CN103642554A - Combustion improver for boiler and preparation method and application thereof - Google Patents
Combustion improver for boiler and preparation method and application thereof Download PDFInfo
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- CN103642554A CN103642554A CN201310739658.XA CN201310739658A CN103642554A CN 103642554 A CN103642554 A CN 103642554A CN 201310739658 A CN201310739658 A CN 201310739658A CN 103642554 A CN103642554 A CN 103642554A
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- parts
- oxide
- boiler
- ignition dope
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- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- 238000002485 combustion reaction Methods 0.000 title abstract description 14
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 16
- 239000003245 coal Substances 0.000 claims abstract description 15
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 14
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 14
- DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 claims abstract description 14
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims abstract description 13
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000000292 calcium oxide Substances 0.000 claims abstract description 8
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 claims abstract description 8
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 8
- IATRAKWUXMZMIY-UHFFFAOYSA-N strontium oxide Chemical compound [O-2].[Sr+2] IATRAKWUXMZMIY-UHFFFAOYSA-N 0.000 claims abstract description 8
- RSJKGSCJYJTIGS-UHFFFAOYSA-N undecane Chemical compound CCCCCCCCCCC RSJKGSCJYJTIGS-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002283 diesel fuel Substances 0.000 claims abstract description 7
- 239000003502 gasoline Substances 0.000 claims abstract description 7
- 239000003350 kerosene Substances 0.000 claims abstract description 7
- 239000000395 magnesium oxide Substances 0.000 claims abstract description 7
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 claims abstract description 7
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 claims abstract description 7
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000012188 paraffin wax Substances 0.000 claims abstract description 7
- 239000011787 zinc oxide Substances 0.000 claims abstract description 7
- 239000002994 raw material Substances 0.000 claims abstract description 5
- -1 4 parts Chemical compound 0.000 claims description 33
- 239000000203 mixture Substances 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 9
- 238000010304 firing Methods 0.000 claims description 7
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 claims description 7
- 229960004643 cupric oxide Drugs 0.000 claims description 6
- 238000010438 heat treatment Methods 0.000 claims description 6
- PQIOSYKVBBWRRI-UHFFFAOYSA-N methylphosphonyl difluoride Chemical group CP(F)(F)=O PQIOSYKVBBWRRI-UHFFFAOYSA-N 0.000 claims description 6
- 230000003647 oxidation Effects 0.000 claims description 6
- 238000007254 oxidation reaction Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims 1
- CBFCDTFDPHXCNY-UHFFFAOYSA-N icosane Chemical compound CCCCCCCCCCCCCCCCCCCC CBFCDTFDPHXCNY-UHFFFAOYSA-N 0.000 abstract 2
- BKIMMITUMNQMOS-UHFFFAOYSA-N nonane Chemical compound CCCCCCCCC BKIMMITUMNQMOS-UHFFFAOYSA-N 0.000 abstract 2
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 abstract 2
- JPJALAQPGMAKDF-UHFFFAOYSA-N selenium dioxide Chemical compound O=[Se]=O JPJALAQPGMAKDF-UHFFFAOYSA-N 0.000 abstract 2
- KUPLEGDPSCCPJI-UHFFFAOYSA-N tetracontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC KUPLEGDPSCCPJI-UHFFFAOYSA-N 0.000 abstract 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N triacontane Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 abstract 2
- 239000005751 Copper oxide Substances 0.000 abstract 1
- 229910000431 copper oxide Inorganic materials 0.000 abstract 1
- YDLYQMBWCWFRAI-UHFFFAOYSA-N n-Hexatriacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCC YDLYQMBWCWFRAI-UHFFFAOYSA-N 0.000 abstract 1
- UJMWVICAENGCRF-UHFFFAOYSA-N oxygen difluoride Chemical compound FOF UJMWVICAENGCRF-UHFFFAOYSA-N 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- OLTHARGIAFTREU-UHFFFAOYSA-N triacontane Natural products CCCCCCCCCCCCCCCCCCCCC(C)CCCCCCCC OLTHARGIAFTREU-UHFFFAOYSA-N 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 5
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- 239000000428 dust Substances 0.000 description 3
- 239000000446 fuel Substances 0.000 description 3
- 229910044991 metal oxide Inorganic materials 0.000 description 3
- 150000004706 metal oxides Chemical class 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000006213 oxygenation reaction Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Solid Fuels And Fuel-Associated Substances (AREA)
- Incineration Of Waste (AREA)
- Liquid Carbonaceous Fuels (AREA)
Abstract
The invention provides a combustion improver for a boiler. The combustion improver is prepared from the following raw materials in parts by weight: 4 parts of sodium carbonate, 4 parts of coal powder, 4 parts of iron oxide, 4 parts of zinc oxide, 4 parts of copper oxide, 4 parts of calcium oxide, 4 parts of magnesium oxide, 4 parts of aluminum oxide, 16 parts of selenium dioxide, 16 parts of strontium oxide, 16 parts of difluorine monoxide, 16 parts of No. 97 gasoline, 16 parts of No. -20 diesel oil, 16 parts of ethanol, 16 parts of kerosene, 10 parts of paraffin, 10 parts of n-octane, 10 parts of nonane, 10 parts of decane, 10 parts of undecane, 10 parts of dodecane, 10 parts of eicosane, 10 parts of triacontane and 10 parts of tetracontane. The combustion improver provided by the invention can reduce pollution, improve combustion efficiency and prolong the service life of the boiler. The invention further provides a preparation method and application of the combustion improver.
