CN103630950A - Novel waterproof antireflection film material - Google Patents

Novel waterproof antireflection film material Download PDF

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Publication number
CN103630950A
CN103630950A CN201310531210.9A CN201310531210A CN103630950A CN 103630950 A CN103630950 A CN 103630950A CN 201310531210 A CN201310531210 A CN 201310531210A CN 103630950 A CN103630950 A CN 103630950A
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CN
China
Prior art keywords
waterproof
antireflecting film
sealant
teleblem
thickness
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201310531210.9A
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Chinese (zh)
Inventor
白永平
邵志敏
丁丽萍
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Wuxi Haite New Material Research Institute Co Ltd
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Wuxi Haite New Material Research Institute Co Ltd
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Application filed by Wuxi Haite New Material Research Institute Co Ltd filed Critical Wuxi Haite New Material Research Institute Co Ltd
Priority to CN201310531210.9A priority Critical patent/CN103630950A/en
Publication of CN103630950A publication Critical patent/CN103630950A/en
Pending legal-status Critical Current

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Abstract

The invention discloses a novel waterproof antireflection film material, which comprises a waterproof top film (1), a sealing layer (2), a waterproof bottom film (3), a first antireflection film (4) and a second antireflection film (5). Through the adoption of the manner, the novel waterproof antireflection film material has the advantages that water-resistant and antifouling effects are realized, the intensity is high, wear resistance, light weight, thinness and convenience are realized, the structure is simple, stray light and reflected light are eliminated, the service life is long, and the like. The novel waterproof antireflection film material has wide market prospects in the popularization aspect.

