CN103627504A - Special punching shear liquid for AP NK-W environment-friendly air conditioner aluminum foil and preparation method thereof - Google Patents
Special punching shear liquid for AP NK-W environment-friendly air conditioner aluminum foil and preparation method thereof Download PDFInfo
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- CN103627504A CN103627504A CN201310543629.6A CN201310543629A CN103627504A CN 103627504 A CN103627504 A CN 103627504A CN 201310543629 A CN201310543629 A CN 201310543629A CN 103627504 A CN103627504 A CN 103627504A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title abstract description 7
- 229910052782 aluminium Inorganic materials 0.000 title abstract description 7
- 239000011888 foil Substances 0.000 title abstract 2
- 239000000314 lubricant Substances 0.000 claims abstract description 41
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 34
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 18
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- -1 alcohol ethers Chemical class 0.000 claims description 40
- 239000005030 aluminium foil Substances 0.000 claims description 36
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 229910052799 carbon Inorganic materials 0.000 claims description 6
- 239000002351 wastewater Substances 0.000 claims description 6
- 238000006065 biodegradation reaction Methods 0.000 claims description 5
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 4
- 150000003333 secondary alcohols Chemical class 0.000 claims description 4
- CUVLMZNMSPJDON-UHFFFAOYSA-N 1-(1-butoxypropan-2-yloxy)propan-2-ol Chemical group CCCCOCC(C)OCC(C)O CUVLMZNMSPJDON-UHFFFAOYSA-N 0.000 claims description 3
- XYVAYAJYLWYJJN-UHFFFAOYSA-N 2-(2-propoxypropoxy)propan-1-ol Chemical compound CCCOC(C)COC(C)CO XYVAYAJYLWYJJN-UHFFFAOYSA-N 0.000 claims description 3
- 229920000742 Cotton Polymers 0.000 claims description 3
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- 239000000835 fiber Substances 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- 238000009736 wetting Methods 0.000 claims description 3
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 10
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 5
- 238000001816 cooling Methods 0.000 abstract description 4
- 238000003912 environmental pollution Methods 0.000 abstract description 4
- 230000000149 penetrating effect Effects 0.000 abstract description 4
- 230000015556 catabolic process Effects 0.000 abstract description 2
- 238000006731 degradation reaction Methods 0.000 abstract description 2
- 230000001050 lubricating effect Effects 0.000 abstract description 2
- 239000013556 antirust agent Substances 0.000 abstract 2
- 239000008139 complexing agent Substances 0.000 abstract 2
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 231100000956 nontoxicity Toxicity 0.000 abstract 1
- 238000010008 shearing Methods 0.000 abstract 1
- 239000003570 air Substances 0.000 description 22
- 239000010730 cutting oil Substances 0.000 description 13
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 10
- 239000010949 copper Substances 0.000 description 10
- 229910052802 copper Inorganic materials 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
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- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 2
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 2
- 238000005476 soldering Methods 0.000 description 2
- RPAJSBKBKSSMLJ-DFWYDOINSA-N (2s)-2-aminopentanedioic acid;hydrochloride Chemical compound Cl.OC(=O)[C@@H](N)CCC(O)=O RPAJSBKBKSSMLJ-DFWYDOINSA-N 0.000 description 1
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Abstract
The invention relates to a special punching shear liquid for an AP NK-W environment-friendly air conditioner aluminum foil and a preparation method thereof, wherein the punching shear liquid comprises the following components in parts by weight: 83.5-90.5 parts of electrolytic anion water, 8-12 parts of low molecular alcohol ether lubricant A, 1-4 parts of low molecular alcohol ether lubricant B and 0.3-0.5 part of efficient water-based antirust agent; when in preparation, tap water is subjected to three-stage filtration and then is subjected to electrification electrolysis through an electrode to obtain the electrolytic anion water in parts by weight, and meanwhile, the low molecular alcohol ether lubricant A and the low molecular alcohol ether lubricant B in parts by weight are compounded into a complexing agent; finally, the electrolytic anion water and the complexing agent are blended with the high-efficiency aqueous antirust agent in parts by weight. Thus, the punching and shearing liquid has unique polarity and non-polarity, high penetrating capacity, good cooling and lubricating effect, no toxicity, no harm, extremely low smell, easy degradation and decomposition by microbes, no environmental pollution, environment friendship and low cost.