Description
Technical field
The present invention relates to a kind of ignition dope, be specifically related to the ignition dope that a kind of boiler is used, and its preparation method and application.
Background technology
Along with the problem of whole society's environmental pollution and energy consumption is more and more paid attention to, country and every profession and trade are more and more stricter to the restriction of the sulphur emissions of coal firing boiler, enterprise is also constantly seeking the approach that reduces the consumption of coal equal energy source, further to reduce production costs simultaneously.The solution that is developed as these problems of ignition dope provides feasible approach.But existing ignition dope is for improving efficiency of combustion and reducing disposal of pollutants two aspects and can not take into account, combustion-supporting effect can not be satisfied the demand, therefore be necessary to develop a kind of new coal firing boiler ignition dope, further to improve efficiency of combustion and to play good solid sulphur depositing dust effect simultaneously.
Summary of the invention
The object of the invention is to: a kind of boiler ignition dope is provided, can reduces pollution, improve efficiency of combustion, prolonged boiler work-ing life.
Another object of the present invention is to: the preparation method of the ignition dope described in providing.
Above-mentioned purpose of the present invention is achieved through the following technical solutions:
A kind of boiler ignition dope is provided, by the raw material of following weight part, is prepared from:
4 parts, sodium carbonate, 4 parts of coal dusts, 4 parts of ferric oxide, 4 parts, zinc oxide, 4 parts of cupric oxide, 4 parts, calcium oxide, 4 parts, magnesium oxide, 4 parts, aluminum oxide, 16 parts of tin anhydride, 16 parts of strontium oxides, 16 parts of 16 parts ,-No. 20 diesel oil of oxidation 16 parts, No. 97 gasoline of difluoro, 16 parts of ethanol, 16 parts of kerosene, 10 parts, paraffin, 10 parts of octanes, 10 parts of nonanes, 10 parts of decane, 10 parts of undecanes, 10 parts of dodecanes, 10 parts of eicosanes, 10 parts of triacontanes, 10 parts of tetracontanes.
The preparation method of the ignition dope described in the present invention also provides, comprises the following steps:
1) by weight, at 25 ℃, limit heating edge adds 4 parts of sodium carbonate and 4 parts of coal dusts in 10000 parts of water, and then slowly add successively 4 parts of ferric oxide, 4 parts, zinc oxide, 4 parts of cupric oxide, 4 parts, calcium oxide, 4 parts, magnesium oxide, 4 parts, aluminum oxide, after adding, maintain the temperature at 50 ℃, stir 12 hours, obtain mixture I, be down to 30 ℃ standby;
2) by weight, at 30 ℃, limit heating edge slowly adds successively 16 parts of tin anhydride, 16 parts of strontium oxides, 16 parts of 16 parts ,-No. 20 diesel oil of oxidation 16 parts, No. 97 gasoline of difluoro, 16 parts of ethanol, 16 parts of kerosene in 10000 parts of water, after adding, maintain the temperature at 90 ℃, stir 12 hours, obtain mixtures II, be down to 30 ℃ standby;
3) by weight, at 30 ℃ in 980000 parts of water disposable mixture I, the step 2 that adds step 1) to obtain) mixtures II that obtains, and 10 parts of 10 parts, paraffin, 10 parts of octanes, 10 parts of nonanes, 10 parts of decane, 10 parts of undecanes, 10 parts of dodecanes, 10 parts of eicosanes, 10 parts of triacontanes and tetracontanes, after adding, maintain the temperature at 80 ℃, stir 12 hours, obtain ignition dope of the present invention.
