality.Blank drop equivalent clear water.General each processing arranges 5 concentration gradients.With SPSS statistical analysis software, carry out statistical analysis, calculate the LC of each medicament
50, evaluate according to this activity of reagent agent to examination worm, according to the abundant calculating co-toxicity coefficient of Sun Yun (CTC).
The indoor joint toxicity measuring result of table 4 cycloxaprid and meta-tolyl-N-methylcarbamate (MTMC) (24 hours)
Measurement result is in Table 4, measurement result shows: cycloxaprid and meta-tolyl-N-methylcarbamate (MTMC) are hybridly prepared into binary built agent by active ingredient part by weight 15:1,3:1,1:1,1:5,1:15, co-toxicity coefficient to brown planthopper nymph in 3 age is respectively 129.1,140.7,145.7,142.7,133.6, show that cycloxaprid and meta-tolyl-N-methylcarbamate (MTMC) all have synergistic effect to brown planthopper afterwards in 15:1～1:15 ratio is composite, wherein particularly remarkable to the synergistic effect of brown planthopper after the two is composite in 3:1～1:5 ratio.
Application Example 5
The indoor joint toxicity measuring test of cycloxaprid and Methomyl
Cycloxaprid and Methomyl are pressed to active ingredient part by weight 10:1, 2:3, 1:1, 1:6, 1:12 mixing is made into binary built agent, test method is with reference to the agricultural industry criteria NY/T 1154.1-2006 > > of the < < People's Republic of China (PRC), the agricultural industry criteria NY/T 1154.7-2006 > > of the < < People's Republic of China (PRC), adopt drop method, take tea lesser leafhopper nymph as examination worm, within after medicine 24 hours, check dead borer population, calculate lethality.Blank drop equivalent clear water.General each processing arranges 5 concentration gradients.With SPSS statistical analysis software, carry out statistical analysis, calculate the LC of each medicament
50, evaluate according to this activity of reagent agent to examination worm, according to the abundant calculating co-toxicity coefficient of Sun Yun (CTC).
The indoor joint toxicity measuring result of table 5 cycloxaprid and Methomyl (24 hours)
Measurement result is in Table 5, measurement result shows: cycloxaprid and Methomyl are hybridly prepared into binary built agent by active ingredient part by weight 10:1,2:3,1:1,1:6,1:12, the co-toxicity coefficient of tea lesser leafhopper nymph is respectively to 127.6,137.5,146.3,148.0, show that cycloxaprid and Methomyl all have synergistic effect to tea lesser leafhopper afterwards in 10:1～1:12 ratio is composite, wherein particularly remarkable to the synergistic effect of tea lesser leafhopper after the two is composite in 1:6～1:12 ratio.
Application Example 6
The indoor joint toxicity measuring test of cycloxaprid and UC-51762
Cycloxaprid and UC-51762 are pressed to active ingredient part by weight 1:100, 14:1, 2:3, 1:5, 1:14 mixing is made into binary built agent, test method is with reference to the agricultural industry criteria NY/T 1154.6-2006 > > of the < < People's Republic of China (PRC), the agricultural industry criteria NY/T 1154.7-2006 > > of the < < People's Republic of China (PRC), adopt dip method, take cotton cotton bollworm nymph in 3 age as examination worm, within after medicine 24 hours, check dead borer population, calculate lethality.Blank dipping equivalent clear water.General each processing arranges 5 concentration gradients.With SPSS statistical analysis software, carry out statistical analysis, calculate the LC of each medicament
50, evaluate according to this activity of reagent agent to examination worm, according to the abundant calculating co-toxicity coefficient of Sun Yun (CTC).
The indoor joint toxicity measuring result of table 6 cycloxaprid and UC-51762 (24 hours)
Measurement result is in Table 6, measurement result shows: cycloxaprid and UC-51762 are hybridly prepared into binary built agent by active ingredient part by weight 1:100,14:1,2:3,1:5,1:14, co-toxicity coefficient to cotton bollworm nymph in 3 age is respectively 124.5,139,7,134.9,149.4,143.7, show that cycloxaprid and UC-51762 all have synergistic effect to cotton bollworm afterwards in 1:100～14:1 ratio is composite, wherein particularly remarkable to the synergistic effect of cotton bollworm after the two is composite in 1:5～1:14 ratio.