Description
[technical field]
The invention belongs to the working fluid technical field that air conditioner aluminium foil sheet punching machining is used, relate in particular to special-purpose punching liquid of a kind of AP NK-W environment protection type air conditioner aluminium foil and preparation method thereof.
[background technology]
At present, air-conditioning is mainly comprised of compressor, condenser, vaporizer and expansion valve four major parts, in starting of air conditioner, air compressor is compressed into refrigerant the gas of High Temperature High Pressure, cold media gas is derived heat when flowing through condenser under the effect of copper pipe high-performance heat absorption, copper pipe imports heat on the large-area aluminium foil of multi-disc again through aluminium foil, under the high efficiency and heat radiation effect of aluminium foil, heat is dispersed in atmosphere by external host fan, High Temperature High Pressure cold media gas is because the decline of temperature has become highly pressurised liquid, refrigerant liquid has become highly pressurised liquid into cryogenic high pressure liquid by expansion valve, again the copper pipe by vaporizer carry out high efficiency heat absorption and aluminium foil carry out high efficiency and heat radiation absorb air in heat make ambient air temperature step-down, and by gas blower, freezing air is produced by boasting and reached air conditioner refrigeration effect, at this moment refrigerant is owing to absorbing airborne heat, temperature uprises and becomes gas, then through compressor, carry out same circulation again and reach the object that continues refrigeration.Aluminium foil in above process (aluminum heat scattering sheet that air-conditioning condenser and vaporizer use) plays vital effect.
Traditional aluminium foil stamping and cutting oil is mainly to add the agent of part oil soluble lubricating to reconcile into by low viscosity mineral type solvent oil, and the technical process that adopts traditional aluminium foil stamping and cutting oil that aluminium foil is processed as to air-conditioning heat dissipation aluminium fin is:
1, blanking is that 0.1mm~0.2mm aluminium strip volume (being produced through hot rolling, cold rolling, finishing by aluminium ingot) is enclosed within on rotation axis by thickness.
2, oil, by oil groove, make aluminium foil surface stay a certain amount of stamping and cutting oil aluminium foil.
3, patrix, goes out hole (copper pipe through hole) by punch die by aluminium foil by the aluminium foil with stamping and cutting oil.
4, fin assembling, then wears copper pipe by the pressing of multi-disc aluminium foil.
5, tube, rises by copper pipe slightly make between copper pipe and aluminium foil in conjunction with tightr.
6, solvent cleaning, falls stamping and cutting oil by solvent cleaning.
7, copper pipe soldering, the gap between aluminium foil and copper pipe is fastening with soldering tech welding.
8, tightness test, assembling and the scatterer input of weld is water-soluble, in copper pipe, inflate, to detect, whether there is rack of fusion and cause leaking gas and get blister.
9, baking, take the speed of 1.2m/min by the aluminium foil of going out and enters temperature as 120 ℃, and the baking box of long 15m toasts, and aluminium foil is dried.
10, finished product packing.
But, adopt traditional stamping and cutting oil processing air-conditioning heat dissipation aluminium fin to have following defect:
(1) alcohol ether adopting is primary alconol, and in body metabolism, because the higher meeting of its activity becomes the virose aldehyde material of tool, infringement human organs is liver particularly, and human body skin is had to larger stimulation, and human body is damaged.
(2) rust-preventive agent major part adopts the Sodium Nitrite of not environmental protection, also has part to adopt and is difficult for biodegradable binary and tribasic carboxylic acid class rust-preventive agent, and environmental pollution is serious, is unfavorable for environmental protection, and post-processed expense is large.
(3) cost is higher.
[summary of the invention]
The above-mentioned technical problem of the present invention for solving; a kind of unique polarity and nonpolar that has is provided; penetrating power is high; Cooling and Lubricator is effective, nontoxic, and smell is extremely low; very easily be degraded by microorganisms, decompose; do not pollute the environment, very environmental protection, special-purpose punching liquid of air conditioner aluminium foil that cost is low and preparation method thereof.