Description

New waterproof antireflecting film material
Technical field
The present invention relates to membrane material field, particularly relate to a kind of new waterproof antireflecting film material.
Background technology
Film is the material with Selective Separation function, utilize the Selective Separation of film can realize solid, liquid, gas, the separation of light etc., this detachment process is physical process, do not comprise the variation of phase or add auxiliary agent, at present, membrane technology also demonstrates its vital role and the bright outlook in daily life day by day, wherein particularly remarkable with the effect of blooming, blooming is often applicable to building, automobile, photography, the fields such as electronic devices and components, existing blooming comprises high transmittance film, high-reflecting film, antireflecting film, photomask etc., wherein antireflecting film (claiming again anti-reflection film) often adopts direct method of coating preparation, the outside surface of film fully contacts with empty G&W, the antifouling ability of water resistant, the normal use and the life-span that have had a strong impact on antireflecting film are lasting.
Summary of the invention
The technical matters that the present invention mainly solves is to provide a kind of new waterproof antireflecting film material; by adopting two-layer antireflecting film to increase, reduce catoptrical effect; and be coated with waterproof membrane at the outside surface of antireflecting film; reached the antifouling defencive function of water resistant; make its use lasting, loss is little, lightweight robust thin, not easy to wear, simple in structure, be conducive to large-scale promotion, on new waterproof antireflecting film material universal, have market outlook widely.
For solving the problems of the technologies described above, the invention provides a kind of new waterproof antireflecting film material, comprising:
(1) waterproof teleblem,
(2) sealant,
(3) waterproof counterdie,
(4) first antireflecting films,
(5) second antireflecting films,
It is characterized in that,
The material of described waterproof teleblem is one or more of tygon, polypropylene, polyester vinyl and polyester propylene, preferably includes density and is greater than 0.935 g/cm 3high density polyethylene, the molecular structure of described waterproof teleblem is pore type, hole is less than 0.02mm, thickness is 0.05 ~ 0.1mm, and the outside surface of described waterproof teleblem is also evenly coated with coating, and the material of described coating is fluoride, antifouling for water resistant, the thickness of described coating is less than 50nm;
Described sealant connects the inside surface of described waterproof teleblem, the material of sealant is that weight proportion is petchem and the polyolefin of 2:1, the structure of sealant is grating structure or reticulate texture, and for the further infiltration of block water molecule, the thickness of described sealant is 300 ~ 500nm;
Described waterproof counterdie connects the inside surface of described sealant, the material of waterproof counterdie comprises tygon, polyester vinyl and acrylate, the weight proportion of preferred acrylate is greater than 50%, the structure of described waterproof counterdie is pore type, hole is less than the hole of described waterproof teleblem, and thickness is less than the thickness of described waterproof teleblem and is greater than the thickness of described sealant;
Described the first antireflecting film connects the inside surface of described waterproof counterdie, the material of described the first antireflecting film comprises a kind of of silicon nitride, monox, silicon sulfide, magnesium fluoride, titanium dioxide, vulcanized lead, lead selenide, ceramic infrared light infrared anti-reflection film or vinyl silsesquioxane hybridized film, thickness is 1/4th of visible light wavelength, for reducing the light wave of this thickness institute corresponding wavelength, the wavelength coverage of wherein said visible ray is 400 ~ 700nm, and the thickness range of described the first antireflecting film is 100 ~ 175nm;
Described the second antireflecting film connects the inside surface of described the first antireflecting film, and the material of the second antireflecting film is identical with the material of the first antireflecting film, and thickness range is 100 ~ 175nm.
In a preferred embodiment of the present invention, the method for coating of described fluoride comprises infusion method and Vacuum Coating method.
In a preferred embodiment of the present invention, between described waterproof teleblem and described sealant, described sealant and described waterproof counterdie, all adopt thermoplastic adhesives to be connected.
In a preferred embodiment of the present invention, the method for coating of described the first antireflecting film and described the second antireflecting film all adopts Vacuum Coating method.
In a preferred embodiment of the present invention, described waterproof teleblem, sealant, waterproof counterdie, the first antireflecting film and the second antireflecting film all have thermoplasticity.
In a preferred embodiment of the present invention, the gross thickness of described waterproof teleblem, sealant, waterproof counterdie, the first antireflecting film and the second antireflecting film is less than 0.2mm.
The invention has the beneficial effects as follows: new waterproof antireflecting film material of the present invention has that water resistant is antifouling, intensity is high, wear-resistant, frivolous convenience, simple in structure, eliminate the advantages such as veiling glare and reflected light, long service life, on new waterproof antireflecting film material universal, have market outlook widely.
accompanying drawing explanation
Fig. 1 is the structural representation of a preferred embodiment of a kind of new waterproof antireflecting film of the present invention material.
embodiment
Below the technical scheme in the embodiment of the present invention is clearly and completely described, obviously, described embodiment is only a part of embodiment of the present invention, rather than whole embodiment.Embodiment based in the present invention, those of ordinary skills, not making all other embodiment that obtain under creative work prerequisite, belong to the scope of protection of the invention.