The application of ignition dope described in the present invention also provides in coal firing boiler, oil-firing boiler or gas fired-boiler.
In ignition dope of the present invention, metal oxide can play oxygenation effect as oxygenate, thereby increases speed of response; Some metal oxides react the salts substances generating and as catalyzer, have improved the reactive behavior of fuel with sodium carbonate solution, fuel combustion is obtained more abundant, more complete; Some metal oxide can also play the effect of sulphur-fixing agent and dustfall agent, and such as ferric oxide, calcium oxide etc. can be reduced the discharge of coal smoke and sulfurous gas effectively, thereby reduces atmospheric pollution.In a word, ignition dope of the present invention has obtained comparatively comprehensively effect after preparing in specific proportions with plurality of raw materials, not only have excellent combustion-supporting property during use, can significantly improve the efficiency of combustion of fuel, has also possessed to fall pollutions, reduction of discharging and the beneficial effect such as put simultaneously.
In the middle of actual use, aspect combustion-supporting property, when ignition dope of the present invention enters after boiler combustion layer, flame can raise to some extent, and color shoals, and has increased intensity of combustion and density.Along with the increase of time, furnace temperature raises, and quantity of steam, boiler output all will increase; Burning coal layer expands and raises, and slag is loose, and remaining carbon reduces, and boiler wall dirt progressively comes off, and thermo-efficiency improves.Pressing down aspect sulphur and depositing dust; after using ignition dope of the present invention, find; total sulphur content in Boiler Cinder Surveying has turned over one times; further reduced the desulphurization cost of enterprise, smoke dust discharge concentration and blackness are cut down, and lime-ash carbon content rate reduces; improved thus atmospheric environment; flame is stable simultaneously, and body of heater is protected, and has extended boiler life.
Embodiment
Embodiment 1
A coal firing boiler ignition dope, is prepared from by the raw material of following weight part:
4 parts, sodium carbonate, 4 parts of coal dusts, 4 parts of ferric oxide, 4 parts, zinc oxide, 4 parts of cupric oxide, 4 parts, calcium oxide, 4 parts, magnesium oxide, 4 parts, aluminum oxide, 16 parts of tin anhydride, 16 parts of strontium oxides, 16 parts of 16 parts ,-No. 20 diesel oil of oxidation 16 parts, No. 97 gasoline of difluoro, 16 parts of ethanol, 16 parts of kerosene, 10 parts, paraffin, 10 parts of octanes, 10 parts of nonanes, 10 parts of decane, 10 parts of undecanes, 10 parts of dodecanes, 10 parts of eicosanes, 10 parts of triacontanes, 10 parts of tetracontanes.
Preparation method comprises the following steps:
1) by weight, at 25 ℃, limit heating edge adds 4 parts of sodium carbonate and 4 parts of coal dusts in 10000 parts of water, and then slowly add successively 4 parts of ferric oxide, 4 parts, zinc oxide, 4 parts of cupric oxide, 4 parts, calcium oxide, 4 parts, magnesium oxide, 4 parts, aluminum oxide, after adding, maintain the temperature at 50 ℃, stir 12 hours, obtain mixture I, be down to 30 ℃ standby;
2) by weight, at 30 ℃, limit heating edge slowly adds successively 16 parts of tin anhydride, 16 parts of strontium oxides, 16 parts of 16 parts ,-No. 20 diesel oil of oxidation 16 parts, No. 97 gasoline of difluoro, 16 parts of ethanol, 16 parts of kerosene in 10000 parts of water, after adding, maintain the temperature at 90 ℃, stir 12 hours, obtain mixtures II, be down to 30 ℃ standby;
3) by weight, at 30 ℃ in 980000 parts of water disposable mixture I, the step 2 that adds step 1) to obtain) mixtures II that obtains, and 10 parts of 10 parts, paraffin, 10 parts of octanes, 10 parts of nonanes, 10 parts of decane, 10 parts of undecanes, 10 parts of dodecanes, 10 parts of eicosanes, 10 parts of triacontanes and tetracontanes, after adding, maintain the temperature at 80 ℃, stir 12 hours, obtain ignition dope of the present invention.
Ignition dope of the present invention with time can to enter boiler by the mode spraying into boiler combustion layer combustion-supporting.The dosage spraying into can be determined according to the actual needs of producing.
Ignition dope of the present invention, the performance recording according to the detection method identical with GB13271-2001 is in Table 1-3.