For solving the problems of the technologies described above, the present invention adopts following technical scheme:
The special-purpose punching liquid of AP NK-W environment protection type air conditioner aluminium foil, its composition and parts by weight are:
Electrolysis anion water 83.5~90.5,
Low mass molecule alcohol ethers lubricant A 8~12,
Low mass molecule alcohol ethers lubricant B 1~4,
High efficiency water rust-preventive agent 0.3~0.5.
Further, described low mass molecule alcohol ethers lubricant A and low mass molecule alcohol ethers lubricant B are biodegradation type secondary alcohol, on the carbon atom of its connection hydroxyl, also connect a methyl.
Further, described high efficiency water rust-preventive agent is high efficiency composition rust-preventive agent.
Further, described low mass molecule alcohol ethers lubricant A is dipropylene glycol propyl ether, and described low mass molecule alcohol ethers lubricant B is dipropylene glycol butyl ether, and described high efficiency water rust-preventive agent is the compound amine borate of high temperature.
A preparation method for the special-purpose punching liquid of AP NK-W environment protection type air conditioner aluminium foil, comprises the following steps:
By obtaining high purity after tap water successively, fibre active carbon cotton through PPF and accurate gac three-stage filtration, purify waste water, and by the electrolysis of switching on of purifying waste water of electrode pair high purity, obtain the electrolysis anion water of above-mentioned parts by weight;
By the low mass molecule alcohol ethers lubricant A of above-mentioned parts by weight and low mass molecule alcohol ethers lubricant B, be combined into a kind of recombiner with outstanding wetting, film forming and lubricity;
Recombiner by the aforementioned electrolysis anion water obtaining, low mass molecule alcohol ethers lubricant A and low mass molecule alcohol ethers lubricant B, reconciles into punching liquid with the high efficiency water rust-preventive agent of above-mentioned parts by weight.
Further, described electrode is titanium alloy electrode.
The invention has the beneficial effects as follows:
The punching liquid making by above-mentioned composition and parts by weight and preparation method, has unique polarity and nonpolar, and penetrating power is high, can effectively on aluminium foil, form oil film, and then improves its Cooling and Lubricator effect; And nontoxic, smell is also extremely low, is also very easily degraded by microorganisms, decomposes, can environmental pollution, very environmental protection, cost is low.
[embodiment]
In order to make object of the present invention, technical scheme and advantage clearer, below in conjunction with subordinate list and embodiment, the present invention is further elaborated.Should be appreciated that specific embodiment described herein, only in order to explain the present invention, is not intended to limit the present invention.
The special-purpose punching liquid of a kind of AP NK-W environment protection type air conditioner aluminium foil of the present invention, its composition and parts by weight are:
Electrolysis anion water 83.5~90.5,
Low mass molecule alcohol ethers lubricant A 8~12,
Low mass molecule alcohol ethers lubricant B 1~4,
High efficiency water rust-preventive agent 0.3~0.5.
Described low mass molecule alcohol ethers lubricant A and low mass molecule alcohol ethers lubricant B are biodegradation type secondary alcohol, on the carbon atom of its connection hydroxyl, also connect a methyl, as: low mass molecule alcohol ethers lubricant A is dipropylene glycol propyl ether, and low mass molecule alcohol ethers lubricant B is dipropylene glycol butyl ether; Described high efficiency water rust-preventive agent is high efficiency composition rust-preventive agent, if high efficiency water rust-preventive agent is the compound amine borate of high temperature.
The preparation method of the special-purpose punching liquid of AP NK-W environment protection type air conditioner aluminium foil of the present invention, comprises the following steps:
Tap water is obtained to high purity successively after PPF cotton, fibre active carbon and accurate gac three-stage filtration purifies waste water, and by electrode (as titanium alloy electrode) to the high purity electrolysis of switching on of purifying waste water, make Na in high-purity water+, Ca 2+, Mg2+, the positively charged ion such as K+, H+ shift to cathode electrode under the effect of electric power, cause the water of cathode electrode periphery for being rich in alkaline water hydroxy, Cl in while high-purity water-,
,
,
, OH-wait negatively charged ion to move down anode electrode in electric power effect, cause the water of anode electrode periphery for being rich in hydrionic sour water; Finally obtain the electrolysis anion water of above-mentioned parts by weight;
By the low mass molecule alcohol ethers lubricant A of above-mentioned parts by weight and low mass molecule alcohol ethers lubricant B, be combined into a kind of recombiner with outstanding wetting, film forming and lubricity;
Recombiner by the aforementioned electrolysis anion water obtaining, low mass molecule alcohol ethers lubricant A and low mass molecule alcohol ethers lubricant B, reconciles into punching liquid with the high efficiency water rust-preventive agent of above-mentioned parts by weight.