The embodiment of the present invention comprises:
A new waterproof antireflecting film material, comprising: 1, waterproof teleblem, 2, sealant, 3, waterproof counterdie, the 4, first antireflecting film, the 5, second antireflecting film.
A new waterproof antireflecting film material, comprising:
(1) waterproof teleblem 1,
(2) sealant 2,
(3) waterproof counterdie 3,
(4) first antireflecting films 4,
(5) second antireflecting films 5,
It is characterized in that,
The material of described waterproof teleblem 1 is one or more of tygon, polypropylene, polyester vinyl and polyester propylene, preferably includes density and is greater than 0.935 g/cm 3high density polyethylene, the molecular structure of described waterproof teleblem 1 is pore type, hole is less than 0.02mm, thickness is 0.05 ~ 0.1mm, and the outside surface of described waterproof teleblem 1 is also evenly coated with coating, and the material of described coating is fluoride, antifouling for water resistant, the thickness of described coating is less than 50nm;
Described sealant 2 connects the inside surface of described waterproof teleblem 1, the material of sealant 2 is that weight proportion is petchem and the polyolefin of 2:1, the structure of sealant 2 is grating structure or reticulate texture, and for the further infiltration of block water molecule, the thickness of described sealant 2 is 300 ~ 500nm;
Described waterproof counterdie 3 connects the inside surface of described sealant 2, the material of waterproof counterdie 3 comprises tygon, polyester vinyl and acrylate, the weight proportion of preferred acrylate is greater than 50%, the structure of described waterproof counterdie 3 is pore type, hole is less than the hole of described waterproof teleblem 1, and thickness is less than the thickness of described waterproof teleblem 1 and is greater than the thickness of described sealant 2;
Described the first antireflecting film 4 connects the inside surface of described waterproof counterdie 3, the material of described the first antireflecting film 4 comprises a kind of of silicon nitride, monox, silicon sulfide, magnesium fluoride, titanium dioxide, vulcanized lead, lead selenide, ceramic infrared light infrared anti-reflection film or vinyl silsesquioxane hybridized film, thickness is 1/4th of visible light wavelength, for reducing the light wave of this thickness institute corresponding wavelength, the wavelength coverage of wherein said visible ray is 400 ~ 700nm, and the thickness range of described the first antireflecting film 4 is 100 ~ 175nm;
Described the second antireflecting film 5 connects the inside surface of described the first antireflecting film 4, and the material of the second antireflecting film 5 is identical with the material of the first antireflecting film 4, and thickness range is 100 ~ 175nm.
Preferably, the method for coating of described fluoride comprises infusion method and Vacuum Coating method, and wherein most of inorganic fluoride is water-soluble, does not have a water resisting property, and most of organic fluoride has a water resisting property, and often adopts organic fluoride as the antifouling coating of water resistant here; The method of infusion method plated film is seldom used, and the existing Vacuum Coating methods that use, are evenly plated in fluoride on described waterproof teleblem 1 more, by film and airborne water and greasy dirt isolation, plays the most direct protective effect.
Preferably, between described waterproof teleblem 1 and described sealant 2, described sealant 2 and described waterproof counterdie 3, all adopt thermoplastic adhesives to be connected, wherein thermoplastic adhesives are solid binder at normal temperatures, after the heating of being heated, be molten into liquid, after again cooling, it is still solid, thermoplastic adhesives are generally used thermoplastic resin preparation, as polyurethane, polystyrene, polyacrylate, ethene acetate copolymer etc., have very strong cementability.
Preferably, described the first antireflecting film 4 all adopts Vacuum Coating method with the method for coating of described the second antireflecting film 5, and the thickness of antireflecting film is little, uniformity requirement is large, so adopt Vacuum Coating method can improve preparation efficiency and quality.
Preferably, described waterproof teleblem 1, sealant 2, waterproof counterdie 3, the first antireflecting film 4 and the second antireflecting film 5 all have thermoplasticity, make so described new waterproof antireflecting film material have thermoplasticity, can repeatedly heat use in use, plasticity is strong, easy to use.
Preferably, the gross thickness of described waterproof teleblem 1, sealant 2, waterproof counterdie 3, the first antireflecting film 4 and the second antireflecting film 5 is less than 0.2mm, and quality is frivolous, sturdy and durable.
The beneficial effect of new waterproof antireflecting film material of the present invention is:
One, by using waterproof teleblem, sealant and waterproof counterdie jointly as water barrier, water proof anti-soil, has protected antireflecting film effectively layer by layer, and simple in structure, easy preparation, good water-proof effect, be conducive to large-scale production and popularization;
Two, by using two-layer antireflecting film acting in conjunction, increased the effect of antireflection light, strengthened the performance of eliminating veiling glare, quality is frivolous, long service life;
Three, with respect to general waterproof membrane, the waterproof membrane here is also coated with fluoride coating, further, by greasy dirt and water droplet isolation, plays the most direct protective effect.
The foregoing is only embodiments of the invention; not thereby limit the scope of the claims of the present invention; every equivalent structure or conversion of equivalent flow process that utilizes description of the present invention to do; or be directly or indirectly used in other relevant technical field, be all in like manner included in scope of patent protection of the present invention.