Application Example 7
Controlling object: rice fulgorid
Test site: Yongxiu County, Nanchang City paddy field
The application method of embodiment 1～embodiment 8 and control Example 1: ultra low volume spraying contrast medicament: 20% cycloxaprid WP and 20% carbosulfan EC, be diluted with water to the conventional spraying of 30L
Table 7: control rice fulgorid field control effectiveness test result
As can be seen from Table 7: ultra low volume liquids of the present invention adopts ultra low volume spraying method control rice fulgorid, and than contrasting, the conventional spraying of medicament quick-acting is strong, control efficiency good, the lasting period is longer.
Application Example 8
Controlling object: rice fulgorid
Test site: Ke Li village, Xixiangtang District, Nanning City paddy field
The application method of embodiment 9～embodiment 13 and control Example 1: ultra low volume spraying
Contrast medicament: 20% cycloxaprid WP and 25% Bassa EC, be diluted with water to the conventional spraying of 30L.
Table 8: control rice fulgorid test of pesticide effectiveness result
As can be seen from Table 8: ultra low volume liquids of the present invention adopts ultra low volume spraying method control rice fulgorid, and than contrasting, the conventional spraying of medicament quick-acting is strong, control efficiency good, the lasting period is longer.
Application Example 9
Controlling object: sugarcane aphid
Test site: Tao Deng township, Laibin City Ling Dou village sugarcane field
The application method of embodiment 14～embodiment 21 and control Example 1: ultra low volume spraying
Contrast medicament: 20% cycloxaprid WP and 25% triaguron EC, be diluted with water to the conventional spraying of 30L.
Table 9: control sugarcane Control of Aphids result
As can be seen from Table 9: ultra low volume liquids of the present invention adopts ultra low volume spraying method control sugarcane aphid, and than contrasting, the conventional spraying of medicament quick-acting is strong, control efficiency good, the lasting period is longer.
Application Example 10
Controlling object: rice fulgorid
Test site: Ke Li village, Xixiangtang District, Nanning City paddy field
The application method of embodiment 22～embodiment 26 and control Example 1: ultra low volume spraying
Contrast medicament: 20% cycloxaprid WP and 20% meta-tolyl-N-methylcarbamate (MTMC) EC, be diluted with water to the conventional spraying of 30L.
Table 10: control rice fulgorid test of pesticide effectiveness result
As can be seen from Table 10: ultra low volume liquids of the present invention adopts ultra low volume spraying method control rice fulgorid, and than contrasting, the conventional spraying of medicament quick-acting is strong, control efficiency good, the lasting period is longer.
Application Example 11
Controlling object: tea lesser leafhopper
Test site: Anxi County in Fujian Province
Embodiment 27～embodiment 30 ultra low volume liquids application methods: ultra low volume spraying
Contrast medicament: 20% cycloxaprid WP and 20% Methomyl EC, be diluted with water to the conventional spraying of 30L.
Table 11: control tea lesser leafhopper test of pesticide effectiveness result
As can be seen from Table 11: ultra low volume liquids of the present invention adopts ultra low volume spraying method control tea lesser leafhopper, and than contrasting, the conventional spraying of medicament quick-acting is strong, control efficiency good, the lasting period is longer.
Application Example 12
Controlling object: cotton cotton bollworm
Test site: Yongxiu County, Nanchang City Cotton Fields
The application method of embodiment 31～embodiment 35 and control Example 1: ultra low volume spraying
Contrast medicament: 20% cycloxaprid WP and 75% UC-51762 EC, be diluted with water to the conventional spraying of 30L.