The more traditional stamping and cutting oil of the special-purpose punching liquid phase of AP NK-W environment protection type air conditioner aluminium foil of the present invention has following some advantage:
(1) root that traditional stamping and cutting oil Shi Yongyou enterprise pollutes ecotope, is having a strong impact on the enforcement of green manufacturing, recycling economy and the strategy of sustainable development.In addition recent global environment worse becoming, world environments pressure is increasing, so just impels departments of government to require corporate environment just more and more stricter.Its main drawback of tradition aluminium foil stamping and cutting oil is easy volatilization, add that roasting procedure can take more stamping and cutting oil in air to, and be trapped in air, in addition the slip additive of traditional stamping and cutting oil readily biodegradable not, can remain in for a long time in air like this, environment is produced to larger pressure.Present form Xia, enterprise, in order to reach the environmental requirement of departments of government, must spend substantial contribution to be dropped in environmental treatment, and also will take a large amount of environmental monitoring expenses every year, has increased greatly the cost of enterprise, subdues the profit of enterprise.And I take charge of the AP NK-W of research and development and take high purity brine electrolysis as basal liquid, add high-performance and can biodegradable alcohol ether series lubricant agent.Therefore AP NK-W can not produce disgusting smog in the process of baking, and I take charge of additive used is biodegradation type, even if it is residual to evaporate in air also just the short period of time, for some time can be degraded by microorganisms, rather than remain in for a long time in air, pure Green Product to environment definitely without pressure.
(2) in traditional stamping and cutting oil, main component is low carbon chain solvent-borne type base oil, and low carbon chain solvent oil has very strong solvability, in human skin contact, the sebum on skin can be dissolved.Sebum effect on human body skin mainly contains 3 points: 1. skin care, hair.If leave the moist of sebum and nourish, will there will be pachylosis and hair withered.Because the face in the wrong of palm, the sufficient sole of the foot and finger, toes does not have sebiferous gland, all skin cracking phenomenas that often occur; 2. sebum can form lipid film protection skin together with sweat, prevents moisture of skin evaporation; 3. sebum can suppress and kill the bacterium of skin surface.Hand particularly, if this type of low carbon chain solvent oil of Long contact time can go out big area fungi infestation and occur the allergic phenomenas such as erythema.The basal liquid that I take charge of the new A P NK-W of research and development is current publicized drinkable healthy electrolysis anion water, being weakly alkaline, board, mould are played to rust inhibition, is healthy drinkable water, harmless, be to belong to the novel environment friendly working fluid that does not damage HUMAN HEALTH completely.
(3) traditional stamping and cutting oil low carbon chain solvent oil used is mineral type, is to belong to petroleum products, in crude oil, extract, and belongs to Nonrenewable resources, is unfavorable for the strategy of sustainable development, and price is relatively expensive.And I to take charge of the new A P NK-W main component of research and development be brine electrolysis, belong to renewable resources, meet strategy of sustainable development requirement, its price only needs half of traditional punching simultaneously.So new A P NK-W had both met the requirement of National Sustainable Development Strategies, can be enterprise and reduce composition, can improve greatly the only choosing of the profit ,Wei air conditioner aluminium foil processing enterprise of enterprise.