Claims (6)

1. a new waterproof antireflecting film material, comprising:
(1) waterproof teleblem,
(2) sealant,
(3) waterproof counterdie,
(4) first antireflecting films,
(5) second antireflecting films,
It is characterized in that,
The material of described waterproof teleblem is one or more of tygon, polypropylene, polyester vinyl and polyester propylene, preferably includes density and is greater than 0.935 g/cm 3high density polyethylene, the molecular structure of described waterproof teleblem is pore type, hole is less than 0.02mm, thickness is 0.05 ~ 0.1mm, and the outside surface of described waterproof teleblem is also evenly coated with coating, and the material of described coating is fluoride, antifouling for water resistant, the thickness of described coating is less than 50nm;
Described sealant connects the inside surface of described waterproof teleblem, the material of sealant is that weight proportion is petchem and the polyolefin of 2:1, the structure of sealant is grating structure or reticulate texture, and for the further infiltration of block water molecule, the thickness of described sealant is 300 ~ 500nm;
Described waterproof counterdie connects the inside surface of described sealant, the material of waterproof counterdie comprises tygon, polyester vinyl and acrylate, the weight proportion of preferred described acrylate is greater than 50%, the structure of described waterproof counterdie is pore type, hole is less than the hole of described waterproof teleblem, and thickness is less than the thickness of described waterproof teleblem and is greater than the thickness of described sealant;
Described the first antireflecting film connects the inside surface of described waterproof counterdie, the material of described the first antireflecting film comprises a kind of of silicon nitride, monox, silicon sulfide, magnesium fluoride, titanium dioxide, vulcanized lead, lead selenide, ceramic infrared light infrared anti-reflection film or vinyl silsesquioxane hybridized film, thickness is 1/4th of visible light wavelength, for reducing the light wave of this thickness institute corresponding wavelength, the wavelength coverage of wherein said visible ray is 400 ~ 700nm, and the thickness range of described the first antireflecting film is 100 ~ 175nm;
Described the second antireflecting film connects the inside surface of described the first antireflecting film, and the material of the second antireflecting film is identical with the material of the first antireflecting film, and thickness range is 100 ~ 175nm.
2. new waterproof antireflecting film material according to claim 1, is characterized in that, the method for coating of described fluoride comprises infusion method and Vacuum Coating method.
3. new waterproof antireflecting film material according to claim 1, is characterized in that, between described waterproof teleblem and described sealant, described sealant and described waterproof counterdie, all adopts thermoplastic adhesives to be connected.
4. new waterproof antireflecting film material according to claim 1, is characterized in that, the method for coating of described the first antireflecting film and described the second antireflecting film all adopts Vacuum Coating method.
5. new waterproof antireflecting film material according to claim 1, is characterized in that, described waterproof teleblem, sealant, waterproof counterdie, the first antireflecting film and the second antireflecting film all have thermoplasticity.
6. new waterproof antireflecting film material according to claim 1, is characterized in that, the gross thickness of described waterproof teleblem, sealant, waterproof counterdie, the first antireflecting film and the second antireflecting film is less than 0.2mm.
CN201310531210.9A 2013-11-01 2013-11-01 Novel waterproof antireflection film material Pending CN103630950A (en)

Priority Applications (1)

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Publications (1)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104316983A (en) * 2014-11-04 2015-01-28 苏州精创光学仪器有限公司 Waterproof compound antireflection film
CN109664583A (en) * 2018-11-29 2019-04-23 信利光电股份有限公司 A kind of vehicle window film of insulating water-proof
TWI700179B (en) * 2017-06-05 2020-08-01 香港商富智康(香港)有限公司 Housing and method for making same

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09258004A (en) * 1996-03-25 1997-10-03 Ulvac Japan Ltd Antireflection multilayered film and its film formation, as well as its film forming device
JP2005275214A (en) * 2004-03-26 2005-10-06 Fuji Photo Film Co Ltd Antireflection coating, antireflection film, method for manufacturing them, polarizing plate, and image display device
CN1794015A (en) * 2005-11-17 2006-06-28 复旦大学 Water-proof broad band high anti-reflection film and its preparation method
JP2007003672A (en) * 2005-06-22 2007-01-11 Toppan Printing Co Ltd Antireflection film
CN201359642Y (en) * 2008-09-16 2009-12-09 镇江万新光学眼镜有限公司 Resin lens plated with metal conducting layer on surface

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH09258004A (en) * 1996-03-25 1997-10-03 Ulvac Japan Ltd Antireflection multilayered film and its film formation, as well as its film forming device
JP2005275214A (en) * 2004-03-26 2005-10-06 Fuji Photo Film Co Ltd Antireflection coating, antireflection film, method for manufacturing them, polarizing plate, and image display device
JP2007003672A (en) * 2005-06-22 2007-01-11 Toppan Printing Co Ltd Antireflection film
CN1794015A (en) * 2005-11-17 2006-06-28 复旦大学 Water-proof broad band high anti-reflection film and its preparation method
CN201359642Y (en) * 2008-09-16 2009-12-09 镇江万新光学眼镜有限公司 Resin lens plated with metal conducting layer on surface

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104316983A (en) * 2014-11-04 2015-01-28 苏州精创光学仪器有限公司 Waterproof compound antireflection film
TWI700179B (en) * 2017-06-05 2020-08-01 香港商富智康(香港)有限公司 Housing and method for making same
CN109664583A (en) * 2018-11-29 2019-04-23 信利光电股份有限公司 A kind of vehicle window film of insulating water-proof

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Application publication date: 20140312