Table 12: control cotton cotton bollworm test of pesticide effectiveness result
As can be seen from Table 12: ultra low volume liquids of the present invention adopts ultra low volume spraying method control cotton cotton bollworm aphid, and than contrasting, the conventional spraying of medicament quick-acting is strong, control efficiency good, the lasting period is longer.
Claims (8)
1. the ultra low volume liquids containing cycloxaprid and carbamate insecticide, it is characterized in that: the active component of described ultra low volume liquids is cycloxaprid and carbamate insecticide, all the other are surfactant and solvent, and wherein the weight ratio of cycloxaprid and carbamate insecticide is 1:20～20:1; Described carbamate insecticide is any one in carbosulfan, Bassa, triaguron, meta-tolyl-N-methylcarbamate (MTMC), Methomyl, UC-51762.
2. the ultra low volume liquids containing cycloxaprid and carbamate insecticide according to claim 1, is characterized in that: the weight ratio of cycloxaprid and carbamate insecticide is 1:10～10:1.
3. the ultra low volume liquids containing cycloxaprid and carbamate insecticide according to claim 2, is characterized in that: the weight ratio of cycloxaprid and carbamate insecticide is 1:5～5:1.
4. the ultra low volume liquids containing cycloxaprid and carbamate insecticide according to claim 1, it is characterized in that: the weight content sum of cycloxaprid and carbamate insecticide is 0.2%～50%, wherein the weight content of cycloxaprid is 0.1%～20%, and the weight content of carbamate insecticide is 0.1%～30%; Surfactant weight content is 1%～10%.
5. the ultra low volume liquids containing cycloxaprid and carbamate insecticide according to claim 4, is characterized in that: the weight content sum of cycloxaprid and carbamate insecticide is 6%～25%; Wherein the weight content of cycloxaprid is 1%～10%, and the weight content of carbamate insecticide is 5%～15%.
6. the ultra low volume liquids containing cycloxaprid and carbamate insecticide according to claim 1, is characterized in that: described surfactant is one or more the combination in fatty alcohol-polyoxyethylene ether, alkylphenol polyoxyethylene, phenethyl phenol polyethenoxy ether, alkylaryl polyoxyethylene polyoxypropylene ether, aliphatic alcohol polyoxyvinethene phosphate, alkylphenol polyoxyethylene phosphate, phenethyl phenol polyethenoxy ether phosphate, alkylaryl polyoxyethylene polyoxypropylene ether phosphate, castor oil polyoxyethylene ether, calcium dodecyl benzene sulfonate.
7. the ultra low volume liquids containing cycloxaprid and carbamate insecticide according to claim 1, is characterized in that: described solvent is one or more combinations in aromatic hydrocarbon solvent, plant oil solvent and polar solvent; Aromatic hydrocarbon solvent comprises trimethylbenzene, o-dichlorohenzene, durene, diethylbenzene, methyl-propyl benzene, butylbenzene, methyl naphthalene, two wires oil; Plant oil solvent comprises soybean oil, cottonseed oil, corn oil, rapeseed oil, castor oil, turpentine oil, methyl oleate, ethyl oleate; Polar solvent comprises acetophenone, phenmethylol, methyl-sulfoxide, 1-METHYLPYRROLIDONE, DMF, DMA, n-hexyl alcohol, n-octyl alcohol, terpineol.
8. prepare claim 1 to the method for the ultra low volume liquids containing cycloxaprid and carbamate insecticide described in any one in claim 7 for one kind, it is characterized in that: the preparation method of described ultra low volume liquids is, in the reaction vessel stirring at band, first with solvent by after active component stirring and dissolving, add again auxiliary component, fully be uniformly mixed, obtain the ultra low volume liquids containing cycloxaprid and carbamate insecticide; Technological parameter is: it is 60～150 revs/min that mixing speed is controlled, and mixing time is 15～60 minutes, and temperature is normal temperature, and pressure is normal pressure.
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| CN102228041A (en) * | 2011-07-27 | 2011-11-02 | 陕西上格之路生物科学有限公司 | Pesticide composition containing cycloxaprid and carbamate pesticide |
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