In sum, the special-purpose punching liquid of AP NK-W environment protection type air conditioner aluminium foil that the present invention states, by adopting low mass molecule alcohol ethers lubricant A and low mass molecule alcohol ethers lubricant B effectively the surface tension of electrolysis anion water to be reduced, make punching liquid there is unique polarity and nonpolar; And the excellent penetrating power that can effectively improve this punching liquid that coordinates of low mass molecule alcohol ethers lubricant A and low mass molecule alcohol ethers lubricant B and electrolysis anion water can effectively form oil film, and then improve its Cooling and Lubricator effect on aluminium foil; Simultaneously, low mass molecule alcohol ethers lubricant A and low mass molecule alcohol ethers lubricant B are biodegradation type secondary alcohol, its activity is very low does not produce poisonous aldehyde material in body metabolism process, definitely nontoxic to human body, and can effectively be degraded by microorganism in air, the material of degradation production to environment fully pressure-free power, smell is also extremely low, extremely friendly; And high efficiency water rust-preventive agent adopts high efficiency composition rust-preventive agent, has both had highly effective antirust performance, and board is had to splendid rust-proof effect, simultaneously can environmental pollution yet, very environmental protection, cost is low.
Above content is in conjunction with concrete optimal technical scheme further description made for the present invention, can not assert that specific embodiment of the invention is confined to these explanations.For general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, can also make some simple deduction or replace, all should be considered as belonging to protection scope of the present invention.
Claims (6)
1. the special-purpose punching liquid of AP NK-W environment protection type air conditioner aluminium foil, is characterized in that, the composition of described punching liquid and parts by weight are:
Electrolysis anion water 83.5~90.5,
Low mass molecule alcohol ethers lubricant A 8~12,
Low mass molecule alcohol ethers lubricant B 1~4,
High efficiency water rust-preventive agent 0.3~0.5.
2. the special-purpose punching liquid of AP NK-W environment protection type air conditioner aluminium foil according to claim 1, it is characterized in that, described low mass molecule alcohol ethers lubricant A and low mass molecule alcohol ethers lubricant B are biodegradation type secondary alcohol, on the carbon atom of its connection hydroxyl, also connect a methyl.
3. the special-purpose punching liquid of AP NK-W environment protection type air conditioner aluminium foil according to claim 2, is characterized in that, described high efficiency water rust-preventive agent is high efficiency composition rust-preventive agent.
4. the special-purpose punching liquid of AP NK-W environment protection type air conditioner aluminium foil according to claim 3, it is characterized in that, described low mass molecule alcohol ethers lubricant A is dipropylene glycol propyl ether, and described low mass molecule alcohol ethers lubricant B is dipropylene glycol butyl ether, and described high efficiency water rust-preventive agent is the compound amine borate of high temperature.
5. a preparation method for the special-purpose punching liquid of AP NK-W environment protection type air conditioner aluminium foil, is characterized in that, comprises the following steps:
By obtaining high purity after tap water successively, fibre active carbon cotton through PPF and accurate gac three-stage filtration, purify waste water, and by the electrolysis of switching on of purifying waste water of electrode pair high purity, obtain the electrolysis anion water of above-mentioned parts by weight;
By the low mass molecule alcohol ethers lubricant A of above-mentioned parts by weight and low mass molecule alcohol ethers lubricant B, be combined into a kind of recombiner with outstanding wetting, film forming and lubricity;
Recombiner by the aforementioned electrolysis anion water obtaining, low mass molecule alcohol ethers lubricant A and low mass molecule alcohol ethers lubricant B, reconciles into punching liquid with the high efficiency water rust-preventive agent of above-mentioned parts by weight.
6. preparation method according to claim 5, is characterized in that, described electrode is titanium alloy electrode.
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Cited By (2)
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CN104046486A (en) * | 2014-05-05 | 2014-09-17 | 广东欧派斯润滑科技有限公司 | Environment-friendly type air-conditioning copper pipe special-purpose processing liquid |
CN108315092A (en) * | 2018-01-09 | 2018-07-24 | 珠海美合科技股份有限公司 | A kind of aqueous environment protection fin molding coolant liquid and preparation method thereof |
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CN1121106A (en) * | 1995-07-26 | 1996-04-24 | 高翔 | Lubricating oil for punching aluminium foil of heat exchanger |
CN101255377A (en) * | 2008-04-22 | 2008-09-03 | 大连三达奥克化学股份有限公司 | Ultra-thin aluminum foil plate water-based punching drawing oil and production method |
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