Claims (3)
1. a boiler ignition dope, is characterized in that, by the raw material of following weight part, is prepared from:
4 parts, sodium carbonate, 4 parts of coal dusts, 4 parts of ferric oxide, 4 parts, zinc oxide, 4 parts of cupric oxide, 4 parts, calcium oxide, 4 parts, magnesium oxide, 4 parts, aluminum oxide, 16 parts of tin anhydride, 16 parts of strontium oxides, 16 parts of 16 parts ,-No. 20 diesel oil of oxidation 16 parts, No. 97 gasoline of difluoro, 16 parts of ethanol, 16 parts of kerosene, 10 parts, paraffin, 10 parts of octanes, 10 parts of nonanes, 10 parts of decane, 10 parts of undecanes, 10 parts of dodecanes, 10 parts of eicosanes, 10 parts of triacontanes, 10 parts of tetracontanes.
2. the method for preparation ignition dope claimed in claim 1, is characterized in that, comprises the following steps:
1) by weight, at 25 ℃, limit heating edge adds 4 parts of sodium carbonate and 4 parts of coal dusts in 10000 parts of water, and then slowly add successively 4 parts of ferric oxide, 4 parts, zinc oxide, 4 parts of cupric oxide, 4 parts, calcium oxide, 4 parts, magnesium oxide, 4 parts, aluminum oxide, after adding, maintain the temperature at 50 ℃, stir 12 hours, obtain mixture I, be down to 30 ℃ standby;
2) by weight, at 30 ℃, limit heating edge slowly adds successively 16 parts of tin anhydride, 16 parts of strontium oxides, 16 parts of 16 parts ,-No. 20 diesel oil of oxidation 16 parts, No. 97 gasoline of difluoro, 16 parts of ethanol, 16 parts of kerosene in 10000 parts of water, after adding, maintain the temperature at 90 ℃, stir 12 hours, obtain mixtures II, be down to 30 ℃ standby;
3) by weight, at 30 ℃ in 980000 parts of water disposable mixture I, the step 2 that adds step 1) to obtain) mixtures II that obtains, and 10 parts of 10 parts, paraffin, 10 parts of octanes, 10 parts of nonanes, 10 parts of decane, 10 parts of undecanes, 10 parts of dodecanes, 10 parts of eicosanes, 10 parts of triacontanes and tetracontanes, after adding, maintain the temperature at 80 ℃, stir 12 hours, obtain ignition dope of the present invention.
3. the application of ignition dope claimed in claim 1 in coal firing boiler, oil-firing boiler or gas fired-boiler.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310739658.XA CN103642554B (en) | 2013-12-27 | 2013-12-27 | Combustion improver for boiler and preparation method and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310739658.XA CN103642554B (en) | 2013-12-27 | 2013-12-27 | Combustion improver for boiler and preparation method and application thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103642554A true CN103642554A (en) | 2014-03-19 |
| CN103642554B CN103642554B (en) | 2015-03-25 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310739658.XA Expired - Fee Related CN103642554B (en) | 2013-12-27 | 2013-12-27 | Combustion improver for boiler and preparation method and application thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103642554B (en) |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1718699A (en) * | 2005-04-06 | 2006-01-11 | 尹小林 | Catalytic combustion adjuvant for coal |
| CN1842585A (en) * | 2003-06-25 | 2006-10-04 | 卢布里佐尔公司 | Gel additives for fuel that reduce soot and/or emissions from engines |
| CN101381647A (en) * | 2008-10-21 | 2009-03-11 | 梁宴邱 | High-efficiency coal-saving burning additive |
-
2013
- 2013-12-27 CN CN201310739658.XA patent/CN103642554B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1842585A (en) * | 2003-06-25 | 2006-10-04 | 卢布里佐尔公司 | Gel additives for fuel that reduce soot and/or emissions from engines |
| CN1718699A (en) * | 2005-04-06 | 2006-01-11 | 尹小林 | Catalytic combustion adjuvant for coal |
| CN101381647A (en) * | 2008-10-21 | 2009-03-11 | 梁宴邱 | High-efficiency coal-saving burning additive |
Non-Patent Citations (1)
| Title |
|---|
| 朱礼赞等: "燃煤助燃剂技术的研究进展", 《新世纪水泥导报》, vol. 18, no. 5, 20 September 2012 (2012-09-20), pages 2 * |
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| Publication number | Publication date |
|---|---|
| CN103642554B (en) | 2015-03-25 |
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Owner name: SHANGHAI YUEHE TECHNOLOGY CO., LTD. Free format text: FORMER OWNER: CAI QIANG Effective date: 20150709 Free format text: FORMER OWNER: DENG HONGQUAN GAO XUETAI Effective date: 20150709 |
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